KR840003612A - N-메틸카바메이트의 n- 옥살릴 유도체의 제조방법 - Google Patents
N-메틸카바메이트의 n- 옥살릴 유도체의 제조방법 Download PDFInfo
- Publication number
- KR840003612A KR840003612A KR1019830000525A KR830000525A KR840003612A KR 840003612 A KR840003612 A KR 840003612A KR 1019830000525 A KR1019830000525 A KR 1019830000525A KR 830000525 A KR830000525 A KR 830000525A KR 840003612 A KR840003612 A KR 840003612A
- Authority
- KR
- South Korea
- Prior art keywords
- formula
- aryl
- diluent
- methylcarbamate
- preparing
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 9
- 239000003085 diluting agent Substances 0.000 claims 5
- 150000001875 compounds Chemical class 0.000 claims 4
- 125000003118 aryl group Chemical group 0.000 claims 3
- -1 arylthio radical Chemical class 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- CTSLXHKWHWQRSH-UHFFFAOYSA-N oxalyl chloride Chemical compound ClC(=O)C(Cl)=O CTSLXHKWHWQRSH-UHFFFAOYSA-N 0.000 claims 2
- 150000003254 radicals Chemical group 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 125000005108 alkenylthio group Chemical group 0.000 claims 1
- 125000004414 alkyl thio group Chemical group 0.000 claims 1
- 125000000304 alkynyl group Chemical group 0.000 claims 1
- 125000005109 alkynylthio group Chemical group 0.000 claims 1
- 150000005840 aryl radicals Chemical class 0.000 claims 1
- 125000004104 aryloxy group Chemical group 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 239000011230 binding agent Substances 0.000 claims 1
- 125000000392 cycloalkenyl group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 125000000623 heterocyclic group Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- 239000012038 nucleophile Substances 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- 239000000575 pesticide Substances 0.000 claims 1
- 239000011435 rock Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 125000005415 substituted alkoxy group Chemical group 0.000 claims 1
- 125000000547 substituted alkyl group Chemical group 0.000 claims 1
- 125000003107 substituted aryl group Chemical group 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/10—Preparation of carboxylic acid amides from compounds not provided for in groups C07C231/02 - C07C231/08
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/86—Benzo [b] furans; Hydrogenated benzo [b] furans with an oxygen atom directly attached in position 7
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Thiazole And Isothizaole Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Furan Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (13)
- 일반식(Ⅱ)의 아릴 N-클로로옥살릴-N-메틸카바메이트를 일반식(Ⅲ)의 친핵체와 반응시킴을 특징으로 하여 일반식(Ⅰ)의 아릴 N-옥살릴-N-메틸-카바메이트를 제조하는 방법.상기식에서, X는 각각 임의 치환된 알콕시, 알켄옥시, 알킨옥시, 아릴옥시, 알킬티오, 알케닐티오, 알키닐티오, 또는 아릴티오 라디칼을 나타내거나 일반식 -NR3R4의 라디칼을 나타내며(여기에서 R3및 R4는 동일하거나 다르며 수소원자 또는 각각 임의 치환된 알킬, 알케닐, 알키닐, 시클로알킬, 시클로알케닐 또는 아릴 라디칼을 나타내거나, 라디칼 R3및 R4는 그들이 결합된 질소원자와 함께 임의 치환된 헤테로시클릭환을 형성한다), R1은 임의 치환된 아릴 라디칼을 나타낸다.
- 제1항에 있어서, 희석제의 존재하에 반응시킴이 특징인 방법.
- 제2항에 있어서, 희석제가 불활성 유기용매임이 특징인 방법.
- 제1항 내지 제3항중의 어느 하나에 있어서, 보조염기의 존재하에서 반응시킴이 특징인 방법.
- 제1항 내지 제4항중의 어느 하나에 있어서, 0 내지 100℃의 온도에서 반응시킴이 특징인 방법.
- 실제로 실시예 1내지 16중의 어느 하나에서 기술된 바대로, 일반식(Ⅰ)의 화합물을 제조하는 방법.상기식에서, X 및 R1은 제1항에서 정의된 바와 같다.
