KR960005624B1 - 이소올레핀/파라알킬스티렌 공중합체를 함유하는 열가소성 조성물 - Google Patents
이소올레핀/파라알킬스티렌 공중합체를 함유하는 열가소성 조성물 Download PDFInfo
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- KR960005624B1 KR960005624B1 KR1019930700330A KR930700330A KR960005624B1 KR 960005624 B1 KR960005624 B1 KR 960005624B1 KR 1019930700330 A KR1019930700330 A KR 1019930700330A KR 930700330 A KR930700330 A KR 930700330A KR 960005624 B1 KR960005624 B1 KR 960005624B1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/08—Butenes
- C08F210/10—Isobutene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/14—Monomers containing five or more carbon atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/18—Introducing halogen atoms or halogen-containing groups
- C08F8/20—Halogenation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or halogen-containing compounds
- C08L23/283—Iso-olefin halogenated homopolymers or copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
- C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
- C08L71/12—Polyphenylene oxides
- C08L71/123—Polyphenylene oxides not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56346490A | 1990-08-07 | 1990-08-07 | |
| US563,464 | 1990-08-07 | ||
| US07/648,267 US6013727A (en) | 1988-05-27 | 1991-01-31 | Thermoplastic blend containing engineering resin |
| US648,267 | 1991-01-31 | ||
| PCT/US1991/005517 WO1992002582A1 (en) | 1990-08-07 | 1991-08-02 | Thermoplastic composition containing an isoolefin-para-alkylstyrene copolymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR930701536A KR930701536A (ko) | 1993-06-12 |
| KR960005624B1 true KR960005624B1 (ko) | 1996-04-30 |
Family
ID=27073297
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930700330A Expired - Lifetime KR960005624B1 (ko) | 1990-08-07 | 1991-08-02 | 이소올레핀/파라알킬스티렌 공중합체를 함유하는 열가소성 조성물 |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US6013727A (https=) |
| EP (1) | EP0542875B1 (https=) |
| JP (1) | JP3140459B2 (https=) |
| KR (1) | KR960005624B1 (https=) |
| AU (1) | AU8417491A (https=) |
| BR (1) | BR9106738A (https=) |
| CA (1) | CA2048465A1 (https=) |
| DE (1) | DE69114010T2 (https=) |
| ES (1) | ES2078539T3 (https=) |
| TW (1) | TW223643B (https=) |
| WO (1) | WO1992002582A1 (https=) |
Families Citing this family (92)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6013727A (en) * | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
| US5693714A (en) * | 1992-02-27 | 1997-12-02 | Composite Particles, Inc. | Higher modulus compositions incorporating particulate rubber |
| US5385459A (en) * | 1992-06-29 | 1995-01-31 | Bridgestone Corporation | Rubber curing bladders having self release or low adhesion to curing or cured hydrocarbon rubbers |
| EP0580991B1 (en) * | 1992-06-29 | 2000-01-26 | Bridgestone Corporation | Rubbers, rubber compounds, and rubber curing bladders having self release or low adhesion to curing or cured hydrocarbon rubbers |
| US6303691B1 (en) * | 1992-07-31 | 2001-10-16 | Exxon Mobil Chemical Patents Inc. | Impact modification of polyamides |
| ES2139944T3 (es) * | 1994-09-14 | 2000-02-16 | Exxon Chemical Patents Inc | Composiciones de poli(fenilen-eter) de alto impacto. |
| MX9708472A (es) * | 1995-05-03 | 1998-02-28 | Exxon Chemical Patents Inc | Mezclas fisicas compatibilizadas de polipropileno y polimeros de poli(fenileno eter). |
| US5574105A (en) * | 1995-05-12 | 1996-11-12 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomers having improved high temperature performance |
| US5681899A (en) * | 1995-07-17 | 1997-10-28 | Exxon Chemical Patents Inc. | Impact modifier for polyamides containing an elastomer and a halogenated isoolefin copolymer7 |
