KR20190080972A - 할로겐화 환형 화합물의 합성 방법 - Google Patents
할로겐화 환형 화합물의 합성 방법 Download PDFInfo
- Publication number
- KR20190080972A KR20190080972A KR1020197018768A KR20197018768A KR20190080972A KR 20190080972 A KR20190080972 A KR 20190080972A KR 1020197018768 A KR1020197018768 A KR 1020197018768A KR 20197018768 A KR20197018768 A KR 20197018768A KR 20190080972 A KR20190080972 A KR 20190080972A
- Authority
- KR
- South Korea
- Prior art keywords
- formula
- compound
- reaction
- adduct
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/80—Acids; Esters in position 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/28—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
- C07D239/32—One oxygen, sulfur or nitrogen atom
- C07D239/34—One oxygen atom
- C07D239/36—One oxygen atom as doubly bound oxygen atom or as unsubstituted hydroxy radical
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/41—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having five-membered rings with two or more ring hetero atoms, at least one of which being nitrogen, e.g. tetrazole
- A61K31/415—1,2-Diazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/78—Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/79—Acids; Esters
- C07D213/803—Processes of preparation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
- C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
- C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
- C07D235/06—Benzimidazoles; Hydrogenated benzimidazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP08165547 | 2008-09-30 | ||
| EP08165547.4 | 2008-09-30 | ||
| PCT/EP2009/062462 WO2010037688A1 (en) | 2008-09-30 | 2009-09-25 | Process for the synthesis of halogenated cyclic compounds |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167031136A Division KR20160131129A (ko) | 2008-09-30 | 2009-09-25 | 할로겐화 환형 화합물의 합성 방법 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20190080972A true KR20190080972A (ko) | 2019-07-08 |
Family
ID=40351699
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020197018768A Ceased KR20190080972A (ko) | 2008-09-30 | 2009-09-25 | 할로겐화 환형 화합물의 합성 방법 |
| KR1020167031136A Ceased KR20160131129A (ko) | 2008-09-30 | 2009-09-25 | 할로겐화 환형 화합물의 합성 방법 |
| KR1020117009786A Ceased KR20110066201A (ko) | 2008-09-30 | 2009-09-25 | 할로겐화 환형 화합물의 합성 방법 |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167031136A Ceased KR20160131129A (ko) | 2008-09-30 | 2009-09-25 | 할로겐화 환형 화합물의 합성 방법 |
| KR1020117009786A Ceased KR20110066201A (ko) | 2008-09-30 | 2009-09-25 | 할로겐화 환형 화합물의 합성 방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8431710B2 (OSRAM) |
| EP (1) | EP2334645B1 (OSRAM) |
| JP (5) | JP6180705B2 (OSRAM) |
| KR (3) | KR20190080972A (OSRAM) |
| CN (2) | CN106083710B (OSRAM) |
| CA (1) | CA2735921C (OSRAM) |
| WO (1) | WO2010037688A1 (OSRAM) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101652539B1 (ko) | 2008-07-04 | 2016-08-30 | 솔베이(소시에떼아노님) | 알케논의 제조 방법 |
