KR890016224A - 열수축성섬유 조성물 및 그 제조방법 - Google Patents

열수축성섬유 조성물 및 그 제조방법 Download PDF

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KR890016224A
KR890016224A KR1019890002270A KR890002270A KR890016224A KR 890016224 A KR890016224 A KR 890016224A KR 1019890002270 A KR1019890002270 A KR 1019890002270A KR 890002270 A KR890002270 A KR 890002270A KR 890016224 A KR890016224 A KR 890016224A
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fibers
composition
fiber
composition according
heat
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에스.캠프벨 프레데릭
제이.바르니 고오돈
알. 페터슨 드위트
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데이비드 찰스 에반스
알바니 리서치 (유.케이.) 리미티드
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D10/00Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/04Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
    • D04H1/06Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres by treatment to produce shrinking, swelling, crimping or curling of fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/022Non-woven fabric
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • D04H1/482Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with shrinkage
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/593Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives to layered webs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/306Resistant to heat
    • B32B2307/3065Flame resistant or retardant, fire resistant or retardant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • B32B2307/734Dimensional stability
    • B32B2307/736Shrinkable

Abstract

내용 없음

Description

열수축성섬유 조성물 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제 1 도는 본 발명에 따른 삼적층 섬유고조를 12배율로 확대시켜 나타낸 횡단 면도, 제 2 도는 지구조와 내부접착제층을 50배율로 도시한 제 1 도의 상세도, 제 5 도는 단위면적당 서로 다른수의 지주를 가지고 있는 두가지 폴리이미드 부직포의 압축에 대한 압력-변형 도포. 제 7도는 열치미화 누빈 부직포인 지주주위의 매트릭스 섬유 고조의 단면도. 제 8 도는 단위면적당 서로 다른수의 지주를 가진 두 황화폴리페닐렌 부직포의 압축에 대한 압력-변형 도표. 제 9 도는 단위면적당 서로 다른수의 지주를 가진 두 폴리에테르이미드 부직포의 압축에 대한 압력-변형 도표.

Claims (32)

