KR910005679B1 - 올레핀계 또는 스티렌계 중합체의 제조방법 - Google Patents

올레핀계 또는 스티렌계 중합체의 제조방법 Download PDF

Info

Publication number
KR910005679B1
KR910005679B1 KR1019880008788A KR880008788A KR910005679B1 KR 910005679 B1 KR910005679 B1 KR 910005679B1 KR 1019880008788 A KR1019880008788 A KR 1019880008788A KR 880008788 A KR880008788 A KR 880008788A KR 910005679 B1 KR910005679 B1 KR 910005679B1
Authority
KR
South Korea
Prior art keywords
styrene
aluminoxane
olefin
titanium
polymer
Prior art date
Application number
KR1019880008788A
Other languages
English (en)
Korean (ko)
Other versions
KR890002243A (ko
Inventor
히로시 마에자와
마사히꼬 쿠라모또
미찌타께 우오이
Original Assignee
이데미쓰고산 가부시끼가이샤
이데미쓰 쇼스께
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 이데미쓰고산 가부시끼가이샤, 이데미쓰 쇼스께 filed Critical 이데미쓰고산 가부시끼가이샤
Publication of KR890002243A publication Critical patent/KR890002243A/ko
Application granted granted Critical
Publication of KR910005679B1 publication Critical patent/KR910005679B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1019880008788A 1987-07-13 1988-07-13 올레핀계 또는 스티렌계 중합체의 제조방법 KR910005679B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP62173007A JP2566889B2 (ja) 1987-07-13 1987-07-13 オレフィン系重合体またはスチレン系重合体の製造方法
JP?62-173007 1987-07-13
JP173007 1988-07-12

Publications (2)

Publication Number Publication Date
KR890002243A KR890002243A (ko) 1989-04-10
KR910005679B1 true KR910005679B1 (ko) 1991-08-01

Family

ID=15952464

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880008788A KR910005679B1 (ko) 1987-07-13 1988-07-13 올레핀계 또는 스티렌계 중합체의 제조방법

Country Status (5)

Country Link
EP (1) EP0299391B1 (fr)
JP (1) JP2566889B2 (fr)
KR (1) KR910005679B1 (fr)
CA (1) CA1308853C (fr)
DE (1) DE3880568T2 (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2810098B2 (ja) * 1989-03-31 1998-10-15 出光興産株式会社 スチレン系共重合体とその製造法
JP2840605B2 (ja) * 1989-03-20 1998-12-24 出光興産株式会社 スチレン系共重合体及びその製造方法
JP2746409B2 (ja) * 1989-03-31 1998-05-06 出光興産株式会社 スチレン系共重合体及びその製造方法
JP2746410B2 (ja) * 1989-03-31 1998-05-06 出光興産株式会社 スチレン系共重合体及びその製造方法
JP2744282B2 (ja) * 1989-03-31 1998-04-28 出光興産株式会社 スチレン系共重合体及びその製造方法
DE69020470T2 (de) * 1989-04-11 1996-03-07 Mitsui Toatsu Chemicals Verfahren zur herstellung von syndiotaktischem polypropylen.
JP3048591B2 (ja) * 1989-04-11 2000-06-05 三井化学株式会社 シンジオタクチックポリオレフィンの製造方法
US5043408A (en) * 1989-06-26 1991-08-27 Sumitomo Chemical Company, Limited Ethylene-aromatic vinyl compound alternating copolymer and process for the production thereof
EP0739360B1 (fr) 1993-09-17 2001-04-11 Exxon Chemical Patents Inc. Systemes catalyseurs de polymerisation, leur production et utilisation
DE59503827D1 (de) * 1994-06-03 1998-11-12 Pcd Polymere Ag Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
EP0754706B1 (fr) * 1995-07-08 1998-08-05 PCD-Polymere Gesellschaft m.b.H. Catalyseur de polymérisation sur support et son utilisation pour la polymérisation d'oléfine
EP0757995A1 (fr) * 1995-07-08 1997-02-12 PCD-Polymere Gesellschaft m.b.H. Catalyseur de polymérisation sur support et son utilisation pour le polymérisation d'oléfines
JP4090100B2 (ja) * 1998-02-27 2008-05-28 出光興産株式会社 アルミニウム化合物およびその製造方法、オレフィン重合体製造用触媒並びにオレフィン重合体の製造方法
JP5652688B2 (ja) 2007-06-13 2015-01-14 出光興産株式会社 オレフィンと芳香族ビニル化合物からなる共重合体の製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1352996A (fr) * 1960-11-30 1964-02-21 Union Carbide Corp Nouveau procédé de polymérisation d'alpha-oléfines
DE3240383A1 (de) * 1982-11-02 1984-05-03 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von oligomeren aluminoxanen
US4665208A (en) * 1985-07-11 1987-05-12 Exxon Chemical Patents Inc. Process for the preparation of alumoxanes
CA1276748C (fr) * 1985-07-29 1990-11-20 Michitake Uoi Polymere de styrene
JPS62187708A (ja) * 1985-11-11 1987-08-17 Idemitsu Kosan Co Ltd スチレン系重合体の製造法
JPH0662641B2 (ja) * 1985-12-24 1994-08-17 三井石油化学工業株式会社 アルミノオキサン類の製造方法
JPH082925B2 (ja) * 1986-11-10 1996-01-17 出光興産株式会社 スチレン系重合体の製造方法

