KR860003849A - 산화용 촉매 및 그의 제조방법 - Google Patents
산화용 촉매 및 그의 제조방법 Download PDFInfo
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- KR860003849A KR860003849A KR1019850008660A KR850008660A KR860003849A KR 860003849 A KR860003849 A KR 860003849A KR 1019850008660 A KR1019850008660 A KR 1019850008660A KR 850008660 A KR850008660 A KR 850008660A KR 860003849 A KR860003849 A KR 860003849A
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- vanadium
- catalyst
- phosphorus
- ene
- composite oxide
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- 239000003054 catalyst Substances 0.000 title claims 18
- 230000003647 oxidation Effects 0.000 title claims 3
- 238000007254 oxidation reaction Methods 0.000 title claims 3
- 238000002360 preparation method Methods 0.000 title 1
- 239000011148 porous material Substances 0.000 claims description 10
- 239000002131 composite material Substances 0.000 claims description 8
- 229910052720 vanadium Inorganic materials 0.000 claims 16
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 16
- 238000000034 method Methods 0.000 claims 13
- 125000004429 atom Chemical group 0.000 claims 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 9
- 229910052698 phosphorus Inorganic materials 0.000 claims 9
- 239000011574 phosphorus Substances 0.000 claims 9
- 239000004215 Carbon black (E152) Substances 0.000 claims 7
- 150000001875 compounds Chemical class 0.000 claims 7
- 229930195733 hydrocarbon Natural products 0.000 claims 7
- 150000002430 hydrocarbons Chemical class 0.000 claims 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 6
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims 4
- 239000011541 reaction mixture Substances 0.000 claims 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims 3
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 3
- 230000001590 oxidative effect Effects 0.000 claims 3
- 239000007787 solid Substances 0.000 claims 3
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 claims 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 229910052796 boron Inorganic materials 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 229910052804 chromium Inorganic materials 0.000 claims 2
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical compound C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 claims 2
- 229910052802 copper Inorganic materials 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 2
- 150000002484 inorganic compounds Chemical class 0.000 claims 2
- 229910010272 inorganic material Inorganic materials 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 2
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 claims 2
- 229910052744 lithium Inorganic materials 0.000 claims 2
- 229910052748 manganese Inorganic materials 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- 229910052750 molybdenum Inorganic materials 0.000 claims 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 2
- 229910052759 nickel Inorganic materials 0.000 claims 2
- 229910052757 nitrogen Inorganic materials 0.000 claims 2
- 239000003960 organic solvent Substances 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 229910052718 tin Inorganic materials 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- 229910052726 zirconium Inorganic materials 0.000 claims 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 230000003213 activating effect Effects 0.000 claims 1
- 229910052797 bismuth Inorganic materials 0.000 claims 1
- AITLQAAEZWTNIK-UHFFFAOYSA-N butan-1-ol;furan-2,5-dione Chemical compound CCCCO.O=C1OC(=O)C=C1 AITLQAAEZWTNIK-UHFFFAOYSA-N 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- 239000011261 inert gas Substances 0.000 claims 1
- 238000002955 isolation Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/13—Dicarboxylic acids
- C07C57/145—Maleic acid
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Furan Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
첨부도면은 140℃에서 건조된 V―P―O 복합산화물의 기공반경이 10,000Å 이하인 기공에 대한 체적분포를 나타낸 것임.
Claims (20)
- 바나듐 1원자당 인 1―1.3원자로 된 바나듐/인 복합산화물을 함유하고 탄화수소를 말레산 무수물로 산화시키기 위한 촉매에 있어서, 반경 100―1,000Å을 갖는 기공의 기공체적률이 반경 10,000Å 이하를 갖는 기공들의 총기공 체적의 30% 이상인 것을 특징으로 하는 촉매.
- 제1항에 있어서, 100―1,000Å의 반경을 갖는 기공의 기공체적률이 10,000Å 이하의 반경을 갖는 기공들의 총기공체적의 40% 이상인 것을 특징으로 하는 촉매.
- 제1항 또는 제2항에 있어서, 촉매입자의 90%가 1―5마이크로미터의 직경을 갖는 것을 특징으로 하는 촉매.
- 제1항에 있어서, 바나듐 1원자당 인 1.05―1.2원자를 함유하는 것을 특징으로 하는 촉매.
