KR960010731A - 긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법 - Google Patents

긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법 Download PDF

Info

Publication number
KR960010731A
KR960010731A KR1019950028635A KR19950028635A KR960010731A KR 960010731 A KR960010731 A KR 960010731A KR 1019950028635 A KR1019950028635 A KR 1019950028635A KR 19950028635 A KR19950028635 A KR 19950028635A KR 960010731 A KR960010731 A KR 960010731A
Authority
KR
South Korea
Prior art keywords
component
meth
weight
group
parts
Prior art date
Application number
KR1019950028635A
Other languages
English (en)
Inventor
리가몬티 마르코
스탄코 도나토
Original Assignee
넬리 루지오
아토하스 홀딩 씨.브이.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 넬리 루지오, 아토하스 홀딩 씨.브이. filed Critical 넬리 루지오
Publication of KR960010731A publication Critical patent/KR960010731A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/16—Chemical modification with polymerisable compounds
    • C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/125—Monomers containing two or more unsaturated aliphatic radicals, e.g. trimethylolpropane triallyl ether or pentaerythritol triallyl ether
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/106—Esters of polycondensation macromers
    • C08F222/1065—Esters of polycondensation macromers of alcohol terminated (poly)urethanes, e.g. urethane(meth)acrylates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/056—Forming hydrophilic coatings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2427/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2427/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08J2427/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/08—Homopolymers or copolymers of acrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Toxicology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Laminated Bodies (AREA)
  • Paints Or Removers (AREA)
  • Medicinal Preparation (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

본 발명은 하기 물질을 함유하는 조성물에 의하여 제품을 피복하고, 이어서 30~70℃의 온도에서 피복 제품에 U.V.조사를 수행하여 피복물을 그 자체로 중합 및 교차 결합시킴을 특징으로 하는, 열가소성 아크릴 중합체 기재의 긁힘 방지성 및 내마모성의 성형 제품을 제조하는 방법에 관한 것이다: (A)55~95중량%의 2개 이상의 이중 결합을 갖는 하나 이상의 (메트)아크릴 단량체 및/또는 올리고머, (B)5~25중량%의 디비닐에테르 및/또는 에폭시드의 단량체 및/또는 올리고머, (C)(A) 또는 (B)가 극성기를 함유하지 않을 경우, (메트)아크릴레이트 및/또는 모노비닐 에테르의 극성 단일 관능기를 함유하고, 라디칼 및 양이온 형태의 광개시제의 혼합 시스템을 포함하는 0~20중량%의 단량체 및/또는 올리고머.

Description

긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 제품의 표면에 하기 물질을 함유하는 혼합물의 균일층을 도포하고, 이렇게 피복된 제품에 30~70℃의 온도에서 UV조사를 수행함을 특징으로 하는 긁힘 방지성 및 내마모성 필름으로 피복된, 열가소성 아크릴 중합체 기재의 성형 제품, 판 및 필름의 제조 방법: (A)55~95중량%의 2개 이상의 중합성 이중 결합을 갖는 하나 이상의 (메트)아크릴 단량체, 올리고머 또는 이들의 혼합물, (B)5~25중량%의 디비닐에테르 및 에폭시드로부터 선택된 1이상의 단량체, 올리고머, 또는 이들의 혼합물, (C)0~20중량%의 하나 이상의 극성기를 함유하는, 단일 관능성(메트)아크릴 단량체, 올리고머 및 모노비닐 에테르로 구성된 군으로부터 선택한 하나 이상, (D)(A)+(B)+(C)의 100부에 대하여 0.5~6중량부의 라디칼 광개시제, (E)(A)+(B)+(C)의 100부당 0.1~3중량부의 양이온성 광개시제, (F)(A)+(B)+(C)의 100부당 0~8중량부의 콜로이드 실리카 또는 친수성 콜로이드 금부 산화물, 단, (A)+(B)+(C)의 합량이 100이고, 성분(A) 또는 성분(B)가 적어도 하나의 극성기를 함유하지 아니할 경우, 성분(C)가 항상 존재한다.
  2. 제1항에 있어서, 피복되는 제품의 열가소성 아크릴 중합체가 (메트)아크릴산의 C1~C4알킬 에스테르의 (공)중합체 또는 이들과 폴리비닐클로라이드 또는 폴리비닐리덴플루오라이드, 또는 아크릴 탄성체와의 혼합물인 방법.
  3. 제1항에 있어서, 열가소성 아크릴 중합체가 폴리메틸메타아크릴레이트인 방법.
  4. 제1항에 있어서, 성분(A)가 글리콜, 폴리올, 에톡실화 폴리올 및 지방족 우레탄의 다관능성 (메트)아크릴레이트의 단량체, 올리고머 또는 이들의 혼합물인 방법.
  5. 제1항에 있어서, 성분(A)가 우레탄 폴리(메트)아크릴레이트, 펜타에리트리트 트리아크릴레이트, 펜타에리트리트 테트라이크릴레이트, 디펜타에리트리트 펜타아크릴레이트, 1,6-헥산디올 디아크릴레이트 및 트리프로필렌글리콜 디아크릴레이트로 구성된 군으로부터 선택되는 방법.
  6. 제1항에 있어서, 성분(A)가 트리메틸올프로판 트리아크릴레이트 또는 헥산디올 디아크릴레이트와 혼합한 지방족 우레탄 헥사아크릴레이트, 펜타에리트리트 트리아크릴레이트 또는 이들의 혼합물인 방법.
  7. 제1항에 있어서, 성분(B)가 트리에틸렌글리콜 디비닐에테르, 1,4-시클로헥산 디메탄올비닐에테르 및 시클로지방족 에폭시드로 구성된 군으로부터 선택되는 방법.
  8. 제1항에 있어서, 성분(C)가 하나 이상의 히드록실기 또는 카르복실기를 함유하는 히드록시알킬(메트)아크릴레이트, 카르복시알킬메타아크릴레이트 및 모노비닐에테르로 구성된 군으로부터 선택되는 방법.
  9. 제1항에 있어서, 성분(C)가 2-히드록시에틸(메트)아크릴레이트, 2-히드록시프로필(메트)아크릴레이트, 2-카르복시에틸아크릴레이트 및 부탄디올 모노비닐에테르로 구성된 군으로부터 선택되는 방법.
  10. 제1항에 있어서, 성분(D) 및 성분(E) 사이의 중량비가 2이상인 방법.
  11. 제1항에 있어서, UV 조사가 40~60℃의 온도에서 수행되는 방법.
  12. 제1항 내지 제11항 중 어느 한 항에 따른 방법에 의해 수득 가능한, 긁힘 방지성 및 내마모성 필름으로 피복된 열가소성 아크릴 중합체 기재의 성형 제품 및 판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950028635A 1994-09-02 1995-09-01 긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법 KR960010731A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI94A001811 1994-09-02
ITMI941811A IT1274039B (it) 1994-09-02 1994-09-02 Processo per la preparazione di articoli formati a base di polimeri acrilici rivestiti con un film antigraffio e antiabrasione

