KR910000764A - 술폰화된 페닐 포스판류를 함유하는 착화합물 - Google Patents

술폰화된 페닐 포스판류를 함유하는 착화합물 Download PDF

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KR910000764A
KR910000764A KR1019890017637A KR890017637A KR910000764A KR 910000764 A KR910000764 A KR 910000764A KR 1019890017637 A KR1019890017637 A KR 1019890017637A KR 890017637 A KR890017637 A KR 890017637A KR 910000764 A KR910000764 A KR 910000764A
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compound
complex
catalyst
ligand
group
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KR1019890017637A
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KR930003868B1 (ko
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헤르만 볼프강 아
쿨페 윌겐
켈너 윌겐
리에플 헤르베르트
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콘콜, 라이첼트
훽스트 악치엔 게젤샤프트
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Priority claimed from DE3840600A external-priority patent/DE3840600A1/de
Priority claimed from DE3921295A external-priority patent/DE3921295A1/de
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Abstract

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Description

술폰화된 페닐 포스판류를 함유하는 착화합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. 비스(1, 5-시클로옥타디엔) 니켈과 트리스(m-술포페닐)포스판의 트리소듐염의 반응 생성물은 제외하며, 착 리간드로서 트리스(m-술포페닐)포스판의 트리소듐염과 경우에 따라서는 다른 리간드들을 함유함을 특징으로 하는 주기율표의 Ⅶ A족, Ⅷ A족 및 Ⅰ B족 원소들의 착화합물.
  2. 제 1항에 있어서, 하기 일반식에 대응하는 착화합물.
  3. L1 wL2 xMy〔P(C6H4-m-SO3Na)3〕2
  4. 〔상기식에서, L1및 L2는 동일하거나 다르며, 트리스(m-술포페닐)포스판의 트리소듐염 이외에 착화합물의 중앙 원소에 결합될 수 있는 리간드이며; M은 중앙 원자로서 주기율표의 Ⅶ A족, Ⅷ A족 및 ⅠB족 원소를 표시하고; w, x, y 및 z는 정수이고, w 및 x는 각각 0내지 7y이고 y는 1내지 6이며 z는 ≤ 4이다.〕
  5. 제 2항에 있어서, 트리스(m-술포페닐)포스판의 트리소듐염 이외에 더 이상의 리간드로서 H, CO, NO, PF3, H2O, S, 할로겐, π-방향족 리간드, π-올레핀 리간드, 및/또는 π-아세틸렌 리간드를 함유하는 특징으로 하는 착화합물.
  6. 제3항에 있어서, π-방향족 리간드가 시클로펜타디에닐임을 특징으로 하는 착화합물.
  7. 제3항에 있어서, π-올레핀 리간드가 시클로옥타디엔임을 특징으로 하는 착화합물.
  8. 제3항에 있어서, π-아세틸렌 리간드가 디페닐아세틸렌임을 특징으로 하는 착화합물.
  9. 제1또는 2항에 있어서, 중앙 금속이 망간, 철, 루테늄, 코발트, 로듐, 이리듐, 니켈, 팔라듐, 백금, 구리, 은 또는 금임을 특징으로 하는 착화합물.
  10. 제1또는 2항에 있어서, 하기식으로 표현됨을 특징으로 하는 착화합물.
