KR890009366A - 치석 억제 조성물 - Google Patents
치석 억제 조성물 Download PDFInfo
- Publication number
- KR890009366A KR890009366A KR1019880013073A KR880013073A KR890009366A KR 890009366 A KR890009366 A KR 890009366A KR 1019880013073 A KR1019880013073 A KR 1019880013073A KR 880013073 A KR880013073 A KR 880013073A KR 890009366 A KR890009366 A KR 890009366A
- Authority
- KR
- South Korea
- Prior art keywords
- hydrogen
- acid
- composition
- group
- alkyl
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 26
- 208000006558 Dental Calculus Diseases 0.000 title claims 13
- 230000002401 inhibitory effect Effects 0.000 title claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 25
- 239000001257 hydrogen Substances 0.000 claims 25
- -1 alkyl itaconate Chemical compound 0.000 claims 16
- 150000002431 hydrogen Chemical group 0.000 claims 12
- 229910052783 alkali metal Inorganic materials 0.000 claims 11
- 229920001577 copolymer Polymers 0.000 claims 10
- 150000003839 salts Chemical class 0.000 claims 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 9
- 150000001340 alkali metals Chemical group 0.000 claims 8
- 239000002253 acid Substances 0.000 claims 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 6
- 150000001342 alkaline earth metals Chemical group 0.000 claims 6
- 229940091249 fluoride supplement Drugs 0.000 claims 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 5
- 239000003112 inhibitor Substances 0.000 claims 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 4
- 239000011976 maleic acid Substances 0.000 claims 4
- 210000000214 mouth Anatomy 0.000 claims 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 3
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical group OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims 3
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 claims 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 3
- 150000008064 anhydrides Chemical class 0.000 claims 3
- 229920001519 homopolymer Polymers 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 2
- 208000004188 Tooth Wear Diseases 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 1
- XGRSAFKZAGGXJV-UHFFFAOYSA-N 3-azaniumyl-3-cyclohexylpropanoate Chemical compound OC(=O)CC(N)C1CCCCC1 XGRSAFKZAGGXJV-UHFFFAOYSA-N 0.000 claims 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims 1
- FXBVGKCQLSQGBD-UHFFFAOYSA-N CCCCO.OP(=O)OP(O)=O Chemical compound CCCCO.OP(=O)OP(O)=O FXBVGKCQLSQGBD-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 125000005336 allyloxy group Chemical group 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Chemical group 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims 1
- 229940018557 citraconic acid Drugs 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000006071 cream Substances 0.000 claims 1
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical group O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 claims 1
- 229940005740 hexametaphosphate Drugs 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Chemical group 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 claims 1
- DUDRFISLZJPLTJ-UHFFFAOYSA-N methane;phosphoric acid Chemical compound C.OP(O)(O)=O DUDRFISLZJPLTJ-UHFFFAOYSA-N 0.000 claims 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 239000008008 oral excipient Substances 0.000 claims 1
- 239000000546 pharmaceutical excipient Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 229920002959 polymer blend Polymers 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Chemical group 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Chemical group 0.000 claims 1
- 235000013024 sodium fluoride Nutrition 0.000 claims 1
- 239000011775 sodium fluoride Substances 0.000 claims 1
- 229960000414 sodium fluoride Drugs 0.000 claims 1
- 229960004711 sodium monofluorophosphate Drugs 0.000 claims 1
- ANOBYBYXJXCGBS-UHFFFAOYSA-L stannous fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 claims 1
- 229960002799 stannous fluoride Drugs 0.000 claims 1
- 229920001187 thermosetting polymer Polymers 0.000 claims 1
- 239000004634 thermosetting polymer Substances 0.000 claims 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
- A61K8/21—Fluorides; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/92—Oral administration
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- (a)유효량의 불화물 소오스, (b)유효량의 치과용 마모제; 그리고 (c)C3-C5모노불포화 모노카르복실 및 디카르복실산, 이것의 염 및 무수물로부터, 그리고 이러한 산에서 선택된 카르복실 단량체를 최소한 30중량% 함유하는 공중합체로부터, 그리고 이들의 혼합물로부터 선택된 0.01내지 10중량%의 치석방지제를 포함하는 구강조성물.
- 제1항에 있어서, 상기 공중합체의 최소한 한공단량체는 아크릴아미드, 알킬 아크릴레이트, 알킬 이타콘 에이트, 비닐술포산, 히드록시알킬 아크릴레이트, 알콕시알킬아크릴레이트,저급알케닐카르복실레이트. 스티렌술폰산, 알릴옥시히드록시알칸 술폰산, 아크릴아미도알칸술폰산, 포스포노알칸 카르복실산, 술포알킬아크릴레이트, 이들의 염 및 무수물, 그리고 이를 공단량체들의 혼합물로부터 선택된 것을 특징으로 하는 조성물.
- 제2항에 있어서, 불화물 소오스의 양은 상기의 구강조성물에 기초하여 0.005중량% 내지 3.0중량%이고, 상기의 카르복실산 단량체의 양은 상기의 공중합체에 기초하여 40내지 90중량%이고, 그리고 상기의 단독중합체와 공중합체의 분자량은 약400내지 100,000의 범위에 있는 것을 특징으로 하는 조성물.
- 제3항에 있어서, 상기의 공중합체는 상기 공단량체중의 최소한 한 공단량체를 60 내지 10%함유하고, 상기의 불화물 소오스의 양은 0.05내지 1%이고, 그리고 상기의 치석 방지제의 양은 0.1내지 5%인 것을 특징으로 하는 조성물.