- 고체 또는 액화된 가스희석제 또는 담체와 혼합하거나 계면-활성제를 함유하는 액체 희석제 또는 암체와 혼합하여 제1항내지 제5항중의 어느 하나에 따라 제조된 화합물을 활성성분으로서 함유함이 특징인 농약 조성물.
- 제7항에 있어서, 활성화합물을 0.1 내지 95중량% 함유함이 특징인 조성물.
- 일반식(Ⅳ)의 아릴N-메틸카바메이트를 옥살릴클로라이드와 반응시킴을 특징으로 하여 일반식(Ⅱ)의 아릴 N-클로로옥살릴-N-메틸카바메이트를 제조하는 방법.상기 식에서, R1은 제1항에서 정의된 바와 같다.
- 제9항에 있어서, 희석제의 존재하에 반응시킴이 특징인 방법.
- 제9항 또는 제10항에 있어서, 산결합제의 존재하에 반응시킴이 특징인 방법.
- 제9항 내지 제11항중의 어는 하나에 있어서, 0 내지 150℃의 온도에서 반응시킴이 특징인 방법.
- 실제로 실시예 17 내지 23중의 어느 하나에서 기술된 바대로, 일반식(Ⅱ)의 화합물을 제조하는 방법.상기식에서, R1은 제1항에서 정의된 바와 같다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19823205195 DE3205195A1 (de) | 1982-02-13 | 1982-02-13 | N-oxalylderivate von n-methylcarbamaten, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
DEP3205195.6 | 1982-02-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
KR840003612A true KR840003612A (ko) | 1984-09-15 |
Family
ID=6155663
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019830000525A KR840003612A (ko) | 1982-02-13 | 1983-02-10 | N-메틸카바메이트의 n- 옥살릴 유도체의 제조방법 |
Country Status (19)
Country | Link |
---|---|
US (2) | US4507292A (ko) |
EP (1) | EP0087000B1 (ko) |
JP (1) | JPS58148805A (ko) |
KR (1) | KR840003612A (ko) |
AT (1) | ATE16486T1 (ko) |
AU (1) | AU557677B2 (ko) |
BR (1) | BR8300748A (ko) |
CA (1) | CA1242727A (ko) |
CS (1) | CS236783B2 (ko) |
DD (1) | DD208536A5 (ko) |
DE (2) | DE3205195A1 (ko) |
DK (1) | DK61983A (ko) |
ES (1) | ES8404320A1 (ko) |
GR (1) | GR77419B (ko) |
HU (1) | HU191285B (ko) |
IL (1) | IL67880A (ko) |
PL (1) | PL136866B1 (ko) |
PT (1) | PT76182A (ko) |
ZA (1) | ZA83949B (ko) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4532256A (en) * | 1982-12-24 | 1985-07-30 | Ciba-Geigy Corporation | Pesticidal N-methyl-carbamic acid esters |
DE3337858A1 (de) * | 1983-10-18 | 1985-04-25 | Bayer Ag, 5090 Leverkusen | N-oxalylderivate von n-methylcarbamaten, verfahren zu ihrer herstellung und ihre verwendung als schaedlingsbekaempfungsmittel |
US4608371A (en) * | 1985-03-11 | 1986-08-26 | American Cyanamid Company | Combating insects with certain 2,3-dihydro-2,2-dimethyl-7-benzofuranyl N-oxalyl-N-methyl carbamates |
EP0243184A3 (en) * | 1986-04-25 | 1989-05-10 | Roussel-Uclaf | Pesticidal compounds |
US5459151A (en) * | 1993-04-30 | 1995-10-17 | American Home Products Corporation | N-acyl substituted phenyl piperidines as bronchodilators and antiinflammatory agents |
JPH07304723A (ja) * | 1994-05-06 | 1995-11-21 | Nippon Paint Co Ltd | 水酸基を有するアシルカルバメートおよびその製造方法 |
US5859031A (en) | 1995-06-07 | 1999-01-12 | Gpi Nil Holdings, Inc. | Small molecule inhibitors of rotamase enzyme activity |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL293187A (ko) * | 1962-05-24 | |||
GB1017975A (en) * | 1963-06-25 | 1966-01-26 | Boots Pure Drug Co Ltd | Carbamate compounds and herbicidal compositions containing them |
