KR890006662A - 1,3,2-옥사자포스폴리딘 - Google Patents
1,3,2-옥사자포스폴리딘 Download PDFInfo
- Publication number
- KR890006662A KR890006662A KR1019880013583A KR880013583A KR890006662A KR 890006662 A KR890006662 A KR 890006662A KR 1019880013583 A KR1019880013583 A KR 1019880013583A KR 880013583 A KR880013583 A KR 880013583A KR 890006662 A KR890006662 A KR 890006662A
- Authority
- KR
- South Korea
- Prior art keywords
- compound
- tert
- butyl
- alkyl
- composition
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 claims 13
- 125000000217 alkyl group Chemical group 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 5
- 239000011368 organic material Substances 0.000 claims 4
- 230000015556 catabolic process Effects 0.000 claims 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims 3
- 238000006731 degradation reaction Methods 0.000 claims 3
- 238000000034 method Methods 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims 3
- 230000005855 radiation Effects 0.000 claims 3
- -1 2-ethylhexyl Chemical group 0.000 claims 2
- 125000001118 alkylidene group Chemical group 0.000 claims 2
- 150000001602 bicycloalkyls Chemical group 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 239000002530 phenolic antioxidant Substances 0.000 claims 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 2
- 230000000087 stabilizing effect Effects 0.000 claims 2
- 239000000126 substance Substances 0.000 claims 2
- 229920001059 synthetic polymer Polymers 0.000 claims 2
- VNQNXQYZMPJLQX-UHFFFAOYSA-N 1,3,5-tris[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CN2C(N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C(=O)N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C2=O)=O)=C1 VNQNXQYZMPJLQX-UHFFFAOYSA-N 0.000 claims 1
- DXCHWXWXYPEZKM-UHFFFAOYSA-N 2,4-ditert-butyl-6-[1-(3,5-ditert-butyl-2-hydroxyphenyl)ethyl]phenol Chemical compound C=1C(C(C)(C)C)=CC(C(C)(C)C)=C(O)C=1C(C)C1=CC(C(C)(C)C)=CC(C(C)(C)C)=C1O DXCHWXWXYPEZKM-UHFFFAOYSA-N 0.000 claims 1
- NJQMDFDOGBTMRN-UHFFFAOYSA-N 2-(1-adamantyloxy)-3-tert-butyl-1,3,2-oxazaphospholidine Chemical compound CC(C)(C)N1CCOP1OC1(C2)CC(C3)CC2CC3C1 NJQMDFDOGBTMRN-UHFFFAOYSA-N 0.000 claims 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 claims 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 claims 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims 1
- 235000014653 Carica parviflora Nutrition 0.000 claims 1
- 241000243321 Cnidaria Species 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims 1
- 125000004956 cyclohexylene group Chemical group 0.000 claims 1
- 235000014113 dietary fatty acids Nutrition 0.000 claims 1
- 229930195729 fatty acid Natural products 0.000 claims 1
- 239000000194 fatty acid Substances 0.000 claims 1
- 150000004665 fatty acids Chemical class 0.000 claims 1
- 229920001519 homopolymer Polymers 0.000 claims 1
- 239000010977 jade Substances 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 1
- 125000003884 phenylalkyl group Chemical group 0.000 claims 1
- 229920000098 polyolefin Polymers 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- WEHDCBONCFYXKK-UHFFFAOYSA-N tert-butyl 3-(4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)OC(=O)CCC1=CC=C(O)C=C1 WEHDCBONCFYXKK-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6581—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms
- C07F9/6584—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and nitrogen atoms with or without oxygen or sulfur atoms, as ring hetero atoms having one phosphorus atom as ring hetero atom
- C07F9/65842—Cyclic amide derivatives of acids of phosphorus, in which one nitrogen atom belongs to the ring
- C07F9/65844—Cyclic amide derivatives of acids of phosphorus, in which one nitrogen atom belongs to the ring the phosphorus atom being part of a five-membered ring which may be condensed with another ring system
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (18)
- 하기 일반식의 화합물 :상기식에서, n은 1-4이고 ; R1은 C1-C5알킬, C5-C6시클로알킬, 페닐, C1-C18알킬에 의해 치환된 페닐, 알킬 잔기내의 C1-C3페닐알킬 또는 C1-C18알킬에 의해 치환된 페닐알킬이고 ; R2는, n이 1일 때, C1-C18알킬, C5-C12시클로알킬, C7-C18비시클로알킬 또는 C10-C20트리시클로알킬이고 ; n이 2-4일때, C1-C18의 n가(價)지방족 탄화수소이다.