Publications (1)

Publication Number Publication Date
KR960010731A true KR960010731A (ko) 1996-04-20

Family

ID=11369511

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950028635A KR960010731A (ko) 1994-09-02 1995-09-01 긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법

Country Status (7)

Country Link
US (1) US5569498A (ko)
EP (1) EP0699704B1 (ko)
JP (1) JPH08259719A (ko)
KR (1) KR960010731A (ko)
CN (1) CN1127695A (ko)
DE (1) DE69507224T2 (ko)
IT (1) IT1274039B (ko)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100383090B1 (ko) * 2000-07-20 2003-05-12 주식회사 엘지화학 내마모성이 우수한 방현성 필름용 코팅액 조성물, 그의제조방법, 그를 사용하여 제조된 필름 및 그의 제조 방법
KR100503946B1 (ko) * 2001-12-31 2005-07-26 주식회사 디피아이 비수분산성 혼성중합체 조성물 및 이의 제조방법
KR100852562B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 방현성 하드코팅 필름, 방현성 하드코팅 필름의 제조방법,광학 소자, 편광판 및 화상 표시 장치
KR100852561B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 하드코팅 필름, 하드코팅 필름의 제조방법, 광학 소자 및화상 표시 장치
US8124215B2 (en) 2006-03-28 2012-02-28 Nitto Denko Corporation Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1269796B (it) * 1994-05-19 1997-04-15 Marco Rigamonti Processo per la preparazione di articoli formati antigraffio e antiabrasione,a base di polimeri acrilici
US5891942A (en) * 1997-05-01 1999-04-06 Fibre Glass-Evercoat Company, Inc. Coating composition with improved water and mar resistance
US6028124A (en) * 1998-11-25 2000-02-22 Dow Corning Corporation Radiation curable compositions
WO2000044819A1 (en) * 1999-01-28 2000-08-03 Eastman Chemical Company Photocurable coatings for polyester articles
JP2000329903A (ja) * 1999-05-18 2000-11-30 Asahi Denka Kogyo Kk 反射防止膜用剤および反射防止膜製造方法
JP2003049010A (ja) * 2001-08-07 2003-02-21 Toagosei Co Ltd プラスチック物品の製造方法
DE10201420A1 (de) * 2002-01-15 2003-07-24 Basf Ag Strahlungshärtbare Beschichtungen mit verbesserter Haftung
AT500082B1 (de) 2003-10-31 2007-08-15 Senoplast Klepsch & Co Gmbh Mehrschichtiger verbundkörper und dessen herstellung
US6998425B2 (en) * 2003-12-23 2006-02-14 General Electric Company UV curable coating compositions and uses thereof
KR101418409B1 (ko) 2012-05-31 2014-07-09 주식회사 엘지화학 하드코팅 조성물
KR101379491B1 (ko) 2012-05-31 2014-04-01 주식회사 엘지화학 하드코팅 필름 및 이의 제조방법
KR101501686B1 (ko) 2012-05-31 2015-03-11 주식회사 엘지화학 하드코팅 필름
KR101415838B1 (ko) 2012-08-23 2014-07-09 주식회사 엘지화학 하드코팅 조성물
WO2016019568A1 (en) * 2014-08-08 2016-02-11 Honeywell International Inc. 3d organic-inorganic hybridized compositions and methods
CN104327217B (zh) * 2014-08-20 2017-05-31 昆山博益鑫成高分子材料有限公司 一种紫外光固化非硅离型剂及其制备方法
CN104403554B (zh) * 2014-11-25 2017-02-22 佛山佛塑科技集团股份有限公司 紫外光固化涂料及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4156035A (en) * 1978-05-09 1979-05-22 W. R. Grace & Co. Photocurable epoxy-acrylate compositions
US4227978A (en) * 1979-06-27 1980-10-14 Minnesota Mining And Manufacturing Company Photohardenable composition
US4371566A (en) * 1980-09-10 1983-02-01 Panelgraphic Corporation Abrasion resistant coating composition
MX169037B (es) * 1988-03-29 1993-06-17 Rohm & Haas Procedimiento para preparar revestimientos fotocurados
US5258225A (en) * 1990-02-16 1993-11-02 General Electric Company Acrylic coated thermoplastic substrate
DE4130682A1 (de) * 1991-09-14 1993-03-18 Herberts Gmbh Verfahren, ueberzugsmittel und vorrichtung zur herstellung von beschichteten glashohlkoerpern
IT1255297B (it) * 1992-05-26 1995-10-26 Marco Rigamonti Films o lastre antigoccia a base di polimeri acrilici e processo per la loro preparazione

