KR920007958A - 알킬치환 방향족 탄화수소의 제조방법 - Google Patents

알킬치환 방향족 탄화수소의 제조방법 Download PDF

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Publication number
KR920007958A
KR920007958A KR1019910017919A KR910017919A KR920007958A KR 920007958 A KR920007958 A KR 920007958A KR 1019910017919 A KR1019910017919 A KR 1019910017919A KR 910017919 A KR910017919 A KR 910017919A KR 920007958 A KR920007958 A KR 920007958A
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South Korea
Prior art keywords
aromatic hydrocarbon
potassium
substituted aromatic
catalyst
producing
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KR1019910017919A
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English (en)
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KR950001674B1 (ko
Inventor
데루노리 후지다
가즈노리 다까히따
히로야수 오오노
마사야수 이시바시
히데오 오이가와
Original Assignee
다께바야시 쇼오고
미쓰이세끼유 가가꾸고오교오 가부시기가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Priority claimed from JP2277026A external-priority patent/JPH04154733A/ja
Priority claimed from JP3049711A external-priority patent/JP2975702B2/ja
Priority claimed from JP3179283A external-priority patent/JPH04352732A/ja
Priority claimed from JP3204547A external-priority patent/JPH0524813A/ja
Priority claimed from JP3204546A external-priority patent/JPH0525064A/ja
Application filed by 다께바야시 쇼오고, 미쓰이세끼유 가가꾸고오교오 가부시기가이샤 filed Critical 다께바야시 쇼오고
Publication of KR920007958A publication Critical patent/KR920007958A/ko
Application granted granted Critical
Publication of KR950001674B1 publication Critical patent/KR950001674B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • C07C5/10—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of aromatic six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/70—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/18—Phosphorus; Compounds thereof containing oxygen with metals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

내용 없음.

Description

알킬치환 방향족 탄화수소의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 실시예 32에서 사용된 촉매의 세공분포 곡선.
제2도는 실시예 38에서 사용된 촉매의 세공분포 곡선.

Claims (9)

  1. 촉매로서 헤테로폴리산 또는 그의 염 존재하에서, 알킬화제로 방향족 탄화수소를 알킬화시킴을 특징으로 하는 알킬치환 방향족 탄화수소의 제조방법.
  2. 제1항에 있어서, 상기 방향족 탄화수소가 나프탈렌 또는 나프탈렌 유도체인 것이 특징인 알킬치환 방향족 탄화수소의 제조방법.
  3. 제1항에 있어서, 상기 알킬화제가 α-올레핀인 것이 특징인 알킬치환 방향족 탄화수소의 제조방법.
  4. 제1항에 있어서, 상기 촉매인 헤테로폴리산 또는 그의 염이 하기식(I)
    MXH3-XPW12O40(I)
    (식중, M은 주기율표 I a족 금속이고, X는 0~2.8의 수임)으로 표시되는 것인 알킬치환 방향족 탄화수소의 제조방법.
  5. 제4항에 있어서, 상기 주기율표 I a족에 속하는 금속(M)이 칼륨, 루비듐 또는 세슘인 것이 특징인 알킬치환 방향족 탄화수소의 제조방법.
  6. 제1항에 있어서, 상기 촉매가 하기식(1)-1
    KXH3-XPW12O40(1)-1
    (식중, X는 상기 정의한 바와 같음)으로 표시되는 인텅스텐산 칼륨이며, 평균 세공반경이 100~600Å인 다수의 세공을 갖는 것이 특징인 알킬치환 방향족 탄화수소의 제조방법.
  7. 제1항에 있어서, 상기 촉매인 헤테로폴리산 또는 그의 염이 하기식(2)
    MXH4-XSiW12O40(2)
    (식중, M과 X는 상기 정의한 바와 같음)으로 표시되는 것인 알킬치환 방향족 탄화수소의 제조방법.
  8. 제7항에 있어서, 상기 식(2)중 M이 칼륨, 루비듐 또는 세슘인 것이 특징인 알킬치환 방향족 탄화수소의 제조방법.
  9. 제1항에 있어서, 상기 촉매가, 인텅스텐산 수용액과 고체 탄신칼륨을 서로 접촉시켜 얻은 생성물일 것이 특징인 알킬치환 방향족 탄화수소의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910017919A 1990-10-16 1991-10-11 알킬치환 방향족 탄화수소의 제조방법 KR950001674B1 (ko)

