KR930000562A - 폴리에스테르 및 폴리에스테르 조성물의 제법 - Google Patents

폴리에스테르 및 폴리에스테르 조성물의 제법 Download PDF

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KR930000562A
KR930000562A KR1019920009649A KR920009649A KR930000562A KR 930000562 A KR930000562 A KR 930000562A KR 1019920009649 A KR1019920009649 A KR 1019920009649A KR 920009649 A KR920009649 A KR 920009649A KR 930000562 A KR930000562 A KR 930000562A
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South Korea
Prior art keywords
polyester
aromatic
lower alkyl
sulfonic acid
alkyl ester
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KR1019920009649A
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English (en)
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KR960008595B1 (ko
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구니아끼 가와구찌
도시오 나까네
겐지 히지까따
Original Assignee
가스가히 다꾸죠
폴리플라스틱스 가부시끼가이샤
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Priority claimed from JP13123691A external-priority patent/JP2807580B2/ja
Priority claimed from JP13123591A external-priority patent/JP2665074B2/ja
Application filed by 가스가히 다꾸죠, 폴리플라스틱스 가부시끼가이샤 filed Critical 가스가히 다꾸죠
Publication of KR930000562A publication Critical patent/KR930000562A/ko
Priority to KR1019960015928A priority Critical patent/KR960010846B1/ko
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Publication of KR960008595B1 publication Critical patent/KR960008595B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6886—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

폴리에스테르 및 폴리에스테르 조성물의 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 방향족 폴리에스테르를 형성하기 위해 방향족 디카르복실산의 저급 에스테르와 지방족 디올을 반응시키는 것을 포함하고, 방향족 디카르복실산의 저급 알킬 에스테르를 기준으로해서 0.02내지 5.0몰%의 하기 일반식(Ⅰ)로 표시되는 방향족 설폰산 화합물의 존재하에 촉매로써 티타늄 화합물을 사용해서 저급 알킬 에스테르와 디올의 에스테르 교환반응을 시향한 후 에스테르 교환반응 산물을 중축합하는 것을 특징으로 하는 폴리에스테르의 제법.
    HO-R-O-Ar-SO3M (Ⅰ)
    상기식에서, -Ar-은 p-치환 벤젠 및 2,6-치환 나프탈렌기 중에서 선택된 기이고, R은 -CH2CH2-, CH(CH3)CH2-, -CH2CH(CH3)- 및 -CH2CH2OCH- 중에서 선택된 2가의 기이고, M은 리튬, 나트륨 및 칼륨 중에서 선택된 알칼리 금속이다.
  2. 제1항에 있어서, 상기 방향족 설폰산 화합물의 양이 0.02내지 1.8몰%인것.
  3. 제1항에 있어서, 상기 방향족 설폰산 화합물의 양이 0.1내지 5.0몰%인것.
  4. 제1항에 있어서, 상기 방향족 디카르복실산의 저급 알킬 에스테르가 주로 디메틸 테페프탈레이트, 디메틸 2,6-나프탈렌디카르복실레이트 및 디메틸 2,7-나프탈렌카르복실레이트 중에서 선택된 것.
  5. 제1항에 있어서, 상기 지방족 디올이 주로 에틸렌 글리콜, 1,3-프로판디올 및 1,4-부탄디올 중에서 선택되는 것.
  6. 제1항에 있어서, 상기 방향족 설폰산 화합물이 에스테르교환 반응 및 반응계의 유출에 의해 형성된 저급 알콜의 양이 사용된 카르복실산(들)의 저급 알킬 에스테르(들)의 총량을 기준으로 해서 계산한 이론량의 90중량%에 도달하기 전에 부가되는 것.
  7. 제1항에 있어서, 상기 티타늄 화합물이 티타늄 테트라알콕사이드인 것.
  8. 제1항에 방법에 의해 제조된 폴리에스테르.
  9. 주요 반복 단위로 1,4-부틸렌 테레프탈레이트나 1,4-부틸렌-2,6-나프탈레이트를 포함하고, 에스테르 결합을 통해 폴리에스테르의 주쇄단에 결합된 제1항의 방향족 설폰산 화합물의 잔여물을 0.1 내지 5.0몰%(모든 반복 에스테르 유니트를 기준으로)포함하는 폴리에스테르.
  10. (A) 주요 반족단위로서 알킬렌 테레프탈레이트나 알킬렌 나프탈레이트를 포함하는 100중량부의 방향족 폴리에스테르 수지와 (B) 주요 반복 유니트로써 1,4-부틸렌 테레프탈레이트나 1,4-부틸렌 2,6-나프탈레이트와 에스테르 결합을 통해 수지의 주쇄단에 결합된 하기 일반식 (Ⅰ)로 표시되는 0.1 내지 5.0몰%(모든 반복 에스테르 단위를 기준으로)의 방향족 설폰산 화합물 1 내지 100중량부를 혼합하여 제조한 폴리에스테르 수지 조성물.
    HO-R-O-Ar-SO3M (Ⅰ)
    상기식에서, -Ar-은 p-치환 벤젠 및 2,6-치환 나프탈렌기 중에서 선택된 기이고, R은 -CH2CH2-, CH(CH3)CH2-, -CH2CH(CH3)- 및 -CH2CH2OCH2CH2- 중에서 선택된 2가의 기이고, M은 리튬, 나트륨 및 칼륨 중에서 선택된 알칼리 금속이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920009649A 1991-06-03 1992-06-03 폴리에스테르 및 폴리에스테르의 제조방법 KR960008595B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019960015928A KR960010846B1 (ko) 1991-06-03 1996-05-14 폴리에스테르 수지 조성물