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100383090B1 (ko) * 2000-07-20 2003-05-12 주식회사 엘지화학 내마모성이 우수한 방현성 필름용 코팅액 조성물, 그의제조방법, 그를 사용하여 제조된 필름 및 그의 제조 방법
KR100503946B1 (ko) * 2001-12-31 2005-07-26 주식회사 디피아이 비수분산성 혼성중합체 조성물 및 이의 제조방법
KR100852562B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 방현성 하드코팅 필름, 방현성 하드코팅 필름의 제조방법,광학 소자, 편광판 및 화상 표시 장치
KR100852561B1 (ko) * 2006-03-28 2008-08-18 닛토덴코 가부시키가이샤 하드코팅 필름, 하드코팅 필름의 제조방법, 광학 소자 및화상 표시 장치
US8124215B2 (en) 2006-03-28 2012-02-28 Nitto Denko Corporation Hard-coated antiglare film, method of manufacturing the same, optical device, polarizing plate, and image display

Also Published As

Publication number Publication date
US5569498A (en) 1996-10-29
ITMI941811A0 (it) 1994-09-02
EP0699704A1 (en) 1996-03-06
ITMI941811A1 (it) 1996-03-02
DE69507224D1 (de) 1999-02-25
CN1127695A (zh) 1996-07-31
EP0699704B1 (en) 1999-01-13
IT1274039B (it) 1997-07-14
JPH08259719A (ja) 1996-10-08
DE69507224T2 (de) 1999-09-30

Similar Documents

Publication Publication Date Title
KR960010731A (ko) 긁힘 방지성 및 내마모성 필름으로 피복된 아크릴 중합체 기재 성형 제품의 제조방법
JP2540708B2 (ja) 放射線硬化性組成物および使用方法
EP0632111B1 (en) Coating process using radiation curable compositions
JP3253155B2 (ja) 放射線硬化性インキ組成物
US4912185A (en) Cross-linkable casting compositions
JPH0841133A (ja) 放射線硬化性組成物
EP0125710A2 (en) U.V. curable coating for optical fibers
JP2009287017A (ja) 活性エネルギー線硬化性樹脂組成物、硬化物及び物品
JPH0847667A (ja) アクリルポリマーをベースとする耐引掻性耐磨耗性造形品の製造方法
KR20110077577A (ko) 바닥재 코팅용 아이소레이터 조성물 및 바닥재 코팅방법
US5102488A (en) Process for forming cured-resin layer having an antistatic surface
JPH06234554A (ja) 輻射線硬化コーティング被覆光学ガラス繊維
KR100199552B1 (ko) 필름에 고내스크래치성 박막코팅을 부여하는 자외선 경화형 수지조성물
MXPA02006765A (es) Composiciones de revestimiento para madera, curables por luz ultravioleta.
AU601779B2 (en) Cross-linkable casting composition
CA2135089A1 (en) No drop films or plates consisting of acrylic polymers and process for their preparation
JPS62236832A (ja) 密着性に優れた塗料組成物
JP2938941B2 (ja) 成形用ハードコートシート及びその製造方法
JPS6383117A (ja) 硬化被膜形成性被覆材組成物
JP2002212244A (ja) 活性エネルギー線硬化性組成物
JPS6354412A (ja) 光硬化性樹脂組成物
JP3073816B2 (ja) 紫外線硬化型塗料
JPH06145305A (ja) 光重合性樹脂組成物及びその硬化物
JP2001323005A (ja) 活性エネルギー線硬化型組成物および該組成物からなる硬化塗膜を有する被膜形成体
JPH01252553A (ja) 光ファイバー

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid