KR950702600A - 생분해성 중합체 조성물(biodegradable polymeric composition) - Google Patents
생분해성 중합체 조성물(biodegradable polymeric composition) Download PDFInfo
- Publication number
- KR950702600A KR950702600A KR1019950700392A KR19950700392A KR950702600A KR 950702600 A KR950702600 A KR 950702600A KR 1019950700392 A KR1019950700392 A KR 1019950700392A KR 19950700392 A KR19950700392 A KR 19950700392A KR 950702600 A KR950702600 A KR 950702600A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- polymer
- polymer composition
- ethylene
- group
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims abstract 28
- 229920000642 polymer Polymers 0.000 claims abstract 34
- 239000011159 matrix material Substances 0.000 claims abstract 14
- 239000000945 filler Substances 0.000 claims abstract 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract 7
- 239000000194 fatty acid Substances 0.000 claims abstract 7
- 229930195729 fatty acid Natural products 0.000 claims abstract 7
- 150000004665 fatty acids Chemical class 0.000 claims abstract 7
- 229920001059 synthetic polymer Polymers 0.000 claims abstract 6
- 229920002472 Starch Polymers 0.000 claims abstract 5
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract 5
- 239000008107 starch Substances 0.000 claims abstract 5
- 235000019698 starch Nutrition 0.000 claims abstract 5
- 229920000151 polyglycol Polymers 0.000 claims abstract 4
- 239000010695 polyglycol Substances 0.000 claims abstract 4
- 229920000223 polyglycerol Polymers 0.000 claims abstract 3
- 150000005846 sugar alcohols Chemical class 0.000 claims abstract 3
- 229920001169 thermoplastic Polymers 0.000 claims abstract 3
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims abstract 2
- 150000001408 amides Chemical class 0.000 claims abstract 2
- 150000002148 esters Chemical class 0.000 claims abstract 2
- -1 aliphatic alcohols Chemical class 0.000 claims 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 10
- 229920001577 copolymer Polymers 0.000 claims 8
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 7
- 239000002253 acid Substances 0.000 claims 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims 4
- 229920000331 Polyhydroxybutyrate Polymers 0.000 claims 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 4
- 150000007513 acids Chemical class 0.000 claims 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims 4
- 239000012948 isocyanate Substances 0.000 claims 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 4
- 239000000178 monomer Substances 0.000 claims 4
- 239000004014 plasticizer Substances 0.000 claims 4
- 239000005015 poly(hydroxybutyrate) Substances 0.000 claims 4
- 229920000728 polyester Polymers 0.000 claims 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 4
- 239000000600 sorbitol Substances 0.000 claims 4
- 235000010356 sorbitol Nutrition 0.000 claims 4
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims 3
- 239000001913 cellulose Substances 0.000 claims 3
- 229920002678 cellulose Polymers 0.000 claims 3
- 150000001261 hydroxy acids Chemical class 0.000 claims 3
- 150000002513 isocyanates Chemical class 0.000 claims 3
- 229920001451 polypropylene glycol Polymers 0.000 claims 3
- 239000011118 polyvinyl acetate Substances 0.000 claims 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims 3
- 235000013772 propylene glycol Nutrition 0.000 claims 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims 3
- UNVGBIALRHLALK-UHFFFAOYSA-N 1,5-Hexanediol Chemical compound CC(O)CCCCO UNVGBIALRHLALK-UHFFFAOYSA-N 0.000 claims 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims 2
- AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims 2
- 239000002202 Polyethylene glycol Substances 0.000 claims 2
- 229920000954 Polyglycolide Polymers 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- 150000002009 diols Chemical class 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- 239000005038 ethylene vinyl acetate Substances 0.000 claims 2
- 239000004715 ethylene vinyl alcohol Substances 0.000 claims 2
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims 2
- 235000011187 glycerol Nutrition 0.000 claims 2
- RZXDTJIXPSCHCI-UHFFFAOYSA-N hexa-1,5-diene-2,5-diol Chemical compound OC(=C)CCC(O)=C RZXDTJIXPSCHCI-UHFFFAOYSA-N 0.000 claims 2
- 229920001519 homopolymer Polymers 0.000 claims 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 2
- 239000004310 lactic acid Substances 0.000 claims 2
- 235000014655 lactic acid Nutrition 0.000 claims 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 2
- 239000011976 maleic acid Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 claims 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims 2
- 229920000747 poly(lactic acid) Polymers 0.000 claims 2
- 229920001610 polycaprolactone Polymers 0.000 claims 2
- 229920006149 polyester-amide block copolymer Polymers 0.000 claims 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 claims 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 claims 2
