KR930021700A - 초 미립 솔비톨 아세탈 및 크실리톨 아세탈을 함유하는 폴리올레핀 조성물 - Google Patents

초 미립 솔비톨 아세탈 및 크실리톨 아세탈을 함유하는 폴리올레핀 조성물 Download PDF

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KR930021700A
KR930021700A KR1019930007530A KR930007530A KR930021700A KR 930021700 A KR930021700 A KR 930021700A KR 1019930007530 A KR1019930007530 A KR 1019930007530A KR 930007530 A KR930007530 A KR 930007530A KR 930021700 A KR930021700 A KR 930021700A
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존 마니온 마이클
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제리 에이. 코간, 쥬니어.
밀리켄 리서치 코오포레이션
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/15—Heterocyclic compounds having oxygen in the ring
    • C08K5/156—Heterocyclic compounds having oxygen in the ring having two oxygen atoms in the ring
    • C08K5/1575—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/002—Physical properties
    • C08K2201/005—Additives being defined by their particle size in general
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethene-propene or ethene-propene-diene copolymers

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
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  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
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Abstract

본 발명은 정화제를 한 결정 폴리올레핀수지에 배합하는 방법에 관한 것으로 다음일반식을 가지고
(상기식에서 p는 0또는 1이고, m 및 n은 각각 0 내지 3이며 R은 각각 C1-8알킬, C1-4알콕시, 히드록시, 할로겐, C1-6알킬티오, C1-6알킬설폭시 및 불포화 고리의 인접한 탄소원자와 카르보사이클 고리를 형성하는 4 또는 5멤버드 알킬그룹으로 부터 선택된다.)
상기 정화제는 30마이크로 이하의 d97및 15마이크론 이하의 평균입자 크기를 가지며 정화제가 용융수지내 용해 될때까지 170℃이상의 온도에서 폴리올레핀수지와 배합되는 것을 특징으로 한다.

Description

초 미립 솔비톨 아세탈 및 크실리톨 아세탈을 함유하는 폴리올레핀 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 괴상 디벤질리덴 솔비톨 정화제의 광마이크로그래프.
제2도는 괴상 디벤질리덴 솔비톨 정화제의 광마이크로 그래프.
제3도는 괴상 디(p-메틸벤질리덴)솔비톨 정화제의 광마이크로그래프.
제4도는 괴상 디(p-에틸벤질리덴)솔비톨 정화제의 광 마이크로그래프.

Claims (28)