- 제1항에 있어서, n이 1일 화합물.
- 제2항에 있어서, R2가 C1-C18알킬인 화합물.
- 제1항에 있어서, n이 1이고 R2가 C5-C12시클로알킬, C7-C18비시클로알킬 또는 C10-C20트리시클로알킬인 화합물.
- 제1항에 있어서, n이 2-4인 화합물.
- 제5항에 있어서, n이 2이고, R2가 C-2-C10알킬렌, C2-C12알킬리덴, 시클로헥실렌 또는 2,2-펜타메틸렌-프로판-1,3-디일인 화합물.
- 제1항에 있어서, n이 1이고, R1이 메틸이고, R2가 C4-C12알킬인 화합물.
- 제1항에 있어서, n이 1이고, R1이 메틸이고, R2가 시클로알킬인 화합물.
- 제1항에 있어서, n이 2이고, R1이 메틸이고, R2가 C4-C12알킬리덴인 화합물.
- 제1항에 있어서, 2-옥톡시-3-3급-부틸-1,3,2-옥사자포스폴리딘, 2-3급-부톡시-3-3급-부틸-1,3,2-옥사자포스폴리딘, 1,6-비스(3-3급-부틸-1,3,2-옥사자 포스폴리딘-2-일-2-옥시)헥산, 2-(2-에틸헥실옥시)-3-3급-부틸-1,3,2-옥사자포스폴리딘, 2-(1-아다만틸옥시)-3-3급 부틸-1,3,2-옥사자포스폴리딘, 2-(6,7,7-트리메틸-엔도-[2,2,1]-비시클로헵틸옥시)3-3급-부틸-1,3,2-옥사자포스폴리덴 화합물.
- 산화, 열 및 화학선에 의해 저하되기 쉬운 유기물질을 제1항의 적어도 한 화합물로 안정화시킨 물질의 조성물.
- 제11항에 있어서, 유기물질이 합성 중합체인 조성물.
- 제12항에 있어서, 합성 중합체가 폴리올레핀 단일 중합체 또는 혼성 중합체인 조성물.
- 제13항에 있어서, 고급 지방산의 금속염을 포함하는 조성물.
- 제11항에 있어서, 페놀성 산화 방지제를 포함하는 조성물.
- 제15항에 있어서, 상기 페놀성 산화방지제가 네오펜탈테트라일 테트라키스 (3,5-디-3급-부틸-4-히드록시히드로신나메이트), n-옥타데실 3,5-디-3급-부틸-4-히드록시히드로신나메이트, 1,3,5-트리메틸-2,4,6-트리스(3,5-디-3급 부틸-4-히드록시벤질)벤젠, 1,3,5-트리스-(3,5-디-3급 부틸-4-히드록시벤질)이소시아누레이트, 2,6-디-3급 부틸-p-크레졸 또는 2,2'-에틸리덴-비스- (4,6-디-3급-부틸페놀)인 조성물.
- 제1항의 적어도 한 화합물을 유기물질에 혼합함으로써 산화 및 열화학선에 의해 저하되기 쉬운 유기물질을 안정화시키는 방법.
