KR860009070A - 중합체필름, 코우팅 또는 성형품을 안정화 시키는 방법 및 상승 조합물 - Google Patents

중합체필름, 코우팅 또는 성형품을 안정화 시키는 방법 및 상승 조합물 Download PDF

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KR860009070A
KR860009070A KR1019860003461A KR860003461A KR860009070A KR 860009070 A KR860009070 A KR 860009070A KR 1019860003461 A KR1019860003461 A KR 1019860003461A KR 860003461 A KR860003461 A KR 860003461A KR 860009070 A KR860009070 A KR 860009070A
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triazine
group
hydrogen
general formula
compound
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KR1019860003461A
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KR940010222B1 (ko
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빈센트 수우시 피터
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아메리칸 사이아나밋드 캄파니
죤제이 헤이간
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477Six-membered rings
    • C08K5/3492Triazines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/34Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432Six-membered rings
    • C08K5/3435Piperidines
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Cable Accessories (AREA)
  • Mechanical Coupling Of Light Guides (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음

Description

중합체필름, 코우팅 또는 성형품을 안정화 시키는 방법 및 상승 조합물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 (A)와 (B)의 안정화 및 상승적 유효량을 중합체에 첨가하는 것으로 구성되는, 중합체필름, 코우팅 또는 성형품을 빛, 수분 및 산소에 대하여 안정화 시키는 방법 : (A) 2,2,6,6-테트라알킬피렌리딘 화합물, 또는 그의 산부가염 또는 금속화합물과의 착화물; (B) 하기 일반식 (I)로 표허되는 트리스-아릴-s-트리아진 화합물 :
    상기식에서, X,Y 및 Z 각각은 3개 이하의 6-각 고리로 되어있는 방향족 탄소환 라디칼로서, X,Y 및 Z중 적어도 하나는 트리아진 고리와의 부착점에 대해서 오르토 위치인 히드록시기에 의해 치환되며; R1-R9은 각기 수소, 히드록시, 알킬, 알콕시, 설포닉, 카르복시, 할로, 할로알킬 및 아실아미노로 이루어진 군에서 선택된다.
  2. 제1항에 있어서, 상기 중합체가 산촉매 열경하 아클리코우팅 또는 산촉매 열경화 알키드 수지인 방법.
  3. 제1항에 있어서, 상기 피페리딘이 하기 일반식의 화합물들로 이루어진 군에서 선택된 것인 방법.
  4. 제1항에 있어서, 상기 트리아진이 하기 일반식으로 표현되는 화합물인 방법 :
    상기식에서, R은 수소 또는 탄소수 1-18인 알킬이다.
  5. 제4항에 있어서, R이 수소 또는 C8H17인 방법.
  6. 제1항에 있어서, 상기 피페리딘 화합물이 총 수지 고형물을 기준으로 약 0.01-5중량%의 양으로 존재하고, 상기 트리아진 화합물이 총 수지 고형물을 기준으로 약 0.01-5중량%의 양으로 존재하는 방법.
  7. 제1항에 있어서, 상기 피페리딘 화합물과 상기 트리아진 화합물이 각각 총 수지 공형물을 기준으로 약 0.5중량%의 양으로 첨가되는 방법.
  8. 하기(a)와 (b)로 이루어지는, 중합체용 상승적 안정제 조합물 : (a) 2.2.6.6-테트라알킬피페리딘 화합물; (b) 하기 일반식 (I)로 표현되는 트리스-아릴-s-트리아진 화합물 :
    상기식에서, X,Y 및 Z 각각은 3개 이하의 6-각 고리로 되어있는 방향족 탄소환 라디칼로서, X,Y 및 Z중 적어도 하나는 트리아진 고리와의 부착점에 대해서 오르토 위치인 히드록시기에 의해 치환되며; R1-R9은 각기 수소, 히드록시, 알킬, 알콕시, 설포닉, 카르복시, 할로, 할로알킬 및 아실아미노로 이루어진 군에서 선택된다.
  9. 하기(A)와 (B)로 구성되는 광안정성 조성물 : (A) 코우팅 내에서 유용하며 빛에 의해 분해되기 쉬운 합성중합체 ; (B) (1) 2,2,6,6-테트라알킬피페리딘 화합물과, (2) 하기 일반식 (I)로 표현되는 트리스-아릴-s-트리아진 화합물로 이루어지는, 요효량 만큼의 상승적 안정제 조합물 :
    상기식에서, X,Y 및 Z 각각은 3개 이하의 6-각 고리로 되어있는 방향족 탄소환 라디칼로서, X,Y 및 Z중 적어도 하나는 트리아진 고리와의 부착점에 대해서 오르토 위치인 히드록시기에 의해 치환되며, R1-R9은 각기 수소, 히드록시, 알킬, 알콕시, 설포닉, 카르복시, 할로, 할로알킬 및 아실아미노로 이루어진 군에서 선택된다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860003461A 1985-05-03 1986-05-02 중합체 필름, 코우팅 또는 성형품을 안정화시키는 방법 및 상승 조합물 KR940010222B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US730,146 1985-05-03
US06/730,146 US4619956A (en) 1985-05-03 1985-05-03 Stabilization of high solids coatings with synergistic combinations
US730146 2000-12-04

Publications (2)

Publication Number Publication Date
KR860009070A true KR860009070A (ko) 1986-12-19
KR940010222B1 KR940010222B1 (ko) 1994-10-22

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KR1019860003461A KR940010222B1 (ko) 1985-05-03 1986-05-02 중합체 필름, 코우팅 또는 성형품을 안정화시키는 방법 및 상승 조합물

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Country Link
US (2) US4619956A (ko)
EP (1) EP0200190B1 (ko)
JP (1) JPH0764950B2 (ko)
KR (1) KR940010222B1 (ko)
AT (1) ATE68804T1 (ko)
BR (1) BR8601978A (ko)
CA (1) CA1263525A (ko)
DE (1) DE3682106D1 (ko)
ES (1) ES8706763A1 (ko)
MX (1) MX165852B (ko)

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US4740542A (en) 1988-04-26
JPH0764950B2 (ja) 1995-07-12
ES554574A0 (es) 1987-07-01
ES8706763A1 (es) 1987-07-01
EP0200190B1 (en) 1991-10-23
EP0200190A3 (en) 1988-01-07
US4619956A (en) 1986-10-28
CA1263525A (en) 1989-12-05
BR8601978A (pt) 1987-01-06
ATE68804T1 (de) 1991-11-15
DE3682106D1 (de) 1991-11-28
KR940010222B1 (ko) 1994-10-22
JPS61293239A (ja) 1986-12-24
MX165852B (es) 1992-12-08

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