KR890017217A - 페놀의 제조 방법 - Google Patents

페놀의 제조 방법 Download PDF

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Publication number
KR890017217A
KR890017217A KR1019890005869A KR890005869A KR890017217A KR 890017217 A KR890017217 A KR 890017217A KR 1019890005869 A KR1019890005869 A KR 1019890005869A KR 890005869 A KR890005869 A KR 890005869A KR 890017217 A KR890017217 A KR 890017217A
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KR
South Korea
Prior art keywords
molar ratio
acidified
comprised
zeolite
benzene
Prior art date
Application number
KR1019890005869A
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English (en)
Other versions
KR970011703B1 (ko
Inventor
귀벨망 미셸
띠렐 삘립-
Original Assignee
모니끄 바르니에르-그랑쥐
롱-쁠랑 쉬미
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Application filed by 모니끄 바르니에르-그랑쥐, 롱-쁠랑 쉬미 filed Critical 모니끄 바르니에르-그랑쥐
Publication of KR890017217A publication Critical patent/KR890017217A/ko
Application granted granted Critical
Publication of KR970011703B1 publication Critical patent/KR970011703B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/60—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by oxidation reactions introducing directly hydroxy groups on a =CH-group belonging to a six-membered aromatic ring with the aid of other oxidants than molecular oxygen or their mixtures with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

페놀의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 벤젠 및 아산화 질소를 Si02/Al203몰비가 90 이상을 나타내는 산성화된 제올라이트에 존재시키는 것을 특징으로 하는 페놀의 제조 방법.
  2. 제 1 항에 있어서, 산성화된 제올라이트가 90 내지 500에 포함되는 Si02/Al203몰비를 나타내는 HZSM5, HY 및 H-모르데니트제올라이트 중에서 선택되는 것을 특징으로 하는 제조 방법.
  3. 제 1 항에 있어서, 제올라이트가 무기산에 의해 산성화된 것을 특징으로 하는 제조 방법.
  4. 제 1 항에 있어서, 아산화질소는 벤젠에 대해 1 내지 10에 포함되는 계산된 몰비에 따라 사용되는 것을 특징으로 하는 제조 방법.
  5. 제 1 항에 있어서, 반응은 300 내지 500℃에 포함되는 온도에서 실행되는 것을 특징으로 하는 제조 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890005869A 1988-05-02 1989-05-01 페놀의 제조방법 KR970011703B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR88/05850 1988-05-02
FR8805850A FR2630733B1 (fr) 1988-05-02 1988-05-02 Procede de preparations du phenol

Publications (2)

Publication Number Publication Date
KR890017217A true KR890017217A (ko) 1989-12-15
KR970011703B1 KR970011703B1 (ko) 1997-07-14

Family

ID=9365891

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890005869A KR970011703B1 (ko) 1988-05-02 1989-05-01 페놀의 제조방법

Country Status (10)

Country Link
US (1) US5001280A (ko)
EP (1) EP0341165B1 (ko)
JP (1) JP2831029B2 (ko)
KR (1) KR970011703B1 (ko)
BR (1) BR8902015A (ko)
CA (1) CA1325228C (ko)
DE (1) DE68902770T2 (ko)
ES (1) ES2035621T3 (ko)
FI (1) FI92052C (ko)
FR (1) FR2630733B1 (ko)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2648810B1 (fr) * 1989-06-22 1992-02-28 Rhone Poulenc Chimie Procede de preparation de phenols
US5110995A (en) * 1991-03-12 1992-05-05 Institute Of Catalysis Preparation of phenol or phenol derivatives
RU2058286C1 (ru) * 1994-04-12 1996-04-20 Институт катализа им.Г.К.Борескова СО РАН Способ получения фенола или его производных
RU2074164C1 (ru) * 1994-04-12 1997-02-27 Институт катализа им.Г.К.Борескова СО РАН Способ получения фенола или его производных
CN1055029C (zh) * 1996-01-03 2000-08-02 南开大学 一种苯酚直接氧化制对苯二酚的催化剂
US5874646A (en) * 1996-08-07 1999-02-23 Solutia Inc. Preparation of phenol or phenol derivatives
US5892132A (en) * 1996-08-08 1999-04-06 Solutia Inc. Transport hydroxylation reactor
US5874647A (en) * 1996-08-20 1999-02-23 Solutia Inc. Benzene hydroxylation catalyst stability by acid treatment
US5808167A (en) * 1996-08-20 1998-09-15 Solutia Inc. Selective introduction of active sites for hydroxylation of benzene
DE19634406C2 (de) * 1996-08-26 1998-11-26 Hoechst Ag Verfahren zur Herstellung von Hydroxyaromaten durch Umsetzung von Aromaten mit N¶2¶O
DK0929507T3 (da) 1996-10-07 2003-03-24 Solutia Inc Fremgangsmåde til hydroxylering af benzen
US6156938A (en) * 1997-04-03 2000-12-05 Solutia, Inc. Process for making phenol or phenol derivatives
RU2127721C1 (ru) 1997-07-29 1999-03-20 Институт органической химии им.Зелинского РАН Способ получения фенола и его производных
EP0953558B1 (de) * 1998-04-30 2001-11-21 CREAVIS Gesellschaft für Technologie und Innovation mbH Verfahren zur Herstellung von Hydroxylgruppen enthaltenden aromatischen Verbindungen
IN184883B (ko) * 1998-05-13 2000-10-07 Gen Electric
US6232510B1 (en) 1999-02-26 2001-05-15 General Electric Company Method and composition for hydroxylation of aromatic substrates
US6265622B1 (en) 1999-02-26 2001-07-24 General Electric Company Method and composition for hydroxylation of aromatic substrates
RU2155181C1 (ru) 1999-04-05 2000-08-27 Кустов Леонид Модестович Способ окисления бензола и/или толуола в фенол и/или крезолы
US6548718B2 (en) 2000-04-27 2003-04-15 Shell Oil Company Process for catalytic hydroxylation of, saturated or unsaturated, aliphatic compounds
US6437197B1 (en) 2000-04-27 2002-08-20 Shell Oil Company Process for catalytic hydroxylation of aromatic hydrocarbons
DE10123121C1 (de) * 2001-05-07 2002-07-11 Inst Angewandte Chemie Berlin Verfahren zur Herstellung von Hydroxyaromaten

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1547725A (en) * 1923-06-18 1925-07-28 Carlisle H Bibb Production of phenol
US4578521A (en) * 1985-02-04 1986-03-25 Mobil Oil Corporation Shape-selective catalytic oxidation of phenol
IT1207519B (it) * 1985-12-19 1989-05-25 Eniricerche Spa Materiale sintetico cristallino poroso contenetne ossidi di silicio titanio e alluminio.

Also Published As

Publication number Publication date
EP0341165A1 (fr) 1989-11-08
ES2035621T3 (es) 1993-04-16
US5001280A (en) 1991-03-19
JP2831029B2 (ja) 1998-12-02
FR2630733A1 (fr) 1989-11-03
FI92052B (fi) 1994-06-15
FI92052C (fi) 1994-09-26
DE68902770T2 (de) 1993-02-25
BR8902015A (pt) 1989-12-05
FI892058A (fi) 1989-11-03
FR2630733B1 (fr) 1990-07-20
CA1325228C (fr) 1993-12-14
JPH0211531A (ja) 1990-01-16
EP0341165B1 (fr) 1992-09-09
FI892058A0 (fi) 1989-04-28
KR970011703B1 (ko) 1997-07-14
DE68902770D1 (de) 1992-10-15

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