KR840003005A - 3,5-비스(트리플루오로메틸)페녹시 카르복실산과 그 유도체 - Google Patents

3,5-비스(트리플루오로메틸)페녹시 카르복실산과 그 유도체 Download PDF

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KR840003005A
KR840003005A KR1019830000356A KR830000356A KR840003005A KR 840003005 A KR840003005 A KR 840003005A KR 1019830000356 A KR1019830000356 A KR 1019830000356A KR 830000356 A KR830000356 A KR 830000356A KR 840003005 A KR840003005 A KR 840003005A
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trifluoromethyl
bis
phenoxy
group
emollient
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KR1019830000356A
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KR850001330B1 (ko
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조세프 다미코 존 (외 1)
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존 엘미 마우러
몬산토 캄파니
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04Aryloxy-acetic acids; Derivatives thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/32Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02Aryloxy-carboxylic acids; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40Unsaturated compounds
    • C07C59/58Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C07C59/66Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
    • C07C59/68Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/40Unsaturated compounds
    • C07C59/58Unsaturated compounds containing ether groups, groups, groups, or groups
    • C07C59/64Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
    • C07C59/66Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
    • C07C59/68Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
    • C07C59/70Ethers of hydroxy-acetic acid, e.g. substitutes on the ring

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  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

내용 없음

Description

3,5-비스(트리플루오로메틸)페녹시 카르복실산과 그 유도체
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (31)

