KR910007853A - 에폭시화반응 공정 - Google Patents

에폭시화반응 공정 Download PDF

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Publication number
KR910007853A
KR910007853A KR1019900015851A KR900015851A KR910007853A KR 910007853 A KR910007853 A KR 910007853A KR 1019900015851 A KR1019900015851 A KR 1019900015851A KR 900015851 A KR900015851 A KR 900015851A KR 910007853 A KR910007853 A KR 910007853A
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KR
South Korea
Prior art keywords
epoxidation
process according
molybdenum
catalyst
compound
Prior art date
Application number
KR1019900015851A
Other languages
English (en)
Inventor
라메스와렌 엠.
엔. 코크레인 로버트
Original Assignee
원본미기재
아르코 케미칼 테크놀로지 인코오포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 원본미기재, 아르코 케미칼 테크놀로지 인코오포레이티드 filed Critical 원본미기재
Publication of KR910007853A publication Critical patent/KR910007853A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Saccharide Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

에폭시화반응 공정
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 실리콘 산화물에 균일하고 미세하게 분산된 몰리브덴 또는 몰리브덴과 타탄의 혼합 산화물인 불용성 고체촉매의 존재 및 반응조건에서, 유기 히드로과산화물과 올레핀계 불포화 화합물과의 에폭시화 반응 공정.
  2. 제1항에 있어서, 상기 촉매가 몰리브덴 화합물과 테트라알콕시실란의 공가수분해(Co-Hydroiysis)에 의해 제조되는 에폭시화 반응공정.
  3. 제1항에 있어서, 상기 촉매가 50중량%까지의 몰리브덴 산화물을 포함하는 에폭시화 반응공정.
  4. 제1항에 있어서, 상기 촉매가 0.1내지 10 중량%의 몰리브덴 산화물을 포함하는 에폭시화 반응공정.
  5. 상기항들중 어느 한 항에 있어서, 상기 올레핀계 불포화 화합물이 프로필렌인 에폭시화 반응공정.
  6. 제1항에 있어서, 상기 촉매가 몰리브덴 화합물, 티탄화합물 및 테트라 알콕시 실란에 의해 제조되는 에폭시화 반응공정.
  7. 제1항에 있어서, 상기 촉매가 몰리브덴 화합물, 티탄화합물 및 테트라 알콕시 실란에 의해 제조되는 에폭시화 반응공정.
  8. 제7항에 있어서, 상기 티탄화합물이 티탄 알콕시화물인 에폭시화 반응공정.
  9. 상기 제7항에 있어서, 상기 촉매가 에폭시화반응에 사용되기 전에 실릴화되는 에폭시화 반응공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900015851A 1989-10-05 1990-09-29 에폭시화반응 공정 KR910007853A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US41760889A 1989-10-05 1989-10-05
US07417608 1989-10-05
US07/580,426 US5081267A (en) 1989-10-05 1990-09-13 Epoxidation process
US07580426 1990-09-13

Publications (1)

Publication Number Publication Date
KR910007853A true KR910007853A (ko) 1991-05-30

Family

ID=27023790

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900015851A KR910007853A (ko) 1989-10-05 1990-09-29 에폭시화반응 공정

Country Status (12)

Country Link
US (1) US5081267A (ko)
EP (1) EP0421781B1 (ko)
JP (1) JP2895605B2 (ko)
KR (1) KR910007853A (ko)
CN (1) CN1051356A (ko)
AT (1) ATE117998T1 (ko)
BR (1) BR9004975A (ko)
CA (1) CA2026178A1 (ko)
DE (1) DE69016559T2 (ko)
ES (1) ES2066986T3 (ko)
HU (1) HUT55652A (ko)
RU (1) RU2015972C1 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100714107B1 (ko) * 1999-08-12 2007-05-07 아지노모토 가부시키가이샤 코리네형 세균에서 자율 복제할 수 있는 플라스미드

Families Citing this family (14)

