KR830006157A - 플루오로카본 비닐 에테르의 제조방법 및 생성플리머 - Google Patents

플루오로카본 비닐 에테르의 제조방법 및 생성플리머 Download PDF

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KR830006157A
KR830006157A KR1019810002077A KR810002077A KR830006157A KR 830006157 A KR830006157 A KR 830006157A KR 1019810002077 A KR1019810002077 A KR 1019810002077A KR 810002077 A KR810002077 A KR 810002077A KR 830006157 A KR830006157 A KR 830006157A
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integer
acid group
formula
group
acid
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KR1019810002077A
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KR840001981B1 (ko
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레이 에젤 바비
폴 카를 윌리암
어거스트 모드 윌리암
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리챠드 고든 워터맨
더 다우 케미칼 캄파니
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Publication of KR830006157A publication Critical patent/KR830006157A/ko
Priority to KR1019830005799A priority Critical patent/KR850000110B1/ko
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Publication of KR840001981B1 publication Critical patent/KR840001981B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/235—Saturated compounds containing more than one carboxyl group
    • C07C59/305—Saturated compounds containing more than one carboxyl group containing ether groups, groups, groups, or groups
    • C07C59/315—Saturated compounds containing more than one carboxyl group containing ether groups, groups, groups, or groups containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/15—Unsaturated ethers containing only non-aromatic carbon-to-carbon double bonds
    • C07C43/16—Vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14—Monomers containing only one unsaturated aliphatic radical

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

플루오로카본 비닐 에테르의 제조방법 및 생성 플리머
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (3)

  1. 다음 구조식(Ⅱ)의 화합물을 탈카복실화 하여 구조식(Ⅰ)의 화합물을 제조하는 방법.
    상기 구조식에서
    n은 1 또는 1이상의 정수;
    x'는 Cl 또는 Br;
    x는 F,C;,Br 또는 n〉1일 때는 이들의 혼합물을 나타내며;
    a는 0 또는 0 이상의 정수;
    b는 0 또는 0 이상의 정수;
    Y는 산그릅 또는 산그릅으로 쉽게 전환될 수 있는 산 유도체;
    Rf와 R'f는 각각 F,Cl, 퍼플루오로알킬 및 플루오로클로로알킬기 중에서 선택된 것이며;
    z는 F,Cl,Br,OH,NRR' 또는 OA;
    R 및 R'는 각각 수소, 탄소수 1이상의 알킬 및 아릴중에서 선택된 것이며;
    A는 알칼리금속, 4급질소 또는 R을 나타낸다.
  2. 적어도 한가지의 모노머는 다음 (A)그룹에서 선택한 것이며 또 다른 적어도 한가지의 모노머는 (B)그룹에서 선택한 것인, 적어도 두가지 다른 형태의 모노머들을 개시제 존재하에, 중합이 일어나기에 충분한 시간 및 온도에서 반응시켜 중합시키는 방법.
    (A) 다음 일반식으로 표시되는 화합물
    상기 구조식에서
    n은 1 또는 1 이상의 정수;
    X는 Cl,Br 또는 n〉1일때는 이들의 혼합물을 나타내며;
    Y는 산 그릅 또는 산그릅으로 쉽게 전환될 수 있는 산 유도체;
    Rf와 R'f는 각각 F,Cl, 퍼플루오로알킬 및 플루오로클로로알킬기 중에서 선택된 것이며;
    a는 0 또는 0 이상의 정수;
    b는 0 또는 0 이상의 정수;
    (B) 테트라플루오로에틸렌, 트리플루오로모노클로로에틸렌, 트리플루오로에틸렌, 비닐리맨 플루오라이드, 1,1-디플루오로-2,2-디클로로에틸렌, 1,1-디플루오로-2-클로로에틸렌, 헥사플루오로프로필렌, 1,1,1,3,3-펜타플루오로프로필렌, 옥타플루오로이소부틸렌, 에틸렌, 비닐클로라이드, 트리플루오로니트로소메탄, 퍼플루오로니트로소에탄 및 알킬비닐 에텔ㅡ.
  3. 다음 구조식의 펜던트(pendant)그룹을 가지는 폴리머 조성물
    상기 구조식에서
    n은 1또는 1이상의 정수;
    X는 Cl,Br 또는 n〉1일때는 이들의 혼합물을 나타내며;
    Y는 산 그릅 또는 산그릅으로 쉽게 전환될 수 있는 산 유도체;
    a는 0 또는 0 이상의 정수;
    b는 0 또는 0 이상의 정수;
    Rf와 R'f는 상기에서와 같다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019810002077A 1980-06-11 1981-06-10 플루오로카본 비닐 에테르의 제조방법 KR840001981B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019830005799A KR850000110B1 (ko) 1980-06-11 1983-12-07 플루오로카본 비닐에테르의 중합방법

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15853280A 1980-06-11 1980-06-11
US158532 1980-06-11

Related Child Applications (1)

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KR1019830005799A Division KR850000110B1 (ko) 1980-06-11 1983-12-07 플루오로카본 비닐에테르의 중합방법