| DE19655417B4 (de) * | 1995-11-02 | 2008-11-20 | The Yokohama Rubber Co., Ltd. | Thermoplastische Elastomerzusammensetzung und Verfahren zu deren Herstellung, sowie Verwendung der Zusammensetzung für einen Schlauch mit niedriger Permeabilität |
| DE19655416B3 (de) * | 1995-11-02 | 2014-09-25 | The Yokohama Rubber Co., Ltd. | Thermoplastische Elastomerzusammensetzung und Verfahren zu deren Herstellung, sowie Verwendung der Zusammensetzung für einen Schlauch mit niedriger Permeabilität |
| CA2267236A1 (en) * | 1996-11-26 | 1998-06-04 | Exxon Chemical Patents, Inc. | High impact styrene/acrylonitrile polymer blend compositions |
| US6060549A (en) * | 1997-05-20 | 2000-05-09 | Exxon Chemical Patents, Inc. | Rubber toughened thermoplastic resin nano composites |
| US5936039A (en) * | 1997-11-10 | 1999-08-10 | Wang; Kang-Bo | Processes for producing thermoplastic elastomers having improved engineering performance |
| US6069202A (en) * | 1997-12-10 | 2000-05-30 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomer triblend from an engineering thermoplastic, functionalized ethylene and or diene polymer, and brominated isobutylene p-methylstyrene copolymer |
| US6359071B1 (en) * | 1998-01-13 | 2002-03-19 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition, process for producing the same, and pneumatic tire and hose made with the same |
| US6861139B2 (en) * | 1998-04-17 | 2005-03-01 | 3M Innovative Properties Company | Pressure sensitive adhesive composition and adhesive product using the same |
| JP2000035069A (ja) * | 1998-05-15 | 2000-02-02 | Hitachi Koki Co Ltd | 摩擦材およびそれを用いた制動装置、ならびに画像形成装置 |
| CA2282900C (en) | 1999-09-20 | 2011-02-01 | Bayer Inc. | Halogenated terpolymers of isobutylene, diolefin monomer and styrenic monomer |
| JP2003531944A (ja) * | 2000-05-04 | 2003-10-28 | ゼネラル・エレクトリック・カンパニイ | 相溶化ポリフェニレンエーテル−ポリアミド組成物の塗料密着性を改善する方法 |
| US6376598B1 (en) | 2000-06-15 | 2002-04-23 | Exxon Mobil Chemical Patents Inc. | Thermoplastic blend |
| US20020053386A1 (en) * | 2000-09-11 | 2002-05-09 | The Yokohama Rubber Co., Ltd. | Steel cord for tire and radial tire |
| US6552108B1 (en) | 2000-10-11 | 2003-04-22 | Exxonmobil Chemical Patents Inc. | Rubber blends having improved stability and green strength |
| US7019058B2 (en) | 2000-10-11 | 2006-03-28 | Exxonmobil Chemical Patents, Inc. | Halogenated elastomeric compositions having enhanced viscosity |
| KR20030040531A (ko) * | 2000-10-11 | 2003-05-22 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 향상된 점도를 갖는 할로겐화 엘라스토머 조성물 |
| US7714043B2 (en) | 2000-10-18 | 2010-05-11 | Exxonmobil Chemical Patents Inc. | Tire innerliners having improved cold temperature properties |
| AU2002239587A1 (en) * | 2000-12-22 | 2002-07-08 | Exxonmobil Chemical Patents Inc. | Composites comprising semicrystalline random ethylene / propylenecopolymers |
| US8066928B2 (en) * | 2001-01-24 | 2011-11-29 | Acushnet Company | Method of providing a moisture vapor barrier layer to a core of a golf ball |
| US7547746B2 (en) * | 2005-06-09 | 2009-06-16 | Acushnet Company | Golf ball containing centipede polymers |
| US20050227786A1 (en) * | 2002-07-15 | 2005-10-13 | Sullivan Michael J | Golf ball with velocity reduced layer |
| US20080315469A1 (en) * | 2007-06-22 | 2008-12-25 | Hogge Matthew F | Method of providing a moisture vapor barrier layer to a core of a golf ball |
| US6612351B1 (en) * | 2001-02-05 | 2003-09-02 | The Goodyear Tire & Rubber Company | Pneumatic tire having dual air retention quasi envelopes |
