KR960037726A - 자가촉매성 가교제를 갖는 실리콘 유화액으로부터 제조된 탄성중합체 - Google Patents
자가촉매성 가교제를 갖는 실리콘 유화액으로부터 제조된 탄성중합체 Download PDFInfo
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- KR960037726A KR960037726A KR1019960013107A KR19960013107A KR960037726A KR 960037726 A KR960037726 A KR 960037726A KR 1019960013107 A KR1019960013107 A KR 1019960013107A KR 19960013107 A KR19960013107 A KR 19960013107A KR 960037726 A KR960037726 A KR 960037726A
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- refractive index
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- 239000003431 cross linking reagent Substances 0.000 title claims abstract 3
- 229920001296 polysiloxane Polymers 0.000 title claims abstract 3
- 229920001971 elastomer Polymers 0.000 title 1
- 239000000806 elastomer Substances 0.000 title 1
- 239000000839 emulsion Substances 0.000 title 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract 4
- 239000004094 surface-active agent Substances 0.000 claims abstract 4
- 239000006185 dispersion Substances 0.000 claims abstract 3
- 229920000642 polymer Polymers 0.000 claims abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract 3
- -1 polysiloxane Polymers 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims 4
- 239000012071 phase Substances 0.000 claims 3
- 239000008346 aqueous phase Substances 0.000 claims 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims 1
- 238000007865 diluting Methods 0.000 claims 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000002787 reinforcement Effects 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 claims 1
- 229920002959 polymer blend Polymers 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/14—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/045—Polysiloxanes containing less than 25 silicon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/26—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
Claims (5)
- 점도가 5000 내지 500,000mPa·s인 실록산 중합체 또는 중합체 혼합물, 계면 활성제, 물 및 하나 이상의 자가촉매성 가교제를 포함하는 성분들을 혼합시키는 단계 ; 상기 성분들을 상기 성분들이 겔상으로 전환되기에 충분히 높은 전단 조건하에서 혼합시키는 단계 ; 및 임의로 겔상을 물로 희석시키는 단계를 포함하는, 가교결합 폴리실록산 분산액을 제조하는 방법.
- 제1항에 있어서, 혼합 단계 전후에 일반식(여기서 Me는 메틸 그룹이고 z는 3 내지 40의 정수임)의 안정화제를 첨가하는 단계를 추가로 포함하는 방법.
- 제1항에 있어서, 혼합 단계 이전에 메틸트리메톡시실란, 비닐트리메톡시실란, 테트라에틸오르토실리케이트 및 선형 프로필오르토실리케이트로 이루어진 그룹으로부터 선택된 동일반응계 수지 보강제를 첨가시키는 단계를 추가로 포함하는 방법.
- 제1항에 있어서, 상기 분산액이 굴절률을 갖는 가교결합 실록산 상 및 굴절률을 갖는 계면활성제/잔여 수상을 갖고 가교결합 실록산상의 굴절률이 계면활성제/잔여 수상의 굴절률과 일치하는 방법.
- 제1항 내지 제4항 중 어느 한 방법에 의해 수득할 수 있는 가교결합 폴리실록산 분산액.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/430,047 | 1995-04-27 | ||
| US08/430047 | 1995-04-27 | ||
| US08/430,047 US5674937A (en) | 1995-04-27 | 1995-04-27 | Elastomers from silicone emulsions having self-catalytic crosslinkers |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR960037726A true KR960037726A (ko) | 1996-11-19 |
| KR100355499B1 KR100355499B1 (ko) | 2003-02-11 |
Family
ID=23705853
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960013107A Expired - Lifetime KR100355499B1 (ko) | 1995-04-27 | 1996-04-26 | 자가촉매성가교제를갖는실리콘유화액으로부터제조된탄성중합체 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5674937A (ko) |
| EP (1) | EP0739947B1 (ko) |
| JP (1) | JP3602253B2 (ko) |
| KR (1) | KR100355499B1 (ko) |
| CN (1) | CN1134948A (ko) |
| AU (1) | AU702290B2 (ko) |
| CA (1) | CA2174700A1 (ko) |
| DE (1) | DE69623846T2 (ko) |
| TW (1) | TW387003B (ko) |
Families Citing this family (46)
