KR930703374A - 폴리히드록시 카르복실산 및 그 제조방법 - Google Patents

폴리히드록시 카르복실산 및 그 제조방법

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Publication number
KR930703374A
KR930703374A KR1019930701555A KR930701555A KR930703374A KR 930703374 A KR930703374 A KR 930703374A KR 1019930701555 A KR1019930701555 A KR 1019930701555A KR 930701555 A KR930701555 A KR 930701555A KR 930703374 A KR930703374 A KR 930703374A
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South Korea
Prior art keywords
carboxylic acids
carboxylic acid
polyhydroxy
polyhydroxy carboxylic
organic solvent
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KR1019930701555A
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English (en)
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KR970007322B1 (ko
Inventor
가타시 에노모토
마사노부 아지오카
아키히로 야마구치
Original Assignee
사와무라 하루오
미쓰이도오아쓰 가가쿠 가부시키가이샤
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Publication of KR930703374A publication Critical patent/KR930703374A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Biological Depolymerization Polymers (AREA)

Abstract

본 발명은 유기용매를 함유하는 히드록시 카르복실산류 또는 그 올리고머의 반응혼합물중에서, 실질적으로 물의 부재하에 히드록시 카르복실산류 또는 그 올리고머를 탈수축합반응하는 폴리히드록시 카르복실산의 제조방법 및 그것에 의해 얻어진 폴리히드록시 카르복실산에 관한 것이며, 물성 및 가공성이 우수한 폴리히드록시 카르복실산을 제공하는 것이다.

Description

폴리히드록시 카르복실산및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예 32에서 얻은 L-젖산 90%와 D-젖산 10%의 랜덤 코폴리머의13C-NMR스펙트럼의 전체도이다. 제2도는 실시예 32에서 얻은 L-젖산 100%의 랜덤 코펄리머의 카보닐기의13C-NMR스펙트럼이다. 제3도는 비교예 2에서 얻은 L-락티드 90%와 D-락티드 10%의 코폴리머의 카보닐기의13C-NMR스펙트럼이다. 제4도는 DSC에 의한 열분석결과를 나타내는 도면이며, 실시예32에서 얻는 L-젖산 90%와 D-젖산 10%의 랜덤 코폴리머의 열분석 결과를 상부에, 비교예2에서 얻은 L-락티드 90%와 D-락티드 10%의 코폴리머의 결과를 하부에 나타낸다.

Claims (35)

