AR240877A2 - Catalizador destinado a reacciones de oxidacion y procedimiento para prepararlo - Google Patents

Catalizador destinado a reacciones de oxidacion y procedimiento para prepararlo

Info

Publication number
AR240877A2
AR240877A2 AR30232685A AR30232685A AR240877A2 AR 240877 A2 AR240877 A2 AR 240877A2 AR 30232685 A AR30232685 A AR 30232685A AR 30232685 A AR30232685 A AR 30232685A AR 240877 A2 AR240877 A2 AR 240877A2
Authority
AR
Argentina
Prior art keywords
catalyst
vanadium
phosphorus
pores
atom
Prior art date
Application number
AR30232685A
Other languages
English (en)
Other versions
AR240877A1 (es
Original Assignee
Alusuisse Italia Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alusuisse Italia Spa filed Critical Alusuisse Italia Spa
Application granted granted Critical
Publication of AR240877A1 publication Critical patent/AR240877A1/es
Publication of AR240877A2 publication Critical patent/AR240877A2/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/13—Dicarboxylic acids
    • C07C57/145—Maleic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Furan Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

CATALIZADOR DESTINADO A LA OXIDACION DE HIDROCARBUROS PARA FORMAR ANHIDRIDOS MALEICOS QUE CONTIENE UNA MEZCLA DE COMPUESTOS DE VANADIO Y COMPUESTOS DE FOSFORO. EL VOLUMEN TOTAL DE LOS POROS QUE TIENEN UN RADIO COMPRENDIDO ENTRE 100 Y 1000 A, DE LAS PARTICULAS, ES POR LO MENOS UN 30% DEL VOLUMEN TOTAL DE LOS POROS QUE TIENEN UN RADIO INFERIOR A 10000 A; UN 90% DE LAS PARTICULAS DEL CATALIZADOR TIENEN UN DIAMETRO COMPRENDIDO ENTRE 1 Y 5 MICROMETROS, EN TANTO QUE EL CATALIZADOR CONTIENE DE 1 A 1,3 ATOMOS DE FOSFORO POR CADA ATOMO DE VANADIO Y EVENTUALMENTE, ADITIVOS PROMOTORES DE SU ACTIVIDAD ELEGIDOS ENTE LI, TI, ZR, HF, CR, MO, MN, FE, CO, NI, CU, ZN, B, SI, SN Y BI, SOLOS O MEZCLADOS ENTRE SI, EN UNA CANTIDAD COMPRENDIDA ENTRE 0,01 Y 0,3 ATOMO DE DICHO ADITIVO POR CADA ATOMO DE VANADIO, OBTENIENDOSE EL CATALIZADOR INTRODUCIENDO EL COMPUESTO DE FOSFORO EN UN DISOLVENTE ORGANICO, AGREGANDO DE MODO CONTIGUO, EN TRANSCURSO DE 0,5 A 4 HORAS, EL COMPUESTO DE VANADIO, ELIMINANDO INMEDIATA Y CONSTANTEMENTE EL AGUA FORMADA, DURANTE LA REACCION, SEPARANDOSE A CONTINUACION LA MEZCLA OBTENIDA, AISLANDO EL COMPLEJO DE V-P-0 AL ESTADO SOLIDO, SECANDOLO A UNA TEMPERATURA COMPRENDIDA ENTRE 90 Y 150 C Y ACTIVANDOLO A UNA TEMPERATURA COMPRENDIDA ENTRE 200 Y 300 C Y EVENTUALMENTE, REDUCIENDO EL CATALIZADOR ASI OBTENIDO, CON UN HIDROCARBURO GASEOSO DE 2 A 6 ATOMOS DE C, EN AUSENCIA DE OXIGENO MOLECULAR, A UNA TEMPERATURA COMPRENDIDA ENTRE 300 Y 500 C
AR302326A 1984-11-20 1985-11-20 Catalizador destinado a reacciones de oxidacion y procedimiento para prepararlo AR240877A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT23671/84A IT1177272B (it) 1984-11-20 1984-11-20 Catalizzatore per reazioni di ossidazione e procedimento per la sua produzione

Publications (2)

Publication Number Publication Date
AR240877A1 AR240877A1 (es) 1991-03-27
AR240877A2 true AR240877A2 (es) 1991-03-27