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|---|---|---|---|---|
| US5895794A (en) * | 1993-08-30 | 1999-04-20 | Dow Corning Corporation | Shelf stable cross-linked emulsions with optimum consistency and handling without the use of thickeners |
| US5807921A (en) * | 1995-12-21 | 1998-09-15 | Dow Corning Corporation | Silicone elastomers from aqueous silicone emulsions having improved adhesion to substrates |
| US5777026A (en) | 1995-12-28 | 1998-07-07 | Dow Corning Corporation | Surface modified silicone elastomers from aqueous silicone emulsions |
| US5861451A (en) * | 1996-10-31 | 1999-01-19 | Dow Corning Corporation | Sprayable silicone emulsions which form elastomers having smoke and fire resistant properties |
| US5939478A (en) * | 1997-07-21 | 1999-08-17 | Dow Corning Corporation | Silicone polyether stabilized silicone latex solvent thickening |
| US6197878B1 (en) | 1997-08-28 | 2001-03-06 | Eastman Chemical Company | Diol latex compositions and modified condensation polymers |
| EP0915122B1 (en) * | 1997-10-09 | 2002-11-13 | Dow Corning Corporation | Prosess for preparing silicone latexes |
| DE19803468A1 (de) | 1998-01-29 | 1999-08-05 | Wacker Chemie Gmbh | Durch Michael-Addition-ähnliche Reaktionen vernetzte Aminosiliconölemulsionen |
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| US6239378B1 (en) | 1999-02-02 | 2001-05-29 | Dow Corning Corporation | Flame resistant silicone rubber wire and cable coating composition |
| WO2000052083A1 (en) | 1999-03-03 | 2000-09-08 | Eastman Chemical Company | Silicone polymer diol compositions and condensation polymer/silicone polymer blends |
| WO2000052097A1 (en) | 1999-03-03 | 2000-09-08 | Eastman Chemical Company | Polyamide/emulsion polymer blends |
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| KR20210110337A (ko) | 2018-12-31 | 2021-09-07 | 다우 실리콘즈 코포레이션 | 아크릴옥시-작용성 유기실리콘 화합물의 제조 방법 |
| JP2022516511A (ja) | 2018-12-31 | 2022-02-28 | ダウ シリコーンズ コーポレーション | 分岐状有機ケイ素化合物、その調製方法、及びそれにより形成されるコポリマー |
| KR102861862B1 (ko) | 2018-12-31 | 2025-09-22 | 다우 도레이 캄파니 리미티드 | 조성물, 공중합체의 제조 방법, 및 이의 방법 및 최종 용도 |
| JP7579258B2 (ja) * | 2018-12-31 | 2024-11-07 | ダウ シリコーンズ コーポレーション | 分岐状有機ケイ素化合物、その調製方法、及び関連組成物 |
| CN113348199B (zh) | 2018-12-31 | 2023-02-17 | 美国陶氏有机硅公司 | 支链有机硅化合物、制备支链有机硅化合物的方法以及用其形成的共聚物 |
| JP2022515662A (ja) | 2018-12-31 | 2022-02-21 | ダウ シリコーンズ コーポレーション | アクリレート官能性分枝状有機ケイ素化合物、それを調製する方法、及びそれによって形成されたコポリマー |
| JP7512289B2 (ja) | 2018-12-31 | 2024-07-08 | ダウ シリコーンズ コーポレーション | 分岐状有機ケイ素化合物、その調製方法、及びそれを含む組成物 |
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| MX169040B (es) * | 1988-07-07 | 1993-06-17 | Rohm & Haas | Copolimeros estables de emulsion acuosa con funcionalidad de siloxano |
| FR2642765B1 (fr) * | 1989-02-03 | 1991-04-26 | Rhone Poulenc Chimie | Dispersion aqueuse de silicone a base d'aminosilane et/ou d'amidosilane reticulant en un elastomere par elimination de l'eau |
| FR2647798B1 (fr) * | 1989-05-31 | 1991-09-13 | Rhone Poulenc Chimie | Dispersion aqueuse a base d'huiles silicones fonctionnalisees pouvant reticuler en un elastomere par elimination de l'eau |
| US5000861A (en) * | 1989-08-23 | 1991-03-19 | Union Carbide Chemicals And Plastics Co. Inc. | Stable emulsions containing amino polysiloxanes and silanes for treating fibers and fabrics |
| US5145907A (en) * | 1989-09-25 | 1992-09-08 | Dow Corning Corporation | Precured silicone emulsion |
