KR910021470A - 신규의 에틸렌 알파-올레핀 중합체 치환된 모노- 및 디카복실산 분산제 첨가제 - Google Patents

신규의 에틸렌 알파-올레핀 중합체 치환된 모노- 및 디카복실산 분산제 첨가제 Download PDF

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KR910021470A
KR910021470A KR1019910001669A KR910001669A KR910021470A KR 910021470 A KR910021470 A KR 910021470A KR 1019910001669 A KR1019910001669 A KR 1019910001669A KR 910001669 A KR910001669 A KR 910001669A KR 910021470 A KR910021470 A KR 910021470A
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South Korea
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polymer
additive
acid
monounsaturated
ethylene
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KR1019910001669A
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KR0164852B1 (ko
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률 송 원
로씨 앨버드
윌리암 터너 하워드
쥬니어 하워드 커티스 웰보른
딘 런드버그 로버트
구티에레츠 안토니오
아서 클레이스트 로버트
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존 제이. 마혼
엑손 케미칼 패턴츠 인코포레이티드
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Publication of KR910021470A publication Critical patent/KR910021470A/ko
Priority claimed from CA002251599A external-priority patent/CA2251599A1/en
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Abstract

내용 없음

Description

신규의 에틸렌 알파-올레핀 중합체 치환된 모노- 및 디카복실산 분산제 첨가제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (29)

