KR890000153A - 폴리머필름의 선택적 촉매 활성화 - Google Patents

폴리머필름의 선택적 촉매 활성화 Download PDF

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KR890000153A
KR890000153A KR870012542A KR870012542A KR890000153A KR 890000153 A KR890000153 A KR 890000153A KR 870012542 A KR870012542 A KR 870012542A KR 870012542 A KR870012542 A KR 870012542A KR 890000153 A KR890000153 A KR 890000153A
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polymer
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metal
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KR910002491B1 (ko
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테렌스 오코너 쥬니어 마이클
데니스 캐피스트랜 제임스
필립 브로젝 제임스
웨인 모건 얼버트
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아놀드 하비 콜
몬산토 캄파니
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Abstract

내용 없음

Description

폴리머필름의 선택적 촉매 활성화
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도와 제2도는, 본 발명에서 사용한 방법에 대한 물의 효과를 구체적으로 도시한 그래프이고,
제3도는 본발명방법중 여러예에 있어서 금속농도의 효과를 도시한 그래프이다.

Claims (24)

  1. 적어도 하나의 플리머와 적어도 하나의 원소주기율표 제1B족 또는 제8족에 속하는 금속으로된 착화합물을 포함하는 촉매적으로 활성인 표면층을 갖는 것을 특징으로하는 물건.
  2. 제1항에 있어서, 폴리머는 비닐폴리머나 또는 폴리부타디엔, 폴리크로로푸렌 및 폴리이소푸렌으로 구성된 군으로부터 선택된 불포화폴리머임을 특징으로하는 물건.
  3. 제2항에 있어서, 폴리머는 비닐폴리머이고 금속은 팔라듐, 백금, 이리듐, 루테늄, 로듐, 오스뮴, 금, 은 또는 이들의 혼합물이며, 폴리머와 금속은 폴리머의 모노머 단위체와 금속 원자의 몰비가 약 20:1 이상으로 표면층에 존재하도록 함을 특징으로 하는 물건.
  4. 제3항에 있어서, 표면층은 복사에너지에 노출시켜 활성화 되므로써 무전해 도금된 것임을 특징으로하는 물건.
  5. 제4항에 있어서, 표면층은 선택적으로 활성화되어 무전해 도금된 것임을 특징으로하는 물건.
  6. 공칭치수가 약 100나노미터 이하의 환원된 금속 클루스터로 환원될 수 있는 적어도 하나의 원소주기율표 제1B족 또는 제8족 원소의 발생클루스터를 포함하는 폴리머 표면층을 갖는 것을 특징으로하는 물건.
  7. 제6항에 있어서, 환원된 금속의 공칭치수는 실질적으로 약 10나노미터 이하임을 특징으로하는 물건.
  8. 제7항에 있어서, 원소는 팔라듐임을 특징으로하는 물건.
  9. 제6항에 있어서, 표면층은 외부표면의 배면에 발생클루스터를 갖는 것을 특징으로하는 물건.
  10. 적어도 하나의 폴리머와 적어도 하나의 원소주기율표 제1B족 또는 8족 금속의 클루스터를 포함하되 플리머의 모노머 단위체와 금속원자의 몰비가 충분히 높아 금속의 발생클루스터의 형성과 동시에 발생클루스터를 금속클루스터로 훤원시켜 형성하는 복사 에너지로 활성화되기 전까지는 촉매적으로 비활성인 표면층이 되는 촉매적으로활성인 표면층을 갖는 것을 특징으로하는 물건.
  11. 제10항에 있어서, 폴리머는 비닐폴리머이고 몰비는 적어도 약 20:1이며 폴리머가 불포화폴리머인 경우 몰비를 적어도 약 30:1임을 특징으로 하는 물건.