| KR20190080972A (ko) | 2008-09-30 | 2019-07-08 | 솔베이(소시에떼아노님) | 할로겐화 환형 화합물의 합성 방법 |
| GB0903749D0 (en) * | 2009-03-04 | 2009-04-15 | Syngenta Participations Ag | Chemical process |
| US8957254B2 (en) | 2009-07-06 | 2015-02-17 | Solvay Sa | Process for chemical synthesis from an alkenone made from a halogenated precursor |
| PL2451763T3 (pl) | 2009-07-06 | 2015-08-31 | Solvay | Sposób wytwarzania halogenowanych prekursorów alkenonów w obecności rozpuszczalnika |
| EP2662359A1 (en) | 2012-05-08 | 2013-11-13 | Solvay Sa | Ionic Liquids, Method for manufacturing thereof, and Electrochemical Devices Comprising the Same |
| US9365480B2 (en) * | 2012-08-22 | 2016-06-14 | Solvay Sa | Process for the manufacture of alkenones |
| US10038218B2 (en) | 2012-12-20 | 2018-07-31 | Solvay Sa | Salts of N-containing heterocyclic anions as components in electrolytes |
| CN105324371A (zh) * | 2013-06-20 | 2016-02-10 | 巴斯夫欧洲公司 | 由吡啶基肼制备吡啶基吡唑化合物及其衍生物的方法 |
| EP2987782A1 (en) | 2014-08-22 | 2016-02-24 | Solvay SA | Distillation process comprising at least two distillation steps to obtain purified halogenated carboxylic acid halide, and use of the purified halogenated carboxylic acid halide |
| JP2017533941A (ja) | 2014-11-17 | 2017-11-16 | ソルヴェイ(ソシエテ アノニム) | 精製ハロゲン化カルボン酸ハロゲン化物を得るための少なくとも2つの蒸留ステップを含む蒸留プロセス、および精製ハロゲン化カルボン酸ハロゲン化物の使用 |
| WO2016079122A1 (en) | 2014-11-17 | 2016-05-26 | Solvay Sa | A method for producing a chemical compound and apparatus therefor |
| EP3031791A1 (en) | 2014-12-10 | 2016-06-15 | Solvay SA | Halogenation process of 1,1-dihaloethene |
| EP3199522A1 (en) | 2016-02-01 | 2017-08-02 | Solvay SA | Aminothioate derivatives, production thereof and use |
| CN111372908A (zh) | 2017-09-04 | 2020-07-03 | 索尔维公司 | 用于制造二氟乙酰氯的方法和中间体 |
| JP6911143B2 (ja) | 2018-11-07 | 2021-07-28 | 福建永晶科技股▲ふん▼有限公司Fujian Yongjing Technology Co., Ltd | ピラゾール又はピリミジノンの新しい製造方法 |
| JP7489390B2 (ja) * | 2018-12-27 | 2024-05-23 | コルテバ アグリサイエンス エルエルシー | スルホンアミド除草剤プロセス中間生成物の調製 |
| JP2023512000A (ja) | 2020-01-31 | 2023-03-23 | ソルヴェイ(ソシエテ アノニム) | ハロアルキル置換ピリジン化合物の製造のプロセス |
| JP2021079146A (ja) * | 2021-02-22 | 2021-05-27 | 株式会社三洋物産 | 遊技機 |
| JP7315071B2 (ja) * | 2021-03-03 | 2023-07-26 | 株式会社三洋物産 | 遊技機 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0163280A1 (de) | 1984-05-30 | 1985-12-04 | BASF Aktiengesellschaft | Pyrimidylphosphorsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekämpfung von Schädlingen |
| US5569782A (en) | 1993-12-23 | 1996-10-29 | Solvay Fluor Und Derivate Gmbh | Process for preparing polyfluorochlorocarbonyl chlorides and perfluorocarbonyl chlorides with addition of chlorine |
| US5708174A (en) | 1992-03-12 | 1998-01-13 | Smithkline Beecham P.L.C. | Heterocyclic-esters or -amides used as 5-HT4 receptor antagonists |
| US20060128702A1 (en) | 2004-11-23 | 2006-06-15 | Manojit Pal | Heterocyclic and bicyclic compounds, compositions and methods |