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP91-131236 1991-06-03
JP13123691A JP2807580B2 (ja) 1991-06-03 1991-06-03 ポリエステル樹脂組成物
JP13123591A JP2665074B2 (ja) 1991-06-03 1991-06-03 ポリエステルの製造方法
JP91-131235 1991-06-03

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KR1019960015928A Division KR960010846B1 (ko) 1991-06-03 1996-05-14 폴리에스테르 수지 조성물

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KR930000562A true KR930000562A (ko) 1993-01-15
KR960008595B1 KR960008595B1 (ko) 1996-06-28

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US (1) US5302690A (ko)
EP (1) EP0517511B1 (ko)
KR (1) KR960008595B1 (ko)
AT (1) ATE159959T1 (ko)
BR (1) BR9202121A (ko)
DE (1) DE69222982T2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100513106B1 (ko) * 1998-06-20 2005-12-21 주식회사 휴비스 친수성이 우수한 폴리에스테르 수지 및 이의 제조방법

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2758525B2 (ja) * 1992-02-12 1998-05-28 ポリプラスチックス株式会社 改質ポリエステル
CA2395051A1 (en) 1999-12-10 2001-06-14 Jens-Peter Wiegner Catalyst systems for polycondensation reactions
US6319576B1 (en) 2000-11-20 2001-11-20 The Coca-Cola Company Method to increase the crystallization rate of polyesters
JP3623480B2 (ja) * 2002-01-07 2005-02-23 花王株式会社 電子写真用トナー
US20060079395A1 (en) * 2002-05-09 2006-04-13 Jens-Peter Wiegner Catalyst systems for polycondensation reactions
JP3998242B2 (ja) * 2002-10-29 2007-10-24 花王株式会社 トナー用ポリエステル樹脂組成物
US20080167440A1 (en) * 2007-01-10 2008-07-10 Pickel Deanna L Use of copolymerizable sulfonate salts to promote char formation in polyesters and copolyesters
PT2479205E (pt) 2008-03-28 2015-02-09 Equipolymers Gmbh Processo para produzir um poliéster que utiliza um catalisador contendo atrano

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2822348A (en) * 1951-11-14 1958-02-04 Du Pont Ester interchange catalysts
BE572649A (ko) * 1957-11-04
JPS6056180B2 (ja) * 1979-10-17 1985-12-09 旭化成株式会社 射出成形用ポリエステルの結晶化促進剤
EP0030417B2 (en) * 1979-11-30 1994-03-30 Imperial Chemical Industries Plc Compositions of melt-processable polymers having improved processibility, and method of processing
US4489190A (en) * 1980-06-11 1984-12-18 Celanese Corporation Blend of polyalkylene terephthalate and wholly aromatic polyester
US4451611A (en) * 1981-12-15 1984-05-29 Celanese Corporation Process for forming blend of polyalkylene terephthalate and wholly aromatic polyester which exhibits an anisotropic melt phase
US4451606A (en) * 1983-02-23 1984-05-29 General Electric Company Copolymeric nucleating agent for polyester
JP2763575B2 (ja) * 1989-03-31 1998-06-11 ポリプラスチックス株式会社 ポリアルキレンアリレート樹脂組成物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100513106B1 (ko) * 1998-06-20 2005-12-21 주식회사 휴비스 친수성이 우수한 폴리에스테르 수지 및 이의 제조방법

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Publication number Publication date
BR9202121A (pt) 1993-02-02
KR960008595B1 (ko) 1996-06-28
EP0517511A3 (en) 1993-02-03
DE69222982D1 (de) 1997-12-11
US5302690A (en) 1994-04-12
ATE159959T1 (de) 1997-11-15
EP0517511B1 (en) 1997-11-05
DE69222982T2 (de) 1998-06-18
EP0517511A2 (en) 1992-12-09

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