| IL142037A0 (en) * | 2001-03-15 | 2002-03-10 | Agis Ind 1983 Ltd | Pharmaceutical compositions containing a non-steroidal anti-inflammatory drug |
| US6451893B1 (en) * | 2001-05-22 | 2002-09-17 | Microflex Corporation | Soft nitrile zinc oxide free medical gloves |
| EP1404754A4 (en) | 2001-06-07 | 2004-09-08 | Exxonmobil Chem Patents Inc | COPOLYMERS BASED ON HALOGEN ISOBUTYLENE WITH ENHANCED VISCOSITY AND THERMOPLASTIC COMPOSITION CONSISTING OF SUCH COPOLYMERS |
| US7176260B2 (en) * | 2001-06-11 | 2007-02-13 | Microflex Corporation | Soft nitrile medical gloves having improved glove relaxation properties |
| US7951015B2 (en) | 2001-10-09 | 2011-05-31 | Acushnet Company | Multilayer golf ball containing at least three core layers, at least one intermediate barrier layer, and at least one cover layer |
| US6632147B2 (en) | 2001-10-09 | 2003-10-14 | Acushnet Company | Golf ball with vapor barrier layer and method of making same |
| US20030069082A1 (en) * | 2001-10-09 | 2003-04-10 | Sullivan Michael J. | Golf ball with polysulfide rubber layer |
| US20030069085A1 (en) * | 2001-10-09 | 2003-04-10 | Hogge Matthew F. | Golf ball with vapor barrier layer and method of making same |
| US20060128505A1 (en) * | 2001-10-09 | 2006-06-15 | Sullivan Michael J | Golf ball layers having improved barrier properties |
| US7004854B2 (en) * | 2001-10-09 | 2006-02-28 | Acushnet Company | Golf ball with vapor barrier layer and method of making same |
| CN1665870A (zh) | 2002-07-05 | 2005-09-07 | 埃克森美孚化学专利公司 | 官能化的弹性体纳米复合材料 |
| CN100345896C (zh) * | 2002-08-12 | 2007-10-31 | 埃克森美孚化学专利公司 | 增塑聚烯烃组合物 |
| US7998579B2 (en) * | 2002-08-12 | 2011-08-16 | Exxonmobil Chemical Patents Inc. | Polypropylene based fibers and nonwovens |
| US7271209B2 (en) * | 2002-08-12 | 2007-09-18 | Exxonmobil Chemical Patents Inc. | Fibers and nonwovens from plasticized polyolefin compositions |
| US7531594B2 (en) * | 2002-08-12 | 2009-05-12 | Exxonmobil Chemical Patents Inc. | Articles from plasticized polyolefin compositions |
| US8003725B2 (en) * | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| JP4624111B2 (ja) * | 2003-03-06 | 2011-02-02 | 横浜ゴム株式会社 | 改良されたゴムペレット化工程を用いた熱可塑性エラストマー組成物の製造方法 |
| RU2331656C2 (ru) * | 2003-03-06 | 2008-08-20 | Эксонмобил Кемикал Пэйтентс, Инк. | Термопластичная эластомерная композиция, содержащая вулканизированные эластомерные дисперсии с увеличенной вязкостью |
| RU2316569C2 (ru) * | 2003-03-06 | 2008-02-10 | Дзе Екохама Раббер Ко., Лтд | Термопластичная эластомерная композиция с улучшенным способом грануляции каучука |
| RU2323233C2 (ru) * | 2003-03-06 | 2008-04-27 | Дзе Ёкохама Раббер Ко., Лтд | Термопластичная эластомерная композиция с умеренной степенью вулканизации |
| CN100494261C (zh) * | 2003-03-06 | 2009-06-03 | 埃克森美孚化学专利公司 | 具有改进的机械性能和抗疲劳性的热塑性弹性体组合物 |
| AU2003213726A1 (en) * | 2003-03-06 | 2004-09-30 | Exxonmobil Chemical Patents, Inc. | A method for controlling dispersion size of elastomer in thermoplastic elastomer composition |
| AU2003216508A1 (en) * | 2003-03-06 | 2004-09-30 | Exxonmobil Chemical Patents, Inc. | Thermoplastic elastomer composition having moderate cure state |
| US8192813B2 (en) | 2003-08-12 | 2012-06-05 | Exxonmobil Chemical Patents, Inc. | Crosslinked polyethylene articles and processes to produce same |
| US8389615B2 (en) * | 2004-12-17 | 2013-03-05 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin |
| EP1674530A1 (en) | 2004-12-24 | 2006-06-28 | Kraton Polymers Research B.V. | High melt strength thermoplastic elastomer composition |
| US7696266B2 (en) | 2004-12-29 | 2010-04-13 | Exxonmobil Chemical Patents Inc. | Select elastomeric blends and their use in articles |
