KR950704043A - 촉매용 산화아연조성물(zine oxide composition for use in catalysts) - Google Patents

촉매용 산화아연조성물(zine oxide composition for use in catalysts)

Info

Publication number
KR950704043A
KR950704043A KR1019950702264A KR19950702264A KR950704043A KR 950704043 A KR950704043 A KR 950704043A KR 1019950702264 A KR1019950702264 A KR 1019950702264A KR 19950702264 A KR19950702264 A KR 19950702264A KR 950704043 A KR950704043 A KR 950704043A
Authority
KR
South Korea
Prior art keywords
composition
metal
zinc oxide
zinc
compound
Prior art date
Application number
KR1019950702264A
Other languages
English (en)
Other versions
KR100310640B1 (ko
Inventor
내이 배리
Original Assignee
스잔 마가레트 스코트
더 브리티쉬 페트롤륨 캄파니 피.엘.씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 스잔 마가레트 스코트, 더 브리티쉬 페트롤륨 캄파니 피.엘.씨 filed Critical 스잔 마가레트 스코트
Publication of KR950704043A publication Critical patent/KR950704043A/ko
Application granted granted Critical
Publication of KR100310640B1 publication Critical patent/KR100310640B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/72—Copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/825—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with gallium, indium or thallium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

예를 들면, 산화아연과의 스피넬 형태인 3가 또는 4가 금속, 특히 알루미늄 또는 갈륨을 혼합시킴에 의해 산화아연 조성물의 표면적을 증가시키고 가열에 대해 안정화시킨다. 조성물은 바람직하게는 아연 및 상기 금속화합물의 공침 및 소성에 의해 제조한다. 또한, 산화아연 조성물을 Ⅷ족 금속과 혼합할 수 있고, 피셔 트롭쉬방법용 촉매로서 사용할 수도 있다.

Description

촉매용 산화아연 조성물(ZINE OXIDE COMPOSITION FOR USE IN CATALYSTS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (12)

  1. 주기율표의 Ⅷ족 금속 이외의 1이상의 3가 또는 4가 금속을 함유하며, 이 금속은 원자 함량이 아연의 1∼15%이고, 금속 및/또는 산화금속 및/또는 산화금속으로 열적 분해가능한 화합물, 및/또는 산화아연을 사용한 화합물 형태인, 300℃에서 5시간 동안 소성 후 표면적 30㎡/g이상임을 특징으로 하는 산화아연 조성물.
  2. 제1항에 있어서, 금속이 주기율표의 ⅢB족 금속의 하나임을 특징으로 하는 조성물.
  3. 제2항에 있어서, 금속의 일부 이상이 산화아연과의 스피넬(spinel)형태로 존재하는 알루미늄 또는 갈륨임을 특징으로 하는 조성물.
  4. 제1항 내지 제3항 중 어느 한항에 있어서, 300℃에서 5시간 동안 소성 후 표면적 80~150㎡/g임을 특징으로 하는 조성물.
  5. 제1항 내지 제4항 중 어느 한항에 있어서, 아연에 대한 금속의 원자 비율이 1.4~5%임을 특징으로 하는 조성물.
  6. (i)1이상의 침전된 산화아연 및 신화아연으로 열적 분해 가능한 아연 화합물 및 (ii)1이상의 제1항에 정의된 3가 또는 4가 금속 화합물을 함유하고, 이 화합물은 침전된 산화물 또는 금속의 산화물을 열적 분해가능한 화합물이고, 이 금속의 원자 함량은 아연의 1∼15%임을 특징으로 하는 제1항 내지 제5항 중 어느 한항에 따른 조성물용 전구체.
  7. 제6항에 있어서, 산화아연 및 상기 금속의 산화물을 함유하는 공침, 또는 1또는 2모두 산화물 또는 스피넬로 열적 분해가능한 화합물 형태임을 특징으로 하는 전구체.
  8. 제6항 또는 제7항에 따른 전구체를 소성시킴을 특징으로 하는 제1항 내지 제5항 중 어느 한항에 따른 조성물의 제조방법.
  9. 1이상의 천연 금속을 산화아연 조성물에 제1항 내지 제5항 중 어느 한항에 정의된 함량 및 형태로 혼합시켜 제1항 내지 제5항 중 어느 한항에 정의된 조성물을 형성시키는 것으로 구성됨을 특징으로 하는, 300℃에서 5시간 동안 소성 후 표면적 300㎡/g이하인 산화아연 조성물의 표면적을 증가시키는 방법.
  10. 제1항 내지 제5항 중 어느 한항에 정의된 산화아연 조성물과 Ⅷ족 금속 또는 구리를 함유하거나 제8항에 정의된 방법에 의해 제조됨을 특징으로 하는 촉매 조성물.
  11. 제10항에 있어서, 산화아연 조성물상에 코발트를 함침시킴을 특징으로 하는 조성물.
  12. 피셔 트롭쉬 조건하에 환원 활성화시킨 후 Ⅷ족 금속을 함유하고 제10항 또는 제11항에 따르는 촉매조성물상에 일산화탄소 및 수소의 혼합물을 통과시킴을 특징으로 하는 일산화탄소 및 수소의 혼합물을 탄화수소로 전환시키는 피셔 트롭쉬 반응을 수행하는 방법.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019950702264A 1992-12-04 1993-12-02 촉매용산화아연조성물 KR100310640B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB929225372A GB9225372D0 (en) 1992-12-04 1992-12-04 Oxide compositions
GB9225372.3 1992-12-04
PCT/GB1993/002479 WO1994013400A1 (en) 1992-12-04 1993-12-02 Zinc oxide composition for use in catalysts