- 229940070710 valerate Drugs 0.000 claims 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N 1,5-Pentadiol Natural products OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 claims 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 claims 1
- VFFFESPCCPXZOQ-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;oxirane Chemical compound C1CO1.OCC(CO)(CO)CO VFFFESPCCPXZOQ-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims 1
- 229920000945 Amylopectin Polymers 0.000 claims 1
- 229920000856 Amylose Polymers 0.000 claims 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- 239000004970 Chain extender Substances 0.000 claims 1
- 229920002101 Chitin Polymers 0.000 claims 1
- 240000000491 Corchorus aestuans Species 0.000 claims 1
- 235000011777 Corchorus aestuans Nutrition 0.000 claims 1
- 235000010862 Corchorus capsularis Nutrition 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 claims 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims 1
- 239000005058 Isophorone diisocyanate Substances 0.000 claims 1
- 229930195725 Mannitol Natural products 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- 229920000881 Modified starch Polymers 0.000 claims 1
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 claims 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 claims 1
- OORDEDRRTSWSRC-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] acetate Chemical compound CC(=O)OCC(CO)(CO)CO OORDEDRRTSWSRC-UHFFFAOYSA-N 0.000 claims 1
- 239000001361 adipic acid Substances 0.000 claims 1
- 235000011037 adipic acid Nutrition 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 1
- 150000001413 amino acids Chemical class 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 claims 1
- 229920006187 aquazol Polymers 0.000 claims 1
- 229920001400 block copolymer Polymers 0.000 claims 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 150000001735 carboxylic acids Chemical class 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 229920002301 cellulose acetate Polymers 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 claims 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical compound OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 claims 1
- PDXRQENMIVHKPI-UHFFFAOYSA-N cyclohexane-1,1-diol Chemical compound OC1(O)CCCCC1 PDXRQENMIVHKPI-UHFFFAOYSA-N 0.000 claims 1
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 1
- 150000005690 diesters Chemical class 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 1
- 125000005442 diisocyanate group Chemical group 0.000 claims 1
- JXCHMDATRWUOAP-UHFFFAOYSA-N diisocyanatomethylbenzene Chemical compound O=C=NC(N=C=O)C1=CC=CC=C1 JXCHMDATRWUOAP-UHFFFAOYSA-N 0.000 claims 1
- 235000013312 flour Nutrition 0.000 claims 1
- 239000001530 fumaric acid Substances 0.000 claims 1
- 150000004676 glycans Chemical class 0.000 claims 1
- 229920000578 graft copolymer Polymers 0.000 claims 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims 1
- JJTUDXZGHPGLLC-UHFFFAOYSA-N lactide Chemical compound CC1OC(=O)C(C)OC1=O JJTUDXZGHPGLLC-UHFFFAOYSA-N 0.000 claims 1
- 150000002596 lactones Chemical class 0.000 claims 1
- 239000000594 mannitol Substances 0.000 claims 1
- 235000010355 mannitol Nutrition 0.000 claims 1
- 235000012054 meals Nutrition 0.000 claims 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 claims 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 1
- 235000019426 modified starch Nutrition 0.000 claims 1
- 150000002924 oxiranes Chemical class 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229920000573 polyethylene Polymers 0.000 claims 1
- 239000004633 polyglycolic acid Substances 0.000 claims 1
- 239000005056 polyisocyanate Substances 0.000 claims 1
- 229920001228 polyisocyanate Polymers 0.000 claims 1
- 239000004626 polylactic acid Substances 0.000 claims 1
- 229920001282 polysaccharide Polymers 0.000 claims 1
- 239000005017 polysaccharide Substances 0.000 claims 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims 1
- 239000004814 polyurethane Substances 0.000 claims 1
- 229920002635 polyurethane Polymers 0.000 claims 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims 1
- 235000019448 polyvinylpyrrolidone-vinyl acetate copolymer Nutrition 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 150000004756 silanes Chemical class 0.000 claims 1
- 241000894007 species Species 0.000 claims 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- 239000002023 wood Substances 0.000 claims 1
- 239000000811 xylitol Substances 0.000 claims 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 claims 1
- 235000010447 xylitol Nutrition 0.000 claims 1
- 229960002675 xylitol Drugs 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L3/00—Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Biological Depolymerization Polymers (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Abstract
중합체 조성물은 전분 성분, 및 충진제가 분산된 1종이상의 열가소성 합성 중합체 조성물을 함유하는 매트릭스를 함유하며, 매트릭스가 C12∼C22지방산, C12∼C22지방족 알콜, 상기 지방산의 에스테르 및 아미드, 알디톨의 폴리올레판 왁스 및 폴리글리콜 에테르 또는 상기 지방산으로 에스테르화된 폴리글리세롤 및 그의 혼합물로 구성된 군으로부터 선택된 유동화제를 함유하고, 상기 충진제가 매트릭스내에 분산된 유기종의 천연 충진제를 조성물 총중량에 대해 5∼70중량%의 양으로 함유함을 특징으로 한다.