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NL9201482A (nl) * 1992-08-20 1994-03-16 Dsm Nv Epoxidatie Katalysator.
GB9417059D0 (en) * 1994-08-24 1994-10-12 Bp Chem Int Ltd Oxide catalysts
US5840933A (en) * 1996-10-29 1998-11-24 Arco Chemical Technology, L.P. Catalytic converter system and progress
ITMI981633A1 (it) 1998-07-16 2000-01-16 Enitecnologie Spa Catalizzatore a base di molibdeno e suo impiego nell'isomerizzazione di n-paraffine
JP4399913B2 (ja) * 1999-08-25 2010-01-20 住友化学株式会社 オキシラン化合物の製造方法
JP4325045B2 (ja) 1999-11-09 2009-09-02 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法、該触媒及び該触媒を用いたオキシラン化合物の製造方法
JP2001151764A (ja) * 1999-11-19 2001-06-05 Nof Corp エポキシ化合物の製造方法
WO2003050100A1 (en) * 2001-12-05 2003-06-19 Dow Global Technologies Inc. Process of preparing an olefin oxide from olefin and organic hydroperoxide
EP2618929B1 (en) 2010-09-23 2018-03-14 Council of Scientific & Industrial Research An improved process for the epoxidation of fatty acids, their esters and mixtures thereof
CN106964337B (zh) * 2016-01-14 2019-09-20 万华化学集团股份有限公司 一种环氧化催化剂的制备方法、及制备的环氧化催化剂及其应用
CN107876041A (zh) * 2017-11-24 2018-04-06 江南大学 一种应用于液相烯烃环氧化反应的三氧化钼纳米反应器的合成方法
RU2730195C1 (ru) * 2019-11-18 2020-08-19 Андрей Викторович Юндин Двигатель внутреннего сгорания (цикл юндина)
CN113181961B (zh) * 2020-01-14 2022-09-20 万华化学集团股份有限公司 一种丙烯环氧化催化剂的制备方法及其用途
US11918987B2 (en) 2020-01-14 2024-03-05 Wanhua Chemical Group Co., Ltd. Preparation method for propylene epoxidation catalyst and use thereof

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3634464A (en) * 1969-04-02 1972-01-11 Shell Oil Co Olefin epoxidation
DE2148637C3 (de) * 1970-10-01 1982-04-22 Shell Internationale Research Maatschappij B.V., 2596 's-Gravenhage Verfahren zur Herstellung von Katalysatoren vom Metall/Si-Oxid-Typ und deren Verwendung zur Herstellung von Oxiranverbindungen
US3829392A (en) * 1970-10-01 1974-08-13 Shell Oil Co Heterogeneous catalysts for olefin epoxidation
US3923843A (en) * 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
NL7209361A (ko) * 1972-07-04 1974-01-08
US3980586A (en) * 1974-08-28 1976-09-14 Mobil Oil Corporation Modified solid catalyst materials
GB1518338A (en) * 1974-11-18 1978-07-19 Degussa Process for separating epoxidation and hydroxylation catalysts from distillation residues
US4157346A (en) * 1976-10-21 1979-06-05 Olin Corporation Catalytic epoxidation of alkylene compounds
IT1152299B (it) * 1982-07-28 1986-12-31 Anic Spa Procedimento per l'espossidazione di composti olefinici

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100714107B1 (ko) * 1999-08-12 2007-05-07 아지노모토 가부시키가이샤 코리네형 세균에서 자율 복제할 수 있는 플라스미드

Also Published As

Publication number Publication date
ES2066986T3 (es) 1995-03-16
HUT55652A (en) 1991-06-28
HU906343D0 (en) 1991-04-29
CN1051356A (zh) 1991-05-15
BR9004975A (pt) 1991-09-10
DE69016559T2 (de) 1995-05-24
EP0421781B1 (en) 1995-02-01
EP0421781A1 (en) 1991-04-10
CA2026178A1 (en) 1991-04-06
ATE117998T1 (de) 1995-02-15
US5081267A (en) 1992-01-14
JPH03167179A (ja) 1991-07-19
JP2895605B2 (ja) 1999-05-24
RU2015972C1 (ru) 1994-07-15
DE69016559D1 (de) 1995-03-16

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