- 제1항에 있어서, 바나듐 1원자당 촉진제 0.01―0.3(양호하기로는 0.05―0.15) 원자의 비율로 Li, Ti, Zr, Hf, Cr, Mo, Mn, Fe, Co, Ni, Cu, Zn, B, Si, Sn, Bi, 또는 이들의 혼합물로부터 선택되는 촉진제를 함유하는 것을 특징으로 하는 촉매.
- 제1항 내지 제5항중 어느 하나에 있어서, 바나듐 1원자당 인원자 1―1.3의 비율로 바나듐/인 복합산화물을 함유하고 탄화수소를 말레산 무수물로 산화시키기 위한 촉매에 있어, 인 함유 화합물을 유기용매에 도입한 후, 바나듐 함유 화합물을 바나듐 1원자당 인원자 1―1.3의 비율로 0.5―4시간(양호하기로는 0.8―2시간)동안 연속적으로 가한 다음, 반응시 생성된 물을 반응혼합물로부터 연속적 및 직접적으로 제거하고, 반응혼합물을 분리한후, V―P―O 복합산화물을 고체로 단리시킨 다음 90 내지 150℃에서 건조한후 200 내지 300℃에서 활성화시키는 방법에 의해 제조된 촉매.
- 제1항 내지 제6항중 어느 하나에 있어서, 활성화되거나 재활성화할 촉매가 산소분자 부존재하에 300 내지 500℃에서 2―6의 탄소원자를 갖는 가스상 탄화수소성분(양호하기로는 n―부안, 1,3―부타디엔, n―부텐, 부트―1―엔, 시스―부트―2―엔, 트랜스―부트―2―엔 또는 이들의 혼합물)을 복합산화물에 통과시킴으로써 환원되는 것을 특징으로 하는 촉매.
- 제1항 내지 제7항중 어느 하나에 있어서, 촉매가 분활성가스 양호하기로는 CO2또는 질소를 함유하는 가스상 탄화수소 성분에 의해 환원되는 것을 특징으로 하는 촉매.
- 바나듐/인 복합산화물로 구성되고 탄화수소를 말레산 무수물로 산화시키기 위한 촉매의 제조방법에 있어서, 인함유 화합물을 유기용매에 도입한후, 바나듐함유 화합물을 바나듐 1원자당 인원자 1―1.3의 비율로 0.5―4시간(양호하기로는 0.8―2시간) 동안 연속적으로 가한 다음, 반응시 생성된 물을 반응 혼합물로부터 연속적 및 직접적으로 제거하고, 반응혼합물을 분리한 후, V―P―O 복합산화물을 고체로 단리시킨 다음 90 내지 150℃에서 건조한후 200 내지 300℃에서 활성화시키는 것을 특징으로 하는 산화용 촉매의 제조방법.
- 제9항에 있어서, 유기용매로서 C1―C6―알콜, 양호하기로는 메탄올, 에탄올, 프로판올, 부탄올, 1―프로판올, 2―프로판올, 1―부탄올, 2―부탄올, 이소부탄올, 이소―아밀알콜 또는 이들의 혼합물, 더욱 양호하기로는 이소부탄올이 사용되는 것을 특징으로 하는 방법.
- 제9항 또는 제10항에 있어서, 사용된 인―함유 화합물이 5가인(양호하기로는 P2O5) 또는 85중량%(양호하기로는 100중량%)의 H3PO4를 함유하는 것을 특징으로 하는 방법.
- 제9항에 있어서, 5가 바나듐의 무기화합물 또는 4가 바나듐의 무기화합물, 양호하기로는 V2O5이 바나듐―함유 화합물로서 사용되는 것을 특징으로 하는 방법.
- 제9항에 있어서, 바나듐―함유 화합물이 2마이크로미터이하(양호하기로는 1마이크로미터이하)의 입자크기로 사용되는 것을 특징으로 하는 방법.
- 제9항에 있어서, 바나듐 1원자당 1.05 내지 1.2원자의 인이 사용되는 것을 특징으로 하는 방법
- 제9항에 있어서, Li, Ti, Zr, Ht, Cr, Mo, Mn, Fe, Co, Ni, Cu, Zn, B, Si, Sn 또는 Bi, 또는 이들의 혼합물로부터 선택되는 촉진제가 촉진제 대 바나듐의 비율 0.01:1 내지 0.3:1, 양호하기로는 0.05:1 내지 0.15:1로 제조과정에 첨가되는 것을 특징으로 하는 방법.