  1. 대부분의 섬유구조가 적어도 그 섬유간 여러 접착부위에 섬유간 결합을 형성토록 가열 처리된 열 수축성 섬유로 이루어진 섬유구조로 구성된 조성물.
  2. 대부분이 그 구조의 치밀성을 나타내도록 가열처리된 열수축성 섬유를 특징으로한 섬유구조로 이루어진 조성물.
  3. 섬유구조가 대부분이 열수축성섬유를 함유하며 분리된 섬유 그룹을 함유하구, 또한 상기 섬유 그룹의 밀도가 그 구조의 잔류부분의 밀도보다 크게 증가된 밀도의 구조를 나타내도록 열처리 시킬 수 있는 것을 특징으로한 섬유구조로 이루어진 조성물.
  4. 열 수축성 섬유를 포함 하는 섬유구조를 형성하고, 이 구조를 성형표면에 밀착시키고, 그 구조를 수축에 대하여 적어도 한방향으로 제한시키고 상기 물질을 그 구조의 경화성을 증가시키도록 섬유간 결합을 얻기에 충분한 온도 및 시간동안 가열시킨뒤, 상기 표면엣 상기 성형제품을 제거시키는 것을 특징으로한 방법에 의하여 제조된 성형제품의 형태인 조성물.
  5. 전항중 어느 한 항에 있어서, 열처리후 그 구조의 밀도가 일정하지 않은 것을 특징으로 하는 조성물
  6. 전항중 어느 한 항에 있어서, 그 구조가 그 속에 다수의 길이성분을 가지고, 각 성분이 평면에 배향되고 열처리에 의하여 치밀화된 일단의 섬유로 이루어진 것을 특징으로 하는 조성물.
  7. 전항중 어느 한 항에 있어서, 섬유구조가 평면에 대하여 가로방향으로 확장되는 다수의 길이 성분을 가진 층으로 구성된 것을 특징으로 하는 조성물.
  8. 전항중 어느 한 항에 있어서, 섬유가 부직펠트, 니트물 및 직조물중 한 가지 또는 그 이상으로 선택되는 것을 특징으로 하는 조성물.
  9. 제 8 항에 있어서, 섬유고주가 분리된 일련의 섬유층을 포함한 배트인것을 특징으로 하는 조성물.
  10. 전항중 어느 한 항에 있어서, 섬유구조층이 다같이 적층된 섬유물의 여러층으로 형성되는 것을 특징으로 하는 조성물.
  11. 제 10 항에 있어서, 적층 접착제가 아크릴 접착제, 폴리에스테르 접착제, 폴리아미드 접착제, 폴리올레핀적찹제, 폴리우레탄 접착제 및 폴리아미드 접착제로부터 선택하여 사용되는 것을 특징으로한 조성물.
  12. 제 3 항 내지 제 11 항중 어느 한 항에 있어서, 일단의 섬유가 섬유구조의 평면에 횡렬로 형성되고 펠트가 누빔작업에 의하여 또는 수화-엉킴법에 의하여 형성되는 것을 특징으로 하는 조성물.
  13. 전항중 어느 한 항에 있어서, 밀도가 0.005-1.2g/cc의 범위내인 것으로 특징으로 하는 조성물.
  14. 전항중 어느 한 항에 있어서, 섬유길이가 펠트층내에 배향된 펠트층의 섬유고조를 특징으로한 조성물.
  15. 제 14 항에 있어서, 배향된 섬유가 각 층내에 분리된 적층속에 배열되고 인접층의 배향 방향이 각도 5°이상으로 정의되도록 상기된 적층을 배열시킨 것을 특징으로 한느 조성물.
  16. 전항중 어느 한 항에 있어서, 상기 물질을 섬유간 결합을 얻도록 섬유를 수축시키기에 충분한 온도에서 그리고 시간동안 가열시킨 것을 특징으로 하는 조성물.
  17. 전항중 어느 한 항에 있어서, 섬유구조에 대하여 대부분이 상기 섬유로된 섬유들이 폴리아미드섬유, 아크릴섬유, 폴리프로필렌섬유, 황화폴리페닐렌섬유, 폴리이미드섬유, 방향성 에테트케톤섬유 및 폴리에테르이미드섬유로부터 선택된 열수축성섬유임을 특징으로한 조성물.
  18. 전항중 어느 한 항에 있어서, 섬유구조의 각개 섬유가 가소성 있는 저분자량물질을 5 중량% 보다 많지 않은 부분으로 포함 하는 것을 특징으로 하는 조성물.
  19. 제 18항에 있어서, 저분자량 가소성물질을 섬유중합체 및 동일한 중합물질의 저분자량 올리고마용 용매로부터 선택된 것을 특징으로 하는 조성물.
  20. 제 18항 또는 제 19 항에 있어서, 섬유가 폴리이미드 섬유이고 용매가 디메틸포름아미드, N-메틸 피롤리돈, N-비닐 필롤리돈 및 디메틸아세트아미드중 한가지 또는 그 이상으로 구성되는 것을 특징으로한 조성물.
  21. 전항중 어느 한 항에 있어서, 냉각 하는 동안 상기 구조를 계속 억제시키는 억제 상태로 유지시킨뒤 그 억제 상태를 제거하는 동안 그 구조를 치밀화가 되기에 충분한 온도로 가열시키고 반면에 수축에 대하여 상기 구조를 성형 표면에 접착시키는 적어도 어느 한 방향으로 억제 시키는 것을 특징으로 하는 조성물.
  22. 제 4 항 내지 제 21 항중 어느 한 항에 있어서, 섬유구조가 수축에 대하여 적어도 평면으로 억제되어서 실질적으로 수축이 3차원 방향만이 허용되는 것을 특징으로 하는 조성물.
  23. 전항중 어느 한 항에 있어서, 섬유의 유리전이온도를 초과한 온도로 가열시킨 것을 특징으로 하는 조성물.
  24. 전항중 어느 한 항에 있어서, 섬유구조가 연속필라멘트 및 스테플섬유로부터 선택된 실 또는 섬유인 것을 특징으로 하는 조성물.
  25. 제 4 항 내지 제 23항에 어느 한 항에 있어서, 성형 표면이 외형이 삼차원인 판자를 얻도록 하는 적어도 두개의 공유면으로 이루어진 것을 특징으로 하는 조성물.
  26. 제 7항 내지 2제 26 항중 어느 한 항에 있어서, 상기 횡렬방향이 그 층의 평면에 실질적으로 수직인 것을 특진으로 하는 조성물
  27. 전항중 어느 한 항에 있어서, 섬유구조가 경화된 부직 물질의 여러층으로 형성된 적층집합체이고, 상기된 구조가 각층에 횡렬방향으로 확장된 일단의 섬유를 가지고 그리고 그속의 구조가 일단의 치밀화된 섬유를 합성적층의 구조적 경화도에 영향을 미치는 자체각층내 구조적 성분이 형성되도록 성형된 것을 특징으로 하는 조성물.
  28. 제 4 항 내지 제 27항중 어느 한 항에 있어서, 횡렬로 배열된 섬유그룹의 치밀화가 섬유간 결합을 수반하는 것을 특징으로한 조성물.
  29. 전항중 어느 한 항에 있어서, 섬유구조의 섬유가 연신비 2-7배로 형성시키는 것을 특징으로한 조성물.
  30. 전항중 어느 한 항에 있어서, 섬유가 응집 섬유 집합체의 적절한 수축 및 치밀화가 제공되도록 가열시 적어도 15-80% 이상수축 될수 있는 것을 특징으로 하는 조성물.
  31. 전항중 어느 한 항에 있어서, 섬유구조가 하기 일반식의 구조단위를 가진 대부분의 폴리이미드 섬유로 이루어진 것을 특징으로 하는 조성물.
    상기 일반식에서 n은 1 이상의 정수이고 R이
  32. 열수축성섬유로 이루어진 섬유구조를 형성하고, 이 구조를 치밀화되도록 시키는 데 충분한 온도로 가열시키는 반면 수축에 대하여 상기 구조를 적어도 한 방향으로 억제시키고, 상기 치밀화된 구조가 억제제상태로 유지되는 동안 성형표면에 접착시키고 상기 구조를 상기 억제 상태로 유지되는 동안 냉각시킨뒤 상기 억제를 헤제시키는 것을 특징으로 하는 전항중 어느 한 항에 조성물을 제조하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890002270A 1988-04-14 1989-02-25 열수축성섬유 조성물 및 그 제조방법 KR890016224A (ko)

