KR960034167A - 퍼플루오로알킬술포네이트, 술폰이미드 및 술포닐 메티드, 및 이들을 함유하는 전해질 - Google Patents

퍼플루오로알킬술포네이트, 술폰이미드 및 술포닐 메티드, 및 이들을 함유하는 전해질 Download PDF

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KR960034167A
KR960034167A KR1019960005285A KR19960005285A KR960034167A KR 960034167 A KR960034167 A KR 960034167A KR 1019960005285 A KR1019960005285 A KR 1019960005285A KR 19960005285 A KR19960005285 A KR 19960005285A KR 960034167 A KR960034167 A KR 960034167A
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independently
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following formulas
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KR1019960005285A
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엘렌 웨이들 제니퍼
마리오 라매너 윌리암
조셉 크라우스 래리
고워 이네스 무어 조지
조셉 햄록 스티븐
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워렌 리차드 보비
미네소타 마이닝 앤드 매뉴팩츄어링 컴패니
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Publication of KR960034167A publication Critical patent/KR960034167A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C311/00—Amides of sulfonic acids, i.e. compounds having singly-bound oxygen atoms of sulfo groups replaced by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C311/01—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms
    • C07C311/02—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C311/09—Sulfonamides having sulfur atoms of sulfonamide groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton the carbon skeleton being further substituted by at least two halogen atoms
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H01M6/166—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solute
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/36—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids
    • C07C303/38—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of amides of sulfonic acids by reaction of ammonia or amines with sulfonic acids, or with esters, anhydrides, or halides thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
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Abstract

본 발명은 하기 식(1) 및 (2)의 화합물, 매체중에 이들 화합물로 이루어진 군중에서 선택됨 염을 포함하는 전해질 조성물 및 이 전해질 조성물을 포함하는 배터리에 관한 것이다;
상기 식에서, -X-는 -O-, -N-SO2Rf 3또는 (Rf 5SO2)(SO2Rf 4)이고; Z는 -CF2-, -O-,NRf 8- 또는 -SF4, -이며; Rf 1및 Rf 2는 독립적으로 -CF3, 또는 -CmF2m +1, -(CF2)q-SO2-X-M+이고; Rf 3, Rf 4및 Rf 5는 독립적으로 -CF3, -CmF2m +1, -(CF2)4-SO2-X-M+,또는이며; Rf 8은 -CF3, -CmF2m +1, 또는 -(CF2)4-SO2-X-M+이고; Rf 6및 Rf 7은 독립적으로 식 CrF2r을 가진 퍼플루오로알킬렌 부위이며; n은 1~4이고; r은 1~4이며; m은 1~12이고; q는 1~4이며; 및 M+은 반대이온이다.

