KR960001033A - 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지와 도전성 카본 블랙으로 된 열가소성 조성물 - Google Patents

상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지와 도전성 카본 블랙으로 된 열가소성 조성물 Download PDF

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KR960001033A
KR960001033A KR1019950014480A KR19950014480A KR960001033A KR 960001033 A KR960001033 A KR 960001033A KR 1019950014480 A KR1019950014480 A KR 1019950014480A KR 19950014480 A KR19950014480 A KR 19950014480A KR 960001033 A KR960001033 A KR 960001033A
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base resin
polyphenylene ether
carbon black
weight
composition
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KR1019950014480A
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KR100262771B1 (ko
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에버라두스 포투이진 요하네스
후버두스 가브리엘 엠.로메이저 요하네스
바게나 잠
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제이 엘. 샤스킨
제너럴 일렉트릭 캄파니
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20—Conductive material dispersed in non-conductive organic material
    • H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C08L71/126—Polyphenylene oxides modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids

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  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

본 발명은 (a) 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지와 (b) 성분 (a)의 100중량부당 1 내지 7중량부의 도전성 카본 블랙으로 이루어지고, 노치 아이조드 충격 강도가 15KJ/㎡ 이상이며, 체적 저항이 106오옴·㎝ 이하인 열가소성 조성물에 관한 것이다. 본 발명의 조성물은 정전하 분무 코팅법에 의해 용이하게 페인팅될 수 있는 성형제품에 적합하다. 본 발명은 또한 적어도 2단계로 이루어진, 본 발명의 조성물을 제조하기 위한 방법을 제공한다. 제1단계에서 기본 수지를 제조하고, 그 다음 단계에서 이 기본 수지에 카본 블랙을 혼입시킨다. 본 발명은 또한 본 발명의 조성물로 성형된 제품에 관한 것이며 정전하 분무법으로 페인팅되는 그러한 제품에 관한 것이다.

Description

상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지와 도전성 카본 블랙으로 된 열가소성 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a) 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지(base resin)와 (b) 성분 (a)의 100중량부당 1 내지 7중량부의 도전성 카본 블랙으로 이루어지고, 노치 아이조드 충격 강도가 15KJ/㎡ 이상(ISO 180/1A 방법으로 측정)이고, 체적 저항이 106오옴·㎝ 이하(ISO 294에 따라 아령형(dumb-bell) 막대로 성형하고 시편의 양단부를 부러뜨려, 양단부의 부러진 단면에 은 페인트를 칠하고, 이러한 은 페인트를 칠한 부분 사이의 저항을 전기다목적 측정기(multimeter)로 측정하여 얻어진 ISO 3167에 따른 길이 약 70㎜의 다목적 시편 A 타입의 좁고 평행한 부분에서 측정)인 열가소성 조성물.
  2. 제1항에 있어서, 조성물의 용융 점도가 1500S-1및 282℃의 조건에서 ISO 1133에 따라 측정하였을 때 260Pa.5 이하인 것을 특징으로 하는 조성물.
  3. 제1항에 있어서, 상용화된 기본 수지(a)가 (a1) 폴리페닐렌 에테르 수지 10 내지 90중량%[(a1)과 (a2)의 총중량을 기준으로]와, (a2) 폴리아미드 수지 90 내지 10중량%로 이루어진 것임을 특징으로 하는 조성물.
  4. 제1항에 있어서, 상용화제가 말레 산 무수물, 푸마르 산 무수물, 시트르 산, 말 산, 그리고 폴리페닐렌 에테르와 트리멜리트산 무수물 산 클로라이드와의 반응 생성물, 또는 폴리페닐렌 에테르와 말레산 무수물 또는 푸마르 산과의 반응 생성물로 이루어진 군에서 선택되는 것임을 특징으로 하는 조성물.
  5. 제1항에 있어서, 충격 강도 개선제를 함유하는 것을 특징으로 하는 조성물.
  6. 제1항에 있어서, 보강섬유, 안정화제, 염료, 안료, 폴리올레핀, 윤활제들 중 어느 하나의 첨가제를 함유하는 것을 특징으로 하는 조성물.
  7. (1) 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지를 제조하는 공정과 (2) 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지에 도전성 카본블랙을 혼입시키는 공정으로 이루어지는,(a)상용화된 폴리페닐렌에테르-폴리아미드 기본수지와 (b) 성분 (a) 100중량부당 1 내지 7중량부의 도전성 카본 블랙을 함유하는 열가소성 조성물의 제조 방법.
  8. 제7항에 있어서, 도전성 카본 블랙을 기본 수지가 섭씨 300。 이상의 열 용융 상태에 도달한 뒤에 폴리페닐렌에테르 폴리아미드 기본 수지에 혼입시키는 것을 특징으로 하는 방법.
  9. 제7항에 있어서, 10중량% 이상의 카본 블랙을 함유하는 폴리아미드-카본 블랙 마스터 배치의 형태로 카본 블랙을 폴리페닐렌 에테르 폴리아미드 기본 수지에 혼입시키는 것을 특징으로 하는 방법.
  10. 제7항에 있어서, 제1배합 단계에서 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지를 배합하고, 만들어진 이 기본 수지를 도전성 카본 블랙과 함께 제2배합 단계에서 배합하는 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950014480A 1994-06-01 1995-06-01 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지와 도전성 카본 블랙으로 된 열가소성 조성물 KR100262771B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP94108412A EP0685527B1 (en) 1994-06-01 1994-06-01 Thermoplastic composition comprising a compatibilized polyphenylene ether- polyamide base resin and electroconductive carbon black
EP94108412.1 1994-06-01

Publications (2)

Publication Number Publication Date
KR960001033A true KR960001033A (ko) 1996-01-25
KR100262771B1 KR100262771B1 (ko) 2000-08-01

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ID=8215982

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Application Number Title Priority Date Filing Date
KR1019950014480A KR100262771B1 (ko) 1994-06-01 1995-06-01 상용화된 폴리페닐렌 에테르-폴리아미드 기본 수지와 도전성 카본 블랙으로 된 열가소성 조성물

Country Status (7)

Country Link
US (2) US5741846A (ko)
EP (1) EP0685527B1 (ko)
JP (1) JP3151124B2 (ko)
KR (1) KR100262771B1 (ko)
DE (1) DE69401919C5 (ko)
ES (1) ES2098818T3 (ko)
SG (1) SG32347A1 (ko)

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DE69401919T2 (de) 1997-09-18
JP3151124B2 (ja) 2001-04-03
US5741846A (en) 1998-04-21
DE69401919D1 (de) 1997-04-10
US5977240A (en) 1999-11-02
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