  1. 적어도 1종의 아세트 아닐라이드 제초제를 다음과 같은 구조식을 갖는 완화제유효량과 함께 농작물부위에 뿌림으로서 제초제의 유해효과를 감소시키는 완화제의 이용방법.
    여기서 R1은 수소나 C1-C5알킬로 구성된 기로부터 독립적으로 선택되며 n은 1-5의 정수, R2는 다음과 같은 것들은 구성된기로 부터 선택된다.
    여기서 R3는 C1-C5알킬, 농업적으로 적합한 양이온으로 구성된 기로부터 선택되며, R4는 수소나 C1-C5알킬로 구성된 기로부터 독립적으로 선택된다.
  2. 제1항에 있어서 완화제의 이용방법은 완화제를 농작물의 종자에 사전 피복한후 토양에 파종하고 제초제를 뿌리는 것.
  3. 제1항에 있어서 완화제의 이용방법은 제초제를 종자나 파종된 토양에 뿌리고 완화제를 뿌리는 것.
  4. 제1항에 있어서 완화제의 이용방법은 완화제를 종자가 파종된 토양에 뿌리고 제초제를 뿌리는 것.
  5. 제1항에 있어서 완화제의 이용방법은 완화제와 제초제를 혼합한 혼합물은 종자가 파종된 토양에 뿌리는 것.
  6. 제2,3,4,5항에 있어서 완화제는 4-[3,5-비스(트리플루오로메틸)페녹시]부타노익에시드.
  7. 제2,3,4,5항에 있어서 완화제는 에틸 4-[3,5-비스(트리플루오로메틸)페녹시]부티레이트.
  8. 제2,3,4,5항에 있어서 완화제는 2-[3,5-비스(트리플루오로메틸)페녹시]프로피오닉에시드.
  9. 제2,3,4,5항에 있어서 완화제는 [3,5-비스(트리플루오로메틸)페녹시]아세틱에시드.
  10. 제2,3,4,5항에 있어서 완화제는 메틸 [3,5-비스(트리플루오로메틸)페녹시]아세테이트.
  11. 제2,3,4,5항에 있어서 완화제는 2-[3,5-비스(트리플루오로메틸)페녹시]프로판아미드.
  12. 제2,3,4,5항에 있어서 완화제는 에틸 [3,5-비스(트리플루오로메틸)페녹시]아세테이트.
  13. 제2,3,4,5항에 있어서 완화제는 N-메틸 2-[3,5-비스(트리플루오로메틸)페녹시]아세트아미드.
  14. 제2,3,4,5항에 있어서 완화제는 2-[3,5-비스(트리플루오로메틸)페녹시]아세트아미드.
  15. 제2,3,4,5항에 있어서 완화제는 [3,5-비스(트리플루오로메틸)페녹시]아세틱에시드의 나트륨염.
  16. 제2,3,4,5항에 있어서 완화제는 에틸 2-[3,5-비스(트리플루오로메틸)페녹시]프로피오네이트.
  17. 제2,3,4,5항에 있어서 아세트 아닐라이드 제초제는 2-클로로-2′, 6′-디에틸-N-(메톡시메틸)아세트 아닐라이드.
  18. 제2,3,4,5항에 있어서 아세트 아닐라이드 제초제는 2-클로로-2′, 6′-디에틸-N-(부톡시메틸)아세트 아닐라이드.
  19. 제2,3,4,5항에 있어서 아세트 아닐라이드 제초제는 2,3,3-트리클로로알릴 디이소프로필티오 카바메이트.
  20. 제2,3,4,5항에 있어서 아세트 아닐라이드 제초제는 2-클로로-2′-메틸- 6′-메톡시-N-(이소프로필)아세트 아닐라이드.
  21. 제1항에 있어서 농작물의 종류는 사탕수수이다.
  22. 제2,3,4,5항에 있어서 농작물의 종류는 사탕수수이다.
  23. 염기성 조건하에서 3,5-디트리플루오로 메틸페놀과 다음 일반식을 가지는 화합물을 반응시켜 3,5-비스(트리플루오로메틸)페녹시 화합물을 제조하는 방법.
    R - X
    여기에서 R은 다음 구조식을 갖는다.
    여기에서 R1수소와 C1-C5알킬로 구성된 기로부터 독립선택되고 n은 1-5의 정수, R2 로 구성된 기로부터 독립선택되며 여기서 X는 할로겐이며 반응매질로부터 페녹시 화합물을 분리한다.
  24. 염기성 반응 매질존재하에서 3,5-디트리플루오로메틸페놀과 다음 일반식을 가지는 화합물을 반응시켜 3,5-비스(트리플루오로메틸)페녹시 화합물을 제조하는 방법.
    R - X
    여기서 R은 다음과 같은 구조식을 갖는다.
    여기서 R1은 수소와 C1-C5알킬로 구성된 기로부터 독립선택되고 n은 1-5의 정수, R2 로 구성된 기로부터 선택된다. 여기에서 R3는 C1C5알킬, R4는 수소와 C1-C5알킬로 구성된기로부터 선택되며 X는 할로겐, 이반응은 0-100℃의온도에서 반응시킨다.
  25. 제24항에 있어서 반응매질은 불활성유기용매이다.
  26. 제24항에 있어서 반응매질은 염기성수용액이다.
  27. 제25항에 있어서 반응온도는 환류온도이다.
  28. 염기성 반응매질 존재하에서 3,5-디트리플루오로메틸페놀과 다음의 일반식을 가지는 화합물을 반응시켜 3,5-비스(트리플루오로메틸)페녹시 아미드를 제조하는 방법.
    여기에서 R1과 R4는 수소나 C1-C5알킬로 구성된 기로부터 독립적으로 선택되며 X는 할로겐이다.
  29. 제28항에 있어서 반응매질은 불활성 유기용매이며 반응온도는 0-100℃이다.
  30. 염기성 매질 존재하에서 3,5-디트리플루오로메틸페놀과 다음의 구조식을 가지는 화합물을 반응시켜 3,5-비스(트리플루오로메틸)페녹시 에스테르를 제조하는 방법.
    여기에서 R1과 R3는 수소와 C1-C5알킬로 구성된기로 부터 독립적으로 선택되며 X는 할로겐이다.
  31. 제30항에 있어서 반응매질은 불활성유기용매이고 반응온도는 0-100℃이다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019830000356A 1982-02-01 1983-01-31 3, 5-비스(트리플루오로메틸)페녹시 카르복실산과 그 유도체 KR850001330B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/344,652 US4416687A (en) 1982-02-01 1982-02-01 3,5-Bis (trifluoromethyl)phenoxy carboxylic acids and derivatives thereof
US344652 1982-02-01

