MX9501842A - Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina. - Google Patents

Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina.

Info

Publication number
MX9501842A
MX9501842A MX9501842A MX9501842A MX9501842A MX 9501842 A MX9501842 A MX 9501842A MX 9501842 A MX9501842 A MX 9501842A MX 9501842 A MX9501842 A MX 9501842A MX 9501842 A MX9501842 A MX 9501842A
Authority
MX
Mexico
Prior art keywords
reducing amination
aminoethylethanelamine
reducing
products
selectively producing
Prior art date
Application number
MX9501842A
Other languages
English (en)
Other versions
MX197579B (es
Inventor
Stephen Wayne King
Original Assignee
Union Carbide Chem Plastic
Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to DE69512381T priority Critical patent/DE69512381T2/de
Priority to CA002146903A priority patent/CA2146903C/en
Priority to EP95302456A priority patent/EP0737669B1/en
Application filed by Union Carbide Chem Plastic, Corp filed Critical Union Carbide Chem Plastic
Priority to MX9501842A priority patent/MX9501842A/es
Priority to KR1019950009689A priority patent/KR100216935B1/ko
Priority to JP7125620A priority patent/JP2876464B2/ja
Priority to US08/465,186 priority patent/US5891820A/en
Priority to US08/461,549 priority patent/US5600000A/en
Publication of MX9501842A publication Critical patent/MX9501842A/es
Publication of MX197579B publication Critical patent/MX197579B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/02—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C215/04—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated
    • C07C215/06—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic
    • C07C215/14—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic the nitrogen atom of the amino group being further bound to hydrocarbon groups substituted by amino groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8896—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/232—Carbonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C07C209/26—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds by reduction with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/02—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reactions involving the formation of amino groups from compounds containing hydroxy groups or etherified or esterified hydroxy groups
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invencion se relaciona con procesos de aminacion reductivos mejorados mediante los cuales la monoetanolamina y el amoniaco se hacen reaccionar en presencia de hidrogeno y varios catalizadores de aminacion reductivos para selectividad de alto rendimiento para los productos acíclicos tales como aminoetiletanolamina, mientras que reduce la produccion de productos cíclicos tales como piperazina. Cuando el proceso de la presente invencion se lleva a cabo en presencia de metales que contienen un catalizador de aminacion reductivo tal como níquel o níquel y renio en portadores de alumina de transicion, se aumenta la productividad y selectividad a los productos deseados. Alternativamente, el proceso se puede llevar a cabo en presencia de catalizadores semejantes a hidrotalcita o a tacovita que se han mejorado el uso de promotores para lograr los resultados deseados.
MX9501842A 1993-12-22 1995-04-19 Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina. MX9501842A (es)

Priority Applications (8)

Application Number Priority Date Filing Date Title
DE69512381T DE69512381T2 (de) 1993-12-22 1995-04-12 Reduktive Aminierung zur selektiven Herstellung von Aminoethylethanolamin
CA002146903A CA2146903C (en) 1993-12-22 1995-04-12 Reductive amination catalysts for the selective production of aminoethylethanolamine
EP95302456A EP0737669B1 (en) 1993-12-22 1995-04-12 Reductive amination processes for the selective production of aminoethylethanolamine
MX9501842A MX9501842A (es) 1993-12-22 1995-04-19 Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina.
KR1019950009689A KR100216935B1 (ko) 1993-12-22 1995-04-25 아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법
JP7125620A JP2876464B2 (ja) 1993-12-22 1995-04-27 アミノエチルエタノールアミンを選択的に製造するための還元アミノ化方法
US08/465,186 US5891820A (en) 1993-12-22 1995-06-05 Reductive amination processes for the selective production of amino-ethyylethanolamine
US08/461,549 US5600000A (en) 1993-12-22 1995-06-05 Reductive amination processes for the selective production of amino-ethylethanolamine