- 산호, 열, 화학선에 의한 저하에 대해 유기물질을 안정화시키기 위한 제1항의 화합물의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/110,161 | 1987-10-19 | ||
| US07/110,161 US4831178A (en) | 1987-10-19 | 1987-10-19 | Aliphatic esters of 1,3,2-oxazaphospholidines |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR890006662A true KR890006662A (ko) | 1989-06-15 |
Family
ID=22331532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880013583A KR890006662A (ko) | 1987-10-19 | 1988-10-18 | 1,3,2-옥사자포스폴리딘 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4831178A (ko) |
| EP (1) | EP0313517B1 (ko) |
| JP (1) | JPH01135891A (ko) |
| KR (1) | KR890006662A (ko) |
| DE (1) | DE3877508T2 (ko) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4757141A (en) * | 1985-08-26 | 1988-07-12 | Applied Biosystems, Incorporated | Amino-derivatized phosphite and phosphate linking agents, phosphoramidite precursors, and useful conjugates thereof |
| US5258538A (en) * | 1985-08-26 | 1993-11-02 | Applied Biosystems, Inc. | 2,3-disubstituted-1,3,2-oxazaphosphacycloalkanes as nucleic acid linking agents |
| US5147909A (en) * | 1990-08-23 | 1992-09-15 | Ciba-Geigy Corporation | Substituted 1,3,2-benzoxazaphospholidines and stabilized compositions |
| US5147911A (en) * | 1990-08-23 | 1992-09-15 | Ciba-Geigy Corporation | Compositions stabilized with poly-1,3,2-oxazaphospholidines |
| US5075482A (en) * | 1990-08-23 | 1991-12-24 | Ciba-Geigy Corporation | Substituted 3,7,9-trioxa-1-aza-2,8-diphosphaspiro[4.5]decanes and stabilized compositions |
| US5075481A (en) * | 1990-08-23 | 1991-12-24 | Ciba-Geigy Corporation | Poly-1,3,2-oxazaphospholidine stabilizers |
| US5132426A (en) * | 1990-08-23 | 1992-07-21 | Ciba-Geigy Corporation | Substituted 3,7,9-trioxa-1-aza-2,8-diphosphaspiro(4,5)decanes and stabilized compositions |
| US5239103A (en) * | 1990-08-23 | 1993-08-24 | Ciba-Geigy Corporation | Process of making 3,7,9-trioxa-1-aza-2,8-diphosphaspiro[4,5]decanes |
| US5187213A (en) * | 1990-08-23 | 1993-02-16 | Ciba-Geigy Corporation | Stabilized copositions comprising 3,7,9-trioxa-1-aza-2,8-diphosphaspiro[4,5]decanes |
| US5147910A (en) * | 1990-08-23 | 1992-09-15 | Ciba-Geigy Corporation | Compositions stabilized with 3H-1,3,2-oxozaphospholidines |
| US5075484A (en) * | 1990-08-23 | 1991-12-24 | Ciba-Geigy Corporation | 3H-1,3,2-oxazaphospholidines and stabilized compositions |
| EP0473543A3 (en) * | 1990-08-23 | 1992-05-27 | Ciba-Geigy Ag | 1,3,2-oxazaphospholidine stabilizers |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3172903A (en) * | 1965-03-09 | Oxaza- phosphorinane phosphorus ester com- pounds | ||
| DE1065418B (de) * | 1953-03-21 | 1959-09-17 | Montecatini Soc. Gen. per 1'Industria Mineraria e Chimica, Mailand (Italien) | Verfahren zur Herstellung von heterocyclischen Phosphorverbindungen |
| US4757141A (en) * | 1985-08-26 | 1988-07-12 | Applied Biosystems, Incorporated | Amino-derivatized phosphite and phosphate linking agents, phosphoramidite precursors, and useful conjugates thereof |
| US4751319A (en) * | 1986-04-23 | 1988-06-14 | Ciba-Geigy Corporation | 1,3,2-oxazaphospholdine stabilizers |
-
1987
- 1987-10-19 US US07/110,161 patent/US4831178A/en not_active Expired - Fee Related
-
1988
- 1988-10-11 EP EP88810699A patent/EP0313517B1/en not_active Expired - Lifetime
- 1988-10-11 DE DE8888810699T patent/DE3877508T2/de not_active Expired - Fee Related
- 1988-10-18 KR KR1019880013583A patent/KR890006662A/ko not_active Application Discontinuation
- 1988-10-19 JP JP63263834A patent/JPH01135891A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| DE3877508T2 (de) | 1993-07-01 |
| US4831178A (en) | 1989-05-16 |
| DE3877508D1 (de) | 1993-02-25 |
| JPH01135891A (ja) | 1989-05-29 |
| EP0313517A3 (en) | 1990-05-16 |
| EP0313517B1 (en) | 1993-01-13 |
| EP0313517A2 (en) | 1989-04-26 |
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