  1. 폴리올레핀수지 100중량부 및 하기 일반식의 화합물로부터 선택된 정화제 0.01 내지 100중량부를 혼합하고 :
  3. (상기식에서, p는 0또는 1이고, m 및 n은 각각 0 내지 3이며 R은 각각 C1-8알킬, C1-4알콕시, 히드록시, 할로겐, C1-6알킬티오, C1-6알킬설폭시 및 불포화 고리의 인접한 탄소원자와 카르보사이클 고리를 형성하는 4 또는 5멤버드 알킬그룹으로 부터 선택되며 상기 정화제가 분말형태라면 d97은 30마이크론이하 및 평균입자 크기가 15마이크론 이하이다.)
  4. 상기 수지의 용해온도이상에서 적어도 170℃까지 상기 혼합물을 가열하며, 상기 정화제가 수지내 용해될 때까지 상기 수지가 용융상태인 동안 상기 혼합물을 배합시키는 단계로 구성되는 것을 특징으로 하는 정화제를 반-결정 폴리올레핀수지에 배합시키는 방법.
  5. 제1항에 있어서, 혼합물이 폴리올레핀수지 100중량부당 상기 정화제 0.1 내지 15중량부로 구성되는 것을 특징으로 하는 방법.
  6. 제2항에 있어서, 상기 정화제가 d9720마이크론 이하이고 평균입자 크기가 10마이크론 이하인 것을 특징으로 하는 방법.
  7. 제3항에 있어서, p는 1이고 R은 C1-4알킬, 염소, 브롬, 티오에테르 및 불포화 고리의 인접한 탄소원자로 카르보사이클 고리를 형성하는 4멤버드 알킬그룹으로부터 선택되는 것을 특징으로 하는 방법.
  8. 제2항에 있어서, 상기 정화제가 10마이크로 이하의 d97및 6마이크로 하여 평균입자 크기를 가지는 것을 특징으로 하는 방법.
  9. 제5항에 있어서, p가 1이고 R은 C1-4알킬, 염소, 브롬, 티오에테르 및 불포화 고리의 인접한 탄소원자로 카르보사이클 고리를 형성하는 4멤버드 알킬그룹으로부터 선택되는 것을 특징으로 하는 방법.
  10. 제6항에 있어서, 상기 혼합물이 적어도 180℃의 온도까지 가열되는 것을 특징으로 하는 방법.
  11. 제1항에 있어서, 상기 혼합물이 상기 폴리올리펜 수지 100중량부당 정화제 0.1 내지 3중량부로 구성되는 것을 특징으로 하는 방법.
  12. 제8항에 있어서, 상기 정화제가 20마이크론 이하의 d97및 10마이크론 이하의 평균입자 크기를 가지는 것을 특징으로 하는 방법.
  13. 제9항에 있어서, p가 1이고, R이 C1-4알킬, 염소, 브롬, 티오에테르 및 불포화고리의 인접한 탄소원자와 카르보사이클 고리를 형성하는 4멤버드 알킬그룹으로 부터 선택되는 것을 특징으로 하는 방법.
  14. 상기 폴리올레핀 100중량부 및 다음 일반식의 화합물로 부터 선택되는 정화제 0.01 내지 100중량부를 혼합하고;
  16. (상기식에서, p는 0또는 1이고, m 및 n은 각각 0 내지 3이며 R은 각각 C1-4알킬, 염소, 브롬, 티오에테르 및 불포화고리의 인접한 탄소원자와 카르보사이클고리를 형성하는 4멤버드 알킬그룹으로 부터 각각 선택되며 또한 정화제가 분말형태라면 d97은 20마이크론 이하이고 평균입자 크기는 10마이크론이하이다); 상기 혼합물을 상기 수지의 융점이상에서 적어도 170℃ 및 상기 정화제의 융점이하의 온도에서 상기 혼합물을 가열시키며, 상기 정화제가 상기 수지내 용해될 때까지 수지가 용융상태인 동안 상기 혼합물을 배합하는 단계로 구성되는 것을 특징으로 하는 정화제를 반-결정 폴리올레핀 수지에 배합시키는 방법.
  17. 제11항에 있어서, p는 1이고 R이 C1-4알킬, 염소, 브롬, 티오에테르 및 불포화고리의 인접한 탄소원자와 카르보사이클고리를 형성하는 4멤버드 알킬그룹으로 부터 선택되는 것을 특징으로 하는 방법.
  18. 제12항에 있어서, 상기 혼합물을 180℃ 내지 230℃의 온도로 가열시키는 것을 특징으로 하는 방법.
  19. 다음 일반식의 화합물로 구성되고 d97은 30마이크론 이하이고, 평균입자크기가 15마이크론 이하인 것을 특징으로 하는 분말로 만들어진 정화제.
  21. (상기식에서, p는 0또는 1이고, m 및 n은 각각 0 내지 3이며 R은 각각 C1-8알킬, C1-4알콕시, 히드록시, 할로겐, C1-6알킬티오, C1-6알킬설폭시 및 불포화 고리의 인접한 탄소원자와 카르보사이클 고리를 형성하는 4 또는 5멤버드 알킬그룹이다.)
  22. 제14항에 있어서, 상기 정화제가 20마이크론 이하의 d97및 10마이크론 이하의 평균입자 크기를 가지는 것을 특징으로 하는 분말로 만들어진 정화제.
  23. 제15항에 있어서, p가 1이고 R이 C1-4알킬, 염소, 브롬, 티오에테르 및 불포화 고리의 인접한 탄소원자와 카르보사이클 고리를 형성하는 4멤버드 알킬그룹으로 부터 선택되는 것을 특징으로 하는 분말로 만들어진 정화제.
  24. 제14항에 있어서, 상기 정화제가 10마이크론이하의 d97및 6마이크론 이하의 평균입자 크기를 가지는 것을 특징으로 하는 분말로 만들어진 정화제.
  25. 제17항에 있어서, p가 1이고 R이 C1-4알킬, 염소, 브롬, 티오에테르 및 불포화 고리의 인접한 탄소원자와 카르보사이클 고리를 형성하는 4멤버드 알킬그룹으로 부터 선택되는 것을 특징으로 하는 분말로 만들어진 정화제.
  26. 제16항에 있어서, 상기 정화제가 250℃이상이 융점을 가지는 것을 특징으로 하는 분말로 만들어진 정화제.
  27. 제14항에 있어서, 상기 정화제가 250℃이상의 융점을 가지는 것을 특징으로 하는 분말로 만들어진 정화제.
  28. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930007530A 1992-05-01 1993-04-30 초미립 솔비톨 아세탈 및 크실리톨 아세탈로 이루어진 정화제 KR0183059B1 (ko)

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KR1019980035446A KR0183364B1 (en) 1992-05-01 1998-08-27 Polyolefin composition containing ultrafine sorbitol and xylitol acetals

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JP877,405 1992-05-01
US07/877,405 US5198484A (en) 1992-05-01 1992-05-01 Polyolefin composition containing ultrafine sorbitol and xylitol acetals
US877,405 1992-05-01
JP92-257743 1992-09-28

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KR1019980035446A KR0183364B1 (en) 1992-05-01 1998-08-27 Polyolefin composition containing ultrafine sorbitol and xylitol acetals

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CN (1) CN1044127C (ko)
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DE (1) DE69322542T2 (ko)
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AU658995B2 (en) 1995-05-04
RU2128198C1 (ru) 1999-03-27
CA2094697A1 (en) 1993-11-02
US5310950A (en) 1994-05-10
DE69322542T2 (de) 1999-05-06
KR0183059B1 (ko) 1999-05-15
AU3709393A (en) 1993-11-04
MY108763A (en) 1996-11-30
DE69322542D1 (de) 1999-01-28
JP2610772B2 (ja) 1997-05-14
KR0183364B1 (en) 1999-05-15
JPH06145431A (ja) 1994-05-24
EP0569198A1 (en) 1993-11-10
EP0569198B1 (en) 1998-12-16
FI931977A0 (fi) 1993-04-30
RU2203898C2 (ru) 2003-05-10
US5198484A (en) 1993-03-30
FI115917B (fi) 2005-08-15
CN1044127C (zh) 1999-07-14
FI931977A (fi) 1993-11-02
CA2094697C (en) 2002-08-27
BR9301707A (pt) 1993-11-03
MX9302529A (es) 1993-11-01

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