KR920006390A - 비이온성 및 부분적으로는 음이온성으로 안정화되는 물에 분산가능한 폴리우레탄/아크릴 접합 공중합체 - Google Patents

비이온성 및 부분적으로는 음이온성으로 안정화되는 물에 분산가능한 폴리우레탄/아크릴 접합 공중합체 Download PDF

Info

Publication number
KR920006390A
KR920006390A KR1019900015229A KR900015229A KR920006390A KR 920006390 A KR920006390 A KR 920006390A KR 1019900015229 A KR1019900015229 A KR 1019900015229A KR 900015229 A KR900015229 A KR 900015229A KR 920006390 A KR920006390 A KR 920006390A
Authority
KR
South Korea
Prior art keywords
polyurethane
acrylic
copolymer
acid
conjugated
Prior art date
Application number
KR1019900015229A
Other languages
English (en)
Other versions
KR100187306B1 (ko
Inventor
이이. 발라탄 서지오
Original Assignee
윌리엄 쥐. 콩거
바스프 코오포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23656241&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=KR920006390(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by 윌리엄 쥐. 콩거, 바스프 코오포레이션 filed Critical 윌리엄 쥐. 콩거
Publication of KR920006390A publication Critical patent/KR920006390A/ko
Application granted granted Critical
Publication of KR100187306B1 publication Critical patent/KR100187306B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/067—Polyurethanes; Polyureas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C08F299/02—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates
    • C08F299/06—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers from unsaturated polycondensates from polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S525/92—Polyurethane having terminal ethylenic unsaturation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31605—Next to free metal