| US7405328B2 (en) | 2003-06-06 | 2008-07-29 | Solvay Fluor Gmbh | Method for producing alkenone ethers |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| HU217652B (hu) * | 1991-03-07 | 2000-03-28 | E. I. Du Pont De Nemours And Co. | Egy piridin-szulfonamid-vegyület, sói, hidrátjai, komplexei, intermedierjei, előállításuk, valamint a vegyület alkalmazása herbicidként |
| US5235060A (en) * | 1991-07-11 | 1993-08-10 | E. I. Du Pont De Nemours And Company | Certain three component ionic substituted pyridine compounds as intermediates for preparation as herbicides |
| DE4128828A1 (de) | 1991-08-30 | 1993-03-04 | Basf Ag | Ammonium- oder harnstoffhaltige duengemittel und verfahren zu ihrer herstellung |
| JP3843152B2 (ja) * | 1995-08-08 | 2006-11-08 | 石原産業株式会社 | 4−アルコキシ−1,1,1−トリフルオロ−3−ブテン−2−オンの製造方法 |
| GB2305174A (en) * | 1995-09-15 | 1997-04-02 | Zeneca Ltd | Chemical process |
| GB9711114D0 (en) * | 1997-05-29 | 1997-07-23 | Merck Sharp & Dohme | Therapeutic agents |
| DE19821088A1 (de) | 1998-05-12 | 1999-11-18 | Basf Ag | Modifizierte Polykondensate der Asparaginsäure, Verfahren zu ihrer Herstellung und ihre Verwendung in Düngemitteln |
| AU2002235247A1 (en) | 2000-12-29 | 2002-07-16 | Honeywell International, Inc. | Halogenated-alpha,beta-unsaturated-beta-(substituted-amino) carboxylate esters |
| ES2318275T3 (es) | 2003-03-07 | 2009-05-01 | Syngenta Participations Ag | Procedimiento para la produccion de esteres del acido niocotinico sustituidos. |
| DE102004061593A1 (de) | 2004-12-21 | 2006-06-22 | Abbott Gmbh & Co. Kg | Substituierte N-heterocyclische Verbindungen und ihre therapeutische Verwendung |
| KR20080048502A (ko) | 2005-09-29 | 2008-06-02 | 머크 앤드 캄파니 인코포레이티드 | 멜라노코르틴-4 수용체 조절제로서의 아실화스피로피페리딘 유도체 |
| JP5112082B2 (ja) * | 2006-02-02 | 2013-01-09 | クミアイ化学工業株式会社 | ピリドン誘導体及び除草剤 |
| EP2422790A1 (en) * | 2007-02-09 | 2012-02-29 | Emory University | Paramyxovirus family inhibitors and methods of use thereof |
| EP1987717A1 (de) * | 2007-04-30 | 2008-11-05 | Bayer CropScience AG | Pyridoncarboxamide, diese enthaltende nutzpflanzenschützende Mittel und Verfahren zu ihrer Herstellung und deren Verwendung |
| EP2008996A1 (en) | 2007-06-27 | 2008-12-31 | Syngeta Participations AG | Process for the production of pyrazoles |
| JP2011526899A (ja) * | 2008-07-01 | 2011-10-20 | ダウ アグロサイエンシィズ エルエルシー | 2−トリフルオロメチル−5−(1−置換)アルキルピリジンの調製のための改善された方法 |
| KR101652539B1 (ko) | 2008-07-04 | 2016-08-30 | 솔베이(소시에떼아노님) | 알케논의 제조 방법 |
| EP2154167A1 (de) * | 2008-07-30 | 2010-02-17 | Bayer MaterialScience AG | Elektromechanischer Wandler mit einem Polymerelement auf Polyisocyanat-Basis |
| KR20190080972A (ko) * | 2008-09-30 | 2019-07-08 | 솔베이(소시에떼아노님) | 할로겐화 환형 화합물의 합성 방법 |
| WO2011003856A1 (en) | 2009-07-06 | 2011-01-13 | Solvay Sa | Process for the manufacture of halogenated precursors of alkenones under specific conditions |
| KR101782175B1 (ko) | 2009-07-06 | 2017-09-26 | 솔베이(소시에떼아노님) | 알케논의 제조 방법 |
| PL2451763T3 (pl) | 2009-07-06 | 2015-08-31 | Solvay | Sposób wytwarzania halogenowanych prekursorów alkenonów w obecności rozpuszczalnika |
| JP6194245B2 (ja) * | 2013-12-27 | 2017-09-06 | 株式会社Subaru | 信号機認識装置 |
