KR870700226A - 액체 TiCl_4상으로부터 오염물을 제거하는 방법 - Google Patents
액체 TiCl_4상으로부터 오염물을 제거하는 방법Info
- Publication number
- KR870700226A KR870700226A KR860700933A KR860700933A KR870700226A KR 870700226 A KR870700226 A KR 870700226A KR 860700933 A KR860700933 A KR 860700933A KR 860700933 A KR860700933 A KR 860700933A KR 870700226 A KR870700226 A KR 870700226A
- Authority
- KR
- South Korea
- Prior art keywords
- liquid phase
- ticl
- group
- solid
- aryl
- Prior art date
Links
- 239000000356 contaminant Substances 0.000 title claims 2
- 239000007788 liquid Substances 0.000 title 1
- 238000000034 method Methods 0.000 claims 11
- 239000007791 liquid phase Substances 0.000 claims 10
- -1 Organic acid halides Chemical class 0.000 claims 5
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 4
- 150000005826 halohydrocarbons Chemical class 0.000 claims 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 2
- 150000001875 compounds Chemical class 0.000 claims 2
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical group CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 claims 2
- 239000007787 solid Substances 0.000 claims 2
- 239000011949 solid catalyst Substances 0.000 claims 2
- 239000012265 solid product Substances 0.000 claims 2
- 125000003545 alkoxy group Chemical group 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000003054 catalyst Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 230000001376 precipitating effect Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Ceramic Products (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Saccharide Compounds (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 오염물을 유기산할로겐화물(R'는 아릴 또는 알킬기임)과 반응시켜 식 nTiCl4 (n은 0.3-3.0의 수임)의 부가확물을 침전시키고 이 부가착물을 액체상으로부터 분리하는 것을 특징으로 하는, TiCl4로 구성되는 액체상으로부터 식 TiCl3OR(R은 알킬 또는 아릴기임)의 하나 또는 그 이상의 오염물을 제거하는 방법.
- 제1항에 있어서, 액체상이 TiCl4와 할로탄화수소로 구성되는 방법.
- 제2항에 있어서, 액체상이 중량비 30:70-70:30의 TiCl4와 할로탄화수소로 구성되는 방법.
- 제2항 또는 제3항에 있어서, 할로탄화수소가 모노클로로멘젠인 방법.
- 제1항 내지 제4항중 어느 한항에 있어서, 유기산 할로겐화물과의 반응에 이어서, 15℃ 액체상이 이하의 온도로 냉각되는 방법.
- 제1항 내지 제5항중 어느 한항에 있어서, OR기가 1-8 탄소원자의 알콕시기를 나타내는 방법.
- 제6항에 있어서, OR기가 에톡시기인 방법.
- 제1항 내지 제7항중 어느 한항에 있어서, R'가 치환된 또는 치환되지 않은 페닐기인 방법.
- 다음으로 구성되는 1-알켄중합을 위한 고체 촉매성분의 제조방법:(1) 할로탄화수소 존재시에 TiCl4를 식 Mg(OR)nCl2-n(R은 알킬 또는 아릴기임)의 화합물과 반응시키고,(2) 그렇게 해서 얻어진 고체생성물을 액체상으로 부터 분리하고,(3) 식 TiCl3OR의 화합몰로 오염된 액체상을 식(R'는 아릴 또는 알킬기임)의 유기산 할로겐화물과 반응시켜서 식(n은 0.3-3.0 수임)의 부가착물을 침전시키고,(4) 고체 부가착물을 액체상으로 부터 분리시키고,(5) (1)단계의 고체생성물을 (4)단계에서 얻어진 액체상내에 적어도 60℃의 온도에서 적어도 0.5시간동안 슬러리화한 다음,(6) 고체반응 생성물을 액체상으로부터 분리한다.
- 제9항에 있어서, (1)단계가 전자주개 존재시에 수행되는 방법.
- 제10항에 있어서, 전자주개가 지방족알코올의 방향족 에스테르인 방법.
