KR850007976A - 치환이미다졸 및 트리아졸의 제법 - Google Patents

치환이미다졸 및 트리아졸의 제법 Download PDF

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KR850007976A
KR850007976A KR1019850002957A KR850002957A KR850007976A KR 850007976 A KR850007976 A KR 850007976A KR 1019850002957 A KR1019850002957 A KR 1019850002957A KR 850002957 A KR850002957 A KR 850002957A KR 850007976 A KR850007976 A KR 850007976A
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phenyl
compound
substituted
phenoxy
formula
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KR1019850002957A
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KR890001652B1 (ko
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티이 프리드랜더 배리 (외 2)
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다블류 제이 파아머 (외 1)
유니로이알 인코포레이팃드
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D411/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms
    • C07D411/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D411/06—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Agronomy & Crop Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

치환이미다졸 및 트리아졸의 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 하기 구조식(Ⅱ)의 치환아졸화합물을 하기 구조식(Ⅲ)의 화합물과 반응시키는 것으로 구성된 하기 구조식(I)의 화합물의 제조방법.
    상기식들에서 Z 및 Z1은 동일 또는 상이한 것으로 산소, 유황, 또는 NR3이며; 단 Z과 Z1은 동시에 산소는 아니며, 또 Z 또는 Z1중 하나가 유황인 경우 나머지 하나는 NR3가 될 수 없으며; Y는 질소 또는 CH이며; R은 직쇄 또는 분지쇄 C2-Cl2알킬렌이며; Rl은 수소, C<SB1l-C4알킬, 벤질 또는 페닐이며; R2는 페닐, 펜옥시, 페닐설피닐, 페닐설포닐, 페닐아미노, 벤질이거나 또는 할로, Cl-C4알킬, C1-C4알콕시, 니트로, 시아노, 트리할로메틸 또는 모노-, 디-, 트리할로메톡시에 의해 치환된 페닐이거나; 또는 할로 C1-C4알킬, C1-C4알콕시, 니트로, 시아노, 트리할로메틸 또는 모노-, 디-, 트리-할로메톡시에 의해 치환된 펜옥시이다.
  2. 제1항에 있어서, Y가 질소이며, Z이 산소이며, Z1이 유황이며; R이 C2-C5직쇄 또는 분지쇄알킬렌이며 : R1이 수소, 메틸 또는 페닐이며; R2가 페닐, 페닐티오, 펜옥시이거나 또는 불소, 염소, 브롬, 메틸, 메톡시, 트리플루오로메틸 또는 디클로로메톡시에 의해 치환된 페닐이거나 또는 불소, 염소, 브롬,메틸, 메톡시, 트리플루오로메틸 또는 디클로로메톡시에 의해 치환된 펜옥시인 방법.
  3. 제2항에 있어서, R이 C2알킬렌이며; R1이 수소이며; R2가 페닐, 펜옥시, 페닐티오 또는 브롬에 의해 치환된 페닐 또는 브롬에 의해 치환된 펜옥시인 방법.
  4. 제1항에 있어서, 상기한 구조식(Ⅱ)의 화합물은 적어도 1몰을 상기한 아졸화합물(I) 1몰과 반응시키며, 상기 반응이 산촉매존재하에 일어나는 방법.
  5. 제4항에 있어서, 상기 반응이 불활성탄화수소 용매중에서 수행되는 방법.
  6. 제1항에 있어서, 상기 생성물을 염화탄화수소 용매존재하에 산화제와 반응시켜 하기 구조식의 생성물을 얻는 것으로 구성된 방법.
    상기식에서 Y,R,R1및 R2는 상기한 바와 같으며 Z 및 Z1은 SO,SO2또는 상기한 의미중 하나이나 단 이때 Z과 Z1중 적어도 하나는 SO 또는 SO2이다.
  7. 제6항에 있어서, 상기 염화탄화수소용매가 클로로포름 및 디클로로메탄으로 구성된 군으로부터 선택되며, 상기 산화제가 과산화물 및 과산화산으로 구성된 군으로부터 선택되는 방법.
  8. 제7항에 있어서, 상기 산화제가 1당량 농도로 존재하는 m-클로로과산화 벤조산인 방법.
  9. 제8항에 있어서, 상기 m-클로로과산화 벤조산의 농도가 적어도 2당량인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850002957A 1984-05-02 1985-05-01 치환이미다졸 및 트리아졸 및 그들의 제법 KR890001652B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US60602584A 1984-05-02 1984-05-02
US666,409 1984-10-30
US06/666,409 US4870094A (en) 1984-05-02 1984-10-30 Substituted imidazoles and triazoles
US606,025 1990-10-30

Publications (2)

Publication Number Publication Date
KR850007976A true KR850007976A (ko) 1985-12-11
KR890001652B1 KR890001652B1 (ko) 1989-05-12