Family

ID=11209043

Family Applications (1)

Application Number Title Priority Date Filing Date
AR302326A AR240877A1 (es) 1984-11-20 1985-11-20 Catalizador destinado a reacciones de oxidacion y procedimiento para prepararlo

Country Status (16)

Country Link
US (2) US4668652A (es)
EP (1) EP0182078B1 (es)
JP (1) JPS61181540A (es)
KR (1) KR860003849A (es)
CN (1) CN1005685B (es)
AR (1) AR240877A1 (es)
AT (1) ATE60256T1 (es)
BR (1) BR8505808A (es)
CA (1) CA1264728A (es)
DE (1) DE3581496D1 (es)
ES (1) ES8608927A1 (es)
IN (1) IN166342B (es)
IT (1) IT1177272B (es)
NO (1) NO167552C (es)
TR (1) TR22772A (es)
ZA (1) ZA858253B (es)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4996179A (en) * 1989-01-17 1991-02-26 Amoco Corporation Maleic anhydride catalysts and process for their manufacture
US5070060A (en) * 1990-05-21 1991-12-03 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
US5155235A (en) * 1990-07-12 1992-10-13 Mitsui Toatsu Chemicals, Inc. Catalyst for producing maleic anhydride from butane and process for preparing same
US5280003A (en) * 1992-08-24 1994-01-18 Scientific Design Company, Inc. Static condition process for the preparation of phosphorous/vanadium oxidation catalyst
US5296436A (en) * 1993-01-08 1994-03-22 Scientific Design Company, Inc. Phosphorous/vanadium oxidation catalyst
US5641722A (en) * 1994-09-15 1997-06-24 Huntsman Petrochemical Corporation High performance VPO catalyst and process of preparation thereof
IT1290407B1 (it) * 1996-04-29 1998-12-03 Lonza Spa Procedimento per la trasformazione di un precursore di catalizzatore a base di ossido misto di vanadio/fosforo nel catalizzatore attivo
EP1029591B1 (en) * 1999-02-19 2005-11-02 Nippon Shokubai Co., Ltd. Method for the production of acrylic acid and method for the preparation of the catalyst
ITMI991233A1 (it) * 1999-06-01 2000-12-01 Lonza Spa Procedimento per preparare un precursore di catalizzatore di ossido misto vanadio/fosforo
DE10011307A1 (de) * 2000-03-10 2001-09-13 Basf Ag Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid
DE10211447A1 (de) * 2002-03-15 2003-10-02 Basf Ag Katalysator und Verfahren zur Herstellung von Maleinsäureanhydrid
DE10211449A1 (de) * 2002-03-15 2003-09-25 Basf Ag Katalysator-Precursor für die Herstellung von Maleinsäureanhydrid und Verfahren zu dessen Herstellung
CN1520927A (zh) * 2003-01-30 2004-08-18 ƽ 丁烷氧化制顺丁烯二酸酐V-P-Si复合氧化物催化剂前驱体
EP1514598A1 (en) * 2003-09-15 2005-03-16 Lonza S.p.A. Niobium doped vanadium/phosphorus mixed oxide catalyst
US7357977B2 (en) * 2005-01-13 2008-04-15 International Business Machines Corporation Ultralow dielectric constant layer with controlled biaxial stress
US20090061649A1 (en) * 2007-08-28 2009-03-05 International Business Machines Corporation LOW k POROUS SiCOH DIELECTRIC AND INTEGRATION WITH POST FILM FORMATION TREATMENT
US20090061237A1 (en) * 2007-08-28 2009-03-05 International Business Machines Corporation LOW k POROUS SiCOH DIELECTRIC AND INTEGRATION WITH POST FILM FORMATION TREATMENT
MY155387A (en) 2008-10-21 2015-10-15 Huntsman Petrochemical Llc High pore volume vpo catalyst for maleic anhydride production
CN103108694A (zh) * 2010-09-10 2013-05-15 亨斯迈石油化学有限责任公司 用于生产马来酸酐的具有低钒氧化态的改进型vpo催化剂
CN103691466B (zh) * 2012-09-27 2016-07-06 中国石油化工股份有限公司 一种催化剂前驱体及其制备方法和催化剂及其应用