  12. 촉매적으로 활성인 표면층의 배면이 적어도 하나의 폴리머와 적어도 하나의 원조주기율표 제1B족 또는 제8족 금속의 포함함을 특징으로 하는 물건.
  13. 적어도 하나의 폴리머와 공칭치수가 약 100나노미터 이하인 적어도 하나이 원소주기율표 제1B족 또는 8족 금속의 클루스터로 구성된 촉매적으로 활성인 층을 갖는 표면의 적어도 일면이 무전해적으로 금속 도금된 것을 특징으로하는 물건.
  14. 제13항에 있어서, 도금된 금속은 무전해도금된 산화방지성 구리임을 특징으로하는 물건.
  15. 제14항에 있어서, 구리는 약 250나노미터까자의 입자크기를 갖는 것임을 특징으로 하는 물건.
  16. 제13항에 있어서, 기질은 폴리머섬유사를 포함함을 특징으로하는 물건.
  17. 제13항에 있어서, 기질은 폴리모포음을 포함함을 특징으로하는 물건.
  18. 무전해도금된 선화방지성 구리층의 두께가 3마이크로미터 이하인 표면을 갖는 것을 특징으로하는 물건.
  19. 복사에너지로 필름을 형성화시키기 전까지는 필름이 촉매적으로 비활성을 유지하도록 폴리머의 모노머단위체와 금속원자의 몰비를 충분히 높은 수준으로 유지시킨 적어도 하나의 폴림와 적어도 하나의 원소주기율표 제1B족 또는 제8족 금속으로 구성된 것을 특징으로하는 촉매적으로 활성인 필름형성용액.
  20. 제19항에 있어서, 폴리머는 비질포리머이고 비율은 적어도 20:1 임을 특징으로하는 필름형성용액.
  21. 폴리머기질상에 산화저항성 구리가 무전해적으로 도금된 층을 갖는 것을 특징으로하는 전기전도성 섬유사.
  22. 형성된 필름이 촉매적으로 비활성인 상태를 유지하도록 폴리머의 모노머 단위체와 그속원자의 몰비가 충분히 높게 적어도 하나의 폴리머와 적어도 하나의 원소주기율표 제1B족 또는 제8족 금속으로 구성된 필름 형성용액을 물건의 표면에 피복하여 피복층을 형성한 후, 물건상의 피복층을 건조하여 촉매적으로 비활성인 폴리머 표면층을 얻고 여기에 에너지를 공급하여 발생기 금속 클루스터를 갖는 부분을 형성한 다음, 이를 환원제로 처리하여 금속의 클루스터를 형성시킴을 특징으로하는 물건상에 촉매적으로 활성화 될 수 있는 표면을 제공하는 방법.
  23. 특허청구의 범위 제22항의 방법으로 얻어진 촉매적으로 활성화 될수 있는 표면을 무전해도금용액과 접촉시켜 무전해적으로 금속을 도금시킴을 특징으로하는 무전해도금방법.
  24. 제23항에 있어서, 무전해적으로 도금된 금속은 실질적으로 산화방지성 구리임을 특징으로하는 방법.
    ※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019870012542A 1986-11-07 1987-11-06 폴리머 필름의 선택적 촉매활성화 KR910002491B1 (ko)

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US92849986A 1986-11-07 1986-11-07
US928449 1986-11-07
US928,499 1986-11-07
US064,898 1987-06-19
US07/064,898 US4900618A (en) 1986-11-07 1987-06-19 Oxidation-resistant metal coatings
US064898 1987-06-19

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CA1340386C (en) 1999-02-09
DE3789705D1 (de) 1994-06-01
JPH07110921B2 (ja) 1995-11-29
AU598055B2 (en) 1990-06-14
JPS63159410A (ja) 1988-07-02
EP0271466B1 (en) 1994-04-27
KR910002491B1 (ko) 1991-04-23
AU8087387A (en) 1988-05-12
US4900618A (en) 1990-02-13
EP0271466A3 (en) 1988-10-12
DE3789705T2 (de) 1994-10-20

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