| US7906600B2 (en) | 2004-12-29 | 2011-03-15 | Exxonmobil Chemical Patents Inc. | Processable filled, curable halogenated isoolefin elastomers |
| WO2006121141A1 (ja) * | 2005-05-10 | 2006-11-16 | The Yokohama Rubber Co., Ltd. | 熱可塑性エラストマー組成物 |
| GB0511320D0 (en) | 2005-06-03 | 2005-07-13 | Exxonmobil Chem Patents Inc | Elastomeric structures |
| WO2007011530A2 (en) | 2005-07-15 | 2007-01-25 | Exxonmobil Chemical Patents, Inc. | Elastomeric compositions |
| EP2502742B1 (en) | 2005-10-27 | 2017-06-21 | ExxonMobil Chemical Patents Inc. | Construction comprising tie layer for pneumatic tire |
| US7585914B2 (en) * | 2005-11-09 | 2009-09-08 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions and methods for making the same |
| US7767743B2 (en) | 2006-03-10 | 2010-08-03 | Exxonmobil Chemical Patents Inc. | Processable branched isoolefin-alkylstyrene elastomers |
| US7498381B1 (en) | 2006-08-02 | 2009-03-03 | Exxonmobil Chemical Patents Inc. | Low permeability elastomeric-metal phosphate nanocomposites |
| US8207270B2 (en) | 2006-09-29 | 2012-06-26 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions, methods of making and articles made from the same |
| WO2008051253A1 (en) | 2006-10-26 | 2008-05-02 | Exxonmobil Chemical Patents Inc. | Low moisture permeability laminate construction |
| US7745544B2 (en) * | 2006-11-30 | 2010-06-29 | Exxonmobil Chemical Patents Inc. | Catalytic epoxidation and hydroxylation of olefin/diene copolymers |
| US7615589B2 (en) * | 2007-02-02 | 2009-11-10 | Exxonmobil Chemical Patents Inc. | Properties of peroxide-cured elastomer compositions |
| US8487033B2 (en) | 2007-05-16 | 2013-07-16 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom |
| EP2152764A1 (en) | 2007-05-16 | 2010-02-17 | ExxonMobil Chemical Patents Inc. | Catalyst system for olefin polymerization and polymers produced therefrom |
| US20080306215A1 (en) * | 2007-06-06 | 2008-12-11 | Abhimanyu Onkar Patil | Functionalization of olefin/diene copolymers |
| US8158721B2 (en) * | 2008-06-13 | 2012-04-17 | Exxonmobil Chemical Patents Inc. | Process for preparing dynamically vulcanized alloys |
| US7923491B2 (en) * | 2008-08-08 | 2011-04-12 | Exxonmobil Chemical Patents Inc. | Graphite nanocomposites |
| US9475910B2 (en) | 2009-10-26 | 2016-10-25 | Exxonmobil Chemical Patents Inc. | Elastomer nanocomposites with incorporated process oils |
| US8609760B2 (en) | 2009-11-18 | 2013-12-17 | Exxonmobil Chemical Patents Inc. | Blend partner with natural rubber for elastomeric compounds |
| JP5736677B2 (ja) * | 2010-06-25 | 2015-06-17 | 横浜ゴム株式会社 | 熱可塑性エラストマー組成物およびその製造方法 |
| US8415431B2 (en) | 2010-08-05 | 2013-04-09 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomeric compositions |
| WO2013090702A2 (en) | 2011-12-15 | 2013-06-20 | Sun Chemical Corporation | Sulfide extended epoxy resins and barrier coatings applications thereof |
| WO2013108731A1 (ja) | 2012-01-16 | 2013-07-25 | 味の素株式会社 | 封止用樹脂組成物 |
| US20150225561A1 (en) * | 2012-06-19 | 2015-08-13 | The Yokohama Rubber Co., Ltd. | Thermoplastic elastomer composition and process to produce same |
| JP6184258B2 (ja) * | 2013-09-02 | 2017-08-23 | キヤノン株式会社 | 液体吐出ヘッドの製造方法 |
| WO2016190358A1 (ja) | 2015-05-26 | 2016-12-01 | 株式会社カネカ | 熱可塑性エラストマーの製造方法及び熱可塑性エラストマー |
| KR102171805B1 (ko) * | 2017-04-21 | 2020-10-29 | (주)엘지하우시스 | 바이오 물질을 기반으로 한 uv코팅 조성물 |
| CN111655782B (zh) | 2017-12-18 | 2023-11-10 | 国际人造丝公司 | 用于输送烃流体的热塑性硫化橡胶导管 |
| WO2019147343A1 (en) | 2018-01-29 | 2019-08-01 | Exxonmobil Chemical Patents Inc. | Rubber blends, articles thereof, and methods of making the same |
