KR927003543A - 제미날 디메틸알킬 화합물, 이의 제조방법 및 액정 혼합물에서의 이의 용도 - Google Patents

제미날 디메틸알킬 화합물, 이의 제조방법 및 액정 혼합물에서의 이의 용도 Download PDF

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KR927003543A
KR927003543A KR1019920701830A KR920701830A KR927003543A KR 927003543 A KR927003543 A KR 927003543A KR 1019920701830 A KR1019920701830 A KR 1019920701830A KR 920701830 A KR920701830 A KR 920701830A KR 927003543 A KR927003543 A KR 927003543A
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compound
carbon atoms
crystal mixture
dimethylalkyl
replaced
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KR1019920701830A
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일리안 케르하르트
뮐러 잉그리트
다카마사 하라다
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엥겔하르트, 라피체
훽스트 아크티엔게젤샤프트
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Publication of KR927003543A publication Critical patent/KR927003543A/ko

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/26Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32One oxygen, sulfur or nitrogen atom
    • C07D239/34One oxygen atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/32One oxygen, sulfur or nitrogen atom
    • C07D239/38One sulfur atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D285/00Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
    • C07D285/01Five-membered rings
    • C07D285/02Thiadiazoles; Hydrogenated thiadiazoles
    • C07D285/04Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
    • C07D285/121,3,4-Thiadiazoles; Hydrogenated 1,3,4-thiadiazoles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D405/00Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
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    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/08Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/20Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
    • C09K19/2007Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/34Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C09K19/3441Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom
    • C09K19/345Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom the heterocyclic ring being a six-membered aromatic ring containing two nitrogen atoms
    • C09K19/3458Uncondensed pyrimidines
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    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/34Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C09K19/3441Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom
    • C09K19/345Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom the heterocyclic ring being a six-membered aromatic ring containing two nitrogen atoms
    • C09K19/3458Uncondensed pyrimidines
    • C09K19/3463Pyrimidine with a carbon chain containing at least one asymmetric carbon atom, i.e. optically active pyrimidines
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    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/34Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C09K19/3441Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom
    • C09K19/345Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having nitrogen as hetero atom the heterocyclic ring being a six-membered aromatic ring containing two nitrogen atoms
    • C09K19/3458Uncondensed pyrimidines
    • C09K19/3466Pyrimidine with at least another heterocycle in the chain
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    • C09K19/00Liquid crystal materials
    • C09K19/04Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06Non-steroidal liquid crystal compounds
    • C09K19/34Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C09K19/3491Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having sulfur as hetero atom
    • C09K19/3497Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having sulfur as hetero atom the heterocyclic ring containing sulfur and nitrogen atoms

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  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
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  • Materials Engineering (AREA)
  • Liquid Crystal Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

제미날 디메틸알킬 화합물, 이의 제조방법 및 액정 혼합물에서의 이의 용도
[도면의 간단한 설명]
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (8)

  1. 하기 일반식(I)의 제미날 디메틸알킬 화합물,
    상기식에서, R1은 CH3, 1개 또는 2개의 비인접 -CH2-그룹이 -O-, -S-, -CO-, -CO-O-, -O-CO-, -Si(CH3)2- 또는 -O-CO-O-에 의해 대체될 수 있으며 알킬 라디칼의 H가 F에 의해 대체될 수 있는 탄소수 2내지 16의 직쇄 또는 측쇄(비대칭 탄소원자가 존재 또는 부재하는)알킬 또는 알케닐이거나, 라디칼
    중의 하나이고, A1, A2및 A3은 동일하거나 상이하며, 2개의 H가 F에 의해 치환될 수 있는 1,4-페닐렌, 1,4-사이클로헥실렌, 피라진-2,5-디일, 피리다진-3,6-디일, 피리딘-2,5-디일, 피리미딘-2,5-디일 또는 (1,3,4)-티아디아졸-2,5-디일이며, M1및 M2는 동일하거나 상이한 -CO-O-, -O-CO-, -CO-S-, -S-CO-, -CH2-O-, -O-CH2-, -C≡C- 또는 -CH=CH- 이고 G 및 G1은 1개 또는 2개의 비인접 -CH2-그룹이 -O-, -S-, -O-CO-, -CO- 또는 -O-CO-O-에 의해 대체될 수 있는 동일하거나 상이한 탄소수 1내지 16의 직쇄 또는 측쇄 알킬렌이며, R2, R3, R4및 R5는 동일하거나 상이하며, H이거나 1개의 -CH2-그룹이 -O-, -S-, -CO-O-, -O-CO-, -CO- 또는 -O-CO-O-에 의해 대체될 수 있는 탄소수 1내지 16의 직쇄 또는 측쇄 알킬 또는 탄소수 2내지 16의 알케닐이며, k, l, m 및 n은 0또는 1이고, R6은 탄소수 1내지 10의 직쇄 알킬이다.
  2. 제1항에 있어서, -A1(-M1)k(-A2)1(-M2)m(-A3)n-그룹이
    일반식(I)의 제미날 디메틸알킬 화합물.
  3. 제1항에 있어서, -A1(-M1)k(-A2)1(-M2)m(-A3)n-그룹이
    R1은 1개의 CH2그룹이 -O-, -S-, -CO-, -CO-O- 또는 -O-CO- 에 의해 대체될 수 있는 탄소수 2내지 16의 직쇄 또는 측쇄(비대칭 탄소원자가 존재 또는 부재하는)알킬 또는 알케닐이여, G는 1개의 -CH2-그룹이 -O-, -S-, -CO-O- 또는 -O-CO- 에 의해 대체될 수 있는 탄소수 1내지 16의 직쇄 또는 측쇄 알킬렌이며, R6은 탄소수 1내지 6의 직쇄 알킬인 일반식(I)의 제미날 디메틸알킬 화합물.
  4. 제1항 내지 제3항 중의 어느 한 항에 따른 일반식(I)의 제미날 디메틸알킬 화합물의 액정 혼합물 성분으로서의 용도.
  5. 제4항에 있어서, 액정 혼합물이 네마틱인 용도.
  6. 제5항에 있어서, 액정 혼합물이 강유전성인 용도.
  7. 제1항에 따른 일반식(I)의 제미날 디메틸알킬 화합물 1개 이상의 함유하는 액정 혼합물.
  8. 제7항에 따른 액정 혼합물을 함유하는 전자광학 스위칭 및 디스플레이 장치,
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920701830A 1990-02-02 1991-01-24 제미날 디메틸알킬 화합물, 이의 제조방법 및 액정 혼합물에서의 이의 용도 KR927003543A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE4003012A DE4003012A1 (de) 1990-02-02 1990-02-02 Geminale dimethylalkyl-verbindungen, verfahren zu ihrer herstellung und ihre verwendung in fluessigkristallinen mischungen
DEP4003012.1 1990-06-02
PCT/EP1991/000129 WO1991011441A1 (de) 1990-02-02 1991-01-24 Geminale dimethylalkyl-verbindungen, verfahren zu ihrer herstellung und ihre verwendung in flüssigkristallinen mischungen