- 제4항에 있어서, 상기의 카르복실산 단량체는 아크릴산, 메타크릴산, 이타콘산, 말레산, 말레산무수물, 시트라콘산, 메사콘산, 상기 산들의 염, 그리고 이들의 혼합물로부터 선택되며; 여기서의 아크릴아미드는 아래와 같이 정의되며(식중, R은 수소 및 메틸그룹에서 선택되고 R1및 R2은 수소 및 C1-C12알킬그룹으로부터 개별적으로 선택된다); 알킬 아크릴레이트는 아래의 시과 같이 정의되며(식중, R은 수소 및 메틸그룹에서 선택되고 R1은 C1-C6알킬그룹으로부터 그리고 R1이 R3-Y(R2는 C1-C6알킬그룹이고 Y는 -SO3X, C(O)R3또는 -CO2X(X는 수소, 알칼리금속, 알칼리토금속, 또는 암모늄이다)이다)인 치환된 알킬그룹이고, 그리고 R3는 C1-C3알킬이다); 알킬 이타콘에이트는 아래의 식과 같이 정의되며(식중, R2및 R3는 C1-C4알킬그룹 및 수소로부터 개별적으로 선택되며, 단 R2또는 R3중의 하나가 수소일 수 있긴 하지만 R2및 R3둘 모두가 수소일수는 없다); 비닐 술폰산 및 이들의 염은 아래의 식과 같이 정의되며(식중, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 히드록시알킬 아크릴레이트는 아래의 식과 정의되며(식중, R은 수소 및 C1-C4알킬그룹으로부터 선택된 것이고, R1은 C2-C4알킬렌그룹에서 선택된 것이고 n은 1내지 5이다); 알콕시알킬 아크릴레이트는 아래와 같이 정의되며(식중, R은 수소 및 메틸그룹에서 선택되고 R1은 C2-C4알킬렌 그룹으로부터 선택된 것이고, R2는 C1-C10알킬그룹으로부터 선택된 것이고, n은 1내지 5이다); 저급 알케닐 카르복시레이트는 아래의 식과 같이 정의되며(식중 R은 수소 또는 C1-C6저급알킬그룹이고, R1은 C1-C12알킬그룹에서 선택된 것이다); 비닐알콜은 아래의 식과 같이 정의되며(식중, R은 C1-C6저급알킬그룹이다); 스티렌술포산 및 이것의 염은 아래의 식과 같이 정의되며(식중 R은 C1-C6알킬그룹에서 선택된 것이고 X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 알릴옥시 히드록시알칸술포산 및 그 염은 아래의 식과 같이 정의되며(식중 R및 R1은 수소 및 메틸그룹으로부터 저마다 선택된 것이고, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 아크릴아미도알칼 술포산 및 그 염은 아래의 식과 같이 정의되며(식중 R은 수소 및 메틸그룹으로부터 선택된 것이고 R1및 R2는 수소 및 C1-C4알킬그룹으로부터 저마다 선택된 것이고, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 술포알킬아크릴레이트는 아래의 식과 같이 정의되는(식중, R1은 수소, 메틸 그리고 일반식(이 식에서, R2은 C1-C12알킬렌 그룹에서 선택된 것이고, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다)에서 선택된 것이다)것을 특징으로 하는 조성물.
- 제5항에 있어서, 상기의 아크릴아미드에서의 R1또는 R2둘 모두가 수소가 아니며; 상기의 알킬 아크릴레이트에 있어서의 R1는 C1-C4의 비치환된 알킬그룹이고; 상기의 알킬 이타콘에이트에 있어서의 R2및 R3는 C1-C4의 비치환된 알킬그룹에서 개별적으로 선택된 것이고; 상기의 술포산 및 그 염에 있어서의 X는 알칼리금속 및 암모늄 기로부터 선택된 것이고; 상기의 히드록시알킬 아크릴레이트에 있어서의 R은 수소 및 메틸그룹에서 선택된 것이고 R1는 C2-C3의 알킬렌 그룹으로부터 선택된 것이며; 상기의 알콕시알킬 아크릴레이트에 있어서의 R1는 C2-C3알킬렌 그룹으로부터 선택된 것이고, R2는 C1-C4알킬그룹으로부터 선택된 것이고, n은 1내지 3의 수이고; 상기의 스티렌술포산 및 그 염에 있어서의 R는 수소이고, X는 수소, 암모늄 및 알칼리금속 라디칼로부터 선택된 것이고, 그리고 상기의 -SO3X그룹은 상기의 페닐고리상의 3또는 4위치에 있고; 상기의 아크릴아미도알칼술폰산 및 그 염에 있어서의 R은 수소이고 R1및 R2는 C1-C3알킬그룹으로부터 개별적으로 선택된 것이고; 그리고 상기의 술포알킬 아크릴레이트에 있어서의 R2는 C2-C4알킬렌그룹으로부터 선택된 것이고 X는 수소, 나트륨, 칼륨, 칼슘, 마그네슘 및 그리고 암모늄기로부터 선택된 것임을 특징으로 하는 조성물.
- 제6항에 있어서, 치석의 형성을 억제하는 데에 효과적인 6내지 10의 pH를 가지며, 불화물 소오스의 양은 약50ppm내지 약 2,500ppm의 불화물이온을 제공하느데에 충분한 양이며; 상기의 치석방지제의 양은 1내지 1000ppm이며, 상기의 치과용 마모제의 양은 10내지 70%이며; 그리고 상기의 조성물은 구강용 부형제도 포함하는 것을 특징으로 하는 조성물.
- 제7항에 있어서, 상기의 마모제의 양은 0.1내지 7중량%이며, 이것은 알칼리금속 헥사메타포스페이트, 알칼리금속 트리폴리포스페이트, 디알칼리금속 이산, 트리알칼리금속 일산, 알칼리금속 트리폴리포스페이트, 테트라알칼리금속 피로포스페이트, 히드록시에틸에탄 디포스폰산, 그리고 이들의 혼합물로부터 선택된 것임을 특징으로 하는 조성물.
- 제6항에 있어서, 상기의 치석방지제의 양은 1내지 5%이며, 상기의 공중합체 치석방지제는 2,000내지 20,000의 분자량을 가지며 상기의 모노불포화 카르복실산은 아크릴산, 메타크릴산, 말레산, 말레산 무수물, 이타콘산, 그리고 이들의 혼합물로부터 선택되는 것을 특징으로 하는 조성물.
