KR960037115A - 개선된 환원성 아민화 촉매 - Google Patents

개선된 환원성 아민화 촉매 Download PDF

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Publication number
KR960037115A
KR960037115A KR1019950009292A KR19950009292A KR960037115A KR 960037115 A KR960037115 A KR 960037115A KR 1019950009292 A KR1019950009292 A KR 1019950009292A KR 19950009292 A KR19950009292 A KR 19950009292A KR 960037115 A KR960037115 A KR 960037115A
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catalyst
nickel
rhenium
theta
weight
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KR1019950009292A
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KR100282106B1 (ko
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웨인 킹 스티븐
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카렌 엘. 존슨
유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션
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Priority to EP95302455A priority Critical patent/EP0737514B1/en
Priority to CA002146906A priority patent/CA2146906C/en
Priority to DE69521289T priority patent/DE69521289T2/de
Application filed by 카렌 엘. 존슨, 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 filed Critical 카렌 엘. 존슨
Priority to KR1019950009292A priority patent/KR100282106B1/ko
Priority to JP12561595A priority patent/JP3223440B2/ja
Priority to US08/567,832 priority patent/US5750790A/en
Publication of KR960037115A publication Critical patent/KR960037115A/ko
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Publication of KR100282106B1 publication Critical patent/KR100282106B1/ko

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 환식 성분의 수준이 보다 낮은 알킬렌아민 조성물을 제조하는데 유용한 개선된 환원성 아민화촉매에 관한 것이다. 전형적인 환원성 아민화 촉매가 알루미나, 실리카, 실리카-알루미나 및 실리카-티타니아와 같은 캐리어상에 니켈 또는 니켈-레늄을 함유할지라도, 전이 알루미나로부터 선택된 캐리어를 사용함으로써, 비환식 생성물에 대한 선택성과 촉매의 활성 들 다가 개선되는 것으로 밝혀졌다.

Description

개선된 환원성 아민화 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 델타, 테타, 감마/테타, 델타/테타, 테타/알파 알루미나 상 및 이들의 혼합물로 이루어진 그룹 중에서 선택된 전이 알루미나 캐리어를 혼입시킨, 촉매적으로 유효한 하나 이상의 환원성 아민화 금속을 포함하는 고형 환원성 아민화 촉매.
  2. 제1항에 있어서, 촉매적으로 유효한 환원성 아민화 금속(들)이 니켈, 레늄, 코발트, 로듐, 이리듐, 루테늄, 아연, 팔라듐 및 백금으로 이루어진 그룹 중에서 선택되는 촉매.
  3. 제2항에 있어서, 촉매적으로 유효한 환원성 아민화 금속이, 레늄에 대한 니켈의 원자비가 약 1:1 내지 약 200:1인 니켈과 레늄인 촉매.
  4. 제3항에 있어서, 레늄에 대한 니켈의 원자비가 약 5:1 내지 100:1인 촉매.
  5. 제4항에 있어서, 레늄에 대한 니켈의 원자비가 약 10:1 내지 50:1인 촉매.
  6. 제1항에 있어서, 총 금속 함량이, 캐리어의 중량을 기준으로 하여, 약 1 내지 30중량%인 촉매.
  7. 제6항에 있어서, 총 금속 함량이, 캐리어의 중량을 기준으로 하여, 약 5 내지 15중량%인 촉매.
  8. 제1항에 있어서, 붕소를 추가로 포함하는 촉매.
  9. 레늄에 대한 니켈의 원자비가 약 10:1 내지 약 50:1이고 존재하는 니켈과 레늄의 총량이, 감마/테타전이 알루미나 캐리어의 중량을 기준으로 하여, 약 5 내지 15중량%임을 특징으로 하는, 감마/테타 전이 알루미나 캐리어를 혼입시킨, 니켈과 레늄 금속으로 포함하는 환원성 아민화 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950009292A 1993-12-22 1995-04-20 모노에탄올아민의 환원성 아민화방법 KR100282106B1 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP95302455A EP0737514B1 (en) 1993-12-22 1995-04-12 Reductive amination processes for the selective production of aminoethylethanolamine
CA002146906A CA2146906C (en) 1993-12-22 1995-04-12 Reductive amination catalysts
DE69521289T DE69521289T2 (de) 1993-12-22 1995-04-12 Reduktive Aminierung zur selektiven Herstellung von Aminoethylethanolamin
KR1019950009292A KR100282106B1 (ko) 1993-12-22 1995-04-20 모노에탄올아민의 환원성 아민화방법
JP12561595A JP3223440B2 (ja) 1993-12-22 1995-04-27 改良還元アミノ化触媒
US08/567,832 US5750790A (en) 1993-12-22 1995-12-06 Reductive amination catalysts

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US17182393A 1993-12-22 1993-12-22
EP95302455A EP0737514B1 (en) 1993-12-22 1995-04-12 Reductive amination processes for the selective production of aminoethylethanolamine
CA002146906A CA2146906C (en) 1993-12-22 1995-04-12 Reductive amination catalysts
KR1019950009292A KR100282106B1 (ko) 1993-12-22 1995-04-20 모노에탄올아민의 환원성 아민화방법
JP12561595A JP3223440B2 (ja) 1993-12-22 1995-04-27 改良還元アミノ化触媒
US08/567,832 US5750790A (en) 1993-12-22 1995-12-06 Reductive amination catalysts

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Publication Number Publication Date
KR960037115A true KR960037115A (ko) 1996-11-19
KR100282106B1 KR100282106B1 (ko) 2001-02-15

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US (1) US5750790A (ko)
EP (1) EP0737514B1 (ko)
JP (1) JP3223440B2 (ko)
KR (1) KR100282106B1 (ko)
CA (1) CA2146906C (ko)
DE (1) DE69521289T2 (ko)

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Also Published As

Publication number Publication date
EP0737514B1 (en) 2001-06-13
JP3223440B2 (ja) 2001-10-29
KR100282106B1 (ko) 2001-02-15
US5750790A (en) 1998-05-12
JPH08299798A (ja) 1996-11-19
CA2146906A1 (en) 1996-10-13
DE69521289D1 (de) 2001-07-19
CA2146906C (en) 1999-03-16
EP0737514A1 (en) 1996-10-16
DE69521289T2 (de) 2002-05-02

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