- 제9항에 있어서, 촉진제가 탄산염, 질산염, 염화물, 브롬화물, 황산염 또는 아세테이트 같은 염 또는 산화물로서 첨가되는 것을 특징으로 하는 방법.
- 제9항에 있어서, 고체가 90 내지 150℃, 양호하기로는 130 내지 140℃에서 건조되는 것을 특징으로 하는 방법.
- 제9항에 있어서, 활성화되거나 재활성화할 촉매가 산소분자 부존재하에 300 내지 500℃에서 2―6의 탄소원자를 갖는 가스상 탄화수소 성분, 양호하기로는 n―부탄, 1,3―부타디엔, n―부엔, 부트―1―엔, 시스―부트―2―엔, 트랜스―부트―2―엔 또는 이들의 혼합물을 복합산화물에 통과시킴으로써 환원되는 것을 특징으로 하는 방법.
- 제9항에 있어서, 촉매가 불활성가스, 양호하기로는 CO2또는 질소를 함유하는 가스상 탄화수소 성분에 의해 환원되는 것을 특징으로 하는 방법.
- 제1항에 있어서, 1,3―부타디엔, n―부탄, n―부텐, 부트―1―엔, 시스―부트―1―엔, 트랜스―부트―2―엔 또는 이들의 혼합물, 양호하기로는 n―부탄올 말레산 무수물로 부분적으로 산화시키기 위해 사용되는 촉매.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT23671/84A IT1177272B (it) | 1984-11-20 | 1984-11-20 | Catalizzatore per reazioni di ossidazione e procedimento per la sua produzione |
IT23,671A/84 | 1984-11-20 |
Publications (1)
Publication Number | Publication Date |
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KR860003849A true KR860003849A (ko) | 1986-06-13 |
Family
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KR1019850008660A KR860003849A (ko) | 1984-11-20 | 1985-11-20 | 산화용 촉매 및 그의 제조방법 |
Country Status (16)
Country | Link |
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US (2) | US4668652A (ko) |
EP (1) | EP0182078B1 (ko) |
JP (1) | JPS61181540A (ko) |
KR (1) | KR860003849A (ko) |
CN (1) | CN1005685B (ko) |
AR (1) | AR240877A1 (ko) |
AT (1) | ATE60256T1 (ko) |
BR (1) | BR8505808A (ko) |
CA (1) | CA1264728A (ko) |
DE (1) | DE3581496D1 (ko) |
ES (1) | ES8608927A1 (ko) |
IN (1) | IN166342B (ko) |
IT (1) | IT1177272B (ko) |
NO (1) | NO167552C (ko) |
TR (1) | TR22772A (ko) |
ZA (1) | ZA858253B (ko) |
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US5155235A (en) * | 1990-07-12 | 1992-10-13 | Mitsui Toatsu Chemicals, Inc. | Catalyst for producing maleic anhydride from butane and process for preparing same |
US5280003A (en) * | 1992-08-24 | 1994-01-18 | Scientific Design Company, Inc. | Static condition process for the preparation of phosphorous/vanadium oxidation catalyst |
US5296436A (en) * | 1993-01-08 | 1994-03-22 | Scientific Design Company, Inc. | Phosphorous/vanadium oxidation catalyst |
US5641722A (en) * | 1994-09-15 | 1997-06-24 | Huntsman Petrochemical Corporation | High performance VPO catalyst and process of preparation thereof |
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ITMI991233A1 (it) * | 1999-06-01 | 2000-12-01 | Lonza Spa | Procedimento per preparare un precursore di catalizzatore di ossido misto vanadio/fosforo |
DE10011307A1 (de) * | 2000-03-10 | 2001-09-13 | Basf Ag | Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid |
DE10211447A1 (de) * | 2002-03-15 | 2003-10-02 | Basf Ag | Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid |
DE10211449A1 (de) * | 2002-03-15 | 2003-09-25 | Basf Ag | Katalysator-Precursor für die Herstellung von Maleinsäureanhydrid und Verfahren zu dessen Herstellung |
CN1520927A (zh) * | 2003-01-30 | 2004-08-18 | ƽ | 丁烷氧化制顺丁烯二酸酐V-P-Si复合氧化物催化剂前驱体 |
EP1514598A1 (en) * | 2003-09-15 | 2005-03-16 | Lonza S.p.A. | Niobium doped vanadium/phosphorus mixed oxide catalyst |
