KR850002831A - 디메틸디클로로실란의 직접 합성방법 및 첨가제로서 세슘을 함유하는 그를 위한 촉매 - Google Patents

디메틸디클로로실란의 직접 합성방법 및 첨가제로서 세슘을 함유하는 그를 위한 촉매 Download PDF

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Publication number
KR850002831A
KR850002831A KR1019840005936A KR840005936A KR850002831A KR 850002831 A KR850002831 A KR 850002831A KR 1019840005936 A KR1019840005936 A KR 1019840005936A KR 840005936 A KR840005936 A KR 840005936A KR 850002831 A KR850002831 A KR 850002831A
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South Korea
Prior art keywords
cesium
catalyst
metal
zinc
compound
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KR1019840005936A
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KR900005184B1 (ko
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옴므(외 1) 크리스띠앙쁘르드
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쟝-루이세그네
롱쁠랑스빼샬리뜨 쉬미끄
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Publication of KR850002831A publication Critical patent/KR850002831A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/16—Preparation thereof from silicon and halogenated hydrocarbons direct synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Surface Acoustic Wave Elements And Circuit Networks Thereof (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Silicon Polymers (AREA)
  • Inorganic Fibers (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Paper (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

내용 없음

Description

디메틸디클로로실란의 직접 합성방법 및 첨가제로서 세슘을 함유하는 그를 위한 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 실리콘, 및 구리 또는 구리화합물을 함유하는 촉매로 이루어진 고체접촉 매스에 메틸클로라이드를 반응시킴으로써 디메틸디클로로실란을 제조하는 방법에 있어서, 촉매가 나아가 실리콘과 촉매와의 고체접촉매스에 대해 약 30~1000ppm의 주석 및 안티몬 중에서 선택된 하나이상의 금속 또는 주석 및/또는 안티몬의 화합물(주석 및/또는 안티몬금속으로 계산). 및 약 0.05~4%의 세슘 또는 세슘화합물(세슘금속으로 계산)을 함유함을 특징으로 하는 방법.
  2. 제1항에 있어서, 주석 및/또는 안티몬의 함량이 약 80~250ppm임을 특징으로 하는 방법.
  3. 제1 또는 2항에 있어서, 세슘함량이 0.1~1.5%임을 특징으로 하는 방법.
  4. 제1 내지 3항중 어느 하나에 있어서, 촉매가 나아가 고체접촉 매스에 대해 약 0.1~3%의 아연 또는 아연화합물(아연금속으로 계산)을 함유함을 특징으로 하는 방법.
  5. 제4항에 있어서, 9중량%이하의 아연을 구리의 염소화반응에 촉매작용을 미치며 그리고/또는 구리 염 및 /또는 세슘과 저융점상 또는 공융물질을 형성하는 금속으로 대치함을 특징으로 하는 방법.
  6. 제5항에 있어서, 금속을 알루미늄, 카드뮴, 망간, 니켈 및 은중에서 선택함을 특징으로 하는 방법.
  7. 제1 내지 6항중 어느 하나에 있어서, 90중량%이하의 세슘 또는 세슘화합물(세슘금속으로 계산)을 리튬, 나트륨 또는 칼륨 및 루비듐 중에서 선택된 다른 알칼리금속, 또는 그러한 알칼리금속의 화합물로 대치할 수 있음을 특징으로 하는 방법.
  8. 제1 내지 7항중 어느 하나에 있어서, 아연의 중량비가 0.2~1%임을 특징으로 하는 방법.
  9. 제1 내지 8항중 어느 하나에 있어서, 사용되는 촉매를 구리, 염화제일구리 및 염화제이구리 중에서 선택함을 특징으로 하는 방법.
  10. 메틸클로라이드를 실리콘과 반응시킴으로써 직접합성을 수행하기 위한 제1 내지 9항중 어느하나에 따른 촉매.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019840005936A 1983-09-28 1984-09-27 디메틸디클로로실란의 직접 합성방법 KR900005184B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8315400 1983-09-28
FR8315400A FR2552437B1 (fr) 1983-09-28 1983-09-28 Procede et catalyseur avec le cesium comme additif pour la synthese directe du dimethyldichlorosilane

