KR930016388A - 아민 옥사이드 - Google Patents

아민 옥사이드 Download PDF

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Publication number
KR930016388A
KR930016388A KR1019930000772A KR930000772A KR930016388A KR 930016388 A KR930016388 A KR 930016388A KR 1019930000772 A KR1019930000772 A KR 1019930000772A KR 930000772 A KR930000772 A KR 930000772A KR 930016388 A KR930016388 A KR 930016388A
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South Korea
Prior art keywords
amine
solution
oxide
cellulose
oxides
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KR1019930000772A
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English (en)
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아슈테거 스테판
아이힝어 디이터
팔크 하인쯔
토이블 귄터
Original Assignee
알프레드 빔머·요제프 짜우너
렌찡 악티엔게젤샤프트
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Publication of KR930016388A publication Critical patent/KR930016388A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C291/00—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00
    • C07C291/02—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00 containing nitrogen-oxide bonds
    • C07C291/04—Compounds containing carbon and nitrogen and having functional groups not covered by groups C07C201/00 - C07C281/00 containing nitrogen-oxide bonds containing amino-oxide bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
  • Dental Preparations (AREA)
  • Mold Materials And Core Materials (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

본 발명은 하기 일반식(I)의 아만- 옥사이드에 관한 것으로서, 이 화합물은 결정화 경향이 감소된 성형가능 또는 방적가능 셀룰로오스 용액의 제조에 유리하게 사용될 수 있다.
상기 식에서, R1및 R2는 1 내지 4개의 탄소원자로 이루어진 알킬기이고, R3은 수소, 히드록실기 또는 C1-C4의 알콕시기이며 m 및 n 은 각각 조건 1≤m≤8 및 0≤n≤4를 만족하는 정수이고, 단, R3이 히드록실기이면 n은 0이 아니다.

Description

아민 옥사이드
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (13)

  1. 하기 일반식(I)의 아민-옥사이드:
    상기 식에서, R1및 R2는 1내지 4개의 탄소원자로 이루어진 알킬기이고, R3은 수소 또는 히드록실기이며, m 및 n은 각각 조건 1≤m≤8 및 0≤n≤4를 만족하는 정수이고, 단, R3이 히드록실기이면 n은 0이 아니다.
  2. 제1항에 있어서, m은 2이고 n이 0,1 또는 2 중 어느 하나인 것을 특징으로 하는 일반식(I)의 아민-옥사이드.
  3. 하기 식(Ia)의 2-(N,N-디메틸아미노에톡시)-에탄올-N-옥사이드:
  4. 3차 아민을 H2O2로 처리함에 의해 산화시킴으로써 이루어지는, 제1항 내지 3항의 아민-옥사이드의 제조방법에 있어서, 3차 아민으로서 하기 일반식(Ⅱ)의 화합물이 사용되는 것을 특징으로 하는 방법:
    (상기 식에서, R1, R2, R3, m 및 n은 상기 정의된 바와 같다)
  5. 셀룰로오스 및 3차 아민-옥사이드를 함유하고 있는 성형가능한 또는 방적가능한 용액으로서, 3차 아민-옥사이드로서, R1, R2, n 및 m이 상기 정의된 바와 같고, R3이 수소, 히드록실기 또는 C1-C4의 알콕시기이며, 단 R3이 히드록실기 또는 알콕시기일때 n은 0이 아닌, 제1항의 일반식(I)의 화합물, 특히 제3항의 식(Ia)의 3차 아민-옥사이드가 포함되며, 임의로 물 또는 비-용매와 같은 보조 물질이 포함되는 것을 특징으로 하는 용액.
  6. 제5항에 있어서, 물이 포함되지 않으며 10중량% 이상의 셀룰로오스가 함유되는 것을 특징으로 하는 용액.
  7. 제5항 또는 6항에 있어서, 안정화제가 함유되는 것을 특징으로 하는 용액.
  8. 제7항에 있어서, 안정화제로서 플라본 그룹의 화합물, 바람직하게는 루틴(3,3',4',5,7-펜타히드록시-플라본-3-루티노사이드), 케르세틴(3',3,3',5,7-펜타히드록시-플라본) 또는 모린(2',3,4',5,7-펜타히드록시-플라본)이 성형물질 또는 방적물질을 토대로 0.001 내지 1.5중량%의 양으로 함유되는 것을 특징으로 하는 용액.
  9. 제7항에 있어서, H2O2와 옥살산의 혼합물이 안정화제로서 사용되는 것을 특징으로 하는 용액.
  10. 제5항 내지 9항중 어느 한 항에 있어서, 셀룰로오스 외에 다른 중합체가 함유되는 것을 특징으로 하는 용액.
  11. 제5항 내지 10항중 어느 한 항에 있어서, 다른 아민-옥사이드로서 N-메틸-모르폴린-N-옥사이드가 사용되는 것을 특징으로 하는 용액.
  12. 셀룰로오스 함유 물질과 3차 아민-옥사이드의 혼합물이 가온되는 것으로 이루어지는, 제5항 내지 11항중 어느 한 항 또는 2이상의 항의 성형가능 또는 방적 가능 용액의 제조방법에 있어서, 상기 혼합물에 다른 가용성 중합체가 임의로 첨가되고, 제1항, 2항 , 3항 또는 5항의 아민-옥사이드가 임의로 N-메틸-모르폴린-N-옥사이드와 조합되어 3차 아민-옥사이드로서 사용되며, 포함될 수 있는 모든 물이 임의로 제거되는 것을 특징으로 하는 방법.
  13. 아민-옥사이드중의 셀룰로오스의 용액이 성형장치를 통하여 가압되고, 임의로 연신되고 응집되는 것으로 이루어지는 셀룰로오스 성형물의 제조방법에 있어서, 제5항 내지 11항중 어느 한 항의 용액이 아민-옥사이드중의 셀룰로오스의 용액으로서 사용되는 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930000772A 1992-01-23 1993-01-21 아민 옥사이드 KR930016388A (ko)