Also Published As

Publication number Publication date
JPS6416803A (en) 1989-01-20
EP0299391B1 (fr) 1993-04-28
JP2566889B2 (ja) 1996-12-25
EP0299391A1 (fr) 1989-01-18
DE3880568D1 (de) 1993-06-03
DE3880568T2 (de) 1993-10-07
KR890002243A (ko) 1989-04-10
CA1308853C (fr) 1992-10-13

Similar Documents

Publication Publication Date Title
EP0587143B1 (fr) Catalyseur pour polymérisation de composés vinyliques
US4680353A (en) Process for production of styrene polymers
KR910005679B1 (ko) 올레핀계 또는 스티렌계 중합체의 제조방법
RU2086563C1 (ru) Способ получения полистирола и каталитическая система для его получения
US4990580A (en) Process for production of styrene polymers
US5420089A (en) Catalyst for the production of styrene-based polymers
EP0389981B1 (fr) Procédé de préparation d'un polymère à base de styrène
JPH0374410A (ja) アルミノキサン組成物，その製造方法および前記アルミノキサン組成物を用いたオレフィン系重合体の製造法
JP4519231B2 (ja) スチレン−ブタジエン・ブロックコポリマー
RU2118329C1 (ru) Способ получения катализатора, каталитическая система для полимеризации олефинов и способ полимеризации олефинов
KR960005169B1 (ko) 알루미녹산의 제조방법
JP2531583B2 (ja) スチレン系共重合体およびその製造方法
KR950012723B1 (ko) 스티렌계 중합체의 제조방법
JP2866434B2 (ja) アルミノキサンの製造方法
US5212232A (en) Process for production of styrene-based polymers
EP0363506B1 (fr) Procédé de préparation de polymères à base de styrène
KR100349979B1 (ko) 스티렌계 중합용 다중금속 메탈로센 촉매 및 이를 이용한스티렌계 중합체의 제조방법
KR19990030925A (ko) 신디오탁틱 입체규칙성을 갖는 극성 스티렌계 중합체 및 그 제조방법
EP0812860B1 (fr) Procédé de préparation de compositions d'organo-aluminoxane
USRE35289E (en) Process for production of styrene polymers
JP2566889C (fr)
KR100343892B1 (ko) 스티렌계 중합용 신규 메탈로센 촉매 및 이를 이용한중합방법
WO2004067586A2 (fr) Systemes catalytiques a metaux de transition melanges pour la polymerisation de monomeres polymerisables
JP2013203878A (ja) 芳香族ビニル化合物重合体の製造方法

Legal Events

Date Code Title Description
A201 Request for examination
G160 Decision to publish patent application
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20010725

Year of fee payment: 11

LAPS Lapse due to unpaid annual fee