CN106622315B (zh) * 2015-11-02 2019-05-17 中国石油化工股份有限公司 一种钒磷氧化物及其制备方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3293268A (en) * 1964-03-23 1966-12-20 Princeton Chemical Res Inc Production of maleic anhydride by oxidation of n-butane
US3864280A (en) * 1972-06-19 1975-02-04 Chevron Res Catalyst for a n-butane oxidation to maleic anhydride
US4187235A (en) * 1972-09-18 1980-02-05 Chevron Research Company Method for preparing maleic anhydride
CH598863A5 (es) * 1975-01-10 1978-05-12 Lonza Ag
US4178298A (en) * 1976-05-21 1979-12-11 Lonza, Ltd. Process for preparing maleic anhydride
US4092269A (en) * 1976-10-15 1978-05-30 Monsanto Company Phosphorus-vanadium-oxygen catalysts having a specific pore volume
US4151116A (en) * 1977-08-05 1979-04-24 Halcon Research And Development Corporation Preparation of maleic anhydride
SU727217A1 (ru) * 1978-05-03 1980-04-15 Институт Физической Химии Им. Л.В. Писаржевского Ан Украинской Сср Способ приготовлени ванадий-фосфорного катализатора дл окислени бутана в малеиновый ангидрид
DE3010710A1 (de) * 1980-03-20 1981-09-24 Chemische Werke Hüls AG, 4370 Marl Verfahren zur herstellung von katalysatoren fuer die gasphaseoxidation von gesaettigten und/oder ungesaettigten c(pfeil abwaerts)4(pfeil abwaerts)-kohlenwasserstoffen zu maleinsaeureanhydrid
US4283288A (en) * 1980-05-14 1981-08-11 Standard Oil Company (Indiana) Oxidation of butane to maleic anhydride
US4283307A (en) * 1980-06-02 1981-08-11 Denka Chemical Corporation Catalyst structure for the partial oxidation of n-butane to produce maleic anhydride
US4410752A (en) * 1980-07-10 1983-10-18 The Standard Oil Company Process for the oxydehydrogenation of ethane to ethylene
US4448893A (en) * 1981-07-24 1984-05-15 The Standard Oil Company Preparation of improved mixed vanadium phosphorus oxide catalyst and their use in oxidation processes
US4472527A (en) * 1982-03-31 1984-09-18 Mitsubishi Chemical Industries Ltd. Process for preparing an oxidation catalyst composition
US4435521A (en) * 1982-05-24 1984-03-06 Exxon Research & Engineering Co. Heterogeneous process for preparing vanadium phosphorus oxygen containing catalyst composition
US4416803A (en) * 1982-05-26 1983-11-22 Standard Oil Company (Indiana) Process for the manufacture of catalysts useful for the oxidation of butane to malelic anhydride
US4525471A (en) * 1982-09-23 1985-06-25 The Standard Oil Company Attrition resistant microspheroidal fluid bed catalysts containing the mixed oxides of vanadium and phosphorus
US4518523A (en) * 1983-03-04 1985-05-21 The Standard Oil Company Method for adding make-up fluid bed oxidation catalysts for fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus

Also Published As

Publication number Publication date
CN1005685B (zh) 1989-11-08
NO854616L (no) 1986-05-21
JPH0582261B2 (es) 1993-11-18
IT8423671A1 (it) 1986-05-20
IT1177272B (it) 1987-08-26
KR860003849A (ko) 1986-06-13
NO167552C (no) 1991-11-20
EP0182078A2 (de) 1986-05-28
ES8608927A1 (es) 1986-09-01
EP0182078B1 (de) 1991-01-23
US4668652A (en) 1987-05-26
AR240877A1 (es) 1991-03-27
ATE60256T1 (de) 1991-02-15
US4713464A (en) 1987-12-15
ZA858253B (en) 1986-06-25
EP0182078A3 (en) 1988-01-13
CA1264728A (en) 1990-01-23
CN85107878A (zh) 1986-05-10
NO167552B (no) 1991-08-12
IT8423671A0 (it) 1984-11-20
BR8505808A (pt) 1986-08-12
JPS61181540A (ja) 1986-08-14
TR22772A (tr) 1988-07-01
ES547602A0 (es) 1986-09-01
DE3581496D1 (de) 1991-02-28
IN166342B (es) 1990-04-14

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