KR960010731A - 긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법 - Google Patents

긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법 Download PDF

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KR960010731A
KR960010731A KR1019950028635A KR19950028635A KR960010731A KR 960010731 A KR960010731 A KR 960010731A KR 1019950028635 A KR1019950028635 A KR 1019950028635A KR 19950028635 A KR19950028635 A KR 19950028635A KR 960010731 A KR960010731 A KR 960010731A
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리가몬티 마르코
스탄코 도나토
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넬리 루지오
아토하스 홀딩 씨.브이.
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Abstract

본 발명은 하기 물질을 함유하는 조성물에 의하여 제품을 피복하고, 이어서 30~70℃의 온도에서 피복 제품에 U.V.조사를 수행하여 피복물을 그 자체로 중합 및 교차 결합시킴을 특징으로 하는, 열가소성 아크릴 중합체 기재의 긁힘 방지성 및 내마모성의 성형 제품을 제조하는 방법에 관한 것이다: (A)55~95중량%의 2개 이상의 이중 결합을 갖는 하나 이상의 (메트)아크릴 단량체 및/또는 올리고머, (B)5~25중량%의 디비닐에테르 및/또는 에폭시드의 단량체 및/또는 올리고머, (C)(A) 또는 (B)가 극성기를 함유하지 않을 경우, (메트)아크릴레이트 및/또는 모노비닐 에테르의 극성 단일 관능기를 함유하고, 라디칼 및 양이온 형태의 광개시제의 혼합 시스템을 포함하는 0~20중량%의 단량체 및/또는 올리고머.

Description

긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 제품의 표면에 하기 물질을 함유하는 혼합물의 균일층을 도포하고, 이렇게 피복된 제품에 30~70℃의 온도에서 UV조사를 수행함을 특징으로 하는 긁힘 방지성 및 내마모성 필름으로 피복된, 열가소성 아크릴 중합체 기재의 성형 제품, 판 및 필름의 제조 방법: (A)55~95중량%의 2개 이상의 중합성 이중 결합을 갖는 하나 이상의 (메트)아크릴 단량체, 올리고머 또는 이들의 혼합물, (B)5~25중량%의 디비닐에테르 및 에폭시드로부터 선택된 1이상의 단량체, 올리고머, 또는 이들의 혼합물, (C)0~20중량%의 하나 이상의 극성기를 함유하는, 단일 관능성(메트)아크릴 단량체, 올리고머 및 모노비닐 에테르로 구성된 군으로부터 선택한 하나 이상, (D)(A)+(B)+(C)의 100부에 대하여 0.5~6중량부의 라디칼 광개시제, (E)(A)+(B)+(C)의 100부당 0.1~3중량부의 양이온성 광개시제, (F)(A)+(B)+(C)의 100부당 0~8중량부의 콜로이드 실리카 또는 친수성 콜로이드 금부 산화물, 단, (A)+(B)+(C)의 합량이 100이고, 성분(A) 또는 성분(B)가 적어도 하나의 극성기를 함유하지 아니할 경우, 성분(C)가 항상 존재한다.
  2. 제1항에 있어서, 피복되는 제품의 열가소성 아크릴 중합체가 (메트)아크릴산의 C1~C4알킬 에스테르의 (공)중합체 또는 이들과 폴리비닐클로라이드 또는 폴리비닐리덴플루오라이드, 또는 아크릴 탄성체와의 혼합물인 방법.
  3. 제1항에 있어서, 열가소성 아크릴 중합체가 폴리메틸메타아크릴레이트인 방법.
  4. 제1항에 있어서, 성분(A)가 글리콜, 폴리올, 에톡실화 폴리올 및 지방족 우레탄의 다관능성 (메트)아크릴레이트의 단량체, 올리고머 또는 이들의 혼합물인 방법.
  5. 제1항에 있어서, 성분(A)가 우레탄 폴리(메트)아크릴레이트, 펜타에리트리트 트리아크릴레이트, 펜타에리트리트 테트라이크릴레이트, 디펜타에리트리트 펜타아크릴레이트, 1,6-헥산디올 디아크릴레이트 및 트리프로필렌글리콜 디아크릴레이트로 구성된 군으로부터 선택되는 방법.
  6. 제1항에 있어서, 성분(A)가 트리메틸올프로판 트리아크릴레이트 또는 헥산디올 디아크릴레이트와 혼합한 지방족 우레탄 헥사아크릴레이트, 펜타에리트리트 트리아크릴레이트 또는 이들의 혼합물인 방법.
  7. 제1항에 있어서, 성분(B)가 트리에틸렌글리콜 디비닐에테르, 1,4-시클로헥산 디메탄올비닐에테르 및 시클로지방족 에폭시드로 구성된 군으로부터 선택되는 방법.
  8. 제1항에 있어서, 성분(C)가 하나 이상의 히드록실기 또는 카르복실기를 함유하는 히드록시알킬(메트)아크릴레이트, 카르복시알킬메타아크릴레이트 및 모노비닐에테르로 구성된 군으로부터 선택되는 방법.
  9. 제1항에 있어서, 성분(C)가 2-히드록시에틸(메트)아크릴레이트, 2-히드록시프로필(메트)아크릴레이트, 2-카르복시에틸아크릴레이트 및 부탄디올 모노비닐에테르로 구성된 군으로부터 선택되는 방법.
  10. 제1항에 있어서, 성분(D) 및 성분(E) 사이의 중량비가 2이상인 방법.
  11. 제1항에 있어서, UV 조사가 40~60℃의 온도에서 수행되는 방법.
  12. 제1항 내지 제11항 중 어느 한 항에 따른 방법에 의해 수득 가능한, 긁힘 방지성 및 내마모성 필름으로 피복된 열가소성 아크릴 중합체 기재의 성형 제품 및 판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950028635A 1994-09-02 1995-09-01 긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법 KR960010731A (ko)

