KR930012103A - 표백촉매, 표백조성물 및 얼룩기질의 표백방법 - Google Patents

표백촉매, 표백조성물 및 얼룩기질의 표백방법 Download PDF

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Publication number
KR930012103A
KR930012103A KR1019920024785A KR920024785A KR930012103A KR 930012103 A KR930012103 A KR 930012103A KR 1019920024785 A KR1019920024785 A KR 1019920024785A KR 920024785 A KR920024785 A KR 920024785A KR 930012103 A KR930012103 A KR 930012103A
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KR
South Korea
Prior art keywords
bleaching
integer
manganese
aryl
optionally substituted
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KR1019920024785A
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English (en)
Inventor
헤이즈 로날드
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원본미기재
유니레버 엔브이
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Application filed by 원본미기재, 유니레버 엔브이 filed Critical 원본미기재
Publication of KR930012103A publication Critical patent/KR930012103A/ko

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3902Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905Bleach activators or bleach catalysts
    • C11D3/3932Inorganic compounds or complexes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring

Abstract

하기 일반식(Ⅰ)를 가진 착화합물을 함유하는 표백촉매
사이 식에서, Mn는 Ⅱ,Ⅲ또는 Ⅳ산화상태의 망간이며, X는 배위 또는 브리지하는 부분이며, p는 1 내지 3의 정수이고, Y는 대이온으로서 그의 형태는 양의 정수, O또는 음의 정수인 착염물전하 z에 따라 달라지며, q는 z/[전하 Y]이며, L은 거대환상 유기분자인 리간드이다.

Description

표백촉매, 표백조성물 및 얼룩기질의 표백방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 하기 일반식 (Ⅰ)의 착화합물을 함유하는 표백촉매.
    상기 식에서, Mn는 Ⅱ,Ⅲ또는 Ⅳ산화상태의 망간이며, X는
    (여기서, R은 수소, 또는 임의치환된 알킬 또는 아릴임), 및 R'COO-(여기서 R'는 임의치환된 알킬 및 아릴임),및 이의 혼합물로부터 선택된 배위부분이며, p는 1내지 3의 정수이고, z는 착화합물의 전하로써 양의 정수, O또는 음의 정수이며, Y는 대이온으로서 그의 형태는 z에 따라 달라지며, q는 z/[전하 Y]이며, L은 상기 일반식(B')을 가진 거대환상 유기분자인 리간드이며, t는 2내지 3의 정수이고 s는 3내지 4의 정수이고, u는 0또는 1이며, R¹,R²및 R³는 각각 독립적으로 수소, 또는 임의치환된 알킬 또는 아릴이며, 단 여기서, P가 3이고 Mn이 Ⅳ산화상태의 망간인 경우 X는 각각 RO-가 아니다.
  2. 제1항에 있어서, 리간드 L에서 t가 2이고, s가 3이고, u가 1이고, R¹,R²및 R³는 각각 독립적으로 수소 또는 메틸인 표백촉매.
  3. (i)2내지 30중량%의 퍼옥시화합물 및 (ⅱ) 퍼옥시 화합물의 표백활성을 촉매화하기에 유효한 양으로 존재하는 제1항에 정의된 표백촉매를 함유하는 표백조성물.
  4. 제3항에 있어서, 조성물을 기본으로 0.0005내지 0.5중량%의 망간함량에 해당하는 농도로 표백촉매를 함유하는 표백조성물.
  5. 제3항 또는 제4항에 있어서, 0.5내지 50중량%의 표면활성물질을 추가로 함유하는 표백조성물.
  6. 제3항 내지 5항중 어느 한 항에 있어서, 5내지 80중량%의 세정보강제를 추가로 함유하는 표백조성물.
  7. 퍼옥시화합물 및 하기 일반식(I)의 망간착화합물을 서로 상호작용하여 기질상에 세정효과를 제공하기에 유효한 양으로 수성매체중의 얼룩기질에 접촉시킴을 포함하는 얼룩기질의 표백방법.
    상기 식에서, Mn는 Ⅱ,Ⅲ또는 Ⅳ산화상태의 망간이며, X는 (여기서, R은 수소, 또는 임의치환된 알킬 또는 아릴임), 및 이의 혼합물로부터 선택된 배위부분이며, p는 1내지 3의 정수이고, z는 착화합물의 전하로써 양의 정수, O또는 음의 정수이며, Y는 대이온으로서 그의 형태는 z에 따라 달라지며, q는 z/[전하 Y]이며, L은 상기 일반식(B')을 가진 거대환상 유기분자인 리간드이며, t는 2내지 3의 정수이고 s는 3내지 4의 정수이고, u는 0또는 1이며, R¹,R²및 R³는 각각 독립적으로 수소, 또는 임의치환된 알킬 또는 아릴이며, 단 여기서, P가 3이고 Mn이 Ⅳ산화상태의 망간인 경우 X는 각각 RO-가 아니다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920024785A 1991-12-20 1992-12-19 표백촉매, 표백조성물 및 얼룩기질의 표백방법 KR930012103A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB919127060A GB9127060D0 (en) 1991-12-20 1991-12-20 Bleach activation
GB9127060.3 1992-03-04

Publications (1)

Publication Number Publication Date
KR930012103A true KR930012103A (ko) 1993-07-20

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ID=10706591

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1019920024785A KR930012103A (ko) 1991-12-20 1992-12-19 표백촉매, 표백조성물 및 얼룩기질의 표백방법
KR92024784A KR960002630B1 (en) 1991-12-20 1992-12-19 Bleach activation

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR92024784A KR960002630B1 (en) 1991-12-20 1992-12-19 Bleach activation

Country Status (12)

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EP (1) EP0549272A1 (ko)
JP (1) JPH05263098A (ko)
KR (2) KR930012103A (ko)
CN (1) CN1074237A (ko)
AU (1) AU3029792A (ko)
BR (1) BR9205100A (ko)
CA (1) CA2085720A1 (ko)
GB (2) GB9127060D0 (ko)
MX (1) MX9207471A (ko)
NO (1) NO924895L (ko)
TW (1) TW232706B (ko)
ZA (2) ZA929850B (ko)

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