- 제9항에 있어서, 상기의 치석방지제는 아래와 같은 공중합체들로부터 선택된 것임을 특징으로 하는 조성물.(a)AA:MAA;t-BuAm의 60:20:20 공중합체(b)AA:HPA의 63:37 공중합체(c)AA:AMPS의 51:49 공중합체(d)말레산의 100단독중합체(e)아크릴산의 100단독중합체여기서, AA=아크릴산 MAA=메타크릴산 HPA=히드록시프로필 아크릴레이트 AMPS=2-아크릴아미드-2-메틸프로판술포산.
- 제5항에 있어서, 조성물이 크리임의 형태이고; 상기의 불화물 소오스는 불화나트륨, 불화제1주석, 모노플루오로인산나트륨 및 이들의 혼합물로부터 선택되 것이고; 상기의 치과용 마모제의 양은 10내지75%이며 그 마모제는 실리카, 수화된 알루미늄, 불용성 메탄인산염, 열경화성 중합체수지, 그리고 이들의 혼합물로부터 선택된 것이고; 그리고 상기의 구강을 부형제의 양은 10내지 90중량%인 것을 특징으로 하는 조성물.
- 제1항에 정의된 조성물을 구강에 가하는 것을 포함하는 치석 억제 방법.
- 제3항에 정의된 조성물을 구강에 가하는 것을 포함하는 치석 억제 방법.
- 제4항에 정의된 조성물을 구강에 바르는 것을 포함하는 치석 억제 방법.
- 제5항에 정의된 조성물을 치아에 바르는 것을 포함하는 치석 억제 방법.
- 제7항에 정의된 조성물을 치아에 바르는 것을 포함하는 치석 억제 방법.
- 제11항에 정의된 조성물을 치아에 바르는 것을 포함하는 치석 억제 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/135,803 US4842847A (en) | 1987-12-21 | 1987-12-21 | Dental calculus inhibiting compositions |
| US135.803 | 1987-12-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR890009366A true KR890009366A (ko) | 1989-08-01 |
Family
ID=22469747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880013073A KR890009366A (ko) | 1987-12-21 | 1988-10-07 | 치석 억제 조성물 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4842847A (ko) |
| EP (1) | EP0321650A1 (ko) |
| JP (1) | JPH01172316A (ko) |
| KR (1) | KR890009366A (ko) |
| CN (1) | CN1034667A (ko) |
| AU (1) | AU2092988A (ko) |
| PT (1) | PT88612A (ko) |
| ZA (1) | ZA886021B (ko) |
Families Citing this family (168)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4931273A (en) * | 1985-09-13 | 1990-06-05 | Colgate-Palmolive Company | Anticalculus oral composition |
| US5017362A (en) * | 1985-09-13 | 1991-05-21 | Colgate-Palmolive Company | Anticalculus oral composition |
| US5139769A (en) * | 1985-09-13 | 1992-08-18 | Colgate-Palmolive Company | Anticalculus oral composition |
| US4889712A (en) * | 1986-03-20 | 1989-12-26 | Colgate-Palmolive Company | Anticalculus oral composition |
| US4892724A (en) * | 1988-05-09 | 1990-01-09 | The B. F. Goodrich Company | Tartar inhibiting oral compositions and method |
| US4892725A (en) * | 1988-05-09 | 1990-01-09 | The B. F. Goodrich Company | Tartar inhibition on teeth |
| US4923684A (en) * | 1989-05-08 | 1990-05-08 | Beecham, Inc. | Tripolyphosphate-containing anti-calculus toothpaste |
| GB9007074D0 (en) * | 1990-03-29 | 1990-05-30 | Beecham Inc | Novel compositions |
| US4985236A (en) * | 1989-05-08 | 1991-01-15 | Beecham Inc. | Tripolyphosphate-containing anti-calculus toothpaste |
| US5089255A (en) * | 1989-06-26 | 1992-02-18 | Colgate-Palmolive Company | Dental remineralization |
| US5017363A (en) * | 1989-11-15 | 1991-05-21 | Gillette Canada, Inc. | Stabilized stannous fluoride toothpaste |
| US5009883A (en) * | 1989-11-15 | 1991-04-23 | Gillette Canada Inc. | Aqueous stannous fluoride non-abrasive home treatment gel compositions |
| US4970065A (en) * | 1989-11-15 | 1990-11-13 | Gillette Canada Inc. | Stabilized aqueous stannous fluoride mouthwash |
| US4961924A (en) * | 1989-11-15 | 1990-10-09 | Gillette Canada Inc. | Stabilized stannous fluoride toothpaste |
| AU648040B2 (en) * | 1989-11-15 | 1994-04-14 | Gillette Canada Inc. | Stabilized stannous fluoride compositions for oral care |
| US5009884A (en) * | 1989-11-15 | 1991-04-23 | Gillette Canada Inc. | Stabilized aqueous stannous fluoride mouthwash |
| US4960586A (en) * | 1989-11-15 | 1990-10-02 | Gillette Canada Inc. | Aqueous stannous fluoride non-abrasive home treatment gel compositions |
| US5013541A (en) * | 1990-04-18 | 1991-05-07 | Conopco, Inc. | Poly(alpha-hydroxy acrylic acid) and derivatives as antitartar actives in oral compositions |
| US5011682A (en) * | 1990-04-18 | 1991-04-30 | Conopco, Inc. | Hypophosphite-containing cotelomers as antitartar agents |
| US5213789A (en) * | 1990-08-02 | 1993-05-25 | The Procter & Gamble Company | Use of a carboxy-containing copolymer to inhibit plaque formation without tooth staining |
| US5283924A (en) * | 1990-09-21 | 1994-02-08 | Gillette Canada, Inc. | Interdental foam brush and treatment gel combination therewith |
| US5143719A (en) * | 1991-04-16 | 1992-09-01 | Chesebrough-Pond's Usa Co. | Anticalculus oral composition containing combinations of organophosphorus polycarboxylate cotelomers and inorganic polyphosphate salts |
| US5194246A (en) * | 1991-04-16 | 1993-03-16 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Anticalculus oral compositions containing combinations of polymers |
| US5211559A (en) * | 1991-07-18 | 1993-05-18 | Gillette Canada Inc. | Dental treatment tray for holding medicament gel |