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
JP2277026A JPH04154733A (ja) 1990-10-16 1990-10-16 エチル化ナフタレン類の製造方法
JP90-277026 1990-10-16
JP3049711A JP2975702B2 (ja) 1991-03-14 1991-03-14 アルキル置換芳香族化合物の製造方法
JP4971091 1991-03-14
JP91-49711 1991-03-14
JP91-49710 1991-03-14
JP91-179283 1991-07-19
JP3179283A JPH04352732A (ja) 1991-03-14 1991-07-19 アルキル置換芳香族化合物の製造方法
JP91-204546 1991-07-22
JP3204547A JPH0524813A (ja) 1991-07-22 1991-07-22 リンタングステン酸カリウムの製造法
JP91-204547 1991-07-22
JP3204546A JPH0525064A (ja) 1991-07-22 1991-07-22 アルキル置換芳香族化合物の製造方法

Publications (2)

Publication Number Publication Date
KR920007958A true KR920007958A (ko) 1992-05-27
KR950001674B1 KR950001674B1 (ko) 1995-02-28

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US (1) US5254766A (ko)
EP (1) EP0481360B1 (ko)
KR (1) KR950001674B1 (ko)
AT (1) ATE147715T1 (ko)
CA (1) CA2053469C (ko)
DE (1) DE69124182T2 (ko)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4138155A1 (de) * 1991-11-21 1993-05-27 Basf Ag Verfahren zur herstellung von im wesentlichen alkalifreien titansilikat-kristallen mit zeolithstruktur
US5919725A (en) * 1993-11-19 1999-07-06 Exxon Research And Engineering Co. Heteropoly salts or acid salts deposited in the interior of porous supports
WO1995013869A1 (en) * 1993-11-19 1995-05-26 Exxon Research & Engineering Company Heteropoly compounds and use in aromatic alkylation
JPH08119880A (ja) * 1994-09-27 1996-05-14 Mitsubishi Oil Co Ltd １，２，４，５，−ジメチルジイソプロピルベンゼンの製造方法
CN1062848C (zh) * 1994-12-28 2001-03-07 中国石油化工总公司 异丁烷与丁烯烷基化制取烷基化油的方法
FR2828486B1 (fr) * 2001-08-08 2005-06-17 Inst Francais Du Petrole Procede de production de phenylalcanes utilisant un catalyseur contenant au moins un heteropolyacide
US6930074B2 (en) * 2002-04-26 2005-08-16 Conocophillips Company - I. P. Legal Desulfurization and sorbent for the same
US7074737B2 (en) * 2003-12-23 2006-07-11 Supresta U.S. Llc Alkylation of triphenylphosphate
JP4985101B2 (ja) * 2006-05-29 2012-07-25 住友化学株式会社 ヘテロポリ酸塩触媒、ヘテロポリ酸塩触媒の製造方法及びアルキル芳香族化合物の製造方法
US9126883B2 (en) * 2013-06-20 2015-09-08 Uop Llc Recycle of reactor effluent in an alkylaromatic process
CN103691484B (zh) * 2013-12-17 2016-09-28 中国科学院长春应用化学研究所 一种固体酸催化剂、其制备方法及双烯烃化合物的制备方法
CN105289747A (zh) * 2015-11-25 2016-02-03 广东工业大学 一种负载型催化剂及其制备方法与催化长链烷基萘的合成方法
CN109231274B (zh) * 2018-11-05 2020-10-09 中南大学 用含钨碱煮渣制备光催化剂磷钨酸钾的方法

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* Cited by examiner, † Cited by third party
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US2773921A (en) * 1953-09-30 1956-12-11 Staudard Oil Company Phosphoric acid-vanadium pentoxide catalyst and hydrocarbon conversions therewith
US3346657A (en) * 1964-12-30 1967-10-10 Gulf Research Development Co Process for alkylating aromatic hydrocarbons using supported heteropoly acid catalyst
US4094922A (en) * 1975-02-18 1978-06-13 Standard Oil Company Alkylation of aromatics using amphora shaped catalysts
JPH0618796B2 (ja) * 1985-03-27 1994-03-16 軽質留分新用途開発技術研究組合 パラジアルキルベンゼンの製造方法
JPS61280439A (ja) * 1985-05-13 1986-12-11 Idemitsu Kosan Co Ltd アルケニル芳香族炭化水素誘導体の製造方法
US5097061A (en) * 1988-06-24 1992-03-17 Nippon Petrochemicals Co., Ltd. Method for preparing α-(4-isobutylphenyl)propionic acid or its precursor
JP2546545B2 (ja) * 1990-02-02 1996-10-23 株式会社日本触媒 アルキルナフタレン類の製造方法

Also Published As

Publication number Publication date
DE69124182T2 (de) 1997-06-05
EP0481360A2 (en) 1992-04-22
CA2053469A1 (en) 1993-01-20
KR950001674B1 (ko) 1995-02-28
US5254766A (en) 1993-10-19
DE69124182D1 (de) 1997-02-27
ATE147715T1 (de) 1997-02-15
EP0481360A3 (en) 1994-09-07
EP0481360B1 (en) 1997-01-15
CA2053469C (en) 1997-08-26

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