Publications (2)

Publication Number Publication Date
KR850002831A true KR850002831A (ko) 1985-05-20
KR900005184B1 KR900005184B1 (ko) 1990-07-20

Family

ID=9292609

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019840005936A KR900005184B1 (ko) 1983-09-28 1984-09-27 디메틸디클로로실란의 직접 합성방법

Country Status (17)

Country Link
US (1) US4656301A (ko)
EP (1) EP0138678B1 (ko)
JP (1) JPS6081188A (ko)
KR (1) KR900005184B1 (ko)
AT (1) ATE28461T1 (ko)
AU (1) AU567760B2 (ko)
BR (1) BR8404849A (ko)
CA (1) CA1246533A (ko)
DE (1) DE3464918D1 (ko)
ES (1) ES8602821A1 (ko)
FI (1) FI77040C (ko)
FR (1) FR2552437B1 (ko)
HK (1) HK62790A (ko)
NO (1) NO167666C (ko)
NZ (1) NZ209672A (ko)
PT (1) PT79274B (ko)
ZA (1) ZA847491B (ko)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4500724A (en) * 1983-07-28 1985-02-19 General Electric Company Method for making alkylhalosilanes
FR2552438B1 (fr) * 1983-09-28 1985-11-08 Rhone Poulenc Spec Chim Procede et catalyseur avec un alcalin comme additif pour la synthese directe du dimethyldichlorosilane
FR2577930B1 (fr) * 1985-02-22 1987-06-05 Rhone Poulenc Spec Chim Procede et catalyseur avec un metal alcalino-terreux choisi comme additif parmi le calcium, le magnesium et le beryllium pour la synthese directe du dimethyldichlorosilane
FR2577929B1 (fr) * 1985-02-22 1987-06-05 Rhone Poulenc Spec Chim Procede et catalyseur avec le baryum et/ou le strontium comme additif pour la synthese directe du dimethyldichlorosilane
US4762940A (en) * 1987-12-11 1988-08-09 Dow Corning Corporation Method for preparation of alkylhalosilanes
US4973725A (en) * 1988-06-28 1990-11-27 Union Carbide Chemicals And Plastics Company Inc. Direct synthesis process for organohalohydrosilanes
DE3823308A1 (de) * 1988-07-09 1990-01-11 Bayer Ag Verfahren zur herstellung von organosilanen
DE3841417A1 (de) * 1988-12-08 1990-06-13 Bayer Ag Verfahren zur herstellung von organosilanen
DE3929865A1 (de) * 1989-09-08 1991-03-14 Bayer Ag Verfahren zur herstellung von alkylhalogensilanen
US4965388A (en) * 1990-01-02 1990-10-23 Dow Corning Corporation Method for preparing organohalosilanes
FR2665446B1 (fr) * 1990-07-31 1992-11-27 Rhone Poulenc Chimie Procede et catalyseur comprenant un compose de lanthanide comme additif promoteur pour la synthese directe du dimethyldichlorosilane.
DE4408113A1 (de) * 1994-03-10 1995-09-14 Wacker Chemie Gmbh Verfahren zur Herstellung von Methylchlorsilanen
KR100407518B1 (ko) * 1995-12-29 2004-02-25 고려화학 주식회사 디메틸디클로로실란의제조방법
DE19817775A1 (de) * 1998-04-21 1999-10-28 Wacker Chemie Gmbh Verfahren zur Herstellung von Organochlorsilanen
FR2848124B1 (fr) * 2002-12-09 2006-03-10 Rhodia Chimie Sa Utilisation d'une composition comprenant cuivre, metal alcalin et phosphore comme systeme catalytique pour conduire la synthese directe d'alkylhalogenosilanes en attenuant la formation de coke
FR2848211B1 (fr) * 2002-12-09 2005-01-14 Rhodia Chimie Sa Procede et systeme catalytique comprenant un metal alcalin et du phosphore comme additifs promoteurs pour la synthese directe d'alkylhalogenosilanes
CN102292343A (zh) 2008-12-23 2011-12-21 道康宁公司 生产有机卤代氢硅烷的方法
DE102013209604A1 (de) * 2013-05-23 2014-11-27 Wacker Chemie Ag Verfahren zur Herstellung von Methylchlorsilanen

