KR940009270A - 이온 경화성 엘라스토머 중합체 조성물 - Google Patents
이온 경화성 엘라스토머 중합체 조성물 Download PDFInfo
- Publication number
- KR940009270A KR940009270A KR1019930021135A KR930021135A KR940009270A KR 940009270 A KR940009270 A KR 940009270A KR 1019930021135 A KR1019930021135 A KR 1019930021135A KR 930021135 A KR930021135 A KR 930021135A KR 940009270 A KR940009270 A KR 940009270A
- Authority
- KR
- South Korea
- Prior art keywords
- mol
- vdf
- copolymer
- composition
- general formula
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract 10
- 229920001971 elastomer Polymers 0.000 title 1
- 239000000806 elastomer Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
- 229920001973 fluoroelastomer Polymers 0.000 claims abstract 10
- 150000001336 alkenes Chemical class 0.000 claims abstract 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract 2
- -1 triazine compound Chemical class 0.000 claims abstract 2
- 239000000178 monomer Substances 0.000 claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- 229920001577 copolymer Polymers 0.000 claims 3
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims 2
- 239000003431 cross linking reagent Substances 0.000 claims 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 2
- 108010000020 Platelet Factor 3 Proteins 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3442—Heterocyclic compounds having nitrogen in the ring having two nitrogen atoms in the ring
- C08K5/3462—Six-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
60몰%미만의 VDF를 함유하는 플루오로엘라스토머 및 수소화올레핀을 함유하는 플루오로엘라스토머로부터 선택된 VDF-함유 플루오로엘라스토머의 이온경화는, 촉진제로서 하기 일반식(I) 또는 (II)의 트리아진 화합물을 사용함으로써 개량된다:
[식중, R은 H 또는 C1~C4알킬이고;R´는 R 또는 벤질, 아릴알킬이고;X는 Cl, Br, I, 비스페녹시기 또는 O-CH2Rf-CH2R?? 2(Rf는 퍼플루오로옥시알킬렌 사슬이고 R는 -OH 또는 -O-이다)이다]. 특허청구하고자 하는 것은 상기 촉진제를 함유하는 플루오로엘라스토머 조성물이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (8)
- 이온경화성이며 경화 촉진제로 하기 일반식(I)의 화합물 및 하기 일반식(II)의 화합물의 1종 이상을 함유하고, a)60몰% 미만의 VDF를 함유하며 수소화올레핀 유래 단량체 단위를 함유하지 않는 공중합체 및 b)수소화 올레핀 유래 단량체 단위를 함유하는 공중합체로 부터 선택된, VDF 단량체 단위를 함유하는 플루오로엘라스토머 공중합체 기재 조성물:[식중, R은 H 또는 탄소수 1~4의 알킬이다.][식중, R은 H 또는 탄소수 1~4의 알킬이고;R´는 H, 탄소수 1~4의 알킬, 벤질, 또는 탄소수 7~11의 아릴알킬이며;X는 Cl, Br, I, 일반식의 비스페녹시기, 또는 일반식 -CH??2-Rf-CH2-R2(식중, Rf는 평균 분자량이 350~2,000이고 일반식 (CF2CF2O-)및/또는 () 및/또는 (-CF2O)및/또는 () 및/또는 ()의 퍼플루오로옥시알킬렌 단위를 함유하는 퍼플루오로폴리옥시알킬렌 사슬이며;R2는 -OH 또는 -O-이다)의 기이거나 X는 식 BF4 -, PF3 --, ZnCl4- 또는 CdCl4-의 반대이온일 수 있다]
- 제1항에 있어서, 플루오로엘라스토머 공중합체가, (a)형이며, VDF 유래 단량체 단위와 함께, HFP, HFPE, TFE, CTFE 및 PAVE로부터 선택된 그외의 단량체 1종 이상으로 구성된 조성물.
- 제1항에 있어서, 플루오로엘라스토머 공중합체가, (b)형이며, VDF 4~75몰%, 탄소수 1~4의 올레핀 2~35몰%, TFE 0~60몰%, 및 HFP, HFPE, CTFE 및 PAVE로부터 선택된 1종 이상의 단량체 0~40몰%를 함유하는 조성물.
- 제3항에 있어서, 플루오로엘라스토머 공중합체가 40몰%이하의 VDF 및 5~25몰%의 수소화 올레핀을 함유하는 조성물.