| US5320831A (en) * | 1992-12-30 | 1994-06-14 | The Procter & Gamble Company | Oral compositions |
| US5320830A (en) * | 1992-12-30 | 1994-06-14 | The Procter & Gamble Company | Oral compositions |
| GB9307004D0 (en) * | 1993-04-02 | 1993-05-26 | Smithkline Beecham Plc | Method of treatment |
| AU6537594A (en) * | 1993-04-02 | 1994-10-24 | Smithkline Beecham Plc | An oral hygiene pretreatment composition |
| US5560905A (en) * | 1994-05-13 | 1996-10-01 | The Proctor & Gamble Company | Oral compositions |
| US5578294A (en) * | 1994-05-13 | 1996-11-26 | The Procter & Gamble Company | Oral compositions |
| US5849271A (en) * | 1995-06-07 | 1998-12-15 | The Procter & Gamble Company | Oral compositions |
| US6713049B1 (en) * | 1999-11-12 | 2004-03-30 | The Procter & Gamble Company | Oral compositions providing optimal surface conditioning |
| US20060171907A1 (en) * | 1996-11-21 | 2006-08-03 | The Procter & Gamble Company | Oral care compositions providing enhanced whitening and stain prevention |
| US20030206874A1 (en) * | 1996-11-21 | 2003-11-06 | The Proctor & Gamble Company | Promoting whole body health |
| US6350436B1 (en) * | 1996-11-21 | 2002-02-26 | The Procter & Gamble Company | Method of reducing staining of stannous in dentifrice compositions |
| US6592853B2 (en) * | 1999-03-10 | 2003-07-15 | Block Drug Company, Inc. | Dentin desensitizer containing stannous fluoride |
| US20070025928A1 (en) * | 1999-11-12 | 2007-02-01 | The Procter & Gamble Company | Stannous oral care compositions |
| US10470985B2 (en) | 1999-11-12 | 2019-11-12 | The Procter & Gamble Company | Method of protecting teeth against erosion |
| MXPA02004787A (es) | 1999-11-12 | 2002-08-30 | Procter & Gamble | Composiciones bucales estanosas mejoradas. |
| US20040146466A1 (en) | 1999-11-12 | 2004-07-29 | The Procter & Gamble Company | Method of protecting teeth against erosion |
| MXPA02004783A (es) | 1999-11-12 | 2002-08-30 | Procter & Gamble | Composiciones orales estannosas en dos fases mejoradas. |
| FR2810545B1 (fr) * | 2000-06-23 | 2004-05-07 | Snf Sa | Utilisation comme epaississants en cosmetique de copolymeres neutralises comportant des motifs d'acides faible et des motifs d'acide fort, et compositions cosmetiques les contenant |
| WO2004078165A1 (ja) * | 2003-03-07 | 2004-09-16 | Toagosei Co., Ltd. | 貼付剤用基剤及びそれを用いた貼付剤 |
| WO2005003192A1 (en) * | 2003-06-26 | 2005-01-13 | Symyx Technologies, Inc. | Synthesis of photoresist polymers |
| US20050152855A1 (en) * | 2003-09-19 | 2005-07-14 | Damian Hajduk | Materials for enhanced delivery of hydrophilic active agents in personal care formulations |
| US8765155B2 (en) * | 2007-08-30 | 2014-07-01 | Colgate-Palmolive Company | Oral care strip or tape and methods of use and manufacture thereof |
| EP2249794A4 (en) * | 2008-02-08 | 2014-01-08 | Colgate Palmolive Co | COMPOSITIONS AND METHODS COMPRISING BASIC AMINO ACID PEPTIDES AND PROTEASES |
| RU2469701C2 (ru) | 2008-02-08 | 2012-12-20 | Колгейт-Палмолив Компани | Продукт для ухода за полостью рта и способы его применения |
| AU2008349846B2 (en) | 2008-02-08 | 2012-05-31 | Colgate-Palmolive Company | Arginine salts and their uses for the treatment of illnesses in the oral cavity |
| JP5624477B2 (ja) | 2008-02-08 | 2014-11-12 | コルゲート・パーモリブ・カンパニーＣｏｌｇａｔｅ−Ｐａｌｍｏｌｉｖｅ Ｃｏｍｐａｎｙ | 口腔ケア製品ならびにその使用および製造の方法 |
| CN101938986B (zh) | 2008-02-08 | 2015-11-25 | 高露洁-棕榄公司 | 包含碱性氨基酸和可溶性碳酸盐的组合物 |
| AU2009212318B2 (en) * | 2008-02-08 | 2012-12-13 | Colgate-Palmolive Company | Oral care methods and systems |
| US20110014136A1 (en) | 2008-02-08 | 2011-01-20 | Colgate-Palmolive Company | Oral care product and methods of use and manufacture thereof |
| WO2009099455A1 (en) | 2008-02-08 | 2009-08-13 | Colgate-Palmolive Company | Oral care product and methods of use and manufacture thereof |
| EP2249789A4 (en) | 2008-02-08 | 2014-01-15 | Colgate Palmolive Co | COMPOSITIONS AND METHODS FOR THE TREATMENT OF XEROSOMY |
| CN102099004B (zh) | 2008-05-16 | 2014-08-06 | 高露洁-棕榄公司 | 口腔用组合物及其应用 |
| TWI404544B (zh) | 2008-08-11 | 2013-08-11 | Colgate Palmolive Co | 含珠粒之口腔保健組成物 |
| RU2482836C1 (ru) | 2009-04-02 | 2013-05-27 | Колгейт-Палмолив Компани | Изменяющие цвет потребительские продукты |
| CA2756934A1 (en) | 2009-04-02 | 2010-10-07 | Colgate-Palmolive Company | Oral care compositions comprising tetrapotassium pyrophosphate |
| WO2010121213A2 (en) | 2009-04-16 | 2010-10-21 | Forsyth Dental Infirmary For Children | Antibacterial compositions |
