GB1389237A - Hydrocarbon conversion process and catalytic composite therefor - Google Patents

Hydrocarbon conversion process and catalytic composite therefor

Info

Publication number
GB1389237A
GB1389237A GB3233672A GB3233672A GB1389237A GB 1389237 A GB1389237 A GB 1389237A GB 3233672 A GB3233672 A GB 3233672A GB 3233672 A GB3233672 A GB 3233672A GB 1389237 A GB1389237 A GB 1389237A
Authority
GB
United Kingdom
Prior art keywords
sbf
catalyst
per cent
hydrocarbon conversion
mole per
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3233672A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Oil Products Co
Original Assignee
Universal Oil Products Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Universal Oil Products Co filed Critical Universal Oil Products Co
Priority to GB3233672A priority Critical patent/GB1389237A/en
Publication of GB1389237A publication Critical patent/GB1389237A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2702—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously
    • C07C5/271—Catalytic processes not covered by C07C5/2732 - C07C5/31; Catalytic processes covered by both C07C5/2732 and C07C5/277 simultaneously with inorganic acids; with salts or anhydrides of acids
    • C07C5/2718—Acids of halogen; Salts thereof; complexes thereof with organic compounds
    • C07C5/2721—Metal halides; Complexes thereof with organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/20—Acids of halogen; Salts thereof ; Complexes thereof with organic compounds
    • C07C2/22—Metal halides; Complexes thereof with organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/70—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/03—Acids of sulfur other than sulfhydric acid or sulfuric acid, e.g. halosulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1206—Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/133—Compounds comprising a halogen and vanadium, niobium, tantalium, antimonium or bismuth
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Abstract

1389237 Hydrocarbon conversion catalysts UNIVERSAL OIL PRODUCTS CO 11 July 1972 32336/72 Heading B1E [Also in Divisions Cl and C5] Catalyst for use in hydrocarbon conversion processes such as cracking, alkylation, transalkylation, dealkylation, disproportionation, isomerization and polymerization (including oligomerization) comprises inert porous support material selected from activated carbon, activated charcoal and graphite in combination with an active catalytic complex prepared from antimony pentafluoride and an acid component selected from hydrogen fluoride and fluosulphonic acid (HSO 3 F). The catalyst, which may be in the form of spheres, pills or extrudates, may contain from 0.05 to 0.5 parts by weight of complex per part by weight of support material which preferably has a surface area of from 50 to 1000 m<SP>2</SP>/g. The complex, which apparently is prepared merely by mixing antimony pentafluoride with the acid component, may contain from 0.1 to 1 moles of antimony pentafluoride per mole of acid component; reference is made to the complexes SbF 5 -. 2HF and SbF 5 . 2HSO 3 F and to the corresponding ionic species H 2 F<SP>+</SP> SbF 6 <SP>-</SP> and H 2 SO 3 F<SP>+</SP>SbF 5 SO 3 F<SP>-</SP>. As exemplified, catalyst is prepared by immersing spheres of activated carbon having a diameter of 1/16 inch, a surface area of 800 m<SP>2</SP>/g and pore diameters in the 20-100 Angstrom range in an anhydrous solution containing 33 mole per cent SbF 5 and 67 mole per cent HSO 3 F (Example 1) or 25 mole per cent SbF 5 and 75 mole per cent HF (Example 2) and thereafter removing excess solution. Reference also is made to the preparation of catalyst comprising activated charcoal by mixing followed by compression or by immersion.
GB3233672A 1972-07-11 1972-07-11 Hydrocarbon conversion process and catalytic composite therefor Expired GB1389237A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB3233672A GB1389237A (en) 1972-07-11 1972-07-11 Hydrocarbon conversion process and catalytic composite therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3233672A GB1389237A (en) 1972-07-11 1972-07-11 Hydrocarbon conversion process and catalytic composite therefor

Publications (1)

Publication Number Publication Date
GB1389237A true GB1389237A (en) 1975-04-03

Family

ID=10337023

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3233672A Expired GB1389237A (en) 1972-07-11 1972-07-11 Hydrocarbon conversion process and catalytic composite therefor

Country Status (1)

Country Link
GB (1) GB1389237A (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2192406A (en) * 1986-06-05 1988-01-13 British Petroleum Co Plc Catalysed pyrolysis of methane-containing gases
US5346676A (en) * 1990-12-24 1994-09-13 Crossland Clifford S Apparatus of alkylation using alkanes and olefins
EP1074300A2 (en) * 1999-08-03 2001-02-07 Atofina Chemicals, Inc. Fluorination catalysts comprising antimony V
US6262327B1 (en) 1998-04-22 2001-07-17 China Petrochemical Corporation Process for alkylation of isoparaffin with olefin
US6492571B1 (en) 1999-07-22 2002-12-10 China Petroleum Corporation Process for alkylation of isoparaffin with olefin
US7674945B2 (en) 2004-01-19 2010-03-09 China Petroleum & Chemical Corporation Process for alkylation of an aromatic hydrocarbon or isoalkane with an olefin over the catalysis of a solid acid
WO2016210006A2 (en) 2015-06-22 2016-12-29 Exelus, Inc. Improved catalyzed alkylation, alkylation catalysts, and methods of making alkylation catalysts
WO2023064644A2 (en) 2021-10-15 2023-04-20 Exelus Inc. Solid acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2192406A (en) * 1986-06-05 1988-01-13 British Petroleum Co Plc Catalysed pyrolysis of methane-containing gases
US5346676A (en) * 1990-12-24 1994-09-13 Crossland Clifford S Apparatus of alkylation using alkanes and olefins
US6262327B1 (en) 1998-04-22 2001-07-17 China Petrochemical Corporation Process for alkylation of isoparaffin with olefin
US6492571B1 (en) 1999-07-22 2002-12-10 China Petroleum Corporation Process for alkylation of isoparaffin with olefin
EP1074300A2 (en) * 1999-08-03 2001-02-07 Atofina Chemicals, Inc. Fluorination catalysts comprising antimony V
EP1074300A3 (en) * 1999-08-03 2003-11-19 Atofina Chemicals, Inc. Fluorination catalysts comprising antimony V
US7674945B2 (en) 2004-01-19 2010-03-09 China Petroleum & Chemical Corporation Process for alkylation of an aromatic hydrocarbon or isoalkane with an olefin over the catalysis of a solid acid
WO2016210006A2 (en) 2015-06-22 2016-12-29 Exelus, Inc. Improved catalyzed alkylation, alkylation catalysts, and methods of making alkylation catalysts
EP3733290A2 (en) 2015-06-22 2020-11-04 Exelus, Inc. Improved catalyzed alkylation, alkylation catalysts, and methods of making alkylation catalysts
WO2023064644A2 (en) 2021-10-15 2023-04-20 Exelus Inc. Solid acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents
US11851386B2 (en) 2021-10-15 2023-12-26 Exelus, Inc. Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents

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Legal Events

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PCNP Patent ceased through non-payment of renewal fee