Abstract

내용 없음

Description

비이온성 및 부분적으로는 음이온성으로 안정화되는 물에 분산가능한 폴리우레탄/아크릴 접합 공중합체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 폴리이소시아네이트와, 이소시아네이트와 반응하는 적어도 두개의 작용기를 가지는 화합물과, 이소시아네이트와 반응하는 단일 작용기를 가지는 폴리에테르와, 의 반응생성물인 에틸렌계 말단 폴리우레탄 거대단량체와, 하나 이상의 에틸렌계 불포화 단량체와, 의 반응 생성물로 되는 물과 희석가능한 폴리우레탄/아크릴 접합 공중합체.
  2. 제1항에 있어서, 차단제와 더 반응하는 폴리우레탄/아크릴 접합 공중합체.
  3. 제2항에 있어서, 상기 차단제가 디올, 트리올, 아미노포리올 및 이들의 혼합물로 부터 선택되는 폴리우레탄/아크릴 접합 공중합체.
  4. 제3항에 있어서, 상기차단제가 3개 내지 12개의 탄소원자를 가지는 직쇄 또는 분자쇄 라올, 바람직하게는 프로필렌 글리콜, 부틸렌 글리콜, 네오 펜틸글리콜 또는 1,6-헥산디올, 3개 내지 12개의 탄소원자를 가지는 직쇄 또는 분자쇄 지방족 트리올, 바람직하게는 트리메틸올에탄, 트리메틸올프로판, 펜타에틸트리톨 또는 이들의혼합물, 또는 2개 내지 12개의 탄소원자를 가지는 아미노 폴리올, 바람직하게는 아미노에탄올 또는 디에탄올아민, 으로부터 선택되는 폴리우레탄/아크릴 접합 공중합체.
  5. 상기 항들중 어느 한 항에 있어서, 약 15,000달톤 내지 60,000달톤의 평균분자량을 가지는 폴리우레탄/아크릴 접합 공중합체.
  6. 상기 항들중 어느 한 항에 있어서, 이소시아네이트와 반응하는 적어도 두개의 적용기를 가지는 상기의 화합물이 에스테르 폴리올, 디올, 트리올 및 이들의 혼합물로 이루어진 그룹으로 부터 선택되는 폴리우레탄/아크릴 접합 공중합체.
  7. 제6항에 있어서, 이소시아네이트와 반응하는 적어도 두개의 작용기를 가지는 상기의 화합물이, 3개 내지 12개의 탄소원자를 가지는 직쇄 또는 분지쇄 지방족 디올, 바람직하게는 에틸렌 글리콜, 프로필렌 글리콜, 부틸렌 글리콜, 네오펜틸 글리콜, 1,6-헥산디올 및 이들의 혼합물, 3개 내지 12개의 탄소원자를 가지는 직쇄 또는 분자쇄 지방족 트리올, 바람직하게는 트리메틸로에탄, 트리메틸로 프로판, 펜타에틸트리톨 및 이들의 혼합물, 또는 4개 내지 12개의 탄소원자를 가지는 폴리에스테르 폴리올, 바람직하게는 3-히드록시2,2-디메틸프로피온산의 3-히드록시-2,2-디메틸프로필 에스테르, 로부터 선택되는 폴리우레탄/아크릴 접합 공중합체.
  8. 상기 항들 중 어느 한 항에 있어서, 상기 폴리이소시아네이트가, 지방족 폴리이소시아네이트, 시클로지방족 폴리이소시아네이트, 지방족 이소시안유레이트 및 이들의 혼합물로부터 선택되거나, 바람직하게는 1,4-테트라메틸렌 디이소시아네이트, 1,6-헥사메틸렌 디이소시아네이트, 1,3-비스-[2-(2-이소시아네이트)프로필]벤젠(TMXPI),메타-크실렌 디이소시아네이트,비스-(이소시아네이토에틸 푸마레이트), 이소포론 디이소시아네이트(IPDI)및 메틸렌비스-(4-시클로헥실 이소시아네이트)로 부터 선택되는 폴리우레탄/아크릴 접합 공중합체.
  9. 상기 항들중 어느 한 항에 있어서, 상기 에틸렌계 불포화 단량체가, 아크릴산, 메트아크릴산, 아크릴산의 C1-C6알킬 에스테르, 메트아크릴산의 C1-C6알킬 에스테르, 아크릴산의 C1-C6히드로알킬 에스테르, 메트아크릴산의 C1-C6히드로알킬 에스테르, 푸말산의 C1-C6알킬 에스테르, 푸말산의 C-C히드록시알킬 에스테르, 스티렌 및 비닐톨투엔으로 이루어진 그룹에서 선택되는 폴리우레탄/아크릴 접합 공중합체.
  10. 상기 항들중 어느 한 항에 있어서, 상기 폴리에테르가 폴리에테르 알코올 또는 폴리에테르아민으로 부터 선택되며, 바람직하게는 약1,200달톤 내지 3,000달톤의 평균 분자량을 가지는 폴리에테르 알코올로 부터 선택되는 폴리우레탄/아크릴 접합 공중합체.
  11. 상기 항들중 어느 한 항에 있어서, 상기 에틸렌계 말단기 폴리우레탄 거대단량체가 약3,000달톤 내지 20,000달톤의 평균분자량을 가지는 폴리우레탄/아크릴 접합 공중합체.
  12. 제10항에 있어서, 상기 접합 공중합체가 약5중량% 내지 25중량%의 상기 폴리에테르 알코올을 포함하는 폴리우레탄/아크릴 접합 공중합체.
  13. 제1항에 있어서, 폴리이소아네이트와, 이소시아네이트와 반응하는 적어도 두개의 작용기를 가지는 화합물과, 이소시아네이트와 반응하는 단일 작용기를 가지는 폴리에테르와, 의 반응 생성물인 에틸렌계 말단 폴리우레탄 거대 단량체 약12중량% 내지 25중량%와, 아크릴산의 C1-C6알킬 에스테르, 메트아크릴산의 C1-C6알킬 에스테르, 아크릴산의 C1-C6히드록시알킬 에스테르, 메트아크릴산의 C1-C6히드록시알킬 에스테르, 푸말산의 C1-C6히드록시알킬 에스테르, 푸살산의 C1-C6히드록시알킬 에스테르, 스티렌, 비닐톨투엔, 아크릴산, 및 메트아크릴산으로 이루어진 그룹에서 선택된 하나 이상의 에틸렌계 불포화 단량체와, 의 반응 생성물로 되는 물과 희석 가능한 폴리우레탄/아크릴 접합 공중합체.
  14. 상기의 항들중 어느 한 항에 따른 물과 희석 가능한 폴리우레탄/아크릴 접합 공중합체 약30중량% 내지 약 80중량%를 포함하는 안료페이스트.
  15. 제1항 내지 제13항중 어느 한 항에 따른 물과 희석가능한 폴리우레탄/아크릴 접합 공중합체로 되는 코팅조성물의 하나 이상의 기초피막으로 코팅된 기본체.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900015229A 1989-10-06 1990-09-25 비이온적으로 안정화되고 부분적으로는 음이온적으로 안정화된 수분산성폴리우레탄/아크릴그라프트 공중합체 KR100187306B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/417,998 US5169719A (en) 1989-10-06 1989-10-06 Nonionically and partially anionically stabilized water-dispersible polyurethane/acrylic graft copolymers
US07/417998 1989-10-06
US7/417998 1989-10-06