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US17153993A 1993-12-22 1993-12-22
CA002146903A CA2146903C (en) 1993-12-22 1995-04-12 Reductive amination catalysts for the selective production of aminoethylethanolamine
EP95302456A EP0737669B1 (en) 1993-12-22 1995-04-12 Reductive amination processes for the selective production of aminoethylethanolamine
MX9501842A MX9501842A (es) 1993-12-22 1995-04-19 Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina.
KR1019950009689A KR100216935B1 (ko) 1993-12-22 1995-04-25 아미노에틸에탄올아민을 선택적으로 제조하기 위한 환원 아민화 반응 촉매 및 이를 사용하는 환원 아민화 반응법
JP7125620A JP2876464B2 (ja) 1993-12-22 1995-04-27 アミノエチルエタノールアミンを選択的に製造するための還元アミノ化方法
US08/465,186 US5891820A (en) 1993-12-22 1995-06-05 Reductive amination processes for the selective production of amino-ethyylethanolamine

Publications (2)

Publication Number Publication Date
MX9501842A true MX9501842A (es) 1997-04-30
MX197579B MX197579B (es) 2000-07-18

Family

ID=32097192

Family Applications (1)

Application Number Title Priority Date Filing Date
MX9501842A MX9501842A (es) 1993-12-22 1995-04-19 Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina.

Country Status (7)

Country Link
US (1) US5891820A (es)
EP (1) EP0737669B1 (es)
JP (1) JP2876464B2 (es)
KR (1) KR100216935B1 (es)
CA (1) CA2146903C (es)
DE (1) DE69512381T2 (es)
MX (1) MX9501842A (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19706876A1 (de) * 1997-02-21 1998-08-27 Basf Ag Verfahren zur Herstellung von Carbonsäuren oder deren Estern durch Carbonylierung von Olefinen
SE513250C2 (sv) * 1997-11-11 2000-08-07 Akzo Nobel Nv Amineringsförfarande för framställning av polyaminer
US6534441B1 (en) * 1999-03-06 2003-03-18 Union Carbide Chemicals & Plastics Technology Corporation Nickel-rhenium catalyst for use in reductive amination processes
DE10028432A1 (de) * 2000-06-13 2001-12-20 Basell Polyolefine Gmbh Auf calciniertes Hydrotalcit geträgerter Katalysatorfeststoff zur Olefinpolymerisation
DE10349059A1 (de) * 2003-10-17 2005-05-19 Basf Ag Verfahren zur destillativen Auftrennung von Gemischen enthaltend Ethylenamine
JP4972315B2 (ja) * 2005-12-28 2012-07-11 花王株式会社 含窒素化合物の製造方法
KR20100111712A (ko) 2008-01-03 2010-10-15 아크조 노벨 엔.브이. 에틸렌 아민의 제조 방법
BRPI0914009A2 (pt) 2008-10-06 2015-07-28 Union Carbide Chem Plastic Método para reparar uma triamina cíclica
WO2010042168A2 (en) 2008-10-06 2010-04-15 Dow Global Technologies Inc. Methods for making ethanolamine(s) and ethyleneamine(s) from ethylene oxide and ammonia, and related methods
EP2352585B1 (en) 2008-10-06 2020-06-17 Union Carbide Corporation Low metal loaded, alumina supported, catalyst compositions and amination process
JP2012504610A (ja) 2008-10-06 2012-02-23 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー エチレンアミンの製造方法
CN102227258B (zh) * 2008-10-06 2014-02-19 联合碳化化学品及塑料技术公司 包括酸性混合金属氧化物作为载体的低金属(镍和铼)催化剂组合物
JP5806116B2 (ja) 2008-10-06 2015-11-10 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー 求核性化合物のトランスアルコキシル化
EP2344445B1 (en) 2008-10-06 2017-05-10 Union Carbide Chemicals & Plastics Technology LLC A process to selectively manufacture diethylenetriamine (deta) or other desirable ethylenamines via continuous transamination of ethylenediamine (eda), and other ethyleneamines over a heterogeneous catalyst system
BR112014015064A2 (pt) * 2011-12-22 2017-06-13 Dow Global Technologies Llc método para preparar composição contendo piperazina e aminoetiletanolamina
US9162995B2 (en) 2011-12-29 2015-10-20 Dow Global Technologies Llc Formation of higher molecular weight cyclic polyamine compounds from cyclic polyamine compounds
WO2013102097A2 (en) 2011-12-29 2013-07-04 Dow Global Technologies Llc Cyclic amine compounds, compositions, and polyurethane foams made therefrom
WO2013102053A1 (en) 2011-12-29 2013-07-04 Dow Global Technologies Llc Amine polyether polyols and polyurethane foam compositions made from cyclic amine compounds
EP3077444B1 (en) 2013-12-02 2018-04-25 Dow Global Technologies LLC Preparation of high molecular weight, branched, acyclic polyalkyleneamines and mixtures thereof
JP6443706B2 (ja) 2014-09-03 2018-12-26 コーニング インコーポレイテッド 層状プラグを有するハニカム体及びその製造方法
CN114315613B (zh) * 2021-12-27 2024-03-19 江苏康恒化工有限公司 一种羟乙基乙二胺的合成工艺