Description
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Claims (18)
- 매트릭스가 C12∼C22지방산, C12∼C22지방족 알콜, 상기 지방산의 에스테르 및 아미드, 알디톨의 폴리올레판 왁스 및 폴리글리콜 에테르 또는 상기 지방산으로 에스테르화된 폴리글리세롤 및 그의 혼합물로 구성된 군으로부터 선택된 유동화제를 함유하며, 충진제가 매트릭스내에 분산된 유기종의 천연 충진제를 조성물 총중량에 대해 5∼70중량%의 양으로 함유함을 특징으로 하는, 전분 성분, 및 충진제가 분산된 1종이상의 열가소성 합성 중합체 성분을 함유하는 매트릭스를 함유하는 중합체 조성물.
- 제1항에 있어서, 충진제가 목분, 호도각분, 셀룰로스, 목면, 황마, 라피아, 쌀겨, 동물 강모, 키틴 및 입상 전분 및 그의 혼합물로 구성된 군으로부터 선택됨을 특징으로 하는 중합체 조성물.
- 제2항에 있어서, 충진제의 평균 크기가 0.5∼500마이크론, 바람직하게는 1.5∼300마이크론임을 특징으로 하는 중합체 조성물.
- 충진제가 실란, 티타네이트 및 지르코네이트로부터 선택된 가교제로 표면처리된 중합체 조성물.
- 제1항 내지 제4항중 어느 한항에 있어서, 전분 성분을 가소제 및/또는 물의 존재하에 열가소성 합성 중합체 성분과 함께 압출-자비함으로써 매트릭스 재료를 수득하는 중합체 조성물.
- 제1항 내지 제5항중 어느 한항에 있어서, 합성 성분이; 폴리비닐 알콜; 폴리비닐 아세테이트; 에틸렌, 프로필렌, 이소부텐 및 스티렌으로부터 선택된 올레핀의 공중합체와 아크릴산, 메타크릴산, 알킬아크릴레이트, 알킬메타크릴레이트, 말레인산, 비닐 알콜 및 비닐 아세테이트로 구성된 군으로부터 선택된 1종이상의 단량체와의 공중합체; 탄소수 2∼24의 히드록시지방족산, 상응하는 락톤 또는 락티드의 단독 중합체 및 공중합체; 이가 카르복실산과 지방족 디올의 폴리에스테르중합체; 다당류의 그래프 공중합체 및 그의 혼합물을 함유하는 중합체 조성물.
- 제6항에 있어서, 매트릭스 재료의 합성 중합체 성분이, 폴리비닐 알콜, 폴리-에틸렌-아크릴산, 폴리-에틸렌-비닐-알콜, 폴리비닐 아세테이트, 폴리-에틸렌-비닐 아세테이트, 폴리-에틸렌-무수-말레인산 및 그의 혼합물로 구성된 군으로부터 선택된 중합체를 함유하는 중합체 조성물.