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ITMI941811A IT1274039B (it) 1994-09-02 1994-09-02 Processo per la preparazione di articoli formati a base di polimeri acrilici rivestiti con un film antigraffio e antiabrasione
ITMI94A001811 1994-09-02

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100383090B1 (ko) * 2000-07-20 2003-05-12 주식회사 엘지화학 내마모성이 우수한 방현성 필름용 코팅액 조성물, 그의제조방법, 그를 사용하여 제조된 필름 및 그의 제조 방법
KR100503946B1 (ko) * 2001-12-31 2005-07-26 주식회사 디피아이 비수분산성 혼성중합체 조성물 및 이의 제조방법
KR100852562B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 방현성 하드코팅 필름, 방현성 하드코팅 필름의 제조방법,광학 소자, 편광판 및 화상 표시 장치
KR100852561B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 하드코팅 필름, 하드코팅 필름의 제조방법, 광학 소자 및화상 표시 장치
US8124215B2 (en) 2006-03-28 2012-02-28 Nitto Denko Corporation Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1269796B (it) * 1994-05-19 1997-04-15 Marco Rigamonti Processo per la preparazione di articoli formati antigraffio e antiabrasione,a base di polimeri acrilici
US5891942A (en) * 1997-05-01 1999-04-06 Fibre Glass-Evercoat Company, Inc. Coating composition with improved water and mar resistance
US6028124A (en) * 1998-11-25 2000-02-22 Dow Corning Corporation Radiation curable compositions
WO2000044819A1 (en) * 1999-01-28 2000-08-03 Eastman Chemical Company Photocurable coatings for polyester articles
JP2000329903A (ja) * 1999-05-18 2000-11-30 Asahi Denka Kogyo Kk 反射防止膜用剤および反射防止膜製造方法
JP2003049010A (ja) * 2001-08-07 2003-02-21 Toagosei Co Ltd プラスチック物品の製造方法
DE10201420A1 (de) * 2002-01-15 2003-07-24 Basf Ag Strahlungshärtbare Beschichtungen mit verbesserter Haftung
AT500082B1 (de) 2003-10-31 2007-08-15 Senoplast Klepsch & Co Gmbh Mehrschichtiger verbundkörper und dessen herstellung
US6998425B2 (en) * 2003-12-23 2006-02-14 General Electric Company UV curable coating compositions and uses thereof
KR101501686B1 (ko) 2012-05-31 2015-03-11 주식회사 엘지화학 하드코팅 필름
KR101451848B1 (ko) * 2012-05-31 2014-10-16 주식회사 엘지화학 하드코팅 필름의 제조방법
KR101379491B1 (ko) 2012-05-31 2014-04-01 주식회사 엘지화학 하드코팅 필름 및 이의 제조방법
KR101470465B1 (ko) 2012-08-23 2014-12-08 주식회사 엘지화학 하드코팅 필름
WO2016019568A1 (en) * 2014-08-08 2016-02-11 Honeywell International Inc. 3d organic-inorganic hybridized compositions and methods
CN104327217B (zh) * 2014-08-20 2017-05-31 昆山博益鑫成高分子材料有限公司 一种紫外光固化非硅离型剂及其制备方法
CN104403554B (zh) * 2014-11-25 2017-02-22 佛山佛塑科技集团股份有限公司 紫外光固化涂料及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4156035A (en) * 1978-05-09 1979-05-22 W. R. Grace & Co. Photocurable epoxy-acrylate compositions
US4227978A (en) * 1979-06-27 1980-10-14 Minnesota Mining And Manufacturing Company Photohardenable composition
US4371566A (en) * 1980-09-10 1983-02-01 Panelgraphic Corporation Abrasion resistant coating composition
MX169037B (es) * 1988-03-29 1993-06-17 Rohm & Haas Procedimiento para preparar revestimientos fotocurados
US5258225A (en) * 1990-02-16 1993-11-02 General Electric Company Acrylic coated thermoplastic substrate
DE4130682A1 (de) * 1991-09-14 1993-03-18 Herberts Gmbh Verfahren, ueberzugsmittel und vorrichtung zur herstellung von beschichteten glashohlkoerpern
IT1255297B (it) * 1992-05-26 1995-10-26 Marco Rigamonti Films o lastre antigoccia a base di polimeri acrilici e processo per la loro preparazione

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100383090B1 (ko) * 2000-07-20 2003-05-12 주식회사 엘지화학 내마모성이 우수한 방현성 필름용 코팅액 조성물, 그의제조방법, 그를 사용하여 제조된 필름 및 그의 제조 방법
KR100503946B1 (ko) * 2001-12-31 2005-07-26 주식회사 디피아이 비수분산성 혼성중합체 조성물 및 이의 제조방법
KR100852562B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 방현성 하드코팅 필름, 방현성 하드코팅 필름의 제조방법,광학 소자, 편광판 및 화상 표시 장치
KR100852561B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 하드코팅 필름, 하드코팅 필름의 제조방법, 광학 소자 및화상 표시 장치
US8124215B2 (en) 2006-03-28 2012-02-28 Nitto Denko Corporation Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display

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IT1274039B (it) 1997-07-14
DE69507224D1 (de) 1999-02-25
US5569498A (en) 1996-10-29
DE69507224T2 (de) 1999-09-30
EP0699704A1 (en) 1996-03-06
EP0699704B1 (en) 1999-01-13
CN1127695A (zh) 1996-07-31
ITMI941811A0 (it) 1994-09-02
ITMI941811A1 (it) 1996-03-02
JPH08259719A (ja) 1996-10-08

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