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4123462A (en) * 1976-01-07 1978-10-31 Union Carbide Corporation Amination process using nickel-rhenium catalysts
GB8707304D0 (en) * 1987-03-26 1987-04-29 Bp Chem Int Ltd Chemical process
US5202490A (en) * 1987-09-30 1993-04-13 Union Carbide Chemicals & Plastics Technology Corporation Process for thr manufacture of diethylenetriamine and aminoethylethanolamine
US5352835A (en) * 1993-02-08 1994-10-04 Texaco Chemical Company Supported catalysts for amination
US5340466A (en) * 1993-04-19 1994-08-23 Texaco Inc. Hydrodesulfurization of cracked naphtha with hydrotalcite-containing catalyst

Also Published As

Publication number Publication date
DE69512381D1 (de) 1999-10-28
JPH08319261A (ja) 1996-12-03
MX197579B (es) 2000-07-18
JP2876464B2 (ja) 1999-03-31
KR960037640A (ko) 1996-11-19
CA2146903A1 (en) 1996-10-13
DE69512381T2 (de) 2000-04-06
CA2146903C (en) 2000-01-25
EP0737669A1 (en) 1996-10-16
KR100216935B1 (ko) 1999-10-01
US5891820A (en) 1999-04-06
EP0737669B1 (en) 1999-09-22

Similar Documents

Publication Publication Date Title
MX9501842A (es) Procesos de aminacion reductivos para la produccion selectiva de aminoetiletanolamina.
CA1050051A (en) Process for the production of unsaturated hydrocarbons
US3270059A (en) Production of diaminoalkanes
WO1999061143A3 (en) Fischer-tropsch processes and catalysts using fluorided alumina supports
TW349936B (en) Process for the production of ethanol and isopropanol
MY118936A (en) Hydrogenation reaction catalyst precursor, process for production thereof and process for production of alcohol.
MY113720A (en) Process for the preparation of hydrogen and carbon monoxide containing mixtures
ZA200105547B (en) Process for catalytic ammonia production - preparation and recovery of ammonia synthesis catalyst.
US6204411B1 (en) Process for the production of aromatic amines
PL337338A1 (en) Catalytic hydrogenation of nitrobenzene to 4-aminodiphenylamine in presence of a hydroxylic compound and a solvent
AU620518B2 (en) Process for the preparation of a, w -diamines
MXPA01001346A (es) Procedimiento mejorado para la obtencion de hexametilendiamina.
RU1833355C (ru) Cпocoб пoлучehия c углeboдopoдob
JP5062647B2 (ja) アミン類の製造方法
CA2251539A1 (en) Coproduction of 6-aminocapronitrile and hexamethylenediamine
MXPA02000907A (es) Catalizadores de hidrogenacion tolerantes al azufre.
MX9600600A (es) Procedimiento de alto rendimiento para la sintesis de urea.
US5789620A (en) Process for the preparation of 1,4-bis(aminomethyl) cyclohexane
US11833493B2 (en) Metal catalyst, method of C-N coupling using the same and applications of the same
Baris et al. Ammonia synthesis over alumina and magnesia supported ruthenium: Comparative kinetic study of the promotive action of metallic and ionic potassium.
JPH0211541A (ja) 高級ニトリルから水素添加によりアミンを製造する方法
JPH0592139A (ja) パラジウム触媒及び置換されていてもよいシクロヘキシルアミンと置換されていてもよいジシクロヘキシルアミンの混合物の製造でのその使用
EP0451979A2 (en) Continuous preparation of secondary amines from nitriles using cobalt and zirconium
MY124142A (en) Process for preparing 6-aminocapronitrile
Osaki et al. Tungsten disulfide prepared from ammonium tetrathiotungstate as a catalyst with high performance for the selective hydrogenation of CO2 to CO