Publications (2)

Publication Number Publication Date
KR920006390A true KR920006390A (ko) 1992-04-27
KR100187306B1 KR100187306B1 (ko) 1999-05-15

Family

ID=23656241

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900015229A KR100187306B1 (ko) 1989-10-06 1990-09-25 비이온적으로 안정화되고 부분적으로는 음이온적으로 안정화된 수분산성폴리우레탄/아크릴그라프트 공중합체

Country Status (10)

Country Link
US (1) US5169719A (ko)
EP (1) EP0424705B1 (ko)
JP (1) JP3088444B2 (ko)
KR (1) KR100187306B1 (ko)
AU (1) AU635768B2 (ko)
BR (1) BR9004912A (ko)
CA (1) CA2021326C (ko)
DE (1) DE69024024T2 (ko)
ES (1) ES2081889T3 (ko)
NZ (1) NZ235161A (ko)

Families Citing this family (93)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0471972B1 (en) * 1990-07-13 1997-03-26 BASF Corporation Metallic water borne base coat composition
DK0608021T3 (da) * 1993-01-21 1997-10-20 Akzo Nobel Nv Vanddispergerbar hybridpolymer.
DE4332015A1 (de) * 1993-09-21 1995-03-23 Basf Lacke & Farben Verfahren zur Herstellung von Decklackschichten
DE4339870A1 (de) * 1993-11-23 1995-05-24 Basf Lacke & Farben Verfahren zur Herstellung einer zweischichtigen Lackierung und wäßrige Lacke
JPH09505631A (ja) * 1994-04-30 1997-06-03 ワッカー−ケミー・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 水性コーティング組成物及び観察される色が視角に依存する多層塗り塗装系の製造方法
US5650461A (en) * 1994-08-17 1997-07-22 State Of Israel-Ministry Of Defence, Armament Development Authority, Rafael Paint compositions for high infra-red reflectivity with a low gloss property
DE4437535A1 (de) * 1994-10-20 1996-04-25 Basf Lacke & Farben Polyurethanmodifziertes Polyacrylat
US5639841A (en) * 1995-02-28 1997-06-17 Union Carbide Chemicals & Plastics Technology Corporation Polymers containing macromonomer mixtures
DE19535502A1 (de) * 1995-09-25 1997-03-27 Bayer Ag Pigmentpräparationen
JPH09157342A (ja) * 1995-12-07 1997-06-17 Nof Corp ポリウレタン樹脂の水系分散物、ポリウレタン樹脂グラフト重合体の水系分散物および水系塗料組成物
DE19602040A1 (de) * 1996-01-20 1997-07-24 Herberts Gmbh Wäßrige Polymer/Polyurethan-Harz-Bindemitteldispersion, deren Herstellung, Überzugsmittel und Verwendung
DE19611812A1 (de) * 1996-03-26 1997-10-02 Herberts Gmbh Wasserverdünnbare Dispersion, Verfahren zu ihrer Herstellung und Überzugsmittel
US6153690A (en) * 1996-05-29 2000-11-28 Rohm And Haas Company Method of producing isocyanate-modified latex polymer
US6057400A (en) * 1996-06-06 2000-05-02 The Sherwin-Williams Company Waterborne basecoat compositions for use in basecoat/clearcoat applications
ES2143860T3 (es) * 1996-09-06 2000-05-16 Dupont Performance Coatings Revestimientos acuosos, su produccion y su utilizacion para la produccion de pinturas de capas multiples.
US5859111A (en) * 1996-12-18 1999-01-12 National Starch And Chemical Investment Holding Corporation Processes for making nonionic aqueous polyurethane dispersions
DE19705219C2 (de) * 1997-02-12 2002-10-24 Basf Coatings Ag Universell einsetzbare Pigmentpasten und ihre Verwendung zur Herstellung von wäßrigen Lacken
US5955532A (en) * 1997-07-17 1999-09-21 E. I. Du Pont De Nemours And Company Aqueous coating composition of a self-stabilized crosslinked latex
WO2000046265A1 (de) 1999-02-03 2000-08-10 Basf Coatings Ag Polyurethan und seine verwendung in der wässrigen kunststofflackierung
US6239209B1 (en) 1999-02-23 2001-05-29 Reichhold, Inc. Air curable water-borne urethane-acrylic hybrids