- 제1항 내지 제6항중 어느 한항에 있어서, 중합체 성분이; B1) 폴리-엡실론-카프로락톤, 및 특히 4,4'-디페닐메탄 디이소시아네이트, 톨루일렌 디이소시아네이트, 이소포론 디이소시아네이트 또는 헥사메틸렌 디이소시아네이트와 같은, 엡실론-카프로락톤과 이소시아네이트의 공중합체; B2) 락트산의 중합체 또는 폴리락티드, 글리콜산의 중합체 또는 폴리글리코리드, 락트산 및 글리콜산의 공중합체; B3) 폴리히드록시부티레이트, 폴리히드록시부티레이트/발레레이트; B4) 특히 폴리에틸렌 및 폴리부틸렌 아디페이트 또는 세바케이트와 같은, 디카르복실산과 지방족 디올 유래의 중합체; B5) 히드록시산의 단독 중합체 및 공중합체, 특히 폴리-엡실론-카르로락톤, 및 1 이상의 하기 성분간에 형성된 블럭 또는 그래프트 공중합체; ⅰ) 셀룰로스 또는 변성 셀룰로스, 예를 들어 카르복시메틸셀룰로스 및 셀룰로스 아세테이트; ⅱ) 아밀로스, 아밀로펙틴, 천연 또는 변성전분; ⅲ) 디올(예:에틸렌 글리콜, 프로필렌 글리콜, 부틸렌 글리콜, 폴리옥시에틸렌 글리콜, 폴리옥시프로필렌 글리콜, 네오펜틸 글리콜, 1,4-부탄디올, 시클로헥산디올), 및 말단 디올기를 갖는 폴리에스테르의 예비중합체 또는 중합체로부터 선택된 화합물과 하기로부터 선택된 단량체와의 반응으로부터 생성된 중합체; -이가 방향족 또는 지방족 이소시아네이트, -이가 방향족 또는 지방족 에폭시드, -디카르복실산 지방족산(예:말론산, 숙신산, 말레인산, 푸마르산, 이타콘산, 글루타르산, 아디프산, 피멜산, 수베르산, 아젤산 및 세바크산), -디카르복실산 시클로지방족산(예:시클로헥산디카르복실산, 2,2,2-디시 클로옥탄디카르복실산) 또는 -방향족산 또는 무수물(예:프탈산) ⅳ) 폴리우레탄, 디이소시아네이트 및 아미노알콜 유래의 폴리아미드-우레탄, 폴리아미드, 디카르복실산 및 아미노알콜 유래의 폴리에스테르-아미드, 아미노산 및 글리콜의 디에스테르 유래의 폴리에스테르-요소, ⅴ) 폴리히드록시화 중합체(예:전체적으로 또는 부분적으로 가수분해된, 폴리비닐 알콜, 에틸렌-비닐 알콜 공중합체), ⅵ) 폴리비닐 피롤리돈, 폴리비닐 피롤리돈-비닐 아세테이트 공중합체 및 폴리에틸옥사졸린, B6) 히드록시산의 단량체, 및 이소시아네이트, 에폭시드, 페닐에스테르 및 지바족 카르보네이트와 같은 사슬 연장제로부터 수득된 폴리에스테르; B7) 부분 가교결합된 히드록시산의 단량체와 트리멜리트산, 피로멜리트산, 폴리이소시아네이트 및 폴리에폭시드와 같은 다가산으로부터 수득된 폴리에스테르로부터 선택된 1종이상의 중합체를 함유하는 중합체 조성물.
- 제6항에 있어서, 매트릭스 재료의 합성 중합체 성분이; A) 폴리비닐 알콜, 폴리-에틸렌-비닐 알콜, 폴리-에틸렌-아크릴산, 폴리-에틸렌-비닐 아세테이트, 폴리비닐 아세테이트로 구성된 군으로부터 선택된 1종이상의 중합체, 및 B) 폴리-엡실론-카프로락톤, 엡실론-카프로락톤의 공중합체, 폴리락트산, 폴리글리콜산, 엡실론-카프로락톤과 이소시아네이트의 공중합체, 폴리히드록시부티레이트, 폴리히드록시부티레이트/발레레이트로 구성된 군으로부터 선택된 1종이상의 중합체를 (A)군의 중합체 및 (B)군의 중합체간의 1:4∼4:1로 함유하는 중합체 조성물.
- 제1항 내지 제6항중 어느 한항에 있어서, 글리세린, 에틸렌 글리콜, 프로필렌 글리콜, 에틸렌 디글리콜, 프로필렌 디글리콜, 에틸렌 트리글리콜, 프로필렌 트리글리콜, 폴리에틸렌 글리콜, 폴리프로필렌 글리콜, 1,2-프로판디올, 1,3-프로판디올, 1,2-, 1,3-, 1,4-부탄디올, 1,5-펜타디올, 1,6-, 1,5-헥산디올, 1,2,6-, 1,3,5-헥산트리올, 네오펜틸 글리콜, 트리메틸올 프로판, 펜타에리트리톨, 솔르비톨 및 그의 아세테이트, 에톡실레이트 및 프로폭실레이트 유도체로 구성된 군으로부터 선택된 가소제를 함유하는 중합체 조성물.
- 제10항에 있어서, 가소제가, 소르비톨 에톡실레이트, 글리세롤 에톡실레이트, 펜타에리트리톨 에톡실레이트, 소르비톨 아세테이트, 펜타에리트리톨 아세테이트로 구성된 군으로부터 선택된 중합체 조성물.
