KR930019605A - 데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도 - Google Patents
데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도 Download PDFInfo
- Publication number
- KR930019605A KR930019605A KR1019930004235A KR930004235A KR930019605A KR 930019605 A KR930019605 A KR 930019605A KR 1019930004235 A KR1019930004235 A KR 1019930004235A KR 930004235 A KR930004235 A KR 930004235A KR 930019605 A KR930019605 A KR 930019605A
- Authority
- KR
- South Korea
- Prior art keywords
- decyl alcohol
- mixture
- hydroformylation
- butadiene
- isomeric
- Prior art date
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
- C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
- C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
본 발명은 부타디엔을 하이드로포밀화시켜 알데하이드 혼합물을 수득하고, 이 반응으로부터 분리한 알데하이드 혼합물을 축합시켜 알돌 혼합물을 형성시킨 다음 이 알돌 혼합물을 분리 및 수소화시켜 이성체성 데실알콜의 혼합물을 수득하는 것에 관한 것이다. 프탈산을 사용하여 이성체성 데실 알콜 혼합물을 에스테르화하면 가소제로서 사용되는 이성체성 데실 프탈레이트가 수득된다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (10)
- 부타디엔을 하이드로포밀화시켜 알데하이드 혼합물을 수득하고, 반응 생성물로부터 생성된 알데하이드 혼합물을 분리한 다음,알데하이드혼합물을 축합시켜 알돌 혼합물을 형성시키고, 이 알돌 혼합물을 분리 및 수소화 시켜 이성체성 데실 알콜의 혼합물을 형성시킴으로써 수득한 이성체성 데실 알콜 혼합물.
- 제1항에 있어서, 부타디엔의 하이드로포밀화를 로듐촉매 존재하에 수행함을 특징으로 하는 이성체성 데실알콜 혼합물.
- 제1항 또는 제2항에 있어서, 부타디엔의 하이드로 포르밀화를 촉매로서 물 및 수용성 로듐-포스핀 착물존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
- 제3항에 있어서, 부타다엔의 하이드로포밀화를 리간드로서 설폰화된 포스핀을 함유하는 촉매인 수용성 로듐착물 존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
- 제3항 또는 제4항에 있어서, 부타디엔의 하이드로포밀화를 리간드로서 설폰화된 알킬-또는 아릴포스핀을 함유하는 수용성 로듐 착물 존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
- 제3항 또는 제4항에 있어서, 부타디엔의 하이드로포밀화를 리간드로서 설폰화된 아릴알킬-또는 알킬아릴디 포스핀을 함유하는 촉매인 수용성 로듐 착물 존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
- 제3항 내지 제6항중 어느 한 항 이상에 있어서, 부타디엔의 하이드로포밀화를 촉매로서 물 및 수용성 로듐-포스핀 착물 존재하에 70내지 150℃의 온도에서 및 0.4내지 30MPa의 압력하에, 수성상 대 유기상의 용적비를 0.1내지 10:1로 하고, 수성 촉매 용액중 로듐 농도를 20 내지 2000ppm로 하여 로륨 몰당 4내지 100몰의 포스핀을 사용하여 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
- 제9항 내지 제7항중 어느 한 항 이상에 있어서, 수성 촉매 용액이 상이동 시약을 함유하는 이성체성 데실 알콜 혼합물.
- 프탈산 또는 프탈살 무수물을 제1항 내지 제8항중 어느 한 항 이상에서 청구된 이성체성 데실 알콜 혼합물로 에스테르화시켜 수득한 이성체성 디데실 프탈레이트 혼합물.