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KR927003543A true KR927003543A (ko) 1992-12-18

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US (1) US5366657A (ko)
EP (1) EP0513069A1 (ko)
JP (1) JP2995089B2 (ko)
KR (1) KR927003543A (ko)
CA (1) CA2075198A1 (ko)
DE (1) DE4003012A1 (ko)
IE (1) IE910362A1 (ko)
NO (1) NO922978D0 (ko)
PT (1) PT96647A (ko)
WO (1) WO1991011441A1 (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5478496A (en) * 1987-04-16 1995-12-26 Merck Patent Gesellschaft Mit Beschrankter Haftung Media containing thiazole derivatives and thiadiazole derivatives and having a smectic liquid-crystalline phase
WO1994010116A1 (en) * 1992-10-26 1994-05-11 Sumitomo Chemical Company, Limited Acetylene derivative, process for producing the same, liquid crystal composition containing the same as active ingredient, and liquid crystal element made therefrom
KR20030011894A (ko) * 2000-06-13 2003-02-11 바스프 악티엔게젤샤프트 5-페닐 치환된 2-(시아노아미노)피리미딘 살균제

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57177096A (en) * 1981-04-23 1982-10-30 Nippon Oil Co Ltd Oil composition for refrigerator
JPH0631365B2 (ja) * 1985-12-27 1994-04-27 東燃株式会社 トラクシヨン流体
DE3782531T2 (de) * 1986-04-21 1993-05-06 Ajinomoto Kk Optisch aktive verbindung und fluessigkristalline zusammensetzung.
GB8714537D0 (en) * 1987-06-22 1987-07-29 Ici Plc Pyrazine derivatives
US5085792A (en) * 1987-06-23 1992-02-04 Toa Nenryo Kogyo, K.K. Synthetic traction fluid
JP2691405B2 (ja) * 1987-11-06 1997-12-17 チッソ株式会社 強誘電性液晶組成物
JPH01139571A (ja) * 1987-11-26 1989-06-01 Chisso Corp 2−フエニリル−5−アルカノイルオキシピリミジン
US5034151A (en) * 1988-03-28 1991-07-23 Canon Kabushiki Kaisha Mesomorphic compound, ferroelectric liquid crystal composition containing same and ferroelectric liquid crystal device
GB8812342D0 (en) * 1988-05-25 1988-06-29 Ici America Inc Bicyclic compounds

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Publication number Publication date
IE910362A1 (en) 1991-08-28
PT96647A (pt) 1991-10-31
JPH05504349A (ja) 1993-07-08
DE4003012A1 (de) 1991-08-08
WO1991011441A1 (de) 1991-08-08
NO922978L (no) 1992-07-28
US5366657A (en) 1994-11-22
CA2075198A1 (en) 1991-08-03
JP2995089B2 (ja) 1999-12-27
EP0513069A1 (de) 1992-11-19
NO922978D0 (no) 1992-07-28

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