- 제9항에 있어서, 가소제가 매트릭스 재료의 중량에 대해 1∼50중량%, 바람직하게는 5∼25중량%의 양으로 존재하는 중합체 조성물.
- 제1항 내지 제12항중 어느 한항에 있어서, 중합체 성분 및 전분 성분이 매트릭스 재료내에 1:4∼4:1의 중량비로 존재하는 중합체 조성물.
- 제1항 내지 제13항중 어느 한항에 있어서, 매트릭스 재료가 유동화제로서 알디톨의 폴리글리콜 에테르, 또는 C12∼C22지방산으로 에스테르화된 폴리글리세롤을 함유하는 중합체 조성물.
- 제14항에 있어서, 유동화제의 알디톨이 소르비톨, 크실리톨 및 만니톨로 구성된 군으로부터 선택되는 중합체 조성물.
- 제14항에 있어서, 유동화제의 폴리글리콜이 폴리에틸렌 글리콜 및 폴리프로필렌 글리콜로 구성된 군으로부터 선택되는 중합체 조성물.
- 제1항 내지 제16항중 어느 한 항에 있어서, 유동화제가 매트릭스 재료의 중량에 대해 0.1∼10중량%의 양으로 존재하는 중합체 조성물.
- 제1항 내지 제17항중 어느 한항의 조성물로 제조된 성형품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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ITTO920672A IT1256914B (it) | 1992-08-03 | 1992-08-03 | Composizione polimerica biodegradabile. |
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1992
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- 1993-06-14 AU AU44186/93A patent/AU675954B2/en not_active Ceased
- 1993-06-14 WO PCT/EP1993/001530 patent/WO1994003543A1/en active IP Right Grant
- 1993-06-14 DK DK93914663T patent/DK0652910T3/da active
- 1993-06-14 AT AT93914663T patent/ATE172483T1/de not_active IP Right Cessation
- 1993-06-14 ES ES93914663T patent/ES2124313T3/es not_active Expired - Lifetime
- 1993-06-14 EP EP93914663A patent/EP0652910B1/en not_active Expired - Lifetime
- 1993-06-14 KR KR1019950700392A patent/KR100272484B1/ko not_active IP Right Cessation
- 1993-06-14 JP JP50492094A patent/JP3549203B2/ja not_active Expired - Fee Related
- 1993-06-14 CA CA002141562A patent/CA2141562C/en not_active Expired - Fee Related
- 1993-06-14 US US08/362,589 patent/US5874486A/en not_active Expired - Lifetime
- 1993-06-14 DE DE69321730T patent/DE69321730T2/de not_active Expired - Lifetime
- 1993-06-22 TW TW082104925A patent/TW492995B/zh not_active IP Right Cessation
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20010086308A (ko) * | 2000-01-14 | 2001-09-10 | 임현덕 | 종이를 포함하는 사출성형 조성물 및 그의 제조방법 |
US9382385B2 (en) | 2012-12-06 | 2016-07-05 | Lg Chem, Ltd. | Lactide copolymer, and resin composition and film comprising same |
US9382386B2 (en) | 2012-12-06 | 2016-07-05 | Lg Chem, Ltd | Lactide copolymer, method for preparing same, and resin composition comprising same |
Also Published As
Publication number | Publication date |
---|---|
HK1013302A1 (en) | 1999-08-20 |
IT1256914B (it) | 1995-12-27 |
DE69321730D1 (de) | 1998-11-26 |
JPH07509514A (ja) | 1995-10-19 |
ATE172483T1 (de) | 1998-11-15 |
ITTO920672A1 (it) | 1994-02-03 |
AU675954B2 (en) | 1997-02-27 |
ITTO920672A0 (it) | 1992-08-03 |
EP0652910A1 (en) | 1995-05-17 |
ES2124313T3 (es) | 1999-02-01 |
WO1994003543A1 (en) | 1994-02-17 |
US5874486A (en) | 1999-02-23 |
TW492995B (en) | 2002-07-01 |
DK0652910T3 (da) | 1999-06-28 |
AU4418693A (en) | 1994-03-03 |
DE69321730T2 (de) | 1999-05-27 |
EP0652910B1 (en) | 1998-10-21 |
KR100272484B1 (ko) | 2000-11-15 |
CA2141562C (en) | 2004-03-30 |
JP3549203B2 (ja) | 2004-08-04 |
CA2141562A1 (en) | 1994-02-17 |
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