KR830007497A - 올레핀산 및 에스테르의 제조방법 - Google Patents
올레핀산 및 에스테르의 제조방법 Download PDFInfo
- Publication number
- KR830007497A KR830007497A KR1019810003316A KR810003316A KR830007497A KR 830007497 A KR830007497 A KR 830007497A KR 1019810003316 A KR1019810003316 A KR 1019810003316A KR 810003316 A KR810003316 A KR 810003316A KR 830007497 A KR830007497 A KR 830007497A
- Authority
- KR
- South Korea
- Prior art keywords
- general formula
- compound
- mercury
- barium
- catalyst
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 5
- 239000002253 acid Substances 0.000 title claims 2
- 150000002148 esters Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 claims 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 4
- 239000003054 catalyst Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
- 229910052788 barium Inorganic materials 0.000 claims 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims 2
- 229910017052 cobalt Inorganic materials 0.000 claims 2
- 239000010941 cobalt Substances 0.000 claims 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims 2
- 229910052753 mercury Inorganic materials 0.000 claims 2
- 239000011591 potassium Substances 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 229910052701 rubidium Inorganic materials 0.000 claims 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims 2
- 229910052715 tantalum Inorganic materials 0.000 claims 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims 2
- 229910052716 thallium Inorganic materials 0.000 claims 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- CFJZIXJQSWEWOS-UHFFFAOYSA-N [Ba].[Hg] Chemical group [Ba].[Hg] CFJZIXJQSWEWOS-UHFFFAOYSA-N 0.000 claims 1
- GSUVLAOQQLOGOJ-UHFFFAOYSA-N [S].[Ge] Chemical compound [S].[Ge] GSUVLAOQQLOGOJ-UHFFFAOYSA-N 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 229910052793 cadmium Inorganic materials 0.000 claims 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims 1
- 229910052792 caesium Inorganic materials 0.000 claims 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000010949 copper Substances 0.000 claims 1
- 229910052732 germanium Inorganic materials 0.000 claims 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 229910052738 indium Inorganic materials 0.000 claims 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- 229910052746 lanthanum Inorganic materials 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 229910052758 niobium Inorganic materials 0.000 claims 1
- 239000010955 niobium Substances 0.000 claims 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- -1 phosphorus compound Chemical class 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 229910052720 vanadium Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 239000012808 vapor phase Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 다음 일반식(Ⅱ)의 화합물을 산소분자 존재하에서 촉매량 만큼의 다음 일반식(Ⅰ)의 촉매와 접촉시키는 반응 단계를 거쳐 다음 일반식(Ⅲ)의 화합물을 제조하는 증기상 제법.상기 일바식에서R 내지 R˝´는 각각 독립하여 수소 또는 C1-C4 알킬 레디칼이고,M은 칼륨, 루비듐 및 세슘중 적어도 1개이며,X는 바륨, 란타늄, 칼ㄻ, 알루미늄, 은, 카드뮴,티타늄, 탈륨, 수은 , 납 및 아연중 저겅도 1개이고, M´a〉인 경우, 철, 코발트, 니ㅔㄹ, 스트론륨, 망간, 이듐, 탄탈륨, 게르마늄 황 배릴륨중 적어도 2개이ㅕ.a 는 0 내지 약 2의 수이고, 또b 는 기타 존재원소의 원자가를 맞추기 위한 수이다.
- 제1항에 있어서 M이 칼륨 또는 루비듐인 제법.
- 제2항에 있어서 X가 바륨, 수은, 탈륨, 납인 제법.
- 제2항에 있어서 X가 바륨 수은 또는 납인 제법.
- 제4항에 있어서 a가 0인 제법/
- 제4항에 있어서 A〉0인 제법.
- 제6항에 이어서 M´가 철, 코발트, 탄탈륨 또는 게르마늄 제법.
- 제7항에서 있어서 일반식(Ⅰ)ㅇ서의 인의 밑글자가 약 0.5 내지 1.35, 알카리그목(M)의 밑글자가약 0.8 내지 2, 구리의 밑글자가 약 0.1 내지 0.8 바나듐의 밑글자가약 0.1내지 0.8이고 또 X의 밑굴자가 약 0.02 내지 0.5인 제법
- 제8항에 있어서 촉매가 100% 활성 형태인 제법.
- 제8항에 있어서 촉매가 지지체로 희석된 제법.
- 제10항에 있어서 지지체가 저표면적 알루미나안 제법.
