KR20230043173A - 다봉-분포 폴리에틸렌의 제조 방법 - Google Patents

다봉-분포 폴리에틸렌의 제조 방법 Download PDF

Info

Publication number
KR20230043173A
KR20230043173A KR1020237006342A KR20237006342A KR20230043173A KR 20230043173 A KR20230043173 A KR 20230043173A KR 1020237006342 A KR1020237006342 A KR 1020237006342A KR 20237006342 A KR20237006342 A KR 20237006342A KR 20230043173 A KR20230043173 A KR 20230043173A
Authority
KR
South Korea
Prior art keywords
group
alkyl
different
independently
alkoxy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
KR1020237006342A
Other languages
English (en)
Korean (ko)
Inventor
게오르기 키피아니
지르키 카우하넨
산티스 펠리체 데
마르자 무스토넨
마티아스 호프
칼린 시메오노프
킴모 하칼라
자르코 하씨넨
마리아 라니에리
에스코 사이코넨
티이나 해맬래이넨
스테판 폴해머
파스칼 카스트로
이르판 사이드
칼레 칼리오
Original Assignee
보레알리스 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 보레알리스 아게 filed Critical 보레알리스 아게
Publication of KR20230043173A publication Critical patent/KR20230043173A/ko
Pending legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020237006342A 2020-07-23 2021-07-23 다봉-분포 폴리에틸렌의 제조 방법 Pending KR20230043173A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20187383 2020-07-23
EP20187383.3 2020-07-23
PCT/EP2021/070757 WO2022018290A1 (en) 2020-07-23 2021-07-23 Process for the preparation of a multimodal polyethylene

Publications (1)

Publication Number Publication Date
KR20230043173A true KR20230043173A (ko) 2023-03-30

Family

ID=71948416

Family Applications (2)

Application Number Title Priority Date Filing Date
KR1020237006342A Pending KR20230043173A (ko) 2020-07-23 2021-07-23 다봉-분포 폴리에틸렌의 제조 방법
KR1020237006292A Ceased KR20230043168A (ko) 2020-07-23 2021-07-23 메탈로센 착물 및 이로부터 제조된 촉매

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020237006292A Ceased KR20230043168A (ko) 2020-07-23 2021-07-23 메탈로센 착물 및 이로부터 제조된 촉매

Country Status (7)

Country Link
US (2) US12595325B2 (enExample)
EP (2) EP4185621B1 (enExample)
JP (2) JP2023535704A (enExample)
KR (2) KR20230043173A (enExample)
CN (2) CN116194493B (enExample)
ES (1) ES3075765T3 (enExample)
WO (2) WO2022018290A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024143754A1 (ko) 2022-12-26 2024-07-04 주식회사 엘지에너지솔루션 배터리 모듈 및 이를 포함하는 배터리 팩 및 차량

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4185621B1 (en) * 2020-07-23 2026-06-03 Borealis GmbH Process for the preparation of a multimodal polyethylene
CN119095725A (zh) * 2022-04-06 2024-12-06 北欧化工公司 多层膜
CN119053447A (zh) * 2022-04-06 2024-11-29 北欧化工公司 多层膜
WO2023198600A1 (en) 2022-04-11 2023-10-19 Borealis Ag Copolymer
EP4703426A1 (en) 2024-08-27 2026-03-04 Borealis GmbH Method for controlling polymer material formation