  11. 망간화합물(n5-C5H5)Mn(CO)2〔P(C6H4-m-SO3Na3〕,(n5-C5H5)Mn(CO)〔P(C6H4-m-SO3Na3〕2또는철화합물Fe(CO)4〔P(C6H4-m-SO3Na3〕,Fe(CO)3〔P(C6H4-m-SO3Na3〕2,Fe4(CO)11〔P(C6H4-m-SO3Na3〕또는 루테늄 화합물 Ru(NO)2〔P(C6H4-m-SO3Na)3〕2,RuCl2〔P(C6H4-m-SO3Na)3〕2또는 코발트 화합물Co2(CO)6〔P(C6H4-m-SO3Na)3〕2,CoH(CO)〔P(C6H4-m-SO3Na)3〕3,CoH2〔P(C6H4-m-SO3Na)3〕3,Co2(CO)4(H5C6-C≡C-C6H5)〔P(C6H4-m-SO3Na)3〕2또는 로듐 화합물RhCl〔P(C|6H4-m-SO3Na)3〕3,Rh(NO)〔P(C6H4-m-SO3Na)3〕3,Rh(CH3COO)〔P(C6H4-m-SO3Na)3〕3,Rh(CO)(OH)〔P(C6H4-m-SO3Na)3〕2,Rh(CO)Cl〔P(C6H4-m-SO3Na)3〕2,Rhμ-Cl)(CO)〔P(C6H4-m-SO3Na)3〕2,Rh(OH)(H2O)〔P(C6H4-m-SO3Na)3〕3,Rh2〔P(C6H4-m-SO3Na)3〕2〔P(C6H4-m-SO3Na)2(C6H4-m-SO3)〕2,Rh(μ-Cl2)
  12. (n4-C8H12)〔P(C6H4-m-SO3Na)3〕2,Rh6(CO)7〔P(C6H4-m-SO3Na)3〕9,또는 어리듐 화합물Ir(NO)〔P(C6H4-m-SO3Na)3〕3,IrH(CO)〔P(C6H4-m-SO3Na)3〕3,Irμ-Cl)(n4C8H12)〔P(C6H4-m-SO3Na3〕2또는 니켈 화합물Ni〔P(C6H4-m-SO3Na)3〕3,Ni(CO)2〔P(C6H4-m-SO3Na)3〕2,Ni(PF3)2〔P(C6H4-m-SO3Na)3〕2,팔라듐 화합물Pd〔P(C6H4-m-SO3Na)3〕3또는백금 화합물Pt〔P(C6H4-m-SO3Na)3〕4,PtCl2〔P(C6H4-m-SO3Na)3〕2또는구리 화합물Cu3〔P(C6H4-m-SO3Na)3〕2〔μ-P(C6H4-m-SO3Na)2(C6H4-m-SO3)3또는 은 화합물Ag〔P(C6H4-m-SO3Na)3〕2〔P(C6H4-m-SO3Na)2(C6H4-m-SO3〕또는 금 화합물Au2〔P(C6H4-m-SO3Na)3〕2〔μ-P(C6H4-m-SO3)2(C6H4-m-SO3)〕3,Au2S〔P(C6H4-m-SO3Na)3〕2
  13. 수소화 반응 촉매로서 제 1내지 8항 중 어느 한 항에 따른 화합물의 용도.
  14. 물-기체 평형 조절용 촉매로서 제 1내지 8항 중 어느 한 항에 따른 화합물의 용도.
  15. 히드로카르보닐화 반응 촉매로서 제 1내지 8항 중 어느 한 항에 따른 화합물의 용도.
  16. 히드로포르밀화 반응 촉매로서 제 1항 내지 8항 중 어느 한 항에 따른 화합물의 용도.
  17. 산화 반응 촉매로서 제 1항 내지 8항 중 어느 한 항에 따른 화합물의 용도.
  18. 탄소-탄소 이중 결합을 탄소-탄소 다중 결합과 연결시키는 촉매로서 제 1내지 8항 중 어느 한 항에 따른 화합물의 용도.
  19. 제 14항에 있어서, 화합물을 알렌/알킨 커플링 반응 촉매로서 사용함을 특징으로 하는 용도.
  20. 탄소-탄소 이중 결합에 2차 아민을 부가시키는 촉매로서 제 1내지 8항 중 어느 한 항에 따른 화합물의 용도.
  21. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890017637A 1988-12-02 1989-11-30 술폰화된 페닐 포스판류를 함유하는 착화합물 KR930003868B1 (ko)

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DE3840600A DE3840600A1 (de) 1988-12-02 1988-12-02 Sulfonierte phenylphosphane enthaltende komplexverbindungen
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DE3921295A DE3921295A1 (de) 1989-06-29 1989-06-29 Sulfonierte phenylphosphane enthaltende komplexverbindungen
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