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ID=27085117

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KR1019850002957A KR890001652B1 (ko) 1984-05-02 1985-05-01 치환이미다졸 및 트리아졸 및 그들의 제법

Country Status (14)

Country Link
US (1) US4870094A (ko)
EP (1) EP0171137B1 (ko)
KR (1) KR890001652B1 (ko)
AR (1) AR244685A1 (ko)
AU (1) AU579366B2 (ko)
BR (1) BR8502029A (ko)
CA (1) CA1251799A (ko)
DE (1) DE3587790T2 (ko)
DK (1) DK195185A (ko)
ES (1) ES8603874A1 (ko)
FI (1) FI80884C (ko)
HU (1) HU201220B (ko)
NZ (1) NZ211944A (ko)
SU (1) SU1491321A3 (ko)

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ZA866595B (en) * 1985-09-19 1987-04-29 Uniroyal Chem Co Inc Substituted oxathiolanes
DE3628545A1 (de) * 1985-09-23 1987-04-23 Hoechst Ag Arylmethylazole und deren salze, verfahren zu ihrer herstellung, sie enthaltende mittel und ihre verwendung
IL83436A0 (en) * 1986-08-27 1988-01-31 Pennwalt Corp 5-substituted-3-phenyl-3-(1h-imidazol-1-ylmethyl)-2-methylisoxazolidines
US4767868A (en) * 1987-04-10 1988-08-30 Pennwalt Corporation 3-Phenyl-3-(1H-imidazol-1-ylmethyl)-2-methyl-5-[(phenylamino)methyl]isoxazolidines
US4767866A (en) * 1987-04-10 1988-08-30 Pennwalt Corporation 3-Phenyl-3-(1H-1,2,4-triazol-1-ylmethyl)-2-methyl-5-alkylisoxazolidines
NZ221116A (en) * 1986-08-27 1990-01-29 Pennwalt Corp 3-phenyl-3-(1h-1,2,4-triazol-1-ylmethyl)-5-substituted-2-methylisoxazolidines
US4769468A (en) * 1987-04-10 1988-09-06 Penwalt Corporation 5-(acyloxyalkyl)-3-phenyl-3-(1H-imidazol-1-ylmethyl)-2-methylisoxazolidines
US4767867A (en) * 1987-04-10 1988-08-30 Pennwalt Corporation 5-(alkoxyalkyl)-3-phenyl-3-(1H-imidazol-1-ylmethyl)-2-methylisoxazolidines
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EP0296518A1 (de) * 1987-06-22 1988-12-28 Ciba-Geigy Ag Neue Phenylether-derivate als Mikrobizide, Verfahren zu deren Herstellung und deren Verwendung
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US4785117A (en) * 1987-10-02 1988-11-15 Pennwalt Corporation 5,5-disubstituted-3-phenyl-3-phenyl-3-[(1H-imidazol-1-ylmethyl) or (1H-1,2,4-triazol-1-ylmethyl)]-2-methylisoxazolidine derivatives (IR 3012)
IL87797A0 (en) * 1987-10-02 1989-03-31 Pennwalt Corp 5-mono or disubstituted-3-(phenyl or 2-naphthalenyl)-3-((1h-imidazol-1-ylmethyl)-and(1h-1,2,4-triazol-1-ylmethyl))-2-(methyl or benzyl)isoxazolidines
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US4777262A (en) * 1987-10-02 1988-10-11 Pennwalt Corporation 5-(substituted thiomethyl)-3-phenyl-3-(1H-imidazol-1-ylmethyl)-2-methylisoxazolidine derivatives
US4754042A (en) * 1987-10-02 1988-06-28 Pennwalt Corporation 5-{[naphthyl(or 2-oxo-1,3-benzoxathiol-6-yl)oxy]methyl}-3-phenyl-3-(1H-imidazol-1-ylmethyl)-2-methylisoxazolidines
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Also Published As

Publication number Publication date
FI80884B (fi) 1990-04-30
AU579366B2 (en) 1988-11-24
KR890001652B1 (ko) 1989-05-12
FI851726L (fi) 1985-11-03
SU1491321A3 (ru) 1989-06-30
EP0171137B1 (en) 1994-04-06
CA1251799A (en) 1989-03-28
US4870094A (en) 1989-09-26
NZ211944A (en) 1987-09-30
EP0171137A1 (en) 1986-02-12
FI851726A0 (fi) 1985-04-30
AU4193085A (en) 1985-11-07
BR8502029A (pt) 1985-12-31
DE3587790T2 (de) 1994-08-04
HU201220B (en) 1990-10-28
AR244685A1 (es) 1993-11-30
DK195185A (da) 1985-11-03
ES542763A0 (es) 1986-01-01
DE3587790D1 (de) 1994-05-11
HUT37712A (en) 1986-02-28
ES8603874A1 (es) 1986-01-01
FI80884C (fi) 1990-08-10
DK195185D0 (da) 1985-05-01

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