KR950008456A - 데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도 - Google Patents

데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도 Download PDF

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KR950008456A
KR950008456A KR1019940023936A KR19940023936A KR950008456A KR 950008456 A KR950008456 A KR 950008456A KR 1019940023936 A KR1019940023936 A KR 1019940023936A KR 19940023936 A KR19940023936 A KR 19940023936A KR 950008456 A KR950008456 A KR 950008456A
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mixture
decyl alcohol
isomeric
isomeric decyl
reaction
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KR1019940023936A
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바르만 헬무트
그렙 볼프강
하이만스 페터
랍페 페터
뮐러 토마스
스차마이타트 위르겐
비부스 에른스트
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페터스, 라이첼트
훽스트 아크티엔겔샤프트
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Publication of KR950008456A publication Critical patent/KR950008456A/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016—Plasticisers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

이성체성 데실 알콜 혼합물을, 알데히드 혼합물을 형성하기 위한 1-부텐- 및 2-부텐-함유 혼합물의 2단계 하이드로포밀화 반응, 분리 및 혼합된 알데히드 혼합물의 축합으로 알돌 혼합물 형성 및 알돌 혼합물의 분리 및 수소화에 의해 제조한다.
하이드로포밀화반응의 제1단계는 물에 용해된 로듐 촉매 존재하에, 제2단계는 반응매질에 균질하게 용해된 코발트 축매 존재하에 수행된다. 이성체성 데실 알콜 혼합물을 프탈산과 에스테르화시키는 경우 가소제로 사용되는 이성체성 데실 프탈레이트 혼합물이 수득된다.

Description

데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 제1단계는 촉매로서 착물화된 수용성 포스핀을 함유하는 로듐 화합물을 사용하여 온도 70 내지 150℃ 및 압력 0.4 내지 30MPa에서 비균질 반응계중에서, 제2단계는 촉매로서 코발트 화합물의 존재하에 온도 130 내지 180℃ 및 압력 8 내지 30MPa에서 균질상중에서 반응을 수행하여 알데히드 혼합물을 형성하기 위한 1-부텐- 및 2-부텐-함유 혼합물의 2단계 하이드로포밀화 반응, 하이드로포밀화 반응단계로부터 생성된 알데히드 혼합물의 분리 및 혼합, 혼합된 알데히드 혼합물의 축합으로 알돌 혼합물 형성 및 알돌 혼합물의 분리 및 수소화에 의해 수득되는 이성체성 데실 알콜 혼합물.
  2. 제1항에 있어서, 제1하이드로포밀화반응 단계가 100 내지 130℃ 및 1 내지 10MPa의 압력에서 수행되는 이성체성 데실 알콜 혼합물.
  3. 제1항 또는 제2항에 있어서, 제1하이드로포밀화 반응 단계가 수성 촉매 용액을 기준으로 20 내지 1000중량ppm, 바람직하게는 50 내지 500pm의 로듐 농도에서 수행되는 이성체성 데실 알콜 혼합물.
  4. 제1항 내지 제3항중의 어느 한 항에 있어서, 제1하이드로포밀화반응 단계에서 수용성 포스핀이 로듐 몰당 4 내지 100몰 사용되는 이성체성 데실 알콜 혼합물.
  5. 제1항 내지 제4항중의 어느 한 항에 있어서, 상전이 시약이 제1하이드로포밀화반응 단계에서 수성 촉매 용액에 가해지는 이성체성 데실 알콜 혼합물.
  6. 제1항 내지 제5항중의 어느 한 항에 있어서, 제2하이드로포밀화반응 단계가 제2반응 단계내로 도입되는 부텐을 기준으로 0.1 내지 3중량%, 바람직하게는 0.6 내지 1중량%의 코발트 농도에서 수행되는 이성체성 데실 알콜 혼합물.
  7. 프탈산 또는 프탈산 무수물과 제1항 내지 제6항중의 어느 한 항에 따른 이성체성 데실 알콜 혼합물과의 에스테르화반응에 의해 수득되는 이성체성 디데실 프탈레이트 혼합물.
  8. 제7항에 따른 이성체성 디데실 프탈레이트 혼합물의 가소제로서의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940023936A 1993-09-30 1994-09-23 데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도 KR950008456A (ko)

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DE19934333324 DE4333324A1 (de) 1993-09-30 1993-09-30 Decylalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
DEP4333324.9 1993-09-30

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US (2) US5463147A (ko)
EP (1) EP0646563B1 (ko)
JP (1) JP2519399B2 (ko)
KR (1) KR950008456A (ko)
CN (1) CN1101358A (ko)
AU (1) AU7430494A (ko)
BR (1) BR9403828A (ko)
CA (1) CA2132674A1 (ko)
DE (2) DE4333324A1 (ko)
DK (1) DK0646563T3 (ko)
ES (1) ES2127323T3 (ko)
PL (1) PL305158A1 (ko)
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PL305158A1 (en) 1995-04-03
US5463147A (en) 1995-10-31
ZA947457B (en) 1995-05-15
US5462986A (en) 1995-10-31
CA2132674A1 (en) 1995-03-31
CN1101358A (zh) 1995-04-12
EP0646563A1 (de) 1995-04-05
AU7430494A (en) 1995-04-13
JP2519399B2 (ja) 1996-07-31
DK0646563T3 (da) 1999-08-16
BR9403828A (pt) 1995-06-06
JPH07165642A (ja) 1995-06-27
EP0646563B1 (de) 1998-12-09
DE59407436D1 (de) 1999-01-21
DE4333324A1 (de) 1995-04-06
ES2127323T3 (es) 1999-04-16

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