KR960007823A - 복합금속판 및 그 제조방법 - Google Patents

복합금속판 및 그 제조방법 Download PDF

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KR960007823A
KR960007823A KR1019950023409A KR19950023409A KR960007823A KR 960007823 A KR960007823 A KR 960007823A KR 1019950023409 A KR1019950023409 A KR 1019950023409A KR 19950023409 A KR19950023409 A KR 19950023409A KR 960007823 A KR960007823 A KR 960007823A
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resin
layer
composite metal
weight
parts
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KR100310962B1 (ko
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도루 가메야
가츠아키 다카노
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마츠다 즈네미
다이요 세이코 가부시키가이샤
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/08Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by flames
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/14Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by electrical means
    • B05D3/141Plasma treatment
    • B05D3/145After-treatment
    • B05D3/148After-treatment affecting the surface properties of the coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/16Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0008Electrical discharge treatment, e.g. corona, plasma treatment; wave energy or particle radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/24Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate
    • B32B2037/243Coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/06Coating on the layer surface on metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/10Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2310/00Treatment by energy or chemical effects
    • B32B2310/14Corona, ionisation, electrical discharge, plasma treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12556Organic component
    • Y10T428/12569Synthetic resin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31511Of epoxy ether
    • Y10T428/31515As intermediate layer
    • Y10T428/31522Next to metal
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Thermal Sciences (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

내식성, 내후성, 가공성을 아울러 지니는 복합금속판 및 그 제조방법을 제공한다.
금속표면에 화성처리를 행한 후 그 위에 밑칠로서 유기수지계 도료를 도장, 건조하고 이어서 그 위에 변성 폴리올레핀수지의 접착층과 폴리올렌핀수지층의 2층으로 이루어지는 중간층을 50~300 마이크로미터 두께로 형성시켜 폴리올레핀수지층의 표면을 화염처리 또는 코로나방전처리로 표면개질하고 관능기중의 산소량과 표면의 탄소량의 비를 나타내는 O/C 치로 0.05~0.30의 관능기를 생성시키고 다시 덧칠로서 우레탄경화형 폴리에스테르도료 또는 우레탄경화형 불소도료를 8~36 마이크로미터 두께로 도장, 건조시켜서 얻어진 복합금속판.

Description

복합금속판 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 금속판표면에, 최하층의 화성처리층, 그 위에 유기수지계 도료의 밑칠층이 설치되어 있고 그 위에 변성 폴리올레핀수지의 접착층과 폴리올렌핀수지층의 2층이 복합된 50~300 마이크로미터의 중간수지층으로 이 수지층의 표면은 표면개질로 관능기의 양이 관능기중의 산소량과 표면의 탄소량의 비를 나타내는 O/C로 값 0.05~0.30 존재하고 있고, 다시 그 위에 우레탄경화형 폴리에스테르수지 또는 우레탄경화형 불소수지로 8~35 마이크로미터 두께의 덧칠도막을 가지는 것을 특징으로 하는 복합금속판 및 그 제조방법.
  2. 금속표면에 화성처리를 행한 후 그 위에 밑칠로서 유기수지계 도료를 도장, 건조하고 이어서 그 위에 변성 폴리올레핀수지의 접착층과 폴리올렌핀수지층의 2층으로 이루어지는 중간층을 50~300 마이크로미터의 두께로 형성시키고, 폴리올레핀수지층의 표면을 화염처리 또는 코로나방전처리로 표면개질하고, 관능기중의 산소량과 표면의 탄소량의 비를 나타내는 O/C 치로 0.05~0.30의 관능기를 생성시키며 다시 덧칠로서 우레탄경화형 폴리에스테르도료 또는 우레탄경화형 불소도료를 8~36 마이크로미터 두께로 도장, 건조시키는 것을 특징으로 하는 복합금속판 및 그 제조방법.
  3. 제1항에 있어서 밑칠도막중에 방청안료로서 스트론튬크로메이트 또는 징크크로메이트 또는 스트론튬크로메이트와 징크크로메이트의 혼합된 것을 수지 100 중량부에 대하여 10~40 중량부 함유하는 것을 특징으로 하는 복합금속판.
  4. 제1항 또는 제3항에 있어서 중간수지층에 불연성 향상제로서 3 산화안티몬과 브롬소계 난연제를 각각 수지 100 중량부에 대하여 3~15중량부 함유하는 것을 특징으로 하는 복합금속판.
  5. 제1, 3 또는 제4항에 있어서 중간수지층 및 덧칠도막의 양쪽에 불연성 향상제로서 3 산화안티몬과 브롬소계 난연제를 각각 수지 100 중량부에 대하여 3~15중량부 함유하는 것을 특징으로 하는 복합금속판.
  6. 제1, 3, 4 또는 제5항에 있어서 덧칠도막중에 항균·방곰팡이 향상제로서 은을 함유하는 무기계 항균제를 수지 100 중량부에 0.05~2 중량부 함유하는 것을 특징으로 하는 복합금속판.
  7. 제1, 3, 4, 5 또는 제6항에 있어서 중간수지층의 두께가 80~300 마이크로미터인 것을 특징으로 하는 복합금속판.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950023409A 1994-08-25 1995-07-31 복합금속판및그제조방법 KR100310962B1 (ko)

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JP22272794A JP3228022B2 (ja) 1994-08-25 1994-08-25 複合金属板およびその製造方法
JP94-222727 1994-08-25

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KR100310962B1 KR100310962B1 (ko) 2002-07-02

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US (1) US5670261A (ko)
EP (1) EP0698484B1 (ko)
JP (1) JP3228022B2 (ko)
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AU (1) AU694989B2 (ko)
CA (1) CA2146621C (ko)
DE (1) DE69518044T2 (ko)
FI (1) FI112047B (ko)

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DE69518044D1 (de) 2000-08-24
EP0698484A2 (en) 1996-02-28
FI953550A0 (fi) 1995-07-24
US5670261A (en) 1997-09-23
JPH0857417A (ja) 1996-03-05
DE69518044T2 (de) 2001-03-22
AU694989B2 (en) 1998-08-06
AU2042695A (en) 1996-03-07
FI953550A (fi) 1996-02-26
EP0698484B1 (en) 2000-07-19
FI112047B (fi) 2003-10-31
KR100310962B1 (ko) 2002-07-02
CA2146621C (en) 2003-01-28
JP3228022B2 (ja) 2001-11-12
CA2146621A1 (en) 1996-02-26
EP0698484A3 (en) 1996-06-19

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