  1. C3내지 C10모노불포화 모노카복실산 생성 잔기 및 C3내지 C10모노불포화 디카복실산 생성 잔기중 적어도 하나로 치환된 에틸렌 알파-올레핀 중합체〔상기 중합체는 일반식 H2C=CHT1(여기서, T1은 탄소수 1내지 18의 알킬그룹이다)의 알파-올레핀 적어도 하나 및 에틸렌으로부터 유도된 단량체 단위를 포함하며, 약 300내지 20,000의 수평균 분자량을 가지고, 상기 중합체 쇄의 평균 적어도 약 30%가 말단 에테닐리덴 불포화기를 포함한다〕를 포함하며, 약 4.1 미만의 VR값을 가짐을 특징으로 하는 연료 조성물에 유용한 첨가제.
  2. 제1항에 있어서, 상기 중합체가 약 700 내지 약 15,000의 수평균 분자량을 갖는 첨가제.
  3. 제2항에 있어서, 상기 수평균 분자량이 약 1,500 내지 10,000인 첨가제.
  4. 제1항에 있어서, 상기 중합체가 약 20 내지 약 80몰%의 에틸렌 함량을 갖는 첨가제.
  5. 제1항에 있어서, 상기 중합체가 약 45 내지 약 65몰%의 에틸렌 함량을 갖는 첨가제.
  6. 제5항에 있어서, 상기 VR값이 4.0 미만인 첨가제.
  7. 제1항에 있어서, 상기 모노불포화 카복실산 생성 잔기가 (i) 모노 불포화, C4내지 C10디카복실산 (여기에서, (a) 카복실 그룹들은 인접한 탄소원자들에 부착되고 (b) 상기 인접한 탄소 원자들중 적어도 하나는 상기 모노 불포화기의 일부임); (ii)성분 (i)의 무수물 또는 C1내지 C5알콜 유도된 모노-또는 디-에스테르 유도체; (iii) 모노 불포화 C3내지 C10모노카복실산 (여기에서, 탄소-탄소 이중결합은 카복시 그룹에 대해 알릴성이다); 및 (iv) 성분(iii)의 C1내지 C5알콜 유도된 모노- 또는 디-에스테르 유도체로 이루어진 그룹으로 부터 선택된 적어도 하나의 모노불포화 카복실산 반응물로 부터 유도되는 첨가제.
  8. 제7항에 있어서, 상기 모노불포화가 카복실산 반응물이 푸마르산, 이타콘산, 말레산, 말레산 무수물, 클로로말레산, 클로로 말레산 무수물, 아크릴산, 메타크리산, 크로톤산, 신남산 및 상기 산들의 저급 알킬 산 에스테르로 이루어진 그룹으로부터 선택된 적어도 하나의 구성원을 포함하는 첨가제.
  9. 제1항 내지 8항중 어느 한 항에 있어서, 상기 중합체가 에틸렌-공증합체를 포함하는 첨가제.
  10. 제8항에 있어서, 상기 모노불포화 카복실산 반응물이 말레산 무수물을 포함하는 첨가제.
  11. 제1항에 있어서, 상기 중합체가 할로겐을 실질적으로 함유하지 않는 첨가제.
  12. C3내지 C10모노불포화 모노카복실산 생성 잔기 및 C4내지 C10모노불포화 디카복실산 생성 잔기중 적어도 하나로 치환된 에틸렌 알파- 올레핀 중합체〔상기 중합체는 일반식 H2C=CHT1(여기서에서, T1은 탄소수 1내지 2의 알킬그룹이다)의 알파-올레핀 적어도 하나 및 에틸렌으로부터 유도된 단량체 단위를 포함하며, 약 700내지 20,000의 수평균 분자량을 가지고, 상기 중합체 쇄의 평균 적어도 약 60%가 말단 에테닐리덴 불포화기를 포함한다〕를 포함하며, 약 4.1 미만의 VR값을 가짐을 특징으로 하는 첨가제.
  13. 제12항에 있어서, 상기 중합체가 약 30내지 약 70몰%의 에틸렌을 함유하는 첨가제.
  14. 제13항에 있어서, 상기 중합체가 약 45 내지 약 65몰%의 에틸렌을 함유하는 첨가제.
  15. 제13항에 있어서, 상기 중합체가 에틸렌-프로필렌 공증합체를 포함하는 첨가제.
  16. 제15항에 있어서, 상기 중합체가 약 900 내지 약 15,000의 수평균 분자량을 갖는 첨가제.
  17. 제15항에 있어서, 상기 중합체가 약 1,500 내지 약5,000의 수평균 분자량을 갖고, 상기 모노불포화 카복실산 반응물이 말레산 무수물을 포함하는 첨가제.
  18. (A) 일반식 H2C=CHT1(여기서에서, T1은 탄소수 1내지 18의 알킬그룹이다)의 알파-올레핀 적어도 하나 및 에틸렌으로부터 유도된 단량체 단위를 포함하며, 약 300내지 20,000의 수평균 분자량을 갖는 에틸렌 알파-올레핀 중합체(상기 중합체 쇄의 평균 적어도 약 30%가 말단 에테닐리덴 불포화기를 함유한다) ; 와 (B) (i) 모노불포화 C4내지 C10디카복실산(여기에서, (a) 카복실 그룹들은 인접한 탄소원자들에 부착되고 (b) 상기 인접한 탄소원자들중 적어도 하나는 상기 모노불포화기의 일부임); (ii) 성분(i)의 무수물 또는 C1내지 C5알콜 유도된 모노-또는 디-에스테르 유도체; (iii)모노불포화 C3내지 C10모노카복실산 (여기에서, 탄소-탄소 이중결합은 카복시 그룹에 대해 알릴성이다); 및 (iv) 성분 (iii)의 C1내지 C5알콜 유도된 모노-또는 디-에스테르 유도체로 이루어진 그룹으로 부터 선택된 적어도 하나의 모노불포화 카복실산 반응물을, 상기 카복실산 잔기로 치횐된 에틸렌 알파-올레핀 중합체를 함유하는 저 침전성 생성물 혼합물(이때, 상기 생성물 혼합물은 약 4.1 이하의 VR값 및 적어도 약 0.7의 작용도를 특징으로 함)을 형성하기에 충분한 조건하에서 및 충분한 시간동안 접촉시킴을 포함하는 연료 조성물에 유용한 저침전성 첨가제의 제조방법.
  19. 제18항에 있어서, 상기 중합체(a)가 약 300 미만의 분자량을 갖는 상기 중합체의 쇄를 포함하는 저분자량 중합체 분획물 약 5중량% 미만을 함유하는 방법.
  20. 제19항에 있어서, 상기 중합체(a)가 저분자량 중합체 분획물 약 2중량% 미만을 함유하는 방법.
  21. (A) 모노불포화 모노-또는 디카복실산 생성 잔기로 치환된 에틸렌 알파-올레핀 중합체 〔이때, 상기 중합체는 일반식 H2C=CHT1(여기서에서, T1은 탄소수 1내지 18의 알킬그룹이다)의 알파-올레핀 적어도 하나 및 에틸렌으로부터 유도된 단량체 단위를 포함하며, 약 300내지 20,000의 수평균 분자량을 가지며, 상기 중합체쇄의 평균 적어도 약 30%가 말단 에테닐리덴 불포화기를 포함하며; 상기 산 생성 잔기는 (i) 모노불포화 C3내지 C10디카복실산(여기에서, (a) 카복실 그룹들은 인접한 탄소원자들에 부착되고, (b) 상기 인접한 탄소원자들중 적어도 하나, 바람직하게는 둘 모두가 상기 모노불포화기의 일부임) ; (ii) 성분(i)의 부수물 또는C1내지 C5알콜 유도된 모노-또는 디-에스테르 유도체;(iii) 모노불포화 C3내지C10모노카복실산 (여기에서, 탄소-탄소 이중결합은 카복시 그룹에 대해 알릴성이다); 및(iv)성분(iii)의 C1내지 C5알콜 유도된 모노-또는 디-에스테르 유도체로 이루어진 그룹으로부터 선택된 적어도 하나의 모노불포화 카복실산 반응물로부터 유도됨〕; 및 (B) 아민, 알코올, 금속 반응물 및 그들의 혼합물로 이루어진 그룹으로부터 선택된 적어도 하나의 친핵성 시약의 부가물을 포함하는, 연료 조성물에 유용한 첨가제로서 유용한 분산제 부가물 (이때, 상기, 첨가제는 약 4.1 미만의 이하의 VR값을 특징으로 하며, 상기 분산제는 약 4.1 미만의 VR'값을 갖는다).
  22. 제1항에 있어서, 상기 산 생성 잔기가 숙신산 무수물, 숙신산 또는 프로피온산을 포함하는 분산제 부가물.
  23. 제22항에 있어서, 상기 윤활유 분산제가 약 1.11 미만의 VR'/VRr값의 비를 특징으로 하는 분산제 부가물.
  24. 제22항에 있어서, 상기 친핵성 시약이 분자당 2 내지 60개의 탄소원자 및 1 내지 12개의 질소원자를 포함하는 분산제 부가물.
  25. 제24항에 있어서, 상기 아민이 분자당 질소원자 2 내지 약9개를 함유하는 폴리에틸렌폴리아민 (여기서, 알킬렌 그룹은 2 내지 60개의 탄소원자를 함유한단)을 포함하는 분산제 부가물.
  26. 제25항에 있어서, 상기 아민이 폴리에틸렌폴리아민을 포함하는 분산제 부가물.
  27. 제21항 또는 제22항에 있어서, 상기 알파-올레핀이 프로필렌인 분산제 부가물.
  28. 제1항의 치환된 에틸렌 알파-올레핀 중합체 약 0.001 내지 약 0.5중량%를 함유하는 액체 연료 조성물.
  29. 제21항의 분산제 부가물 약 0.001 내지 약 0.5중량%를 함유하는 액체 연료 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910001669A 1988-08-01 1991-01-31 신규의 에틸렌 알파-올레핀 중합체 치환된 모노-및 디카복실산 분산제 첨가제 KR0164852B1 (ko)

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US22675988A 1988-08-01 1988-08-01
US47362490A 1990-02-01 1990-02-01
US473,624 1990-02-01
US08/434,084 US5681799A (en) 1988-08-01 1995-05-03 Ethylene alpha-olefin/diene interpolymer-substituted carboxylic acid dispersant additives
CA002251599A CA2251599A1 (en) 1996-05-16 1996-05-16 Ethylene/alpha-olefin/diene interpolymer-substituted carboxylic acid dispersant additives
PCT/US1996/006993 WO1997043322A1 (en) 1988-08-01 1996-05-16 Ethylene/alpha-olefin/diene interpolymer-substituted carboxylic acid dispersant additives

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JPH055097A (ja) 1993-01-14
MX24336A (es) 1993-06-01
US5681799A (en) 1997-10-28
NO910345D0 (no) 1991-01-29
AU635812B2 (en) 1993-04-01
ES2137157T3 (es) 1999-12-16
JP3157177B2 (ja) 2001-04-16
AU7010991A (en) 1991-10-24
CA2034759A1 (en) 1991-08-02
JP2000510184A (ja) 2000-08-08
CA2034759C (en) 2003-06-03
KR0164852B1 (ko) 1999-01-15
ATE184047T1 (de) 1999-09-15
DE69131560T2 (de) 2000-04-06
BR9100406A (pt) 1991-10-22
EP0441548B1 (en) 1999-09-01
EP0441548A1 (en) 1991-08-14
NO910345L (no) 1991-08-02
DE69131560D1 (de) 1999-10-07

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