KR840004535A - 제올라이트 베타 및 그 제조법 - Google Patents

제올라이트 베타 및 그 제조법 Download PDF

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Publication number
KR840004535A
KR840004535A KR1019830002181A KR830002181A KR840004535A KR 840004535 A KR840004535 A KR 840004535A KR 1019830002181 A KR1019830002181 A KR 1019830002181A KR 830002181 A KR830002181 A KR 830002181A KR 840004535 A KR840004535 A KR 840004535A
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South Korea
Prior art keywords
zeolite
less
acid
zeolite beta
valence
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KR1019830002181A
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English (en)
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KR910003610B1 (ko
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버나드 라피에르 렌
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모빌 오일 코오포레이숀
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026—After-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

내용 없음

Description

제올라이트 베타 및 그 제조법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. SiO2: AlO2의 몰비가 적어도 100:1인 합성결정성 제올라이트 베타.
  2. 제올라이트 베타의 탈알루미늄화에 의해 생산되고, 무수물을 기준으로 하기조성물을 가지는 것으로서, X선 분말회절 패턴이
    11.4±0.2
    7.4±0.2
    6.7±0.2
    4.25±0.1
    3.97±0.1
    3.0 ±0.1
    2.2 ±0.1
    의 d-값에서 횡선을 갖는 것을 특징으로하는 결정성 합성제올라이트:
    여기서, X는 1 이하이고, Y는 적어도 100이고, M은 금속이고, n은 M의 원자가이다.
  3. 제 2 항에 있어서, X가 0.75 이하인 제올라이트.
  4. 제 2 항 또는 제 3 항에 있어서, Y가 적어도 200인 제올라이트.
  5. 하기조성(무수물 기준)을 갖는 제올라이트로부터 알루미늄을 제거하기에 충분한 시간동안 상기 제올라이트와 산을 접촉시키는 것으로 구성되는, SiO2: AlO2의 몰비가 적어도 100:1인 합성결정성 제올라이트 베타를 제조하는 방법.
    여기서, X는 1 이하이고, Y는 100이하이고, M은 금속이고, n은 M의 원자가이다.
  6. 제 5 항에 있어서, 알루미늄을 제거한 후 상기 제올라이트 베타가 하기 조성(무수물 기준)을 가지는 것을 특징으로 하는 방법.
    여기서, X는 1 이하이고, Y는 적어도 100이고, M은 금속이고, n은 M의 원자가이다.
  7. 제 7 항에 있어서, Y가 최소한 200인 방법.
  8. 제 5 항에 있어서, 상기 산이 광물산인 것을 특징으로 하는 방법.
  9. 제 9 항에 있어서, 상기 산이 염산인 것을 특징으로 하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830002181A 1982-05-18 1983-05-18 제올라이트 베타 및 그 제조방법 KR910003610B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US37939982A 1982-05-18 1982-05-18
US379,399 1982-05-18

Publications (2)

Publication Number Publication Date
KR840004535A true KR840004535A (ko) 1984-10-22
KR910003610B1 KR910003610B1 (ko) 1991-06-07

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KR1019830002181A KR910003610B1 (ko) 1982-05-18 1983-05-18 제올라이트 베타 및 그 제조방법

Country Status (18)

Country Link
EP (1) EP0095304B1 (ko)
JP (1) JPS58208131A (ko)
KR (1) KR910003610B1 (ko)
AT (1) ATE21884T1 (ko)
AU (1) AU558176B2 (ko)
BR (1) BR8302597A (ko)
CA (1) CA1206132A (ko)
DE (1) DE3365825D1 (ko)
DK (1) DK161380C (ko)
ES (1) ES522480A0 (ko)
FI (1) FI72498C (ko)
GR (1) GR78847B (ko)
IN (1) IN158396B (ko)
NO (1) NO160350C (ko)
NZ (1) NZ204091A (ko)
PH (1) PH18808A (ko)
PT (1) PT76708B (ko)
ZA (1) ZA833587B (ko)

Cited By (1)

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KR100769021B1 (ko) * 2006-04-04 2007-10-23 주식회사 효성 탈알루미늄된 제올라이트 베타 촉매를 이용한1,5-디메틸테트랄린의 제조방법