| US11413800B2 (en) | 2019-05-20 | 2022-08-16 | Kraton Polymers Llc | Molding compositions and articles made thereof |
| WO2021262838A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom |
| WO2021262842A1 (en) | 2020-06-26 | 2021-12-30 | Exxonmobil Chemical Patents Inc. | COPOLYMERS OF ETHYLENE, α-OLEFIN, NON-CONJUGATED DIENE, AND ARYL-SUBSTITUTED CYCLOALKENE, METHODS TO PRODUCE, BLENDS, AND ARTICLES THEREFROM |
| JP7587192B2 (ja) * | 2021-07-29 | 2024-11-20 | 横浜ゴム株式会社 | 冷媒輸送用ホース |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2516741A (en) * | 1944-10-12 | 1950-07-25 | Standard Oil Dev Co | Composition of brittle resin and styrene-isobutylene copolymer |
| US3037954A (en) * | 1958-12-15 | 1962-06-05 | Exxon Research Engineering Co | Process for preparing a vulcanized blend of crystalline polypropylene and chlorinated butyl rubber |
| US3658950A (en) * | 1969-05-27 | 1972-04-25 | Gen Motors Corp | Thermoplastic resin containing styrene-acrylonitrile copolymer and chlorinated polyethylene |
| US4026968A (en) * | 1974-08-15 | 1977-05-31 | Exxon Research And Engineering Company | Bromobutyl rubber-styrene-acrylonitrile graft copolymers |
| US4172859A (en) * | 1975-05-23 | 1979-10-30 | E. I. Du Pont De Nemours And Company | Tough thermoplastic polyester compositions |
| US4174358A (en) * | 1975-05-23 | 1979-11-13 | E. I. Du Pont De Nemours And Company | Tough thermoplastic nylon compositions |
| US4197379A (en) * | 1976-03-03 | 1980-04-08 | Monsanto Company | Elastoplastic compositions of rubber and polyamide |
| US4173556A (en) * | 1976-03-03 | 1979-11-06 | Monsanto Company | Elastoplastic compositions of rubber and polyamide |
| US4143098A (en) * | 1976-03-18 | 1979-03-06 | Exxon Research & Engineering Co. | Cdb rubber modified thermoplastics |
| DE2651435C3 (de) * | 1976-11-11 | 1980-11-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von bromierten Polymerisationsprodukten des Styrols |
| US4130534A (en) * | 1976-12-27 | 1978-12-19 | Monsanto Company | Elastoplastic compositions of butyl rubber and polyolefin resin |
| US4207404A (en) * | 1978-12-06 | 1980-06-10 | Monsanto Company | Compositions of chlorinated polyethylene rubber and nylon |
| US4226953A (en) * | 1979-02-22 | 1980-10-07 | Monsanto Company | Thermoplastic compositions of styrene-acrylonitrile resin and nitrile rubber |
| US4350794A (en) * | 1979-07-23 | 1982-09-21 | Monsanto Company | High-impact polyamide molding and extrusion resin compositions |
| DE3169225D1 (en) * | 1980-04-04 | 1985-04-18 | Stamicarbon | Polymer composition |
| US4287324A (en) * | 1980-05-12 | 1981-09-01 | Monsanto Company | Compositions of epichlorohydrin rubber and polyester |
| US4297453A (en) * | 1980-05-12 | 1981-10-27 | Monsanto Company | Compositions of epichlorohydrin rubber and nylon |
| US4338413A (en) * | 1980-10-16 | 1982-07-06 | Monsanto Company | Polymer blends |
| US4348502A (en) * | 1981-01-23 | 1982-09-07 | Monsanto Company | Thermoplastic compositions of nylon and ethylene-vinyl acetate rubber |
| NL8104413A (nl) * | 1981-09-25 | 1983-04-18 | Stamicarbon | Polymeercompositie. |
| US4419499A (en) | 1982-03-25 | 1983-12-06 | Monsanto Company | Compositions of urethane rubber and nylon |
| US4548995A (en) | 1983-04-01 | 1985-10-22 | Exxon Research & Engineering Co. | Process for the manufacture of halogenated polymers |
| US4639487A (en) * | 1984-07-11 | 1987-01-27 | Exxon Research & Engineering Co. | Heat shrinkable thermoplastic olefin composition |
| US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5162445A (en) * | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US4794143A (en) * | 1988-03-24 | 1988-12-27 | Polysar Limited | Polymer composition containing CPE and styrene polymer |