| DE3932025A1 (de) * | 1989-09-26 | 1991-04-04 | Wacker Chemie Gmbh | Waessrige dispersionen von organopolysiloxanen |
| FR2659342B1 (fr) * | 1990-03-08 | 1994-03-18 | Rhone Poulenc Chimie | Dispersion aqueuse a base d'huiles silicones reticulant, par elimination de l'eau en un elastomere resistant a la flamme. |
| JPH0633335B2 (ja) * | 1990-05-29 | 1994-05-02 | 信越化学工業株式会社 | オルガノポリシロキサンの製造方法 |
| CA2043282A1 (en) * | 1990-06-07 | 1991-12-08 | Ronald P. Gee | Process for making polysiloxane emulsions |
| US5175057A (en) * | 1991-06-25 | 1992-12-29 | General Electric Company | Adhesion promoters for room temperature vulcanizable silicone compositions |
| DE4124588A1 (de) * | 1991-07-24 | 1993-01-28 | Wacker Chemie Gmbh | Besonders feinteilige kieselsaeuremikrodispersionen sowie verfahren zu ihrer herstellung |
| JPH0551459A (ja) * | 1991-08-22 | 1993-03-02 | Toray Dow Corning Silicone Co Ltd | 有機ケイ素重合体の製造方法 |
| DE4132697A1 (de) * | 1991-10-01 | 1993-04-08 | Wacker Chemie Gmbh | Verfahren zur herstellung von organopolysiloxanharz |
| JP2904317B2 (ja) * | 1991-10-11 | 1999-06-14 | 信越化学工業株式会社 | オルガノポリシロキサン樹脂の製造方法 |
| JP3251658B2 (ja) * | 1992-08-26 | 2002-01-28 | 東レ・ダウコーニング・シリコーン株式会社 | シリコーン水性エマルジョン組成物 |
| FR2697025B1 (fr) * | 1992-10-20 | 1995-02-03 | Rhone Poulenc Chimie | Procédé de préparation d'émulsions aqueuses d'huiles et/ou de gommes et/ou de résines silicones. |
| FR2697021B1 (fr) * | 1992-10-20 | 1994-12-02 | Rhone Poulenc Chimie | Dispersions aqueuses à base d'huiles silicones visqueuses pouvant réticuler par élimination de l'eau et leur utilisation à la réalisation de joints élastomères silicones. |
| US5449712A (en) * | 1993-01-13 | 1995-09-12 | Thoro System Products, Inc. | Organosilicon emulsions for rendering porous substrates water repellent |
| JP3556259B2 (ja) * | 1993-12-24 | 2004-08-18 | 東レ・ダウコーニング・シリコーン株式会社 | オルガノポリシロキサンエマルジョンおよび該エマルジョンにより処理してなる繊維 |
| US5424354A (en) * | 1993-12-28 | 1995-06-13 | Three Bond Co., Ltd. | Room temperature curable polyoganosiloxane composition |
| JPH09323455A (ja) * | 1996-06-05 | 1997-12-16 | Seiko Epson Corp | サーマルプリンタ |
-
1995
- 1995-04-27 US US08/430,047 patent/US5674937A/en not_active Expired - Lifetime
-
1996
- 1996-04-17 DE DE69623846T patent/DE69623846T2/de not_active Expired - Lifetime
- 1996-04-17 EP EP96302659A patent/EP0739947B1/en not_active Expired - Lifetime
- 1996-04-20 TW TW085104738A patent/TW387003B/zh not_active IP Right Cessation
- 1996-04-22 CA CA002174700A patent/CA2174700A1/en not_active Abandoned
- 1996-04-24 AU AU50835/96A patent/AU702290B2/en not_active Ceased
- 1996-04-26 KR KR1019960013107A patent/KR100355499B1/ko not_active Expired - Lifetime
- 1996-04-26 JP JP10722496A patent/JP3602253B2/ja not_active Expired - Lifetime
- 1996-04-26 CN CN96100258A patent/CN1134948A/zh active Pending
-
1997
- 1997-09-30 US US08/940,751 patent/US5994459A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US5994459A (en) | 1999-11-30 |
| EP0739947A2 (en) | 1996-10-30 |
| CA2174700A1 (en) | 1996-10-28 |
| CN1134948A (zh) | 1996-11-06 |
| TW387003B (en) | 2000-04-11 |
| EP0739947A3 (en) | 1997-10-01 |
| EP0739947B1 (en) | 2002-09-25 |
| US5674937A (en) | 1997-10-07 |
| DE69623846D1 (de) | 2002-10-31 |
| DE69623846T2 (de) | 2003-08-07 |
| JPH08302023A (ja) | 1996-11-19 |
| KR100355499B1 (ko) | 2003-02-11 |
| AU702290B2 (en) | 1999-02-18 |
| JP3602253B2 (ja) | 2004-12-15 |
| AU5083596A (en) | 1996-11-07 |
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