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
FI96866C (fi) 1993-11-05 1996-09-10 Borealis As Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
IL129600A0 (en) * 1996-11-15 2000-02-29 Montell Technology Company Bv Heterocyclic metallocenes and polymerization catalysts
JP3624210B2 (ja) 1997-04-16 2005-03-02 独立行政法人理化学研究所 メタロセン錯体
KR20010030814A (ko) 1998-08-03 2001-04-16 야마자끼 히로시 메탈로센 착물의 제조방법
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
US6169051B1 (en) 1999-01-25 2001-01-02 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
SE0300195D0 (sv) 2003-01-28 2003-01-28 Borealis Tech Oy Coating composition, method of preparation thereofand substrate coated therewith
EP1598378A1 (en) * 2004-05-21 2005-11-23 Borealis Technology Oy Process for the preparation of bimodal polyethylene
US7169864B2 (en) 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
BRPI0611557B1 (pt) 2005-03-18 2017-03-28 Basell Polyolefine Gmbh compostos metalocenos bis-indenila em ponte com simetria c2, sistema catalítico dessa classe de compostos e processo de polimerização de a-olefinas com a referida classe de compostos
EP2130859A1 (en) 2008-06-02 2009-12-09 Borealis AG Polymer compositions having improved homogeneity and odour, a method for making them and pipes made thereof
EP2130862A1 (en) * 2008-06-02 2009-12-09 Borealis AG Polymer compositions and pressure-resistant pipes made thereof
KR20140007360A (ko) * 2010-12-22 2014-01-17 보레알리스 아게 가교된 메탈로센 촉매
US9309340B2 (en) 2011-03-30 2016-04-12 Japan Polyethylene Corporation Ethylene-based polymer, polyethylene-based resin composition and use thereof, catalyst component for olefin polymerization, olefin polymerization catalyst containing the component, and method for producing ethylene-based polymer by using the catalyst
JP5906893B2 (ja) * 2011-03-30 2016-04-20 日本ポリエチレン株式会社 オレフィン重合用触媒成分、該成分を含むオレフィン重合用触媒、該触媒を用いたオレフィン系重合体の製造方法、および該方法によって製造したオレフィン系重合体
WO2013007650A1 (en) * 2011-07-08 2013-01-17 Borealis Ag Catalysts
JP5776602B2 (ja) * 2012-03-29 2015-09-09 日本ポリエチレン株式会社 容器用ポリエチレン樹脂組成物及びそれよりなる成形体
ES2674576T3 (es) 2012-12-21 2018-07-02 Borealis Ag Catalizador
EP2907841A1 (en) * 2014-02-14 2015-08-19 Borealis AG Polypropylene composite
CN110483670B (zh) * 2014-03-20 2021-11-30 日本聚丙烯株式会社 茂金属配合物和生产烯烃聚合物的方法
GB2533770B (en) * 2014-12-22 2021-02-10 Norner Verdandi As Polyethylene for pipes
JP6617623B2 (ja) * 2015-03-25 2019-12-11 日本ポリエチレン株式会社 ポリエチレン系樹脂組成物
JP6844340B2 (ja) 2016-03-15 2021-03-17 日本ポリエチレン株式会社 メタロセン化合物、それを含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びにそのオレフィン重合用触媒を用いたオレフィン重合体の製造方法
JP6651938B2 (ja) 2016-03-28 2020-02-19 日本ポリエチレン株式会社 ポリエチレン及びその成形体
CN122234261A (zh) * 2016-10-05 2026-06-19 埃克森美孚化学专利公司 茂金属催化剂,催化剂体系和使用其的方法
KR102534541B1 (ko) * 2016-12-15 2023-05-18 보레알리스 아게 고온 용액 중합 공정으로 폴리에틸렌 공중합체를 제조하기 위한 촉매 시스템
WO2018151904A1 (en) * 2017-02-20 2018-08-23 Exxonmobil Chemical Patents Inc. Group 4 catalyst compounds and process for use thereof
ES2945665T3 (es) 2017-03-30 2023-07-05 Borealis Ag Catalizadores de metaloceno activados por aluminoxano
EP4185621B1 (en) * 2020-07-23 2026-06-03 Borealis GmbH Process for the preparation of a multimodal polyethylene
ES2982100T3 (es) 2021-06-24 2024-10-14 Borealis Ag Copolímero de polietileno para una capa de película
EP4359452A1 (en) 2021-06-24 2024-05-01 Borealis AG Process for producing polyethylene polymers
CN117858908A (zh) 2021-06-24 2024-04-09 博里利斯股份公司 具有窄粒径分布的烯烃的聚合工艺

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2024143754A1 (ko) 2022-12-26 2024-07-04 주식회사 엘지에너지솔루션 배터리 모듈 및 이를 포함하는 배터리 팩 및 차량