| TW201109022A (en) | 2009-06-03 | 2011-03-16 | Colgate Palmolive Co | Borinic compositions |
| US20120244091A1 (en) | 2009-12-04 | 2012-09-27 | Chopra Suman K | Non-aqueous, single tube dentrifice whitening compositions, methods of use and manufacture thereof |
| JP5723001B2 (ja) | 2010-06-23 | 2015-05-27 | コルゲート・パーモリブ・カンパニーＣｏｌｇａｔｅ−Ｐａｌｍｏｌｉｖｅ Ｃｏｍｐａｎｙ | 治療用口腔用組成物 |
| CN103153267B (zh) | 2010-08-18 | 2015-07-22 | 高露洁-棕榄公司 | 口腔护理产品及其使用和制备方法 |
| WO2012057739A1 (en) | 2010-10-27 | 2012-05-03 | Colgate-Palmolive Company | Oral care composition comprising arginine and calcium carbonate |
| WO2012061691A1 (en) * | 2010-11-05 | 2012-05-10 | The Procter & Gamble Company | Oral care applicator |
| JP5735653B2 (ja) | 2010-11-08 | 2015-06-17 | コルゲート・パーモリブ・カンパニーＣｏｌｇａｔｅ−Ｐａｌｍｏｌｉｖｅ Ｃｏｍｐａｎｙ | 微小凝集塊を含有する口腔用組成物 |
| MX338600B (es) | 2010-11-12 | 2016-04-22 | Colgate Palmolive Co | Producto para el cuidado bucal asi como metodos para el uso y manufactura del mismo. |
| WO2012064338A1 (en) | 2010-11-12 | 2012-05-18 | Colgate-Palmolive Company | Oral care product and methods of use and manufacture thereof |
| US9717929B2 (en) | 2010-12-07 | 2017-08-01 | Colgate-Palmolive Company | Dentifrice compositions containing calcium silicate and a basic amino acid |
| CN103228246A (zh) | 2010-12-07 | 2013-07-31 | 高露洁-棕榄公司 | 含硅酸钙的洁齿剂组合物 |
| EP2683447B1 (en) * | 2011-03-11 | 2016-11-09 | Unilever PLC | Oral care compositions for temporary tooth whitening |
| BR112014014459A2 (pt) | 2011-12-15 | 2017-06-13 | Colgate Palmolive Co | composições para cuidados orais |
| WO2013089761A1 (en) | 2011-12-16 | 2013-06-20 | Colgate-Palmolive Company | Color changing compositions |
| RU2604667C2 (ru) | 2011-12-21 | 2016-12-10 | Колгейт-Палмолив Компани | Композиции для ухода за полостью рта |
| RU2014129910A (ru) | 2011-12-21 | 2016-02-10 | Колгейт-Палмолив Компани | Композиции для ухода за полостью рта |
| US10123953B2 (en) | 2012-06-21 | 2018-11-13 | The Procter & Gamble Company | Reduction of tooth staining derived from cationic antimicrobials |
| MX355286B (es) | 2012-06-29 | 2018-04-13 | Colgate Palmolive Co | Composiciones orales con alto contenido de agua que comprenden celulosa microcristalina y carboximetilcelulosa. |
| CN104822422B (zh) | 2012-12-03 | 2018-03-13 | 高露洁-棕榄公司 | 用于治疗龋齿的组合物和方法 |
| CA2890537C (en) | 2012-12-05 | 2020-01-21 | Colgate-Palmolive Company | Fluoride-stable zinc containing compositions |
| US20150305993A1 (en) | 2012-12-05 | 2015-10-29 | Colgate-Palmolive Company | Zinc Phosphate Containing Compositions |
| MX352556B (es) | 2012-12-19 | 2017-11-29 | Colgate Palmolive Co | Productos para el cuidado oral que comprenden óxido de zinc y trimetilglicina. |
| EP2934447B1 (en) | 2012-12-19 | 2017-07-26 | Colgate-Palmolive Company | Zinc amino acid halide mouthwashes |
| US9827177B2 (en) | 2012-12-19 | 2017-11-28 | Colgate-Palmolive Company | Antiperspirant products with protein and antiperspirant salts |
| WO2014098828A1 (en) | 2012-12-19 | 2014-06-26 | Colgate-Palmolive Company | Teeth whitening methods, visually perceptible signals and compositions therefor|comprising zinc amino acid halides |
| BR112015014253B1 (pt) | 2012-12-19 | 2019-04-09 | Colgate-Palmolive Company | Composição de higiene bucal compreendendo um complexo de haleto de zinco tetrabásico e aminoácido e usos do complexo |
| US9504858B2 (en) | 2012-12-19 | 2016-11-29 | Colgate-Palmolive Company | Zinc amino acid halide complex with cysteine |
| US10105303B2 (en) | 2012-12-19 | 2018-10-23 | Colgate-Palmolive Company | Oral care composition comprising zinc amino acid halides |
| US9675823B2 (en) | 2012-12-19 | 2017-06-13 | Colgate-Palmolive Company | Two component compositions containing zinc amino acid halide complexes and cysteine |
| KR20150097552A (ko) | 2012-12-19 | 2015-08-26 | 콜게이트-파아므올리브캄파니 | 4가염기성 염화아연 및 트리메틸글리신을 포함하는 구강 관리 제품 |
| US9750670B2 (en) | 2012-12-19 | 2017-09-05 | Colgate-Palmolive Company | Zinc amino acid complex with cysteine |
| EP2934438B1 (en) | 2012-12-19 | 2017-02-15 | Colgate-Palmolive Company | Zinc amino acid/trimethylglycine halide |
| KR20150094651A (ko) | 2012-12-19 | 2015-08-19 | 콜게이트-파아므올리브캄파니 | 아연-아미노산 착체를 포함하는 경구 겔 |
| KR20150097584A (ko) | 2012-12-19 | 2015-08-26 | 콜게이트-파아므올리브캄파니 | 아연 리신 착물 |
| US9498421B2 (en) | 2012-12-19 | 2016-11-22 | Colgate-Palmolive Company | Two component compositions containing tetrabasic zinc-amino acid halide complexes and cysteine |
