KR950032534A - Uv광으로 가교시킬 수 있는 고형 에폭시 수지 조성물 - Google Patents

Uv광으로 가교시킬 수 있는 고형 에폭시 수지 조성물 Download PDF

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Publication number
KR950032534A
KR950032534A KR1019950002554A KR19950002554A KR950032534A KR 950032534 A KR950032534 A KR 950032534A KR 1019950002554 A KR1019950002554 A KR 1019950002554A KR 19950002554 A KR19950002554 A KR 19950002554A KR 950032534 A KR950032534 A KR 950032534A
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South Korea
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polyglycidyl
composition
solid
oligomeric
component
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KR1019950002554A
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KR100358814B1 (ko
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핀터 위르겐
고띠 필립-기욤
뫽클리 알프레트
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베르너 발데크
시바-가이기 아게
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/687—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing sulfur

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 (a)올리고머성, 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르 및 이 올리고머성 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르를 포함하는 혼합물이 35°C 보다 높은 유리 전이 온도(Tg) 를 갖는, 고형올리고머성, 양이온적으로 중합 가능한 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르, 고형 올리고머성, 양이온적으로 중합가능한 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르 및 액성 또는 결정질 단위체 모노-, 디-또는 폴리에폭시 수지의 혼합물, 또는 고형 올리고머성, 양이온적으로 중합가능한 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르 및 환형아세탈의 혼합물, (b)다관능성 친핵성 연쇄 전달제, (c)성분 (a) 를 기제로 하여, 양이온성 중합용 광개시제0.05내지3중량% 및, 임의 성분으로서 (d)1차, 2차 또는 3차 질소원자를 포함하는 화합물을 함유하지 않거나 또는 몰 농도를 기준으로 단지 성분(c)의 50%이하의 양으로 이러한 화합물을 함유하는 분말 피복 조성물용 종래 부가제를 포함하는 고형 조성물에 관한 것이다.

Description

UV광으로 가교시킬 수 있는 고형 에폭시 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. (a)올리고머성, 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르 및 이 올리고머성 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르를 포함하는 혼합물이 35°C보다 높은 유리 전이 온도(TG)를 갖는, 고형 올리고머성, 양이온적으로 중합가능한 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르, 고형 올리고머성, 양이온적으로 중합가능한 폴리글리시딜에테르 또는 폴리글리시딜 에스테르 및 액성 또는 결정질 단위체 모노-,디- 또는 폴리에폭시 수지의 환합물, 또는 고형 올리고머성, 양이온적으로 중합가능한 폴리글리시딜 에테르 또는 폴리글리시딜 에스테르 및 환형 아세탈의 혼합물, (b)다관능성 친핵성 연쇄 전달제, (c)성분(a)를 기제로 하여, 양이온성 중합용 광개시제 0.05내지 3중량% 및, 임의 성분으로서 (d)1차, 2차 또는 3차 질소원자를 포함하는 화합물을 함유하지 않거나 또는 몰 농도를 기준으로 단지 성분(c)의 50%이하의 양으로 이러한 화합물을 함유하는, 분말 피복 조성물용 종래 부가제를 포함하는 고형 조성물.
  2. 제1항에 있어서, 분자 내에 1차, 2차 또는 3차 질소원자를 포함하는 화합물을 함유하지 않는 조성물.
  3. 제1항에 있어서, 성분(a) 가 고형 올리고머성, 폴리글리시딜 에테르 또는 롤리글리시딜 에스테르 또는 고형 에폭시-페놀 노볼락 또는 에폭시-크레졸 노볼락인 조성물.
  4. 제1항에 있어서,성분(a) 가 고형 올리고머성 폴리글리시딜 에테르인 조성물.
  5. 제1항에 있어서, 성분(b) 가 1차 지방족 폴리올인 조성물.
  6. 제1항에 있어서, 성분(c) 가 술포늄 염인 조성물.
  7. 제1항에 있어서, 성분(a) 가 트리아릴술포늄 염인 조성물.
  8. 제1항에 있어서, 성분(c) 가 트리아릴술포늄 헥사플루오로포스페이트 또는 트리아릴술포늄 헥사플루오로 안티모네이트인 조성물.
  9. 제1항에 따른 고형 조성물로 구성된 분말 피복 조성물.
  10. 제1항에 따른 고형 조성물의 분말을 기재 상에 정전기적으로 분무하고, 열을 가해 판을 용융시킨 후 UV 방사선에 의해, 필요하면 가열하여 가교시킴으로써 형성되는 가교된 피막.
  11. 제10항에 있어서,IR방사선에 의해 효과적으로 가열되는 피막.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950002554A 1994-02-09 1995-02-08 Uv광으로가교시킬수있는고형에폭시수지조성물 KR100358814B1 (ko)

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CH94-0/388 1994-02-09
DE94-0/388 1994-02-09
CH38894 1994-02-09

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KR950032534A true KR950032534A (ko) 1995-12-22
KR100358814B1 KR100358814B1 (ko) 2003-03-19

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Country Link
US (1) US6001428A (ko)
EP (1) EP0667381B1 (ko)
JP (1) JP3484552B2 (ko)
KR (1) KR100358814B1 (ko)
BR (1) BR9500473A (ko)
DE (1) DE59507589D1 (ko)
ES (1) ES2141320T3 (ko)
TW (1) TW307791B (ko)

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Also Published As

Publication number Publication date
JP3484552B2 (ja) 2004-01-06
EP0667381A2 (de) 1995-08-16
TW307791B (ko) 1997-06-11
EP0667381A3 (de) 1996-03-20
BR9500473A (pt) 1995-09-26
DE59507589D1 (de) 2000-02-17
JPH07252344A (ja) 1995-10-03
KR100358814B1 (ko) 2003-03-19
EP0667381B1 (de) 2000-01-12
ES2141320T3 (es) 2000-03-16
US6001428A (en) 1999-12-14

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