BE785784A (fr) * | 1971-07-02 | 1973-01-03 | Bayer Ag | Nouveaux esters aryliques d'acides n-methyl-carbamiques n-carboxyles, leur procede de preparation et leurs applications commeinsecticides et acaricides |
DE2928405A1 (de) * | 1979-07-13 | 1981-01-29 | Bayer Ag | Neue n-carboxylierte carbamate, verfahren zu ihrer herstellung und ihre verwendung |
-
1982
- 1982-02-13 DE DE19823205195 patent/DE3205195A1/de not_active Withdrawn
-
1983
- 1983-01-27 US US06/461,368 patent/US4507292A/en not_active Expired - Fee Related
- 1983-01-31 EP EP83100864A patent/EP0087000B1/de not_active Expired
- 1983-01-31 DE DE8383100864T patent/DE3361189D1/de not_active Expired
- 1983-01-31 AT AT83100864T patent/ATE16486T1/de not_active IP Right Cessation
- 1983-02-03 PT PT76182A patent/PT76182A/pt unknown
- 1983-02-08 DD DD83247790A patent/DD208536A5/de unknown
- 1983-02-10 IL IL67880A patent/IL67880A/xx unknown
- 1983-02-10 KR KR1019830000525A patent/KR840003612A/ko not_active Application Discontinuation
- 1983-02-11 CS CS83955A patent/CS236783B2/cs unknown
- 1983-02-11 HU HU83478A patent/HU191285B/hu unknown
- 1983-02-11 ZA ZA83949A patent/ZA83949B/xx unknown
- 1983-02-11 CA CA000421474A patent/CA1242727A/en not_active Expired
- 1983-02-11 BR BR8300748A patent/BR8300748A/pt unknown
- 1983-02-11 DK DK61983A patent/DK61983A/da not_active Application Discontinuation
- 1983-02-11 AU AU11332/83A patent/AU557677B2/en not_active Ceased
- 1983-02-11 ES ES519708A patent/ES8404320A1/es not_active Expired
- 1983-02-11 GR GR70475A patent/GR77419B/el unknown
- 1983-02-11 PL PL1983240541A patent/PL136866B1/pl unknown
- 1983-02-12 JP JP58020576A patent/JPS58148805A/ja active Pending
-
1985
- 1985-01-03 US US06/688,492 patent/US4602033A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4507292A (en) | 1985-03-26 |
US4602033A (en) | 1986-07-22 |
BR8300748A (pt) | 1983-11-16 |
DK61983A (da) | 1983-08-14 |
PL136866B1 (en) | 1986-03-31 |
IL67880A0 (en) | 1983-06-15 |
ZA83949B (en) | 1983-11-30 |
ES519708A0 (es) | 1984-04-16 |
DK61983D0 (da) | 1983-02-11 |
AU557677B2 (en) | 1987-01-08 |
DD208536A5 (de) | 1984-04-04 |
CA1242727A (en) | 1988-10-04 |
AU1133283A (en) | 1983-08-18 |
JPS58148805A (ja) | 1983-09-05 |
GR77419B (ko) | 1984-09-13 |
IL67880A (en) | 1985-11-29 |
CS236783B2 (en) | 1985-05-15 |
ATE16486T1 (de) | 1985-11-15 |
EP0087000B1 (de) | 1985-11-13 |
ES8404320A1 (es) | 1984-04-16 |
PL240541A1 (en) | 1984-11-08 |
HU191285B (en) | 1987-02-27 |
PT76182A (en) | 1983-03-01 |
DE3361189D1 (en) | 1985-12-19 |
DE3205195A1 (de) | 1983-08-25 |
EP0087000A1 (de) | 1983-08-31 |
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A201 | Request for examination | ||
E902 | Notification of reason for refusal | ||
E601 | Decision to refuse application |