| RU2627118C2 (ru) | 2012-12-19 | 2017-08-03 | Колгейт-Палмолив Компани | Комплекс цинк-аминокислота с цистеином |
| BR112015014359B1 (pt) | 2012-12-19 | 2019-04-09 | Colgate-Palmolive Company | Composição anidra para o cuidado pessoal para aplicação na pele ou cabelo e uso de precursores de zinco para formar um haleto de zinco x para a preparação da referida composição |
| US10188112B2 (en) | 2012-12-19 | 2019-01-29 | Colgate-Palmolive Company | Personal cleansing compositions containing zinc amino acid/trimethylglycine halide |
| WO2014204439A1 (en) | 2013-06-18 | 2014-12-24 | Colgate-Palmolive Company | Zinc amino acid halide complex with cysteine |
| US20160000667A1 (en) | 2013-03-19 | 2016-01-07 | Colgate-Palmolive Company | Two-Phase Dentifrices |
| KR102146681B1 (ko) * | 2013-07-18 | 2020-08-21 | 라이온 가부시키가이샤 | 구강 바이오필름 제거제 및 구강용 조성물 |
| EP3071170B1 (en) | 2013-11-22 | 2018-02-28 | Colgate-Palmolive Company | Tooth whitening oral care product |
| CA2934503C (en) * | 2013-12-20 | 2021-03-02 | Colgate-Palmolive Company | Oral care compositions comprising an acrylate/methacrylate/hydroxyethyl methacrylate phosphate co-polymer and a tin salt |
| WO2015099638A1 (en) | 2013-12-23 | 2015-07-02 | Colgate-Palmolive Company | Tooth whitening oral care product |
| CN106456483B (zh) | 2014-06-18 | 2019-08-20 | 高露洁-棕榄公司 | 包含锌-氨基酸络合物和磷酸盐的洁牙剂 |
| RU2017121322A (ru) | 2014-12-19 | 2019-01-23 | Колгейт-Палмолив Компани | Продукт для ухода за полостью рта, предназначенный для отбеливания зубов |
| AU2016271587B2 (en) | 2015-05-29 | 2019-02-21 | Colgate-Palmolive Company | Foaming dentifrice with desensitizing agents |
| EP3247324B1 (en) | 2015-07-01 | 2020-01-01 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| BR112018001056A2 (pt) * | 2015-07-28 | 2018-09-11 | Procter & Gamble | composições para tratamento bucal contendo polímeros, copolímeros ou polímeros cruzados de amps |
| CN108136222B (zh) | 2015-10-08 | 2021-04-23 | 高露洁-棕榄公司 | 口腔护理组合物 |
| BR112018006204B1 (pt) | 2015-10-08 | 2021-03-16 | Colgate-Palmolive Company | composições para higiene bucal |
| CN108367171A (zh) * | 2015-12-24 | 2018-08-03 | 荷兰联合利华有限公司 | 用于生物膜控制的复合材料 |
| AU2017281230B2 (en) | 2016-06-24 | 2018-12-20 | Colgate-Palmolive Company | Oral care compositions and methods of using the compositions |
| US10335615B2 (en) | 2016-06-24 | 2019-07-02 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| CA3023728A1 (en) | 2016-06-24 | 2017-12-28 | Colgate-Palmolive Company | Oral care compositions |
| AU2017281341B2 (en) | 2016-06-24 | 2018-11-15 | Colgate-Palmolive Company | Oral care compositions |
| CN108135804B (zh) | 2016-06-24 | 2021-10-22 | 高露洁-棕榄公司 | 口腔护理组合物 |
| CA3023643A1 (en) | 2016-06-24 | 2017-12-28 | Colgate-Palmolive Company | Zinc lactate and stannous ion oral care composition |
| CA2992631A1 (en) | 2016-06-24 | 2017-12-28 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| US20170367953A1 (en) | 2016-06-24 | 2017-12-28 | Colgate-Palmolive Company | Oral Care Compositions and Methods of Use |
| RU2690177C1 (ru) | 2016-06-24 | 2019-05-31 | Колгейт-Палмолив Компани | Композиции для ухода за полостью рта и способы их применения |
| AU2017351069B2 (en) | 2016-10-24 | 2019-09-12 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| CN110087619B (zh) | 2016-12-21 | 2022-06-28 | 高露洁-棕榄公司 | 口腔护理组合物和使用方法 |
| US10058493B2 (en) | 2016-12-21 | 2018-08-28 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| BR112019012472B1 (pt) | 2016-12-21 | 2022-11-08 | Colgate-Palmolive Company | Composição para higiene bucal compreendendo fonte de zinco, fonte estanosa e fonte de fluoreto |
| MX2019013485A (es) | 2017-05-17 | 2021-12-10 | Colgate Palmolive Co | Composiciones para el cuidado bucal y metodos de uso. |
| CN110868992A (zh) | 2017-07-19 | 2020-03-06 | 高露洁-棕榄公司 | 锌：地衣酸络合物、口腔护理组合物及使用方法 |
| US10744079B2 (en) | 2017-08-23 | 2020-08-18 | Colgate-Palmolive Company | Oral care compositions and uses thereof |
| EP3723700A1 (en) | 2017-12-13 | 2020-10-21 | Colgate-Palmolive Company | Zinc-amino acid-tripolyphosphate complexes |
| WO2019118452A1 (en) | 2017-12-15 | 2019-06-20 | Colgate-Palmolive Company | Novel compounds |
| CN111479614B (zh) | 2017-12-19 | 2022-10-28 | 高露洁-棕榄公司 | 氨基酸氨基甲酸盐络合物 |
| BR112021011213A2 (pt) | 2018-12-20 | 2021-08-24 | Colgate-Palmolive Company | Novos métodos |
| US11058622B2 (en) | 2018-12-20 | 2021-07-13 | Colgate-Palmolive Company | Methods of treating gastric disorders |
| EP3897864A1 (en) | 2018-12-21 | 2021-10-27 | Colgate-Palmolive Company | Zinc-arginine-halide complex |