- 제3항에 있어서, 플루오로엘라스토머 공중합체가 30~36몰%의 VDF, 40~45몰%의 TFE 및 19~28몰의 프로필렌을 함유하는 조성물.
- 제1내지 5중량 어느 한 항에 있어서, 일반식(I) 또는 (II)의 촉진제가 플루오로엘라스토머 공중합체 100중량부당 0.2~1중량%의 양으로 함유하는 조성물.
- 제1내지 5항중 어느 한 항에 있어서, 가교 결합제로서 유기 폴리히드록실 화합물을 함유하는 조성물.
- 제6항에 있어서, 가교 결합제로서 유기 폴리히드록실 화합물을 함유하는 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITMI92A2338 | 1992-10-12 | ||
ITMI922338A IT1255853B (it) | 1992-10-12 | 1992-10-12 | Composizioni di polimeri elastomerici vulcanizzabili per via ionica |
Publications (2)
Publication Number | Publication Date |
---|---|
KR940009270A true KR940009270A (ko) | 1994-05-20 |
KR100301535B1 KR100301535B1 (ko) | 2001-10-22 |
Family
ID=11364096
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930021135A KR100301535B1 (ko) | 1992-10-12 | 1993-10-12 | 이온경화성엘라스토머중합체조성물 |
Country Status (13)
Country | Link |
---|---|
US (1) | US5409998A (ko) |
EP (1) | EP0592931B1 (ko) |
JP (1) | JP3442440B2 (ko) |
KR (1) | KR100301535B1 (ko) |
AT (1) | ATE136048T1 (ko) |
BR (1) | BR9304207A (ko) |
CA (1) | CA2108243C (ko) |
DE (1) | DE69301996T2 (ko) |
DK (1) | DK0592931T3 (ko) |
IT (1) | IT1255853B (ko) |
MX (1) | MX9306335A (ko) |
RU (1) | RU2133761C1 (ko) |
TW (1) | TW254961B (ko) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1292361B1 (it) * | 1997-05-20 | 1999-01-29 | Ausimont Spa | Composizioni fluoroelastomeriche volcanizzabili |
US6239223B1 (en) | 1997-09-05 | 2001-05-29 | Chemfab Corporation | Fluoropolymeric composition |
US7402630B2 (en) * | 2004-12-16 | 2008-07-22 | 3M Innovative Properties Company | Curing compositions for fluoropolymers |
EP2445939B1 (en) | 2009-06-25 | 2020-09-23 | 3M Innovative Properties Company | Curing compositions for fluoropolymers |
RU2539009C2 (ru) * | 2009-10-01 | 2015-01-10 | Асахи Гласс Компани, Лимитед | Сшиваемая фторкаучуковая композиция и сшитое каучуковое изделие |
US8580886B2 (en) | 2011-09-20 | 2013-11-12 | Dow Corning Corporation | Method for the preparation and use of bis (alkoxysilylorgano)-dicarboxylates |
KR20150003148A (ko) | 2011-12-02 | 2015-01-08 | 다우 코닝 코포레이션 | 에스테르―작용성 실란 및 그의 제조 및 용도; 및 상 전이 촉매로서의 이미늄 화합물의 용도 |
US10836893B2 (en) | 2015-12-07 | 2020-11-17 | Dupont Polymers, Inc. | Curing agents for compounds |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3655727A (en) * | 1970-01-16 | 1972-04-11 | Minnesota Mining & Mfg | Curing systems for vinylidine fluoride elastomers |
US3876654A (en) * | 1970-12-23 | 1975-04-08 | Du Pont | Fluoroelastomer composition |
US3686143A (en) * | 1971-03-22 | 1972-08-22 | Du Pont | Guanidine and amidine accelerators for vulcanization of fluoroelastomers |
US3712877A (en) * | 1971-07-06 | 1973-01-23 | Minnesota Mining & Mfg | Curable vinylidene fluoride elastomers containing phosphonium curing agents |
US3857807A (en) * | 1971-11-11 | 1974-12-31 | Daikin Ind Ltd | Fluoroelastomer composition |
US3752787A (en) * | 1972-01-28 | 1973-08-14 | Du Pont | Fluoroelastomer composition containing a triarylphosphorane vulcanization accelerator |
US3933732A (en) * | 1972-09-28 | 1976-01-20 | E. I. Du Pont De Nemours And Company | Fluoroelastomer composition and curing process |