DE19908001A1 (de) 1999-02-25 2000-08-31 Basf Coatings Ag Hochkratzfeste Mehrschichtlackierung, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19908013A1 (de) 1999-02-25 2000-08-31 Basf Coatings Ag Mit aktinischer Strahlung und gegebenenfalls themisch härtbare Pulverslurrys, Verfahren zu ihrer Herstellung und ihre Verwendung
US6635314B1 (en) 1999-03-17 2003-10-21 E. I. Du Pont De Nemours And Company High solids clear coating composition
BR0010383A (pt) 1999-03-17 2002-02-05 Du Pont Composição de revestimento transparente e método de produção de revestimento transparente
US6855779B1 (en) 1999-03-17 2005-02-15 E. I. Du Pont De Nemours And Company High solid epoxy, melamine and isocyanate compositions
CA2361299A1 (en) 1999-03-17 2000-09-21 E.I. Du Pont De Nemours And Company High solids acid etch resistant clear coating composition
NZ514219A (en) 1999-03-17 2003-03-28 High solids acid etch and mar resistant clear coating composition
DE19914896A1 (de) 1999-04-01 2000-10-05 Basf Coatings Ag Thermisch und/oder mit aktinischer Strahlung härtbarer wäßriger Beschichtungsstoff und seine Verwendung
DE19914898C2 (de) 1999-04-01 2002-10-24 Basf Coatings Ag Vernetzungsmittel für auf der Basis von Pyrimidin für thermisch härtbare Zusammensetzungen und deren Verwendung
DE19920799A1 (de) 1999-05-06 2000-11-16 Basf Coatings Ag Thermisch und mit aktinischer Strahlung härtbarer Beschichtungsstoff und seine Verwendung
DE19921457B4 (de) 1999-05-08 2006-05-04 Basf Coatings Ag Modulsystem zur Herstellung wäßriger Beschichtungsstoffe, Verfahren zu deren Herstellung und Verwendung sowie damit hergestellte Lackierungen
DE19924172A1 (de) 1999-05-25 2000-11-30 Basf Coatings Ag Beschichtungsstoff mit einer Mischung aus Kieselsäuren und Harnstoff und/oder Harnstoffderivaten
US6635706B1 (en) 1999-06-23 2003-10-21 Reichhold, Inc. Urethane-acrylic hybrid polymer dispersion
DE19930555C1 (de) 1999-07-02 2001-01-18 Basf Coatings Ag Wäßriger Beschichtungsstoff, insbesondere wäßriger Füller oder Steinschlagschutzgrund
DE19932497A1 (de) 1999-07-12 2001-01-18 Basf Coatings Ag Wäßriger Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung
DE19938759A1 (de) 1999-08-16 2001-02-22 Basf Coatings Ag Beschichtungsstoff und seine Verwendung zur Herstellung hochkratzfester mehrschichtiger Klarlackierungen
DE19940857A1 (de) 1999-08-27 2001-03-01 Basf Coatings Ag Sol-Gel-Überzug für einschichtige oder mehrschichtige Lackierungen
DE19944483A1 (de) 1999-09-16 2001-03-29 Basf Coatings Ag Integriertes Lackierverfahren für Kunststoffteile enthaltende Karosserien oder Kabinen von PKW und Nutzfahrzeugen sowie deren Ersatzteile und Anbauteile
DE19948821A1 (de) 1999-10-09 2001-05-23 Basf Coatings Ag Elektrisch leitfähiger Hydroprimer für Kunststoffe
DE19953203A1 (de) 1999-11-05 2007-12-06 Basf Coatings Ag Verfahren zur Herstellung farb- und/oder effektgebender Mehrschichtlackierungen unter Verwendung selbstvernetzender Pfropfmischpolymerisate von Polyurethanen sowie neue selbstvernetzende Polyurethane und ihre Propfmischpolymerisate
US6342558B1 (en) * 1999-11-17 2002-01-29 Basf Corporation Waterborne primer with improved chip resistance
DE10004494A1 (de) 2000-02-02 2001-08-16 Basf Coatings Ag Physikalisch, thermisch oder thermisch und mit aktinischer Strahlung härtbarer wässriger Beschichtungsstoff und seine Verwendung