| CN113260352A (zh) | 2018-12-26 | 2021-08-13 | 高露洁-棕榄公司 | 口腔护理组合物及使用方法 |
| MX2021008980A (es) | 2019-02-01 | 2021-09-08 | Colgate Palmolive Co | Sistemas conservantes para composiciones de cuidado bucal. |
| EP3930666A1 (en) | 2019-03-29 | 2022-01-05 | Colgate-Palmolive Company | Oral care product |
| WO2020205238A1 (en) | 2019-03-29 | 2020-10-08 | Colgate-Palmolive Company | Oral care product and methods of use and manufacture thereof |
| US11191709B2 (en) | 2019-04-26 | 2021-12-07 | The Procter & Gamble Company | Reduction of tooth staining derived from cationic antimicrobials |
| CA3141540A1 (en) | 2019-06-28 | 2020-12-30 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| CN114025773A (zh) | 2019-06-28 | 2022-02-08 | 高露洁-棕榄公司 | 口腔护理组合物和使用方法 |
| MX2022002257A (es) | 2019-08-27 | 2022-03-22 | Colgate Palmolive Co | Composiciones que contienen fosfato de zinc. |
| WO2021072422A1 (en) | 2019-10-07 | 2021-04-15 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| US20240091115A1 (en) | 2019-10-07 | 2024-03-21 | Colgate-Palmolive Company | Oral Care Compositions and Methods of Use |
| EP4065065A1 (en) * | 2019-11-28 | 2022-10-05 | Unilever IP Holdings B.V. | Antimicrobial compositions comprising modified clay and copolymers |
| BR112022010366A2 (pt) | 2019-12-06 | 2022-08-16 | Colgate Palmolive Co | Produto para higiene bucal e métodos de uso e fabricação do mesmo |
| US20210196588A1 (en) | 2019-12-20 | 2021-07-01 | Colgate-Palmolive Company | Oral Care Compositions and Methods of Use |
| CN113045698B (zh) * | 2019-12-27 | 2024-02-06 | 黄石市森尔新型材料有限公司 | 一种两性离子聚合物及其制备方法、用途 |
| CN111714410B (zh) * | 2019-12-27 | 2024-01-05 | 杭州奥菲生物科技有限公司 | 一种非磷酸体系的口腔护理组合物及其制备方法 |
| CN115315293A (zh) | 2020-03-27 | 2022-11-08 | 高露洁-棕榄公司 | 口腔护理组合物和使用方法 |
| CA3178681A1 (en) | 2020-03-27 | 2021-09-30 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| US11701314B2 (en) | 2020-07-31 | 2023-07-18 | Colgate-Palmolive Company | Processes and methods |
| EP4203897A1 (en) | 2020-12-02 | 2023-07-05 | Colgate-Palmolive Company | Oral care compositions and methods of use |
| US20230338264A1 (en) | 2020-12-18 | 2023-10-26 | Colgate-Palmolive Company | Compositions and Related Methods |
| WO2022133221A1 (en) | 2020-12-18 | 2022-06-23 | Colgate-Palmolive Company | Oral care compositions with amine flourides |
| US20230355487A1 (en) | 2020-12-18 | 2023-11-09 | Colgate-Palmolive Company | Compositions and Related Methods |
| AU2021409652A1 (en) | 2020-12-21 | 2023-07-06 | Colgate-Palmolive Company | Oral care compositions and methods |
| MX2023007072A (es) | 2020-12-21 | 2023-06-26 | Colgate Palmolive Co | Composiciones y metodos para el cuidado bucal. |
| AU2021409793A1 (en) | 2020-12-21 | 2023-07-06 | Colgate-Palmolive Company | Oral care compositions comprising stannous pyrophosphate and a water-soluble alkali metal polyphosphate, and methods |
| EP4200025A1 (en) | 2021-01-25 | 2023-06-28 | Colgate-Palmolive Company | Solid oral care compositions comprising pvp and hec as binder system |
| CN115006276A (zh) | 2021-03-05 | 2022-09-06 | 高露洁-棕榄公司 | 口腔护理组合物及使用方法 |
| US20220339082A1 (en) | 2021-04-23 | 2022-10-27 | Colgate-Palmolive Company | Solid Oral Care Compositions |
| EP4199886A1 (en) | 2021-05-27 | 2023-06-28 | Colgate-Palmolive Company | Oral care compositions and methods |
| AU2022349445A1 (en) | 2021-09-22 | 2024-03-21 | Colgate-Palmolive Company | Oral care compositions comprising guanidine and stannous ion source and methods |
| CA3231150A1 (en) | 2021-09-23 | 2023-03-30 | Carlo DAEP | Oral care compositions and methods of use |
| US20230210733A1 (en) | 2021-12-30 | 2023-07-06 | Colgate-Palmolive Company | Oral Care Compositions and Methods of Use |
| WO2023150296A1 (en) | 2022-02-05 | 2023-08-10 | Colgate-Palmolive Company | Herbal oral care compositions |
| US20230404874A1 (en) | 2022-06-17 | 2023-12-21 | Colgate-Palmolive Company | Oral Compositions and Related Methods |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3966863A (en) * | 1974-12-04 | 1976-06-29 | Beecham Group Limited | Oral hygiene compositions |
| US4122163A (en) * | 1976-08-02 | 1978-10-24 | Indiana University Foundation | Dentifrice preparation comprising purified, calcined kaolin abrasives |
| US4139609A (en) * | 1976-12-27 | 1979-02-13 | Colgate Palmolive Company | Oral compositions containing an anticalculus agent |
| US4110429A (en) * | 1976-12-30 | 1978-08-29 | Colgate-Palmolive Company | Antibacterial oral composition |