  1. 실질적으로 물의 부재하에서, 히드록시 카르복실산류 또는 그 올리고머를 유기용매를 함유하는 반응혼합물 중에서 탈수축합반응하여,중량평균이 약 150,000이상인 폴리히드록시 카르복실산의 제조방법.
  2. 제1항에 있어서, 폴리히드록시 카르복실산의 중량평균 분자량이 50,000이상인 방법.
  3. 제1항에 있어서, 폴리히드록시 카르복실산의 중량평균 분자량이 70,000이상인 방법.
  4. 제1항에 있어서, 폴리히드록시 카르복실산의 중량평균 분자량이 100,000이상인 방법.
  5. 제1항에 있어서, 반응혼합물에서 유기용매의 적어도 일부를 제거하고,제거되는 유기용매의 수분량보다 적든가 동일한 수분량을 가진 추가 유기용매를 반응혼합물에 첨가하는 방법.
  6. 제5항에 있어서, 반응혼합물에서 제거되는 유기용매가 건조체와 접촉되어 수분을 제거하고,추가용매로서 반응혼합물에 되돌아오는 방법.
  7. 제6항에 있어서, 건조체가 분자체류, 오산화이인 또는 금속수소화합물인 방법.
  8. 제7항에 있어서, 건조체가 분자체류인 방법.
  9. 제5항에 있어서, 반응혼합물에 추가로 첨가하는 유기용매의 수분량이 50ppm이하인 방법.
  10. 제5항에 있어서, 반응혼합물이 처음에 공비에 의해 수분을 제거하고, 다음에 반응 혼합물에서 유기용매의 일부가 제거되는 방법.
  11. 제1항에 있어서, 유기용매가 탄화수소게 용매, 할로겐계 용매, 케톤계 용매 및 에테르계 용매인 방법.
  12. 제11항에 있어서, 유기용매가 에테르계 용매인 방법.
  13. 제12항에 있어서, 에테르계 유기용매가 아니졸 또는 페네톨린 방법.
  14. 제1항에 있어서, 디페닐에테르계 용매인 방법.
  15. 제14항에 있어서, 디페닐에테르계 용매가 디페닐에테르인 방법.
  16. 제1항에 있어서, 히드록시 카르복실산류가 젖산인 방법.
  17. 제16항에 있어서, 젖산이 D-및 L-젖산인 방법.
  18. 제1항에 있어서, 히드록시 카르복실산류가 히드록시 카르복실산의 혼합물이며 또한 젖산을 함유하는 방법.
  19. 제18항에 있어서, 혼합물이 젖산과 글리콜산을 함유하는 방법.
  20. 제1항의 방법에서 얻은 폴리히드록시 카르복실산.
  21. 제5항의 방법에서 얻은 폴리히드록시 카르복실산.
  22. 제10항의 방법에서 얻은 폴리히드록시 카르복실산.
  23. 제15항의 방법에서 얻은 폴리히드록시 카르복실산.
  24. 제17항의 방법에서 얻은 폴리히드록시 카르복실산.
  25. 제19항의 방법에서 얻은 폴리히드록시 카르복실산.
  26. 히드록시 카르복실산류 또는 그 올리고머로 되는 반응혼합물에서 직접 얻어지며, 중량평균분자량이 50,000이상인 폴리히드록시 카르복실산.
  27. 제26항에 있어서, 중량평균분자량이 70,00 이상인 폴리히드록시 카르복실산
  28. 제26항에 있어서, 중량평균분자량이 100,000이상인 폴리히드록시 카르복실산
  29. 제26항에 있어서, 히드록시 카르복실산류가 젖산인 폴리히드록시 카르복실산류
  30. 제26항에 있어서, 히드록시 카르복실산류가 D-및 L-젖산으로 되는 혼합물인 폴리히드록시 카르복실산류.
  31. 약 169,27ppm, 약 169.31ppm, 약 169.42ppm, 약 169.49ppm및 약 169.66ppm에13C-NMR흡수스펙트럼을 나타내며, D-젖산단위 및 L-젖산단위를 갖는 폴리히드록시 카르복실산류.
  32. 제26항에 있어서, 히드록시 카르복실산류가 히드록시 카르복실산의 혼합물이며 또한 젖산을 함유하는 폴리히드록시 카르복실산류.
  33. 제26항에 있어서, 히드록시 카르복실산류가 젖산과 글리콜산을 함유하는 혼합물인 폴리히드록시 카르복실산류.
  34. 제26항에 있어서, 폴리히드록시 카르복실산이 투명한 폴리히드록시 카르복실산류.
  35. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930701555A 1991-12-19 1992-12-16 폴리히드록시 카르복실산 및 그 제조방법 KR970007322B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP91-336820 1991-12-19
JP33682091 1991-12-19
JP15652692 1992-06-16
JP92-156526 1992-06-16
PCT/JP1992/001638 WO1993012160A1 (en) 1991-12-19 1992-12-16 Polyhydroxy carboxylic acid and production thereof

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KR930703374A true KR930703374A (ko) 1993-11-29
KR970007322B1 KR970007322B1 (ko) 1997-05-07

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US (1) US5310865A (ko)
EP (1) EP0572675B1 (ko)
KR (1) KR970007322B1 (ko)
DE (1) DE69230032T2 (ko)
ES (1) ES2139646T3 (ko)
FI (1) FI933471A (ko)
WO (1) WO1993012160A1 (ko)

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WO1993012160A1 (en) 1993-06-24
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US5310865A (en) 1994-05-10

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