Also Published As

Publication number Publication date
JP2023535705A (ja) 2023-08-21
US12595325B2 (en) 2026-04-07
US20240002560A1 (en) 2024-01-04
CN116323687B (zh) 2026-07-10
CN116194493A (zh) 2023-05-30
CN116194493B (zh) 2025-04-22
WO2022018293A1 (en) 2022-01-27
EP4185621A1 (en) 2023-05-31
US12583955B2 (en) 2026-03-24
EP4185621B1 (en) 2026-06-03
EP4185622A1 (en) 2023-05-31
CN116323687A (zh) 2023-06-23
KR20230043168A (ko) 2023-03-30
JP2023535704A (ja) 2023-08-21
US20250171481A1 (en) 2025-05-29
ES3075765T3 (en) 2026-08-07
WO2022018290A1 (en) 2022-01-27

Similar Documents

Publication Publication Date Title
CN114127130B (zh) 催化剂体系的改进制备
JP5668253B2 (ja) メタロセン担持触媒組成物及びこれを利用したポリオレフィンの製造方法
US12595325B2 (en) Process for the preparation of a multimodal polyethylene
KR102107084B1 (ko) 혼성 담지 메탈로센 촉매의 제조방법, 상기 제조방법으로 제조된 혼성 담지 메탈로센 촉매, 및 이를 이용하는 폴리올레핀의 제조방법
JP6236155B2 (ja) メタロセン化合物、これを含む触媒組成物およびこれを用いるオレフィン系重合体の製造方法
EP3348585B1 (en) Supported hybrid metallocene catalyst and polyolefin preparation method using same
JP6272477B2 (ja) メタロセン化合物、これを含む触媒組成物およびこれを用いるオレフィン系重合体の製造方法
KR102499596B1 (ko) 프로필렌 폴리머를 제조하는 공정
JP2023535704A5 (enExample)
EP2625212A2 (en) Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
KR102219407B1 (ko) 올레핀 중합 촉매용 전이금속 화합물 및 이를 포함하는 올레핀 중합 촉매
EP3184556B1 (en) Metallocene-supported catalyst and method of preparing polyolefin using the same
KR20160112424A (ko) 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매
EP3330296B1 (en) Method for preparing supported metallocene catalyst
KR20220066744A (ko) 혼성 담지 촉매
CN105518033A (zh) 茂金属化合物及其制备方法
KR101953768B1 (ko) 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매
KR102879091B1 (ko) 폴리올레핀 중합용 촉매 및 이의 제조방법
KR102784732B1 (ko) 메탈로센 화합물 및 이를 포함하는 폴리올레핀 중합용 촉매
KR20190023926A (ko) 에틸렌 올리고머화용 전이금속 화합물을 포함하는 촉매 시스템 및 이를 이용한 선형 알파 올레핀의 제조방법
KR20220076377A (ko) 폴리올레핀의 제조 방법

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PN2301 Change of applicant

St.27 status event code: A-3-3-R10-R13-asn-PN2301

St.27 status event code: A-3-3-R10-R11-asn-PN2301

R11 Change to the name of applicant or owner or transfer of ownership requested

Free format text: ST27 STATUS EVENT CODE: A-3-3-R10-R11-ASN-PN2301 (AS PROVIDED BY THE NATIONAL OFFICE)

R13 Change to the name of applicant or owner recorded

Free format text: ST27 STATUS EVENT CODE: A-3-3-R10-R13-ASN-PN2301 (AS PROVIDED BY THE NATIONAL OFFICE)

D21 Rejection of application intended

Free format text: ST27 STATUS EVENT CODE: A-1-2-D10-D21-EXM-PE0902 (AS PROVIDED BY THE NATIONAL OFFICE)

PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

E13 Pre-grant limitation requested

Free format text: ST27 STATUS EVENT CODE: A-2-3-E10-E13-LIM-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11 Amendment of application requested

Free format text: ST27 STATUS EVENT CODE: A-2-2-P10-P11-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13 Application amended

Free format text: ST27 STATUS EVENT CODE: A-2-2-P10-P13-NAP-X000 (AS PROVIDED BY THE NATIONAL OFFICE)

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000