| CA1338546C (en) * | 1988-05-27 | 1996-08-20 | Kenneth William Powers | Para-alkylstyrene/isoolefin copolymers |
| US6013727A (en) * | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
| US5013793A (en) * | 1990-07-26 | 1991-05-07 | Exxon Chemical Patents Inc. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
| JP2832382B2 (ja) * | 1988-10-28 | 1998-12-09 | アドバンスド・エラストマー・システムズ・エル・ピー | 結晶性ポリオレフィン樹脂及びハロブチルゴム物質の動的加硫アロイ |
| US4978717A (en) | 1989-04-19 | 1990-12-18 | Exxon Chemical Patents Inc. | Thermoelastic composition of ethylene-1-olefin copolymer and rubber |
| US5100947A (en) | 1989-05-26 | 1992-03-31 | Advanced Elastomer Systems, L. P. | Dynamically vulcanized alloys having improved stiffness/impact balance |
| US5063268A (en) * | 1990-06-08 | 1991-11-05 | Exxon Chemical Patents Inc. | Composition for tire treads (E-235) |
| US5118761A (en) | 1991-01-08 | 1992-06-02 | Exxon Chemical Patents Inc. | Thermoplastic composition containing a styrene copolymer resin |
| JPH08509261A (ja) * | 1993-04-19 | 1996-10-01 | エクソン・ケミカル・パテンツ・インク | ｐ−アルキルスチレンとイソオレフィンのグラフトポリマーを含む相溶化ブレンド |
| US5512638A (en) * | 1994-05-03 | 1996-04-30 | Exxon Chemical Patents Inc. | Curing systems for compositions containing halogenated copolymers of isobutylene and para-methylstrene |
| EP0775164B1 (en) * | 1994-08-03 | 2001-11-07 | ExxonMobil Chemical Patents Inc. | Supported ionic catalyst composition |
| US5543484A (en) * | 1994-11-18 | 1996-08-06 | The Penn State Research Foundation | α-olefin/para-alkylstyrene copolymers |
| US5681899A (en) | 1995-07-17 | 1997-10-28 | Exxon Chemical Patents Inc. | Impact modifier for polyamides containing an elastomer and a halogenated isoolefin copolymer7 |
| US5910543A (en) | 1996-12-18 | 1999-06-08 | Advanced Elastomer Systems, L.P. | Thermoplastic elastomer with polar and non-polar rubber components |
-
1991
- 1991-01-31 US US07/648,267 patent/US6013727A/en not_active Expired - Lifetime
- 1991-08-02 AU AU84174/91A patent/AU8417491A/en not_active Abandoned
- 1991-08-02 ES ES91915257T patent/ES2078539T3/es not_active Expired - Lifetime
- 1991-08-02 DE DE69114010T patent/DE69114010T2/de not_active Expired - Lifetime
- 1991-08-02 EP EP91915257A patent/EP0542875B1/en not_active Expired - Lifetime
- 1991-08-02 JP JP03513762A patent/JP3140459B2/ja not_active Expired - Lifetime
- 1991-08-02 WO PCT/US1991/005517 patent/WO1992002582A1/en not_active Ceased
- 1991-08-02 KR KR1019930700330A patent/KR960005624B1/ko not_active Expired - Lifetime
- 1991-08-02 BR BR919106738A patent/BR9106738A/pt not_active IP Right Cessation
- 1991-08-06 CA CA002048465A patent/CA2048465A1/en not_active Abandoned
- 1991-08-19 TW TW080106561A patent/TW223643B/zh active
-
1996
- 1996-11-26 US US08/756,470 patent/US6008282A/en not_active Expired - Fee Related
-
1999
- 1999-11-02 US US09/432,995 patent/US6346571B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69114010D1 (de) | 1995-11-23 |
| EP0542875B1 (en) | 1995-10-18 |
| JP3140459B2 (ja) | 2001-03-05 |
| TW223643B (https=) | 1994-05-11 |
| AU8417491A (en) | 1992-03-02 |
| US6013727A (en) | 2000-01-11 |
| BR9106738A (pt) | 1993-06-29 |
| EP0542875A1 (en) | 1993-05-26 |
| JPH05509349A (ja) | 1993-12-22 |
| CA2048465A1 (en) | 1992-02-08 |
| WO1992002582A1 (en) | 1992-02-20 |
| KR930701536A (ko) | 1993-06-12 |
| ES2078539T3 (es) | 1995-12-16 |
| US6008282A (en) | 1999-12-28 |
| DE69114010T2 (de) | 1996-06-13 |
| US6346571B1 (en) | 2002-02-12 |
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