DE10004487A1 (de) 2000-02-02 2001-08-16 Basf Coatings Ag Physikalisch, thermisch oder thermisch und mit aktinischer Strahlung härtbare wässrige Zusammensetzungen und ihre Folgeprodukte sowie deren Herstellung
DE10004726A1 (de) * 2000-02-03 2001-08-16 Basf Coatings Ag Thermisch und/oder mit aktinischer Strahlung härtbarer wäßriger Beschichtungsstoff und seine Verwendung
DE10008946C1 (de) 2000-02-25 2001-10-18 Basf Coatings Ag Verfahren zur Herstellung farb- und/oder effektgebender Mehrschichtlackierungen auf Automobilkarosserien
US6384131B1 (en) 2000-05-01 2002-05-07 The Sherwin-Williams Company Waterborne basecoat compositions for use in basecoat/clearcoat applications
JP2001354736A (ja) * 2000-06-12 2001-12-25 Lock Paint Kk 水系樹脂組成物
DE10043405C1 (de) 2000-09-04 2002-06-27 Basf Coatings Ag Verfahren zur Herstellung farb- und/oder effektgebender Lackierungen
DE10043810A1 (de) 2000-09-06 2002-04-04 Basf Coatings Ag Bindemittellösung und ihre Verwendung für die KFZ-Kleinstreparatur im Teil
WO2002034808A1 (en) * 2000-10-25 2002-05-02 Akzo Nobel N.V. Photoactivatable water borne coating composition
US6685985B2 (en) 2001-02-09 2004-02-03 Basf Corporation Method of improving the appearance of coated articles having both vertical and horizontal surfaces, and coating compositions for use therein
DE10129899A1 (de) 2001-06-21 2003-01-09 Basf Coatings Ag Physikalisch, thermisch oder thermisch und mit aktinischer Strahlung härtbarer wäßriger Beschichtungsstoff und seine Verwendung
DE10130972C1 (de) 2001-06-27 2002-11-07 Basf Coatings Ag Verfahren zur Herstellung von Beschichtungen aus thermisch und mit aktinischer Strahlung härtbaren Beschichtungsstoffen und mit dem Verfahren herstellbare Lackierungen
DE10206225C1 (de) 2002-02-15 2003-09-18 Basf Coatings Ag Verfahren zur Herstellung farb- und/oder effektgebender Mehrschichtlackierungen
JP2003261818A (ja) * 2002-03-12 2003-09-19 Kansai Paint Co Ltd 高固形分塗料組成物
US6989418B2 (en) 2002-12-31 2006-01-24 Avery Dennison Corporation Aqueous film-forming mixtures and conformable films and articles made therefrom
DE502004007096D1 (de) 2003-02-24 2008-06-19 Basf Se Polymere enthaltend Phosphor- und/oder Phosphonsäure Gruppen zur Metalloberflächenbehandlung
WO2005047390A1 (en) * 2003-11-13 2005-05-26 Akzo Nobel Coatings International B.V. Coating/pretreatment composition and methods of using the same
DE102005012589B4 (de) 2005-03-18 2007-06-14 Basf Coatings Ag Mit UV-A-Strahlung härtbares, lösemittelhaltiges Gemisch, Verfahren zu seiner Herstellung und seine Verwendung
CN101228201B (zh) * 2005-06-07 2011-02-16 路博润高级材料公司 含反应性双键的聚氨酯基颜料分散剂
US8487051B2 (en) 2005-06-07 2013-07-16 Lubrizol Advanced Materials, Inc. Polyurethane based pigment dispersants which contain reactive double bonds
CA2612889C (en) * 2005-07-01 2011-06-28 The Sherwin-Williams Company Multi-layer coating system including a hydroxyl modified polyurethane dispersion binder
WO2008116764A1 (de) * 2007-03-26 2008-10-02 Basf Se Wasseremulgierbare polyisocyanate
DE102007031594A1 (de) 2007-07-06 2009-01-08 Basf Coatings Ag Universeller Spotblender für Einkomponenten- und Zweikomponentenklarlacke
DE102007038487A1 (de) * 2007-08-14 2009-02-19 Basf Coatings Ag Wässriger Beschichtungsstoff, Verfahren zu seiner Herstellung und seine Verwendung
US8092921B2 (en) 2007-08-17 2012-01-10 Ppg Industries Ohio, Inc Clearcoat composition for use in waterborne basecoat-clearcoat composite coatings