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EP0337597B1 (en) 1996-04-10
CH684726B5 (fr) 1995-06-15
FI890905A0 (fi) 1989-02-24
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GB2217355B (en) 1992-12-23
CA1321064C (en) 1993-08-10
EP0337597A3 (en) 1990-12-27
NO890784D0 (no) 1989-02-24
GB2217355A (en) 1989-10-25
GR890100110A (en) 1990-01-31
DK90289A (da) 1989-10-15
NO890784L (no) 1989-10-16
DE68926177T2 (de) 1996-10-02
DK90289D0 (da) 1989-02-24
EP0337597A2 (en) 1989-10-18
BR8900858A (pt) 1989-10-17
FI890905A (fi) 1989-10-15
FR2630135A1 (fr) 1989-10-20
GB8904069D0 (en) 1989-04-05
CH684726GA3 (fr) 1994-12-15
BE1002706A5 (fr) 1991-05-14
ATE136597T1 (de) 1996-04-15
GR1000276B (el) 1992-05-12
ES2010873A6 (es) 1989-12-01
PT89825B (pt) 1995-03-01
JPH01282374A (ja) 1989-11-14
FR2630135B1 (fr) 1992-09-25
DE68926177D1 (de) 1996-05-15
AU3074989A (en) 1989-10-19
AU616243B2 (en) 1991-10-24
PT89825A (pt) 1989-11-10
IL89406A0 (en) 1989-09-10
MX169946B (es) 1993-08-02

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