- 제9항에서 청구된 이성체성 디데실 프탈레이트 혼합물의 가소제로서의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19924210028 DE4210028A1 (de) | 1992-03-27 | 1992-03-27 | Decyclalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher |
DEP4210028.3 | 1992-03-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR930019605A true KR930019605A (ko) | 1993-10-18 |
KR100290220B1 KR100290220B1 (ko) | 2001-05-15 |
Family
ID=6455191
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930004235A KR100290220B1 (ko) | 1992-03-27 | 1993-03-19 | 데실 알콜 혼합물의 제조 방법 및 이에 의해 제조되는 데실 알콜 혼합물로부터 수득가능한 가소제로서의 이성체성 디데실 프탈레이트 혼합물 |
Country Status (16)
Country | Link |
---|---|
US (1) | US5382716A (ko) |
EP (1) | EP0562450B1 (ko) |
JP (2) | JPH0739360B2 (ko) |
KR (1) | KR100290220B1 (ko) |
CN (2) | CN1039706C (ko) |
AT (1) | ATE174317T1 (ko) |
AU (1) | AU659293B2 (ko) |
BR (1) | BR9301282A (ko) |
CA (1) | CA2092040A1 (ko) |
DE (2) | DE4210028A1 (ko) |
DK (1) | DK0562450T3 (ko) |
ES (1) | ES2127227T3 (ko) |
MX (1) | MX9301571A (ko) |
SG (1) | SG44987A1 (ko) |
TW (1) | TW241286B (ko) |
ZA (1) | ZA931988B (ko) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4221472A1 (de) * | 1992-06-30 | 1994-01-05 | Hoechst Ag | Gemische isomerer Decylalkohole, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher |
DE4330489A1 (de) * | 1993-09-09 | 1995-03-16 | Hoechst Ag | Verfahren zur Hydroformylierung von Butadien-1,3 |
DE19532394A1 (de) * | 1995-09-02 | 1997-03-06 | Hoechst Ag | Verfahren zur Herstellung von Pentenalen |
US5925754A (en) * | 1997-04-15 | 1999-07-20 | Union Carbide Chemicals & Plastics Technology Corporation | Epsilon caprolactam compositions |
US5962680A (en) * | 1997-04-15 | 1999-10-05 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for producing epsilon caprolactams |
US5886236A (en) * | 1997-04-15 | 1999-03-23 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing aldehyde acid salts |
DE19956410A1 (de) | 1999-11-24 | 2001-05-31 | Oxeno Olefinchemie Gmbh | Verfahren zur Durchführung von Aldolkondensationen |
US6982295B2 (en) * | 2003-06-16 | 2006-01-03 | Exxonmobil Chemical Patents Inc. | Plasticizers from less branched alcohols |
US6969735B1 (en) | 2004-05-23 | 2005-11-29 | Exxonmobil Chemical Patents Inc. | Plasticizers from less branched decyl alcohols |
US6969736B1 (en) | 2004-05-27 | 2005-11-29 | Exxonmobil Chemical Patents Inc. | Plasticizers from less branched nonyl alcohols |
CN101427678B (zh) * | 2008-07-05 | 2012-05-09 | 山西农业大学 | 一种植物源杀菌剂及其人工合成方法 |
US10633053B1 (en) | 2013-03-15 | 2020-04-28 | Kurt Manufacturing Company, Inc. | Axle arrangement for a bicycle |
ES2701843T3 (es) * | 2015-11-19 | 2019-02-26 | Evonik Degussa Gmbh | Influencia de la viscosidad de mezclas de ésteres basadas en n-buteno mediante empleo selectivo de eteno en la obtención de productos previos de ésteres |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4248802A (en) * | 1975-06-20 | 1981-02-03 | Rhone-Poulenc Industries | Catalytic hydroformylation of olefins |
DE3168398D1 (en) * | 1980-11-20 | 1985-02-28 | Monsanto Co | Preparation of plasticizer alcohols from propylene-butene mixtures |