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Application Number Priority Date Filing Date Title
ATA109/92 1992-01-23
AT0010992A AT396930B (de) 1992-01-23 1992-01-23 Aminoxide

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US (1) US5409532A (ko)
EP (1) EP0553070B1 (ko)
JP (1) JPH05279318A (ko)
KR (1) KR930016388A (ko)
CN (1) CN1074899A (ko)
AT (2) AT396930B (ko)
AU (1) AU667495B2 (ko)
BR (1) BR9300208A (ko)
CA (1) CA2087505A1 (ko)
CZ (1) CZ375292A3 (ko)
DE (1) DE59304224D1 (ko)
DK (1) DK0553070T3 (ko)
ES (1) ES2094517T3 (ko)
FI (1) FI930107A (ko)
GR (1) GR3021574T3 (ko)
HU (1) HUT63375A (ko)
IL (1) IL104353A0 (ko)
MX (1) MX9300291A (ko)
NO (1) NO930216L (ko)
PL (1) PL297487A1 (ko)
SI (1) SI9300037A (ko)
SK (1) SK375292A3 (ko)
TW (1) TW226378B (ko)
ZA (1) ZA93438B (ko)
ZW (1) ZW693A1 (ko)

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Publication number Priority date Publication date Assignee Title
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CA2087505A1 (en) 1993-07-24
BR9300208A (pt) 1993-10-19
HUT63375A (en) 1993-08-30
SK375292A3 (en) 1995-05-10
ATA10992A (de) 1993-05-15
AU3104693A (en) 1993-07-29
ZA93438B (en) 1993-08-25
CN1074899A (zh) 1993-08-04
HU9300184D0 (en) 1993-04-28
ZW693A1 (en) 1993-06-30
ATE144495T1 (de) 1996-11-15
MX9300291A (es) 1993-07-30
AT396930B (de) 1993-12-27
PL297487A1 (en) 1993-11-29
AU667495B2 (en) 1996-03-28
GR3021574T3 (en) 1997-02-28
DE59304224D1 (de) 1996-11-28
DK0553070T3 (da) 1997-04-21
US5409532A (en) 1995-04-25
ES2094517T3 (es) 1997-01-16
IL104353A0 (en) 1993-05-13
SI9300037A (en) 1993-09-30
NO930216D0 (no) 1993-01-22
JPH05279318A (ja) 1993-10-26
CZ375292A3 (en) 1993-12-15
FI930107A (fi) 1993-07-24
EP0553070A1 (de) 1993-07-28
TW226378B (ko) 1994-07-11
EP0553070B1 (de) 1996-10-23
FI930107A0 (fi) 1993-01-12
NO930216L (no) 1993-07-26

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