Description

퍼플루오로알킬술포네이트, 술폰아미드 및 술포닐 메티드, 및 이들을 함유하는 전해질
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 매체중에 하기 식(1) 및 (2)의 화합물로 이루어진 군중에서 선택됨 염을 포함하는 전해질 조성물;
    상기 식에서, -X-는 -O-, -N-SO2Rf 3또는 (Rf 5SO2)(SO2Rf 4)이고; Z는 -CF2-, -O-,NRf 8- 또는 -SF4, -이며; Rf 1및 Rf 2는 독립적으로 -CF3, -CmF2m +1, 또는 -(CF2)q-SO2-X-M+이고; Rf 3, Rf 4및 Rf 5는 독립적으로 -CF3, -CmF2m +1, -(CF2)4-SO2-X-M+,또는이며; Rf 8은 -CF3, -CmF2m +1, 또는 -(CF2)4-SO2-X-M+이고; Rf 6및 Rf 7은 독립적으로 식 CrF2r을 가진 퍼플루오로알킬렌 부위이며; n은 1~4이고; r은 1~4이며; m은 1~12이고; q는 1~4이며; 및 M+은 반대이온이다.
  2. 제1항에 있어서, 상기M+가 알카리 금속, 알칼리 토금속, 전이 금속, 회유토, NH(4-j)Rj +, RjC(NH(2-j)Rj)2및 C(NH(2-j)Rj)3 +(식중, j는 0~2이고, Rj는 -H, 알킬기, 옥스알킬기 또는 아릴기임)로 이루어진 군중에서 선택된 것인 전해질 조성물.
  3. 제1항에 있어서, 상기 염이 하기 식 (3) 내지 (10)의 화합물로 이루어진 군중에서 선택된 것인 전해질 조성물;
  4. 제1항에 있어서, M+FB4 -; M+SbF6 -; M+AsF6 -; M+C1O4 -; M+C-(SO2CF3)3; M+PE6 -; CF3SO3 -M+; (CF3SO2)2N-M+(식중, M+는 반대이온임); 및 이들의 배합물로 이루어진 군중에서 선택됨을 염의 추가로 포함하는 전해질 조성물.
  5. 하나 이상의 양의 전극; 하나 이상의 음의 전극; 및 매체중에 하기 식(1) 및 (2)로 이루어진 군중에서 선택된 염을 포함하는 전해질을 포함한 배터리;
    상기 식에서, -X-는 -O-, -N-SO2Rf 3또는 (Rf 5SO2)(SO2Rf 4)이고; Z는 -CF2-, -O-,NRf 8- 또는 -SF4, -이며; Rf 1및 Rf 2는 독립적으로 -CF3, -CmF2m +1, 또는 -(CF2)q-SO2-X-M+이고; Rf 3, Rf 4및 Rf 5는 독립적으로 -CF3, -CmF2m +1, -(CF2)4-SO2-X-M+,또는이며; Rf 8은 -CF3, -CmF2m +1, 또는 -(CF2)4-SO2-X-M+이고; Rf 6및 Rf 7은 독립적으로 식 -CrF2r을 가진 퍼플루오로알킬렌 부위이며; n은 1~4이고; r은 1~4이며; m은 1~12이고; q는 1~4이며; 및 M+은 반대이온이다.
  6. 하기 식 (1) 및 (2)의 화합물로 이루어진 군중에서 선택된 염;
    상기 식에서, -X-는 -O-, -N-SO2Rf 3또는 (Rf 5SO2)(SO2Rf 4)이고; Z는 -CF2-, -O-,NRf 8- 또는 -SF4, -이며; Rf 1및 Rf 2는 독립적으로 -CF3, -CmF2m +1, 또는 -(CF2)q-SO2-X-M+이고; Rf 3, Rf 4및 Rf 5는 독립적으로 -CF3, -CmF2m +1, -(CF2)4-SO2-X-M+,또는이며; Rf 8은 -CF3, -CmF2m +1, 또는 -(CF2)4-SO2-X-M+이고; Q는 -O-, -N-SO2Rf 3또는 (Rf 5SO2)(SO2Rf 4)이며; Rf 6및 Rf 7은 독립적으로 식 CrF2r을 가진 퍼플루오로알킬렌 부위이며; n은 1~4이고; r은 1~4이며; m은 1~12이고; q는 1~4이며; 및 M+은 반대이온이다.
  7. 제6항에 있어서, 하기 식(5), (6), (7), (8) 및 (9)의 화합물로 군중에서 선택된 염;
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960005285A 1995-03-06 1996-02-29 퍼플루오로알킬술포네이트, 술폰이미드 및 술포닐 메티드, 및 이들을 함유하는 전해질 KR960034167A (ko)

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US08/398,859 1995-03-06
US08/398,859 US5514493A (en) 1995-03-06 1995-03-06 Perfluoroalkylsulfonates, sulfonimides, and sulfonyl methides, and electrolytes containing them

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US (1) US5514493A (ko)
EP (1) EP0731518B1 (ko)
JP (1) JP3926864B2 (ko)
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CA (1) CA2169034A1 (ko)
DE (1) DE69609542T2 (ko)
ES (1) ES2149393T3 (ko)

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JP3926864B2 (ja) 2007-06-06
DE69609542T2 (de) 2001-04-05
ES2149393T3 (es) 2000-11-01
JPH08268998A (ja) 1996-10-15
EP0731518B1 (en) 2000-08-02
CA2169034A1 (en) 1996-09-07
DE69609542D1 (de) 2000-09-07
EP0731518A1 (en) 1996-09-11
US5514493A (en) 1996-05-07

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