US4426542A (en) * | 1981-04-22 | 1984-01-17 | Monsanto Company | Synthesis of plasticizer and detergent alcohols |
GB8430223D0 (en) * | 1984-11-30 | 1985-01-09 | Exxon Research Engineering Co | Hydroformylation of olefins |
DE3542595A1 (de) * | 1985-12-03 | 1987-06-04 | Basf Ag | Verfahren zur herstellung von c(pfeil abwaerts)3(pfeil abwaerts)-c(pfeil abwaerts)2(pfeil abwaerts)(pfeil abwaerts)5(pfeil abwaerts)-alkanolen |
JPS6416092A (en) * | 1987-07-09 | 1989-01-19 | Matsushita Electric Ind Co Ltd | Optical unit for video camera |
US4969953A (en) * | 1988-10-25 | 1990-11-13 | Mitsubishi Kasei Corporation | Alcohol mixture for plasticizer and method for producing the same |
JPH077775B2 (ja) * | 1989-11-10 | 1995-01-30 | 三菱電機株式会社 | リードフレーム搬送方法およびその装置 |
-
1992
- 1992-03-27 DE DE19924210028 patent/DE4210028A1/de not_active Withdrawn
-
1993
- 1993-02-17 TW TW82101092A patent/TW241286B/zh active
- 1993-03-18 ES ES93104422T patent/ES2127227T3/es not_active Expired - Lifetime
- 1993-03-18 EP EP19930104422 patent/EP0562450B1/de not_active Expired - Lifetime
- 1993-03-18 AT AT93104422T patent/ATE174317T1/de not_active IP Right Cessation
- 1993-03-18 SG SG1996011149A patent/SG44987A1/en unknown
- 1993-03-18 DK DK93104422T patent/DK0562450T3/da active
- 1993-03-18 DE DE59309198T patent/DE59309198D1/de not_active Expired - Fee Related
- 1993-03-19 KR KR1019930004235A patent/KR100290220B1/ko not_active IP Right Cessation
- 1993-03-19 CA CA 2092040 patent/CA2092040A1/en not_active Abandoned
- 1993-03-19 JP JP6046093A patent/JPH0739360B2/ja not_active Expired - Lifetime
- 1993-03-19 MX MX9301571A patent/MX9301571A/es not_active IP Right Cessation
- 1993-03-19 ZA ZA931988A patent/ZA931988B/xx unknown
- 1993-03-23 US US08/036,026 patent/US5382716A/en not_active Expired - Fee Related
- 1993-03-24 BR BR9301282A patent/BR9301282A/pt not_active IP Right Cessation
- 1993-03-25 CN CN93103474A patent/CN1039706C/zh not_active Expired - Fee Related
- 1993-03-26 AU AU35453/93A patent/AU659293B2/en not_active Ceased
-
1995
- 1995-08-01 CN CN95108641A patent/CN1122326A/zh active Pending
-
1998
- 1998-11-18 JP JP10327977A patent/JPH11222450A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
US5382716A (en) | 1995-01-17 |
MX9301571A (es) | 1993-11-01 |
EP0562450A3 (en) | 1994-11-23 |
AU3545393A (en) | 1993-09-30 |
AU659293B2 (en) | 1995-05-11 |
CN1122326A (zh) | 1996-05-15 |
DE59309198D1 (de) | 1999-01-21 |
CN1039706C (zh) | 1998-09-09 |
ATE174317T1 (de) | 1998-12-15 |
EP0562450B1 (de) | 1998-12-09 |
SG44987A1 (en) | 1997-12-19 |
TW241286B (ko) | 1995-02-21 |
DK0562450T3 (da) | 1999-08-16 |
JPH0672924A (ja) | 1994-03-15 |
ZA931988B (en) | 1993-10-19 |
KR100290220B1 (ko) | 2001-05-15 |
EP0562450A2 (de) | 1993-09-29 |
DE4210028A1 (de) | 1993-09-30 |
CA2092040A1 (en) | 1993-09-28 |
CN1076936A (zh) | 1993-10-06 |
JPH11222450A (ja) | 1999-08-17 |
JPH0739360B2 (ja) | 1995-05-01 |
ES2127227T3 (es) | 1999-04-16 |
BR9301282A (pt) | 1993-10-05 |
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