- (a) 제9항 내지 제11항중 어느 한항의 방법으로 제조된 고체촉매성분, (b) 트리알킬암모늄 화합물 또는 후자 화합물과 디 알킬 알루미늄 할라이드의 혼합물 및 (C) 지방족 알코올의 방향족 에스테르로 구성되는 촉매계 존재시의 1-알켄 중합방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB85/3000 | 1985-05-20 | ||
| GB8513000 | 1985-05-22 | ||
| GB858513000A GB8513000D0 (en) | 1985-05-22 | 1985-05-22 | Removing contaminants from liquid tici4 phase |
| PCT/EP1986/000301 WO1986007066A2 (en) | 1985-05-22 | 1986-05-16 | A process for removing contaminants from a liquid ticl4 phase |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR870700226A true KR870700226A (ko) | 1987-05-30 |
| KR940000013B1 KR940000013B1 (ko) | 1994-01-05 |
Family
ID=10579543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019860700933A KR940000013B1 (ko) | 1985-05-20 | 1986-05-16 | 액체 TiCl_4상으로부터 오염물을 제거하는 방법 |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US4683215A (ko) |
| EP (1) | EP0202715B1 (ko) |
| JP (1) | JPH0764562B2 (ko) |
| KR (1) | KR940000013B1 (ko) |
| AT (1) | ATE53594T1 (ko) |
| AU (1) | AU589981B2 (ko) |
| BG (1) | BG60380B1 (ko) |
| BR (1) | BR8606682A (ko) |
| CA (1) | CA1254899A (ko) |
| DE (1) | DE3671899D1 (ko) |
| DK (1) | DK27587A (ko) |
| DZ (1) | DZ921A1 (ko) |
| EG (1) | EG18134A (ko) |
| ES (1) | ES8707160A1 (ko) |
| GB (1) | GB8513000D0 (ko) |
| HU (1) | HU199515B (ko) |
| IN (2) | IN171621B (ko) |
| NO (1) | NO170546C (ko) |
| NZ (1) | NZ216237A (ko) |
| TR (1) | TR22390A (ko) |
| WO (1) | WO1986007066A2 (ko) |
| ZA (1) | ZA863760B (ko) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4914257A (en) * | 1988-05-23 | 1990-04-03 | Amoco Corporation | Method and apparatus for recovering high purity toluene, hexane, titanium tetrachloride and tetrahydrofuran from mixtures |
| AU2003215610A1 (en) * | 2002-03-04 | 2003-09-16 | Akzo Nobel N.V. | Treatment of a titanium tetrachloride-containing waste stream |
| JP4540055B2 (ja) * | 2005-03-30 | 2010-09-08 | 東邦チタニウム株式会社 | オレフィン類重合用固体触媒成分の製造方法 |
| WO2009116057A2 (en) * | 2008-03-18 | 2009-09-24 | Reliance Industries Limited | A process for the synthesis of alpha-olefin polymerization procatalysts |
| CN104129812B (zh) * | 2013-05-03 | 2015-09-16 | 中国石油化工股份有限公司 | 一种含钛废液的处理方法 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1809223A (en) * | 1928-05-15 | 1931-06-09 | Armen H Tashjian | Combined conduit and molding |
| GB1148184A (en) * | 1966-07-08 | 1969-04-10 | Henning Jorgensen | Improvements in or relating to ducts for enclosing electrical wiring in buildings |
| IT1042711B (it) * | 1975-09-19 | 1980-01-30 | Montedison Spa | Compnenti di catalizzatori per la polimerizzazione di olefine |
| DE2831830A1 (de) * | 1978-07-20 | 1980-01-31 | Basf Ag | Verfahren zum herstellen einer komponente fuer polymerisationskatalysatoren |
| DE3064564D1 (en) * | 1979-04-30 | 1983-09-22 | Shell Int Research | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| CA1141093A (en) * | 1979-05-17 | 1983-02-08 | Brian L. Goodall | Olefin polymerization catalyst compositions and a process for the polymerization of olefins employing such compositions |