JP2009057451A (ja) * 2007-08-31 2009-03-19 Nippon Polyurethane Ind Co Ltd アクリル・ウレタンブロック共重合体水性エマルジョンおよびその製造方法ならびに水性コーティング材
GB0822674D0 (en) * 2008-12-12 2009-01-21 Nuplex Resins Bv A crosslinkable polymer binder
US8857629B2 (en) 2010-07-15 2014-10-14 International Business Machines Corporation Composite membrane with multi-layered active layer
US8709536B2 (en) 2010-09-01 2014-04-29 International Business Machines Corporation Composite filtration membranes and methods of preparation thereof
US8727135B2 (en) 2010-09-01 2014-05-20 International Business Machines Corporation Composite filtration membranes and methods of preparation thereof
EP2657015B1 (en) * 2010-12-22 2017-06-14 Sumitomo Bakelite Company, Ltd. Surface layer material and melamine decorative laminate
US9022227B2 (en) 2011-03-21 2015-05-05 International Business Machines Corporation Composite membranes and methods of preparation thereof
US20130041042A1 (en) * 2011-08-08 2013-02-14 John S. Boyden, Jr. Polymeric compositions and articles of manufacture for wound and burn treatment and other uses
US9561474B2 (en) 2012-06-07 2017-02-07 International Business Machines Corporation Composite membrane with multi-layered active layer
US20150152287A1 (en) * 2012-06-26 2015-06-04 Axalta Coating Systems Ip Co., Llc Water-based coating compositions
WO2014026780A1 (en) 2012-08-16 2014-02-20 Basf Coatings Gmbh Coating compositions containing benzotrizol based uv-absorbers
RU2665923C2 (ru) 2012-09-28 2018-09-05 Басф Се Вододиспергируемые полиизоцианаты
KR101459727B1 (ko) * 2012-10-26 2014-11-13 부산대학교 산학협력단 폴리아크릴산계 블록 공중합체와 이의 제조방법 및 이를 포함하는 자기마모형 도료 조성물
US20140249274A1 (en) * 2013-03-04 2014-09-04 Bayer Materialscience Llc High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers
US9156298B2 (en) 2013-03-15 2015-10-13 Ford Global Technologies, Llc Method of producing a graphic design on a vehicle body
CN103254755B (zh) * 2013-05-27 2016-01-27 宝山钢铁股份有限公司 具有优异耐候性、耐蚀性和耐碱性的热镀铝锌钢板及其制备方法和表面处理剂
DE102014007805A1 (de) 2014-05-27 2015-12-03 WindplusSonne GmbH Solarabsorber, Verfahren zu seiner Herstellung und seine Verwendung
DE102014013600A1 (de) 2014-09-13 2016-03-17 WindplusSonne GmbH Solarabsorber, Verfahren zu seiner Herstellung und seine Verwendung
EP3387037B1 (en) 2015-12-09 2019-11-06 Basf Se Water-dispersible polyisocyanates
WO2019068529A1 (en) 2017-10-06 2019-04-11 Basf Se DISPERSIBLE POLYISOCYANATES IN WATER
AU2019200390B2 (en) * 2018-01-31 2024-04-11 Dow Global Technologies Llc Coating formulation with a poly(oxyalkylene-urethane) associative thickener modified with a hydrophobic oligomer
DE102018207815A1 (de) 2018-05-18 2019-11-21 Karl Wörwag Lack- Und Farbenfabrik Gmbh & Co. Kg Mehrschichtige, farb- und/oder effektgebende Lackierung sowie Verfahren zur Bildung einer Basislackschicht
US10781310B2 (en) 2019-02-08 2020-09-22 Covestro Llc Polymer polyol stabilizers
CN111072910A (zh) * 2019-12-31 2020-04-28 湖南松井新材料股份有限公司 一种非离子聚氨酯丙烯酸酯及其制备方法与应用
WO2021151774A1 (en) 2020-01-30 2021-08-05 Basf Se Color-stable curing agent compositions comprising water-dispersible polyisocyanates
CN111875769B (zh) * 2020-08-21 2022-03-22 山西省应用化学研究所(有限公司) 一种高固含量水性聚氨酯复合乳液及其制备方法
WO2022184522A1 (de) 2021-03-02 2022-09-09 Basf Se Wasseremulgierbare polyisocyanate mit verbesserten eigenschaften