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2380996A (en) * 1941-09-26 1945-08-07 Gen Electric Preparation of organosilicon halides
US2380995A (en) * 1941-09-26 1945-08-07 Gen Electric Preparation of organosilicon halides
FR1046295A (fr) * 1951-12-11 1953-12-04 Nat D Etudes & De Rech S Aeron Perfectionnements apportés aux procédés pour la fabrication par synthèse de composés organosiliciques halogénés
US2917529A (en) * 1956-07-10 1959-12-15 Du Pont Preparation of alkyl chlorosilanes
DE1161430B (de) * 1961-03-30 1964-01-16 Basf Ag Verfahren zur Herstellung von Alkylchlor-polysilanen und/oder Alkylchlormonosilanen
DE1134671B (de) * 1961-06-22 1962-08-16 Wacker Chemie Gmbh Verfahren zur Herstellung von Methyl- bzw. AEthylchlorsilanen mit hohem Gehalt an Methyl- bzw. AEthyldichlorsilan
SU151336A1 (ru) * 1961-12-08 1962-11-30 С.А. Голубцов Способ получени диметилдихлорсилана
US3555064A (en) * 1967-12-22 1971-01-12 Raisa Anatolievna Turetskaya Method for the manufacture of phenyl and methylphenylchlorosilanes
US3882547A (en) * 1973-10-09 1975-05-13 Riddell Padding structure
SU810707A1 (ru) * 1977-02-01 1981-03-07 Предприятие П/Я А-7925 Способ получени алкилхлорсиланов
US4170570A (en) * 1978-01-03 1979-10-09 Standard Oil Company (Ohio) Process for preparing oxidation catalysts
DE3312775A1 (de) * 1982-04-16 1983-10-27 General Electric Co., Schenectady, N.Y. Verfahren zum herstellen von methylchlorsilanen
FR2552438B1 (fr) * 1983-09-28 1985-11-08 Rhone Poulenc Spec Chim Procede et catalyseur avec un alcalin comme additif pour la synthese directe du dimethyldichlorosilane

Also Published As

Publication number Publication date
KR900005184B1 (ko) 1990-07-20
BR8404849A (pt) 1985-08-13
FI843803L (fi) 1985-03-29
CA1246533A (fr) 1988-12-13
AU3344184A (en) 1985-04-04
FR2552437A1 (fr) 1985-03-29
PT79274B (fr) 1986-11-24
FR2552437B1 (fr) 1986-09-12
EP0138678A2 (fr) 1985-04-24
NZ209672A (en) 1987-03-31
FI843803A0 (fi) 1984-09-27
NO843854L (no) 1985-03-29
ES536289A0 (es) 1985-12-01
NO167666B (no) 1991-08-19
ATE28461T1 (de) 1987-08-15
DE3464918D1 (en) 1987-08-27
ZA847491B (en) 1985-05-29
NO167666C (no) 1991-11-27
FI77040C (fi) 1989-01-10
ES8602821A1 (es) 1985-12-01
PT79274A (fr) 1984-10-01
AU567760B2 (en) 1987-12-03
JPS6343400B2 (ko) 1988-08-30
EP0138678B1 (fr) 1987-07-22
FI77040B (fi) 1988-09-30
JPS6081188A (ja) 1985-05-09
US4656301A (en) 1987-04-07
HK62790A (en) 1990-08-17
EP0138678A3 (ko) 1985-05-22

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