US7357977B2 (en) * | 2005-01-13 | 2008-04-15 | International Business Machines Corporation | Ultralow dielectric constant layer with controlled biaxial stress |
US20090061649A1 (en) * | 2007-08-28 | 2009-03-05 | International Business Machines Corporation | LOW k POROUS SiCOH DIELECTRIC AND INTEGRATION WITH POST FILM FORMATION TREATMENT |
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CN103108694A (zh) * | 2010-09-10 | 2013-05-15 | 亨斯迈石油化学有限责任公司 | 用于生产马来酸酐的具有低钒氧化态的改进型vpo催化剂 |
CN103691466B (zh) * | 2012-09-27 | 2016-07-06 | 中国石油化工股份有限公司 | 一种催化剂前驱体及其制备方法和催化剂及其应用 |
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US4283307A (en) * | 1980-06-02 | 1981-08-11 | Denka Chemical Corporation | Catalyst structure for the partial oxidation of n-butane to produce maleic anhydride |
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-
1984
- 1984-11-20 IT IT23671/84A patent/IT1177272B/it active
-
1985
- 1985-10-04 ES ES547602A patent/ES8608927A1/es not_active Expired
- 1985-10-11 CA CA000492780A patent/CA1264728A/en not_active Expired - Fee Related
- 1985-10-11 AT AT85112927T patent/ATE60256T1/de not_active IP Right Cessation
- 1985-10-11 EP EP85112927A patent/EP0182078B1/de not_active Expired - Lifetime
- 1985-10-11 DE DE8585112927T patent/DE3581496D1/de not_active Expired - Fee Related
- 1985-10-16 IN IN820/MAS/85A patent/IN166342B/en unknown
- 1985-10-18 US US06/789,151 patent/US4668652A/en not_active Expired - Lifetime
- 1985-10-18 JP JP60233140A patent/JPS61181540A/ja active Granted
- 1985-10-25 CN CN85107878.8A patent/CN1005685B/zh not_active Expired
- 1985-10-28 ZA ZA858253A patent/ZA858253B/xx unknown
- 1985-11-18 TR TR46797A patent/TR22772A/xx unknown
- 1985-11-19 BR BR8505808A patent/BR8505808A/pt unknown
- 1985-11-19 NO NO854616A patent/NO167552C/no unknown
- 1985-11-20 AR AR302326A patent/AR240877A1/es active
- 1985-11-20 KR KR1019850008660A patent/KR860003849A/ko not_active Application Discontinuation
-
1986
- 1986-01-27 US US06/819,599 patent/US4713464A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100481805B1 (ko) * | 1999-02-19 | 2005-04-11 | 니폰 쇼쿠바이 컴파니 리미티드 | 기상 부분 산화용 촉매 |
Also Published As
Publication number | Publication date |
---|---|
CN1005685B (zh) | 1989-11-08 |
NO854616L (no) | 1986-05-21 |
JPH0582261B2 (ko) | 1993-11-18 |
IT8423671A1 (it) | 1986-05-20 |
IT1177272B (it) | 1987-08-26 |
NO167552C (no) | 1991-11-20 |
EP0182078A2 (de) | 1986-05-28 |
ES8608927A1 (es) | 1986-09-01 |
EP0182078B1 (de) | 1991-01-23 |
US4668652A (en) | 1987-05-26 |
AR240877A1 (es) | 1991-03-27 |
ATE60256T1 (de) | 1991-02-15 |
US4713464A (en) | 1987-12-15 |
ZA858253B (en) | 1986-06-25 |
EP0182078A3 (en) | 1988-01-13 |
CA1264728A (en) | 1990-01-23 |
AR240877A2 (es) | 1991-03-27 |
CN85107878A (zh) | 1986-05-10 |
NO167552B (no) | 1991-08-12 |
IT8423671A0 (it) | 1984-11-20 |
BR8505808A (pt) | 1986-08-12 |
JPS61181540A (ja) | 1986-08-14 |
TR22772A (tr) | 1988-07-01 |
ES547602A0 (es) | 1986-09-01 |
DE3581496D1 (de) | 1991-02-28 |
IN166342B (ko) | 1990-04-14 |
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