JPS533412B2 (ko) * | 1973-03-19 | 1978-02-06 | ||
SE426839B (sv) * | 1977-12-14 | 1983-02-14 | Montedison Spa | Vulkbara kompositioner av vinylidenfluoridelaster samt forfarande for vulkning herav |
US4233421A (en) * | 1979-02-26 | 1980-11-11 | Minnesota Mining And Manufacturing Company | Fluoroelastomer composition containing sulfonium curing agents |
IT1163158B (it) * | 1983-03-22 | 1987-04-08 | Montedison Spa | Acceleranti per la vulcanizzazione di copolimeri elastomerici |
CA1265288A (en) * | 1984-11-22 | 1990-01-30 | E. I. Du Pont De Nemours And Company | Curable fluoroelastomer composition |
JPH07122013B2 (ja) * | 1987-03-13 | 1995-12-25 | 日本メクトロン株式会社 | 含フツ素エラストマ−組成物 |
CA1328533C (en) * | 1988-04-01 | 1994-04-12 | Werner Marie Aschille Grootaert | Fluoroelastomer composition |
JPH01306454A (ja) * | 1988-06-03 | 1989-12-11 | Nippon Mektron Ltd | フッ素ゴム組成物 |
IT1228054B (it) * | 1988-12-16 | 1991-05-27 | Ausimont Srl | Additivi per la vulcanizzazione con perossidi di fluoroelastomeri contenenti bromo o iodio |
JPH02240130A (ja) * | 1989-03-15 | 1990-09-25 | Denki Kagaku Kogyo Kk | 半導体封止用エポキシ樹脂組成物 |
CA2043971A1 (en) * | 1990-07-13 | 1992-01-14 | Jeffrey D. Weigelt | Curing fluorocarbon elastomers |
JPH0561236A (ja) * | 1991-08-30 | 1993-03-12 | Mita Ind Co Ltd | 電子写真感光体の表面層硬化用触媒 |
-
1992
- 1992-10-12 IT ITMI922338A patent/IT1255853B/it active IP Right Grant
-
1993
- 1993-10-06 DE DE69301996T patent/DE69301996T2/de not_active Expired - Fee Related
- 1993-10-06 AT AT93116130T patent/ATE136048T1/de not_active IP Right Cessation
- 1993-10-06 EP EP93116130A patent/EP0592931B1/en not_active Expired - Lifetime
- 1993-10-06 DK DK93116130.1T patent/DK0592931T3/da active
- 1993-10-08 US US08/133,625 patent/US5409998A/en not_active Expired - Lifetime
- 1993-10-11 RU RU93056153A patent/RU2133761C1/ru not_active IP Right Cessation
- 1993-10-11 BR BR9304207A patent/BR9304207A/pt not_active IP Right Cessation
- 1993-10-12 CA CA002108243A patent/CA2108243C/en not_active Expired - Fee Related
- 1993-10-12 MX MX9306335A patent/MX9306335A/es unknown
- 1993-10-12 KR KR1019930021135A patent/KR100301535B1/ko not_active IP Right Cessation
- 1993-10-12 JP JP27896793A patent/JP3442440B2/ja not_active Expired - Fee Related
- 1993-10-19 TW TW082108686A patent/TW254961B/zh active
Also Published As
Publication number | Publication date |
---|---|
ITMI922338A1 (it) | 1994-04-12 |
RU2133761C1 (ru) | 1999-07-27 |
DE69301996D1 (de) | 1996-05-02 |
JP3442440B2 (ja) | 2003-09-02 |
MX9306335A (es) | 1995-01-31 |
EP0592931B1 (en) | 1996-03-27 |
IT1255853B (it) | 1995-11-17 |
EP0592931A1 (en) | 1994-04-20 |
US5409998A (en) | 1995-04-25 |
ITMI922338A0 (it) | 1992-10-12 |
TW254961B (ko) | 1995-08-21 |
JPH06263950A (ja) | 1994-09-20 |
CA2108243A1 (en) | 1994-04-13 |
KR100301535B1 (ko) | 2001-10-22 |
DK0592931T3 (da) | 1996-04-22 |
BR9304207A (pt) | 1994-05-10 |
CA2108243C (en) | 2007-08-28 |
ATE136048T1 (de) | 1996-04-15 |
DE69301996T2 (de) | 1996-08-08 |
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