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3624020A (en) * 1967-09-27 1971-11-30 Bayer Ag Modified aqueous dispersions
BE757935A (fr) * 1969-10-23 1971-04-01 Bayer Ag Procede de preparation de polymeres cationiques modifies en emulsion
DE1953349C3 (de) * 1969-10-23 1975-07-03 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung wäßriger Dispersionen von Polymerisaten aus olefinisch ungesättigten Monomeren
BE757936A (fr) * 1969-10-23 1971-04-01 Bayer Ag Procede de preparation de polymeres anioniques modifies en emulsion
US4198330A (en) * 1974-04-19 1980-04-15 American Cyanamid Company Polyurethane latices modified by a vinyl polymer
US4119602A (en) * 1977-04-07 1978-10-10 W. R. Grace & Co. Aqueous urethane codispersions
US4318833A (en) * 1980-05-16 1982-03-09 Inmont Corporation Water reducible coating compositions of acrylic-urethane polymers
CS223409B1 (en) * 1981-04-17 1983-10-28 Slavko Hudecek Grafted copolymeres and method of preparation of the same
EP0064809B2 (en) * 1981-04-28 1992-02-12 Imperial Chemical Industries Plc Copolymerisation of unsaturated urethane monomers
US4403085A (en) * 1981-12-14 1983-09-06 Ppg Industries, Inc. Polyurethane crosslinkers, and the process for preparing and using the same
US4521546A (en) * 1981-12-21 1985-06-04 Olin Corporation Graft copolymers from vinyl monomers and polyurethane oligomers and polyurethanes prepared therefrom
US4518724A (en) * 1982-10-04 1985-05-21 Nippon Paint Co., Ltd. Aqueous coating composition
NL8401785A (nl) * 1984-06-04 1986-01-02 Polyvinyl Chemie Holland Werkwijze voor de bereiding van een waterige dispersie van urethan-acrylaat entcopolymeren, alsmede aldus verkregen stabiele waterige dispersie.
JPS6424816A (en) * 1987-07-21 1989-01-26 Mitsui Toatsu Chemicals Photo-setting resin composition
US4794147A (en) * 1987-07-24 1988-12-27 Basf Corporation, Inmont Division Novel non-ionic polyurethane resins having polyether backbones in water-dilutable basecoats
DE3806066A1 (de) * 1988-02-26 1989-09-07 Bayer Ag Verfahren zur herstellung von waessrigen polymerisatdispersionen, die so erhaeltlichen dispersionen und ihre verwendung zur herstellung von beschichtungen
US5093412A (en) * 1989-08-23 1992-03-03 Basf Corporation Macromers for graft polyols and the polyols prepared therefrom