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US4840930A (en) * 1982-05-18 1989-06-20 Mobil Oil Corporation Method for preparing acid stable zeolites and high silica zeolites prepared by it
US4954243A (en) * 1983-11-03 1990-09-04 Mobil Oil Corporation Catalytic cracking with framework aluminum extracted zeolite
NZ209982A (en) * 1983-11-03 1987-04-30 Mobil Oil Corp Zeolite catalyst treated with aluminium-extracting reagent to produce enhanced activity
US4876411A (en) * 1986-01-03 1989-10-24 Mobil Oil Corporation Modified crystalline aluminosilicate zeolite catalyst and its use in the production of lubes of high viscosity index
DE3620581A1 (de) * 1986-06-19 1987-12-23 Basf Ag Verfahren zur herstellung von carbonsaeuren
FR2622575B1 (fr) * 1987-10-29 1990-02-23 Rhone Poulenc Chimie Procede d'hydroxylation de phenols et d'ethers de phenols
GB8810189D0 (en) * 1988-04-29 1988-06-02 Unilever Plc Liquid cleaning products
FR2631956B1 (fr) * 1988-05-25 1990-11-02 Inst Francais Du Petrole Procede d'alkylation de paraffines en presence d'une zeolite beta
ZA893132B (en) * 1989-04-27 1990-12-28 Zeofuels Res Pty Ltd Modification of natural zeolite and its use as an oligomerisation catalyst
GB9007577D0 (en) * 1990-04-04 1990-05-30 Ici Plc Preparation of aromatic compounds
FR2669618B1 (fr) * 1990-11-26 1993-05-07 Elf Aquitaine Procede de desalumination des zeolithes synthetiques a larges pores, catalyseurs et adsorbants organophiles selectifs renfermant les zeolithes desaluminees obtenues selon le procede et zeolithe beta essentiellement silicique.
DE4115263C2 (de) * 1991-05-10 1995-04-06 Taiwan Styrene Monomer Corp Modifizierter Beta-Zeolith
US5200168A (en) * 1992-01-31 1993-04-06 Mobil Oil Corp. Process for the dealumination of zeolite Beta
FR2694549A1 (fr) * 1992-08-06 1994-02-11 Atochem Elf Sa Procédé de préparation de zéolites bêta au titane et zéolites bêta nouvelles.
CN1037166C (zh) * 1994-06-29 1998-01-28 中国石油化工总公司抚顺石油化工研究院 一种β沸石及其制备方法
US5508019A (en) * 1994-06-30 1996-04-16 Arco Chemical Technology, L.P. Dealumination of aluminosilicates
ES2162327T3 (es) * 1996-09-06 2001-12-16 Exxonmobil Chem Patents Inc Procedimiento de alquilacion utilizando zeolitas beta.
CN1061902C (zh) * 1996-10-11 2001-02-14 中国石油化工总公司 一种β沸石的改性方法
FR2755958B1 (fr) * 1996-11-19 1999-01-08 Inst Francais Du Petrole Zeolithe nu-86 desaluminee et son utilisation en conversion des hydrocarbures
FR2758810B1 (fr) * 1997-01-24 1999-02-19 Inst Francais Du Petrole Zeolithe im-5 desaluminee
FR2765236B1 (fr) * 1997-06-25 1999-12-03 Inst Francais Du Petrole Procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines avec un catalyseur a base de zeolithe nu-87 modifiee
FR2765207B1 (fr) * 1997-06-25 1999-08-06 Inst Francais Du Petrole Zeolithe nu-85, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
EP0955093B1 (fr) * 1998-05-06 2003-09-03 Institut Francais Du Petrole Catalyseur à base de zéolithe bêta et d'element promoteur et procédé d'hydrocraquage
US7348465B2 (en) 2005-02-08 2008-03-25 Shell Oil Company Selective alkylation of aromatic hydrocarbons
KR102048913B1 (ko) * 2011-11-25 2019-11-27 미쓰이금속광업주식회사 제올라이트 및 그의 제조 방법, 및 파라핀의 접촉 분해 촉매
JP5470592B2 (ja) * 2011-11-25 2014-04-16 ユニゼオ株式会社 ゼオライト及びその製造方法並びにパラフィンの接触分解触媒

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GB1061847A (en) * 1964-03-23 1967-03-15 Mobil Oil Corp Method for preparing highly siliceous zeolite type materials and the products thereof
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DE2510700C2 (de) * 1975-03-12 1983-01-27 Basf Ag, 6700 Ludwigshafen Verfahren zur Herstellung von Zeolithen mit verbesserter Hochtemperatur- und Säurebeständigkeit
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Publication number Priority date Publication date Assignee Title
KR100769021B1 (ko) * 2006-04-04 2007-10-23 주식회사 효성 탈알루미늄된 제올라이트 베타 촉매를 이용한1,5-디메틸테트랄린의 제조방법

Also Published As

Publication number Publication date
ES8406379A1 (es) 1984-08-01
DK161380B (da) 1991-07-01
AU558176B2 (en) 1987-01-22
DE3365825D1 (en) 1986-10-09
BR8302597A (pt) 1984-01-17
NO160350B (no) 1989-01-02
JPS58208131A (ja) 1983-12-03
FI831722A0 (fi) 1983-05-17
NO160350C (no) 1989-04-12
EP0095304A1 (en) 1983-11-30
PH18808A (en) 1985-09-27
PT76708B (en) 1986-01-21
NZ204091A (en) 1986-03-14
JPH0341408B2 (ko) 1991-06-24
GR78847B (ko) 1984-10-02
IN158396B (ko) 1986-11-08
EP0095304B1 (en) 1986-09-03
DK219783D0 (da) 1983-05-17
ES522480A0 (es) 1984-08-01
AU1437383A (en) 1983-11-24
FI72498B (fi) 1987-02-27
ATE21884T1 (de) 1986-09-15
FI831722L (fi) 1983-11-19
FI72498C (fi) 1987-06-08
CA1206132A (en) 1986-06-17
NO831714L (no) 1983-11-21
PT76708A (en) 1983-06-01
KR910003610B1 (ko) 1991-06-07
DK161380C (da) 1991-12-23
DK219783A (da) 1983-11-19
ZA833587B (en) 1984-12-24

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