Publications (2)

Publication Number Publication Date
KR840003005A true KR840003005A (ko) 1984-08-13
KR850001330B1 KR850001330B1 (ko) 1985-09-19

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KR1019830000356A KR850001330B1 (ko) 1982-02-01 1983-01-31 3, 5-비스(트리플루오로메틸)페녹시 카르복실산과 그 유도체

Country Status (13)

Country Link
US (1) US4416687A (ko)
EP (1) EP0088066B1 (ko)
JP (1) JPS58134048A (ko)
KR (1) KR850001330B1 (ko)
AU (1) AU554260B2 (ko)
BR (1) BR8300476A (ko)
DE (1) DE3360085D1 (ko)
ES (1) ES519346A0 (ko)
NO (1) NO155132C (ko)
NZ (1) NZ203138A (ko)
PH (1) PH18317A (ko)
PT (1) PT76173B (ko)
ZA (1) ZA83617B (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3404401C2 (de) * 1984-02-08 1994-02-10 Hoechst Ag Verwendung von Aryloxy-Verbindungen als Antidots
US4859234A (en) * 1987-09-14 1989-08-22 Ici Americas Inc. Herbicidal compositions of acylated 1,3-dicarbonyl herbicides and phenoxyalkanoic acids, salts, amides and esters therof as antidotes
DE4217928A1 (de) * 1992-05-30 1993-12-02 Hoechst Ag Neue Mischungen aus Herbiziden und Antidots, neue (Hetero-)Aryloxy-Verbindungen, Verfahren zu deren Herstellung, diese enthaltenden Mittel und deren Verwendung
FR2698873B1 (fr) * 1992-12-07 1995-02-24 Lipha Benzocycloheptènes, benzoxépines et benzothiépines activateurs des canaux potassiques, procédé de préparation, composition pharmaceutique les contenant.
TW259690B (ko) 1992-08-01 1995-10-11 Hoechst Ag
EP1917864A1 (en) 2006-11-01 2008-05-07 Nestec S.A. Soluble foaming beverage powder
EP3368509A4 (en) * 2015-10-30 2019-05-01 Trillium Therapeutics Inc. FLUORINATED AMIDE DERIVATIVES AND THEIR USES AS THERAPEUTIC AGENTS
US11512067B2 (en) 2017-09-14 2022-11-29 Daiichi Sankyo Company, Limited Compound having cyclic structure

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR6679625D0 (pt) * 1965-05-27 1973-10-23 Merck & Co Inc Processo para preparar acidos carboxilicos
US3617245A (en) * 1966-04-07 1971-11-02 Fujisawa Pharmaceutical Co Compositions and methods for controlling plant growth
BE795943A (fr) * 1972-02-29 1973-08-27 Bayer Ag Nouveaux derives de 2,4-bis (trifluoromethyl)2-6-nitrophenol, leur procede de preparation et leur application comme herbicides
GB2024213B (en) * 1978-06-30 1982-09-08 Ici Ltd Dihalophenoxypropionic acids and their derivatives and their use as cotton desiccants

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Publication number Publication date
BR8300476A (pt) 1983-11-01
EP0088066B1 (en) 1985-04-03
AU1084883A (en) 1983-08-11
NO155132C (no) 1987-02-18
ZA83617B (en) 1983-12-28
ES8403093A1 (es) 1984-03-01
PT76173A (en) 1983-02-01
KR850001330B1 (ko) 1985-09-19
NO830320L (no) 1983-08-02
ES519346A0 (es) 1984-03-01
PH18317A (en) 1985-05-29
DE3360085D1 (en) 1985-05-09
US4416687A (en) 1983-11-22
JPS58134048A (ja) 1983-08-10
NO155132B (no) 1986-11-10
PT76173B (en) 1985-11-11
NZ203138A (en) 1986-03-14
AU554260B2 (en) 1986-08-14
EP0088066A1 (en) 1983-09-07

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