| SE7809810L (sv) * | 1978-07-28 | 1980-01-29 | Colgate Palmolive Co | Oral komposition |
| US4243658A (en) * | 1979-04-02 | 1981-01-06 | Minnesota Mining And Manufacturing Company | Compositions and methods for reducing elution of therapeutic agents from teeth |
| US4420312A (en) * | 1979-05-23 | 1983-12-13 | J. M. Huber Corporation | Method for production of high fluoride compatibility dentifrice abrasives and compositions |
| US4296096A (en) * | 1979-07-05 | 1981-10-20 | Colgate-Palmolive Company | High viscosity dentifrice |
| US4272513A (en) * | 1980-01-31 | 1981-06-09 | Colgate-Palmolive Company | Stabilized oral composition |
| US4430323A (en) * | 1980-04-29 | 1984-02-07 | Jules Silver | Method for controlling oral mal odors and dental plaque |
| GB2121278B (en) * | 1982-04-20 | 1986-02-12 | Beecham Group Plc | Oral hygiene compositions |
| US4772461A (en) * | 1982-06-22 | 1988-09-20 | The Procter & Gamble Company | Oral compositions |
| DE3378159D1 (en) * | 1982-08-24 | 1988-11-10 | Nat Res Dev | Fluoride-containing compositions |
| EP0105983A1 (en) * | 1982-10-11 | 1984-04-25 | Johnson & Johnson Products Inc. | Alkali metal salts of poly(vinylbenzoic acid) as dental plaque barrier agents |
| US4436721A (en) * | 1983-06-08 | 1984-03-13 | Colgate-Palmolive Company | Oral composition having mole ratio of tetra (methylene phosphonate) to alkali metal fluoride of at least 1.4:1 |
| US4627977A (en) * | 1985-09-13 | 1986-12-09 | Colgate-Palmolive Company | Anticalculus oral composition |
-
1987
- 1987-12-21 US US07/135,803 patent/US4842847A/en not_active Expired - Fee Related
-
1988
- 1988-08-13 EP EP88113194A patent/EP0321650A1/en not_active Withdrawn
- 1988-08-15 ZA ZA886021A patent/ZA886021B/xx unknown
- 1988-08-15 AU AU20929/88A patent/AU2092988A/en not_active Abandoned
- 1988-08-22 JP JP63206498A patent/JPH01172316A/ja active Pending
- 1988-09-28 PT PT88612A patent/PT88612A/pt unknown
- 1988-10-07 KR KR1019880013073A patent/KR890009366A/ko not_active Application Discontinuation
- 1988-12-17 CN CN88108695A patent/CN1034667A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| ZA886021B (en) | 1989-07-26 |
| JPH01172316A (ja) | 1989-07-07 |
| AU2092988A (en) | 1989-06-22 |
| EP0321650A1 (en) | 1989-06-28 |
| PT88612A (pt) | 1989-07-31 |
| US4842847A (en) | 1989-06-27 |
| CN1034667A (zh) | 1989-08-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR890009366A (ko) | 치석 억제 조성물 | |
| ES353530A1 (es) | Un metodo de hacer una composicion para inhibir y eliminar la formacion de incrustaciones. | |
| EP0341660A3 (en) | Tartar inhibition on teeth | |
| KR860003008A (ko) | 구강 조성물 | |
| AU644803B2 (en) | Low molecular weight, water-soluble copolymers, process for their preparation, and detergent compositions comprising such copolymers | |
| EP0341662A3 (en) | Tartar inhibiting oral compositions and method | |
| DE3060877D1 (en) | Use of (meth)acrylic acid and maleic acid copolymers as incrustation inhibitors in detergents | |
| EP0311070A3 (en) | Compositions containing phosphonalkane carboxylic acid for scale inhibition | |
| RU2004113567A (ru) | Реализациия управления доступом к памяти с использованием оптимизаций | |
| KR970065573A (ko) | 포스포네이트-말단기를 갖는 중합체 제조 방법 | |
| JPH0215184A (ja) | モリブデン酸塩組成物による腐食抑制法 | |
| CA2083590A1 (en) | Polymers for the treatment of boiler water | |
| KR880007374A (ko) | 아크릴아미도 알칸 술폰산을 함유하는 공중합체로 수성매질을 처리하기위한 방법 | |
| EP0303747A3 (en) | Acrylic polymer and cement composition containing it | |
| DE3665883D1 (en) | Use in detergents of neutralised and/or amidised polymers containing carboxyl groups | |
| KR880006126A (ko) | 포스폰산 칼슘 물 때 형성 억제제 | |
| GR3034125T3 (en) | A method for inhibiting the deposition of silica and silicate compounds in water systems | |
| ATE94750T1 (de) | Dentalmassen, die bifunktionelle acrylsaeureoder methacrylsaeureester enthalten. | |
| FR2796391B1 (fr) | Composition nettoyante pour surfaces dures | |
| ES8607379A1 (es) | Procedimiento para preparar un copolimero como sustancia mejoradora de detengencia o como aditivo a la misma. | |
| DE3873665D1 (de) | Hitzehaertbare dentalmassen. | |
| KR890003632A (ko) | 스케일 방지제 | |
| US5194246A (en) | Anticalculus oral compositions containing combinations of polymers | |
| RU2004113564A (ru) | Жидкие абразивные чистящие составы | |
| ATE113069T1 (de) | Verwendung von n-(alkyloxy-polyalkoxymethyl) carbonamid-gruppen aufweisenden polymerisaten als zusatz zu wasch- und reinigungsmitteln. |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |