KR960037640A - 아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법 - Google Patents

아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법 Download PDF

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KR960037640A
KR960037640A KR1019950009689A KR19950009689A KR960037640A KR 960037640 A KR960037640 A KR 960037640A KR 1019950009689 A KR1019950009689 A KR 1019950009689A KR 19950009689 A KR19950009689 A KR 19950009689A KR 960037640 A KR960037640 A KR 960037640A
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amination reaction
nickel
reaction catalyst
reduction amination
aminoethylethanolamine
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KR1019950009689A
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KR100216935B1 (ko
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웨인 킹 스티븐
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카렌 엘. 존슨
유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀로지 코포레이션
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Priority to EP95302456A priority Critical patent/EP0737669B1/en
Priority to DE69512381T priority patent/DE69512381T2/de
Priority to CA002146903A priority patent/CA2146903C/en
Priority to MX9501842A priority patent/MX9501842A/es
Application filed by 카렌 엘. 존슨, 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀로지 코포레이션 filed Critical 카렌 엘. 존슨
Priority to KR1019950009689A priority patent/KR100216935B1/ko
Priority to JP7125620A priority patent/JP2876464B2/ja
Priority to US08/461,549 priority patent/US5600000A/en
Priority to US08/465,186 priority patent/US5891820A/en
Publication of KR960037640A publication Critical patent/KR960037640A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/02—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C215/04—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated
    • C07C215/06—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic
    • C07C215/14—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic the nitrogen atom of the amino group being further bound to hydrocarbon groups substituted by amino groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C07C209/26—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
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  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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Abstract

본 발명은 모노에탄올아민과 암모니아를 수소와 다양한 환원 아민화 반응 촉매의 존재하에서 반응시켜 아미노에틸에탄올 아민과 같은 아사이클릭 생성물에 대한 높은 선택도를 수득하고 피페라진과 같은 사이클릭 생성물의 생성을 감소시키는 개선된 환원 아민화 반응법에 관한 것이다. 본 발명의 방법을 전이 알루미나 담체위에 니켈 또는 니켈-레늄과 같은 금속을 함유하는 환원 아민화 반응 촉매의 존재하에서 수행하는 경우, 목적하는 생산물에 대한 생산성과 선택도가 증가한다. 또한 본 방법은 촉진제의 사용에 의해 성능이 향상되는 하이드로탈사이트계 또는 타코바이트계 촉매의 존재하에서 수행하여 목적하는 결과를 달성할 수 있다.

Description

아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 암모니아, 수소 및 전이 알루미나 담체에 혼입시킨 하나 이상의 촉매 작용성 환원 아민화 금속을 포함하는 환원 아민화 반응 촉매(여기서, 니켈 대 레늄의 원자비는 약 1 : 1 내지 약 200 : 1이다)의 존재하에 모노에탄올아민(MEA)을 반응시켜, 피페라진에 대해 아미노에틸에탄올아민량이 증가된 생성 혼합물을 수득함을 포함하는 환원 아민화 반응법.
  2. 제1항에 있어서, 촉매 작용성 환원 아민화 금속이 니켈, 레늄, 코발트, 로듐, 이리듐, 루테늄, 팔라듐 및 백금으로 이루어진 그룹으로부터 선택되는 방법.
  3. 제1항에 있어서, 전이 알루미나 담체가 델타상, 쎄타상, 감마/쎄타상, 델타/쎄타상, 쎄타/알파상 및 이들의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
  4. 제1항에 있어서, 환원 아민화 반응 촉매가 주기율표의 ⅠA족, ⅡA족 및 ⅡB족으로부터 선택되는 원소를 함유하는 화합물로 이루어진 그룹으로부터 선택되는 촉진제를 추가로 포함하는 방법.
  5. 제4항에 있어서, 촉진제가 마그네슘, 아연 또는 이들의 혼합물인 방법.
  6. 암모니아, 수소 및, 일반식〔Mx 2+My 3+(OH)2x+2y〕〔Ay/n n-〕·zH2O의 물질〔여기서, Mx 2+는 마그네슘이고 ; My3+는 알루미늄이고 ; A는 n-가의 탄산염이고 ; n은 1 이상〔예를 들면, 1 내지 4, 주로 1 내지 3)이고 ; z는 양수이다〕과 추가로 니켈 촉진제를 포함하는 환원 아민화 반응 촉매의 존재하에서 MEA를 반응시켜, 피페라진에 대해 아미노에틸에탄올아민량이 증가된 생성 혼합물을 수득함을 포함하는 환원 아민화 반응법.
  7. 암모니아, 수소 및, 일반식〔Mx 2+My 3+(OH)2x+2y〕〔Ay/n n-〕·zH2O의 물질〔여기서, Mx 2+는 니켈이고 ; My 3+는 알루미늄이고 ; A는 n-가의 탄산염이고 ; n은 1 이상〔예를 들면, 1 내지 4, 주로 1 내지 3)이고 ; z는 양수이다〕을 포함하는 환원 아민화 반응 촉매의 존재하에서 MEA를 반응시켜, 피페라진에 대해 아미노에탄올 아민량이 증가된 생성 혼합물을 수득함을 포함하는 환원 아민화 반응법.
  8. 제7항에 있어서, 환원 아민화 반응 촉매가 레늄 금속을 추가로 포함하는 방법.
  9. 일반식〔Mx 2+My 3+(OH)2x+2y〕〔Ay/n n-〕·zH2O의 물질〔여기서, Mx 2+는 니켈이고 ; My 3+는 알루미늄이고 ; A는 n-가의 탄산염이고 ; n은 1 이상〔예를 들면, 1 내지 4, 주로 1 내지 3)이고 ; z는 양수이다〕과 추가로 레늄 금속을 포함하는, 아미노에틸에탄올아민(AEEA)의 선택적 제조용 환원 아민화 반응 촉매.
  10. 일반식〔Mx 2+My 3+(OH)2x+2y〕〔Ay/n n-〕·zH2O의 물질〔여기서, Mx 2+는 마그네슘이고 ; My 3+는 알루미늄이고 ; A는 n-가의 탄산염이고 ; n은 1 이상 (예를 들면, 1 내지 4, 주로 1 내지 3)이고 ; z는 양수이다〕과 추가로 니켈 또는 니켈/레늄 촉진제를 포함하는, AEEA의 선택적 제조용 환원 아민화 반응 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019950009689A 1993-12-22 1995-04-25 아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법 KR100216935B1 (ko)

Priority Applications (8)

Application Number Priority Date Filing Date Title
EP95302456A EP0737669B1 (en) 1993-12-22 1995-04-12 Reductive amination processes for the selective production of aminoethylethanolamine
DE69512381T DE69512381T2 (de) 1993-12-22 1995-04-12 Reduktive Aminierung zur selektiven Herstellung von Aminoethylethanolamin
CA002146903A CA2146903C (en) 1993-12-22 1995-04-12 Reductive amination catalysts for the selective production of aminoethylethanolamine
MX9501842A MX9501842A (es) 1993-12-22 1995-04-19 Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina.
KR1019950009689A KR100216935B1 (ko) 1993-12-22 1995-04-25 아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법
JP7125620A JP2876464B2 (ja) 1993-12-22 1995-04-27 アミノエチルエタノールアミンを選択的に製造するための還元アミノ化方法
US08/461,549 US5600000A (en) 1993-12-22 1995-06-05 Reductive amination processes for the selective production of amino-ethylethanolamine
US08/465,186 US5891820A (en) 1993-12-22 1995-06-05 Reductive amination processes for the selective production of amino-ethyylethanolamine

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US17153993A 1993-12-22 1993-12-22
EP95302456A EP0737669B1 (en) 1993-12-22 1995-04-12 Reductive amination processes for the selective production of aminoethylethanolamine
CA002146903A CA2146903C (en) 1993-12-22 1995-04-12 Reductive amination catalysts for the selective production of aminoethylethanolamine
MX9501842A MX9501842A (es) 1993-12-22 1995-04-19 Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina.
KR1019950009689A KR100216935B1 (ko) 1993-12-22 1995-04-25 아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법
JP7125620A JP2876464B2 (ja) 1993-12-22 1995-04-27 アミノエチルエタノールアミンを選択的に製造するための還元アミノ化方法
US08/465,186 US5891820A (en) 1993-12-22 1995-06-05 Reductive amination processes for the selective production of amino-ethyylethanolamine

Publications (2)

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KR960037640A true KR960037640A (ko) 1996-11-19
KR100216935B1 KR100216935B1 (ko) 1999-10-01

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US (1) US5891820A (ko)
EP (1) EP0737669B1 (ko)
JP (1) JP2876464B2 (ko)
KR (1) KR100216935B1 (ko)
CA (1) CA2146903C (ko)
DE (1) DE69512381T2 (ko)
MX (1) MX9501842A (ko)

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KR100216935B1 (ko) 1999-10-01
EP0737669B1 (en) 1999-09-22
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MX9501842A (es) 1997-04-30
CA2146903A1 (en) 1996-10-13
JPH08319261A (ja) 1996-12-03
US5891820A (en) 1999-04-06
EP0737669A1 (en) 1996-10-16
DE69512381D1 (de) 1999-10-28
CA2146903C (en) 2000-01-25
DE69512381T2 (de) 2000-04-06

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