| DE3274246D1 (en) * | 1981-12-17 | 1987-01-02 | Ici Plc | Catalyst composition, production and use |
| US4535068A (en) * | 1983-09-20 | 1985-08-13 | Shell Oil Company | Olefin polymerization catalyst compositions and polymerization process |
| IN163585B (ko) * | 1983-09-20 | 1988-10-15 | Shell Int Research |
-
1985
- 1985-05-22 GB GB858513000A patent/GB8513000D0/en active Pending
-
1986
- 1986-05-02 CA CA000508204A patent/CA1254899A/en not_active Expired
- 1986-05-08 US US06/860,941 patent/US4683215A/en not_active Expired - Lifetime
- 1986-05-16 DE DE8686200852T patent/DE3671899D1/de not_active Expired - Lifetime
- 1986-05-16 KR KR1019860700933A patent/KR940000013B1/ko not_active IP Right Cessation
- 1986-05-16 HU HU863268A patent/HU199515B/hu not_active IP Right Cessation
- 1986-05-16 AU AU59600/86A patent/AU589981B2/en not_active Ceased
- 1986-05-16 BR BR8606682A patent/BR8606682A/pt not_active IP Right Cessation
- 1986-05-16 WO PCT/EP1986/000301 patent/WO1986007066A2/en unknown
- 1986-05-16 AT AT86200852T patent/ATE53594T1/de active
- 1986-05-16 JP JP61503170A patent/JPH0764562B2/ja not_active Expired - Lifetime
- 1986-05-16 EP EP86200852A patent/EP0202715B1/en not_active Expired - Lifetime
- 1986-05-20 DZ DZ860090A patent/DZ921A1/fr active
- 1986-05-20 ES ES555134A patent/ES8707160A1/es not_active Expired
- 1986-05-20 NZ NZ216237A patent/NZ216237A/xx unknown
- 1986-05-20 IN IN448/DEL/86A patent/IN171621B/en unknown
- 1986-05-20 ZA ZA863760A patent/ZA863760B/xx unknown
- 1986-05-20 TR TR26595/86A patent/TR22390A/xx unknown
- 1986-05-21 EG EG299/86A patent/EG18134A/xx active
-
1987
- 1987-01-19 DK DK027587A patent/DK27587A/da not_active Application Discontinuation
- 1987-01-21 NO NO870260A patent/NO170546C/no not_active IP Right Cessation
- 1987-02-18 BG BG78546A patent/BG60380B1/bg unknown
-
1988
- 1988-07-15 IN IN607/DEL/88A patent/IN171800B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| IN171621B (ko) | 1992-11-28 |
| WO1986007066A2 (en) | 1986-12-04 |
| WO1986007066A3 (en) | 1986-12-31 |
| NZ216237A (en) | 1989-06-28 |
| ZA863760B (en) | 1987-07-29 |
| ATE53594T1 (de) | 1990-06-15 |
| JPS62502888A (ja) | 1987-11-19 |
| EP0202715A1 (en) | 1986-11-26 |
| KR940000013B1 (ko) | 1994-01-05 |
| US4683215A (en) | 1987-07-28 |
| NO170546B (no) | 1992-07-20 |
| BG60380B1 (bg) | 1995-01-03 |
| GB8513000D0 (en) | 1985-06-26 |
| EP0202715B1 (en) | 1990-06-13 |
| DK27587D0 (da) | 1987-01-19 |
| AU5960086A (en) | 1986-12-24 |
| TR22390A (tr) | 1987-03-19 |
| AU589981B2 (en) | 1989-10-26 |
| HU199515B (en) | 1990-02-28 |
| ES555134A0 (es) | 1987-07-16 |
| BR8606682A (pt) | 1987-08-11 |
| EG18134A (en) | 1992-08-30 |
| JPH0764562B2 (ja) | 1995-07-12 |
| NO870260L (no) | 1987-01-21 |
| DE3671899D1 (de) | 1990-07-19 |
| HUT43331A (en) | 1987-10-28 |
| NO170546C (no) | 1992-10-28 |
| DK27587A (da) | 1987-01-19 |
| ES8707160A1 (es) | 1987-07-16 |
| IN171800B (ko) | 1993-01-09 |
| DZ921A1 (fr) | 2004-09-13 |
| CA1254899A (en) | 1989-05-30 |
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