-
2009
- 2009-09-25 KR KR1020197018768A patent/KR20190080972A/ko not_active Ceased
- 2009-09-25 CN CN201610380671.4A patent/CN106083710B/zh active Active
- 2009-09-25 JP JP2011529509A patent/JP6180705B2/ja active Active
- 2009-09-25 CA CA2735921A patent/CA2735921C/en not_active Expired - Fee Related
- 2009-09-25 KR KR1020167031136A patent/KR20160131129A/ko not_active Ceased
- 2009-09-25 KR KR1020117009786A patent/KR20110066201A/ko not_active Ceased
- 2009-09-25 CN CN2009801384364A patent/CN102164898A/zh active Pending
- 2009-09-25 US US13/120,505 patent/US8431710B2/en not_active Expired - Fee Related
- 2009-09-25 EP EP09783436.0A patent/EP2334645B1/en active Active
- 2009-09-25 WO PCT/EP2009/062462 patent/WO2010037688A1/en not_active Ceased
-
2013
- 2013-04-29 US US13/872,860 patent/US8981115B2/en not_active Expired - Fee Related
-
2015
- 2015-06-23 JP JP2015125708A patent/JP6511346B2/ja not_active Expired - Fee Related
-
2017
- 2017-11-24 JP JP2017225725A patent/JP6647268B2/ja active Active
-
2019
- 2019-10-10 JP JP2019186868A patent/JP2020023533A/ja active Pending
-
2021
- 2021-11-12 JP JP2021184880A patent/JP2022028792A/ja active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0163280A1 (de) | 1984-05-30 | 1985-12-04 | BASF Aktiengesellschaft | Pyrimidylphosphorsäureester, Verfahren zu ihrer Herstellung und ihre Verwendung zur Bekämpfung von Schädlingen |
| US5708174A (en) | 1992-03-12 | 1998-01-13 | Smithkline Beecham P.L.C. | Heterocyclic-esters or -amides used as 5-HT4 receptor antagonists |
| US5569782A (en) | 1993-12-23 | 1996-10-29 | Solvay Fluor Und Derivate Gmbh | Process for preparing polyfluorochlorocarbonyl chlorides and perfluorocarbonyl chlorides with addition of chlorine |
| US7405328B2 (en) | 2003-06-06 | 2008-07-29 | Solvay Fluor Gmbh | Method for producing alkenone ethers |
| US20060128702A1 (en) | 2004-11-23 | 2006-06-15 | Manojit Pal | Heterocyclic and bicyclic compounds, compositions and methods |
Non-Patent Citations (1)
| Title |
|---|
| Atherton and Fields, J. Chem. Soc. (C), 1968, p. 1507 - 1513 |
Also Published As
| Publication number | Publication date |
|---|---|
| US8981115B2 (en) | 2015-03-17 |
| CA2735921A1 (en) | 2010-04-08 |
| US8431710B2 (en) | 2013-04-30 |
| KR20110066201A (ko) | 2011-06-16 |
| JP6511346B2 (ja) | 2019-05-15 |
| US20130237710A1 (en) | 2013-09-12 |
| JP2015227339A (ja) | 2015-12-17 |
| EP2334645A1 (en) | 2011-06-22 |
| JP6647268B2 (ja) | 2020-02-14 |
| JP6180705B2 (ja) | 2017-08-16 |
| CN102164898A (zh) | 2011-08-24 |
| CN106083710A (zh) | 2016-11-09 |
| JP2018058869A (ja) | 2018-04-12 |
| JP2022028792A (ja) | 2022-02-16 |
| KR20160131129A (ko) | 2016-11-15 |
| WO2010037688A1 (en) | 2010-04-08 |
| CA2735921C (en) | 2017-03-21 |
| US20110178297A1 (en) | 2011-07-21 |
| CN106083710B (zh) | 2021-03-12 |
| EP2334645B1 (en) | 2019-11-06 |
| JP2020023533A (ja) | 2020-02-13 |
| JP2012504153A (ja) | 2012-02-16 |
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