Publications (2)

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KR830006157A true KR830006157A (ko) 1983-09-17
KR840001981B1 KR840001981B1 (ko) 1984-10-26

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KR1019810002077A KR840001981B1 (ko) 1980-06-11 1981-06-10 플루오로카본 비닐 에테르의 제조방법

Country Status (9)

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EP (1) EP0041737B1 (ko)
JP (2) JPS5728025A (ko)
KR (1) KR840001981B1 (ko)
AT (1) ATE9153T1 (ko)
AU (1) AU541096B2 (ko)
BR (1) BR8103714A (ko)
CA (1) CA1169439A (ko)
DE (1) DE3165764D1 (ko)
ZA (1) ZA813896B (ko)

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US4851161A (en) * 1981-07-02 1989-07-25 E. I. Du Pont De Nemours And Company β-substituted polyfluoropropionate salts and derivatives
US4474700A (en) * 1981-07-02 1984-10-02 E. I. Du Pont DeNemours and Company β-Substituted polyfluoropropionate salts and derivatives
US4576752A (en) * 1982-07-19 1986-03-18 E. I. Du Pont De Nemours And Company β-Substituted polyfluoroethyl compounds
US4766248A (en) * 1982-07-19 1988-08-23 E. I. Du Pont De Nemours And Company β-substituted polyfluoroethyl compounds
US4686300A (en) * 1983-03-07 1987-08-11 E. I. Du Pont De Nemours And Company Polyfluoro gamma-ketoesters and 5-hydroxy gamma lactone analogues thereof
US4513128A (en) * 1983-06-23 1985-04-23 E. I. Du Pont De Nemours And Company Fluorinated vinyl ether copolymers having low glass transition temperatures
US4675453A (en) * 1983-12-27 1987-06-23 E. I. Du Pont De Nemours And Company Process and intermediates for fluorinated vinyl ether monomer
US4595476A (en) * 1984-07-26 1986-06-17 E. I. Du Pont De Nemours And Company Ion exchange membranes pre-expanded with di- and poly ether-glycols
JPH0641494B2 (ja) * 1984-08-31 1994-06-01 旭化成工業株式会社 架橋可能な含フツ素共重合体
US5252193A (en) * 1991-11-04 1993-10-12 E. I. Du Pont De Nemours And Company Controlled roughening of reinforced cation exchange membrane
US6274677B1 (en) * 1997-03-31 2001-08-14 Daikin Industries Ltd. Process for the producing perfluorovinyl ethersulfonic acid derivatives and copolymer of the same
JP2003518139A (ja) * 1997-07-23 2003-06-03 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー オレフィン類の重合
US6326436B2 (en) 1998-08-21 2001-12-04 Dupont Dow Elastomers, L.L.C. Fluoroelastomer composition having excellent processability and low temperature properties
EP1109844B1 (en) 1998-08-21 2004-02-18 Dupont Dow Elastomers L.L.C. Fluoroelastomer composition having excellent processability and low temperature properties
JP3786838B2 (ja) * 1999-04-15 2006-06-14 有限会社 ミレーヌコーポレーション 含リン原子フッ素化陽イオン交換膜，その製造方法およびそれを用いたプロトン伝導型燃料電池
JP2004010744A (ja) * 2002-06-06 2004-01-15 Japan Atom Energy Res Inst 大きなイオン交換容量と優れた耐酸化性を有するフッ素系高分子共重合体及びその製造方法
AU2003241664A1 (en) * 2002-06-14 2004-02-02 Daikin Industries, Ltd. Method of purifying water-soluble fluorinated vinyl ether
DE60312515T2 (de) 2002-06-14 2007-10-04 Daikin Industries, Ltd. Verfahren zur herstellung fluorierter fluorsulfonylalkyl-vinyl-ether
US8658707B2 (en) 2009-03-24 2014-02-25 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expanded functional products obtained therefrom and reaction of the expanded products
US9139669B2 (en) * 2009-03-24 2015-09-22 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expandable functional products obtained therefrom and reaction of the expanded products
JP5375273B2 (ja) * 2009-03-31 2013-12-25 ダイキン工業株式会社 １，３−ジクロロ−１，２，３，３−テトラフルオロ酸化プロピレン及びその製造方法

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JPS604806B2 (ja) * 1975-10-28 1985-02-06 旭化成工業株式会社 パーフロロビニルカルボン酸の製造法
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Also Published As

Publication number Publication date
AU7160481A (en) 1981-12-17
ZA813896B (en) 1983-01-26
JPH0258281B2 (ko) 1990-12-07
AU541096B2 (en) 1984-12-13
DE3165764D1 (en) 1984-10-04
JPH0556338B2 (ko) 1993-08-19
ATE9153T1 (de) 1984-09-15
KR840001981B1 (ko) 1984-10-26
CA1169439A (en) 1984-06-19
BR8103714A (pt) 1982-03-02
EP0041737B1 (en) 1984-08-29
JPS5728025A (en) 1982-02-15
JPH02270842A (ja) 1990-11-05
EP0041737A1 (en) 1981-12-16

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