Also Published As

Publication number Publication date
JP3088444B2 (ja) 2000-09-18
ES2081889T3 (es) 1996-03-16
US5169719A (en) 1992-12-08
CA2021326C (en) 2002-02-05
AU6226490A (en) 1991-04-11
EP0424705A3 (en) 1991-11-27
BR9004912A (pt) 1991-09-10
DE69024024T2 (de) 1996-08-01
KR100187306B1 (ko) 1999-05-15
CA2021326A1 (en) 1991-04-07
AU635768B2 (en) 1993-04-01
NZ235161A (en) 1991-12-23
EP0424705A2 (en) 1991-05-02
JPH03166212A (ja) 1991-07-18
DE69024024D1 (de) 1996-01-18
EP0424705B1 (en) 1995-12-06

Similar Documents

Publication Publication Date Title
KR920006390A (ko) 비이온성 및 부분적으로는 음이온성으로 안정화되는 물에 분산가능한 폴리우레탄/아크릴 접합 공중합체
EP0208845B1 (en) Ultraviolet curable coatings for optical glass fiber
EP0228854B1 (en) Radiation curable acrylated polyurethane oligomer compositions
US4138299A (en) Process utilizing a photopolymerizable and moisture curable coating containing partially capped isocyanate prepolymers and acrylate monomers
CA1064642A (en) Heat-activatable, storage-stable polyurethane powders
EP0767185B1 (en) Acrylate copolymer and polymer composition containing the same
CA1198083A (en) Single coated optical fiber
US4690501A (en) Ultraviolet curable optical glass fiber coatings from acrylate terminated, end-branched polyurethane polyurea oligomers
CA1259725A (en) Post-formable radiation-curing coatings
US5596065A (en) Water-dilutable urethane resins, process for the preparation, and the use thereof
CN102781992B (zh) 含离子基团的热熔粘合剂
EP0168173B1 (en) Radiation curable acrylated polyurethane oligomer compositions
CA2482599A1 (en) Coating compositions containing polyurethane dispersions and highly crosslinked polymer particles
EP0583355B1 (en) Uv curable blend compositions and processes
CZ293372B6 (cs) Vodný systém pro vytváření povlaků z urerhan(met) akrylátisokyanátů obsahujících isokyanátové skupiny a vytvrzovaných pomocí UV
JP2001089683A (ja) イソシアネート基を有する紫外線硬化性ウレタン（メタ）アクリレートを含む弾性塗料系およびその使用
US4265973A (en) Method for coating an object made of a vulcanized polyalkylene rubber
KR960041312A (ko) 무용매 형태로 사용가능한 접착제
CA1236623A (en) Ultraviolet-curable coatings for optical glass fibers having improved adhesion
KR930010141A (ko) 피복 조성물
CA2223998A1 (en) Polyurethane polyols and coatings thereof having reduced viscosity
US4581407A (en) Strong and elastic polyurethane polyurea polycrylates and electron beam-cured coatings containing the same
CA2335258A1 (en) Process for preparing radiation-curable binders, and the coatings produced therewith
GB1575898A (en) Crosslinkable polyurethane resins
US4716209A (en) Strong and elastic polyurethane polyurea polyacrylates and electron beam-cured coatings containing the same

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20081229

Year of fee payment: 11

LAPS Lapse due to unpaid annual fee