Publications (2)

Publication Number Publication Date
KR950704043A true KR950704043A (ko) 1995-11-17
KR100310640B1 KR100310640B1 (ko) 2002-02-28

Family

ID=10726120

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019950702264A KR100310640B1 (ko) 1992-12-04 1993-12-02 촉매용산화아연조성물

Country Status (10)

Country Link
EP (1) EP0671976B1 (ko)
JP (1) JP3361330B2 (ko)
KR (1) KR100310640B1 (ko)
CN (1) CN1046438C (ko)
BR (1) BR9307585A (ko)
DE (1) DE69325919T2 (ko)
DK (1) DK0671976T3 (ko)
GB (1) GB9225372D0 (ko)
MX (1) MX9307659A (ko)
WO (1) WO1994013400A1 (ko)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2847018B2 (ja) * 1993-06-25 1999-01-13 株式会社コスモ総合研究所 二酸化炭素還元反応触媒
DE19960428A1 (de) * 1999-12-15 2001-07-05 Cognis Deutschland Gmbh Oxidische Zink-Aluminium-Katalysatoren
EP1358934A1 (en) * 2002-04-25 2003-11-05 Engelhard Corporation Fischer-Tropsch catalyst
GB0409901D0 (en) * 2004-05-04 2004-06-09 Johnson Matthey Plc Catalysts
CN100427380C (zh) * 2005-06-08 2008-10-22 北京化工大学 一种由层状前驱体法制备高比表面积纳米尖晶石的方法
CN100374200C (zh) * 2005-07-27 2008-03-12 新奥新能(北京)科技有限公司 一种合成气转化催化剂及其制备方法
EP1852182A1 (en) * 2006-05-01 2007-11-07 Engelhard Corporation Fischer-Tropsch Catalyst comprising cobalt and zinc oxide
US8404156B2 (en) * 2008-07-03 2013-03-26 Haldor Topsoe A/S Process for operating HTS reactor
JP5552883B2 (ja) * 2010-04-26 2014-07-16 堺化学工業株式会社 低導電性酸化亜鉛粒子、放熱性フィラー、放熱性樹脂組成物、放熱性グリース、放熱性塗料組成物及び低導電性酸化亜鉛粒子の製造方法
CN102000588B (zh) * 2010-11-11 2013-02-27 中国科学院山西煤炭化学研究所 一种改性氧化锌负载钴催化剂及其制备方法
CN103240093A (zh) * 2013-04-23 2013-08-14 神华集团有限责任公司 一种沉淀铁含钕费托催化剂及其制备方法
JP5867658B2 (ja) * 2013-09-06 2016-02-24 堺化学工業株式会社 四角板状酸化亜鉛粒子
KR101640244B1 (ko) 2013-10-30 2016-07-15 주식회사 엘지화학 유기 아연 촉매의 제조 방법 및 폴리알킬렌 카보네이트 수지의 제조 방법
KR101639364B1 (ko) 2013-11-04 2016-07-13 주식회사 엘지화학 유기 아연 촉매
EP3048128B1 (en) 2013-11-18 2018-04-25 LG Chem, Ltd. Method for preparing polyalkylene carbonate resin
EP3816134A4 (en) * 2018-06-06 2021-07-28 JFE Mineral Company, Ltd. ZINC OXIDE POWDER FOR THE MANUFACTURING OF A ZINC OXIDE SINTER BODY, ZINC OXIDE Sintered BODY AND METHOD FOR THE MANUFACTURING THEREOF
GB202206338D0 (en) * 2022-04-29 2022-06-15 Johnson Matthey Plc Stabilised zinc oxide materials