- 제11항에 있어서 일반식(Ⅱ)의 화합물이 이소부틸산인 제접※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US184,592 | 1980-09-05 | ||
| US06/184,592 US4314075A (en) | 1980-09-05 | 1980-09-05 | Process for the production of olefinic acids and esters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR830007497A true KR830007497A (ko) | 1983-10-21 |
| KR870001316B1 KR870001316B1 (ko) | 1987-07-13 |
Family
ID=22677544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019810003316A KR870001316B1 (ko) | 1980-09-05 | 1981-09-05 | 올레핀산 및 에스테르의 제조방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4314075A (ko) |
| EP (1) | EP0047581B1 (ko) |
| JP (1) | JPS5750938A (ko) |
| KR (1) | KR870001316B1 (ko) |
| CA (1) | CA1150731A (ko) |
| DE (1) | DE3162972D1 (ko) |
| MX (1) | MX159301A (ko) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3145091A1 (de) * | 1981-11-13 | 1983-05-19 | Röhm GmbH, 6100 Darmstadt | Verfahren zur herstellung von methacrylsaeure |
| US4558029A (en) * | 1982-09-13 | 1985-12-10 | The Standard Oil Company | Antimony-containing C4 oxidation catalysts |
| JPS59115750A (ja) * | 1982-12-22 | 1984-07-04 | Nippon Shokubai Kagaku Kogyo Co Ltd | メタクリル酸合成用触媒 |
| US7649111B2 (en) * | 2005-07-25 | 2010-01-19 | Saudi Basic Industries Corporation | Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same |
| CN101273001A (zh) * | 2005-09-23 | 2008-09-24 | 伊士曼化工公司 | 从羧酸混合物制备混合酮的选择性催化剂 |
| CN106008207B (zh) * | 2016-05-31 | 2018-10-02 | 邵阳学院 | 一种复合型磷钨酸盐催化合成柠檬酸酯的方法 |
| CN106045850B (zh) * | 2016-05-31 | 2019-01-18 | 邵阳学院 | 一种复合掺杂磷钨酸盐催化合成柠檬酸酯的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4819614B1 (ko) * | 1970-11-30 | 1973-06-14 | ||
| US3917673A (en) * | 1973-10-26 | 1975-11-04 | Eastman Kodak Co | Catalytic process for the manufacture of unsaturated acids and esters |
| DE2550979C2 (de) * | 1975-11-13 | 1984-06-07 | Röhm GmbH, 6100 Darmstadt | Verfahren zur Herstellung von Methacrylsäure durch oxydative Dehydrierung von Isobuttersäure |
| US4061673A (en) * | 1976-07-30 | 1977-12-06 | Mitsubishi Chemical Industries Ltd. | Manufacture of methacrylic acid |
| JPS5949214B2 (ja) * | 1976-11-24 | 1984-12-01 | 三菱レイヨン株式会社 | 不飽和カルボン酸またはそのエステルの製法 |
| JPS6018212B2 (ja) * | 1977-06-08 | 1985-05-09 | ジェイエスアール株式会社 | メタクリル酸製造用触媒の再生法 |
| YU41495B (en) * | 1979-01-23 | 1987-08-31 | Nippon Kayaku Kk | Process for obtaining methacrolein and methacrylic acid |
| US4232174A (en) * | 1979-03-28 | 1980-11-04 | E. I. Du Pont De Nemours And Company | Catalyst and dehydrogenation process |
-
1980
- 1980-09-05 US US06/184,592 patent/US4314075A/en not_active Expired - Lifetime
-
1981
- 1981-05-15 CA CA000377752A patent/CA1150731A/en not_active Expired
- 1981-06-08 JP JP56087995A patent/JPS5750938A/ja active Pending
- 1981-06-24 MX MX187967A patent/MX159301A/es unknown
- 1981-08-05 EP EP81303569A patent/EP0047581B1/en not_active Expired
- 1981-08-05 DE DE8181303569T patent/DE3162972D1/de not_active Expired
- 1981-09-05 KR KR1019810003316A patent/KR870001316B1/ko active
Also Published As
| Publication number | Publication date |
|---|---|
| EP0047581B1 (en) | 1984-04-04 |
| KR870001316B1 (ko) | 1987-07-13 |
| US4314075A (en) | 1982-02-02 |
| EP0047581A1 (en) | 1982-03-17 |
| CA1150731A (en) | 1983-07-26 |
| DE3162972D1 (en) | 1984-05-10 |
| MX159301A (es) | 1989-05-16 |
| JPS5750938A (en) | 1982-03-25 |
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