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3997582A (en) * 1975-12-08 1976-12-14 Battelle Development Corporation Process and catalyst for synthesizing a gaseous hydrocarbon mixture having a high methane content from carbon monoxide and hydrogen
DE3009633A1 (de) * 1980-03-13 1981-09-24 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von 2-imidazolinen
DE3210708A1 (de) * 1982-03-24 1983-10-06 Basf Ag Katalysator und seine verwendung zur herstellung von methylmethacrylat
DE3306907A1 (de) * 1983-02-26 1984-08-30 Basf Ag, 6700 Ludwigshafen Katalysator und seine verwendung zur herstellung von methylmethacrylat
GB8623233D0 (en) * 1986-09-26 1986-10-29 British Petroleum Co Plc Syngas conversion catalyst

Also Published As

Publication number Publication date
WO1994013400A1 (en) 1994-06-23
DE69325919T2 (de) 1999-12-02
DK0671976T3 (da) 1999-12-06
JPH08504163A (ja) 1996-05-07
GB9225372D0 (en) 1993-01-27
EP0671976A1 (en) 1995-09-20
DE69325919D1 (de) 1999-09-09
JP3361330B2 (ja) 2003-01-07
CN1046438C (zh) 1999-11-17
KR100310640B1 (ko) 2002-02-28
BR9307585A (pt) 1999-08-31
MX9307659A (es) 1994-07-29
CN1090793A (zh) 1994-08-17
EP0671976B1 (en) 1999-08-04

Similar Documents

Publication Publication Date Title
KR950704043A (ko) 촉매용 산화아연조성물(zine oxide composition for use in catalysts)
US3436358A (en) Reforming with a nickel and nickel oxide catalyst on a magnesium-aluminate-spinel containing support
EP0201670B1 (de) Einrichtung zur Aufbereitung von im wesentlichen aus Methanol bestehenden Flüssigkeiten
KR850002041A (ko) 내열성 촉매 및 그 사용방법
PE12497A1 (es) Catalizador y proceso para la preparacion de hidrocarburos
CA2316844A1 (en) Cobalt based fisher-tropsch catalyst
EP0171640A3 (en) Catalyst composition for ultra high temperature operation
TW351682B (en) Three-way conversion catalysts and method for the preparation thereof three way catalysts
AU556215B2 (en) Catalyst for hydrocarbon preparation
US4153580A (en) CO conversion catalyst
Widjaja et al. Oxidation of methane over Pd-supported catalysts
JPS5676246A (en) Hydrogenation catalyst for heavy hydrocarbon oil and preparation thereof
KR940006923A (ko) 세륨(iv)산화물계 조성물, 그의 제조방법 및 용도
WO2005123250B1 (en) High-activity isomerization catalyst and process
GB1213343A (en) Catalytic reaction of carbon monoxide with steam
US4233180A (en) Process for the conversion of carbon monoxide
JPH01266850A (ja) 内燃機関排ガス浄化触媒及びその製法用途
Machida et al. High temperature catalytic combustion over cation-substituted barium hexaaluminates
JP2009034650A (ja) 炭素酸化物のメタン化触媒、その製造方法およびメタン化方法
AU4394097A (en) Cerium and zirconium oxides, mixed oxides and solid solutions having im proved thermal stability for catalysis of exhaust gas systems and methods of producing
JPS63205142A (ja) 炭化水素を水蒸気リフォーミングするための触媒
AU2008311709B2 (en) Hydrocarbon-reforming catalyst and process for producing synthesis gas using the same
ES2063906T3 (es) Procedimiento para la preparacion de un catalizador o precursor de catalizador adecuado para la preparacion de hidrocarburos a partir de monoxido de carbono e hidrogeno, y dicho catalizador.
US3997477A (en) Catalyst for reforming hydrocarbon fuel
KR930000378A (ko) 제2세륨 산화물 기재 조성물, 이의 제조 방법 및 용도

Legal Events

Date Code Title Description
A201 Request for examination
AMND Amendment
E902 Notification of reason for refusal
AMND Amendment
E601 Decision to refuse application
J201 Request for trial against refusal decision
AMND Amendment
B701 Decision to grant
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20090917

Year of fee payment: 9

LAPS Lapse due to unpaid annual fee