KR20160132069A - 비대칭 막 및 관련 방법 - Google Patents
비대칭 막 및 관련 방법 Download PDFInfo
- Publication number
- KR20160132069A KR20160132069A KR1020167027936A KR20167027936A KR20160132069A KR 20160132069 A KR20160132069 A KR 20160132069A KR 1020167027936 A KR1020167027936 A KR 1020167027936A KR 20167027936 A KR20167027936 A KR 20167027936A KR 20160132069 A KR20160132069 A KR 20160132069A
- Authority
- KR
- South Korea
- Prior art keywords
- pmp
- skin
- microporous membrane
- resin
- asymmetric microporous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000012528 membrane Substances 0.000 title claims description 53
- 238000000034 method Methods 0.000 title claims description 46
- 239000011116 polymethylpentene Substances 0.000 claims abstract description 128
- 229920000306 polymethylpentene Polymers 0.000 claims abstract description 101
- 239000000758 substrate Substances 0.000 claims abstract description 62
- 239000012982 microporous membrane Substances 0.000 claims abstract description 49
- 229920000642 polymer Polymers 0.000 claims abstract description 45
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 38
- 239000004743 Polypropylene Substances 0.000 claims abstract description 34
- 229920001155 polypropylene Polymers 0.000 claims abstract description 34
- 239000004698 Polyethylene Substances 0.000 claims abstract description 33
- -1 polyethylene Polymers 0.000 claims abstract description 33
- 229920000573 polyethylene Polymers 0.000 claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 claims abstract description 18
- 229920005989 resin Polymers 0.000 claims description 61
- 239000011347 resin Substances 0.000 claims description 61
- 239000002243 precursor Substances 0.000 claims description 27
- 239000012510 hollow fiber Substances 0.000 claims description 23
- 239000011148 porous material Substances 0.000 claims description 18
- 238000000137 annealing Methods 0.000 claims description 11
- 238000001125 extrusion Methods 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims 3
- 239000011859 microparticle Substances 0.000 claims 2
- 238000005086 pumping Methods 0.000 claims 1
- 229920005597 polymer membrane Polymers 0.000 abstract description 4
- 230000008569 process Effects 0.000 description 19
- 239000000463 material Substances 0.000 description 12
- 239000003921 oil Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000010791 quenching Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229920005570 flexible polymer Polymers 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000002615 hemofiltration Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
- B01D69/087—Details relating to the spinning process
- B01D69/088—Co-extrusion; Co-spinning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/0025—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching
- B01D67/0027—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching by stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
- B01D69/107—Organic support material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1212—Coextruded layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1213—Laminated layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/26—Polyalkenes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/26—Polyalkenes
- B01D71/261—Polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/26—Polyalkenes
- B01D71/262—Polypropylene
-
- B29C47/0057—
-
- B29C47/065—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
- B29C48/0018—Combinations of extrusion moulding with other shaping operations combined with shaping by orienting, stretching or shrinking, e.g. film blowing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/02—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/60—Co-casting; Co-extrusion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C71/00—After-treatment of articles without altering their shape; Apparatus therefor
- B29C71/02—Thermal after-treatment
- B29C2071/022—Annealing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/04—Polymers of ethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/16—EPM, i.e. ethylene-propylene copolymers; EPDM, i.e. ethylene-propylene-diene copolymers; EPT, i.e. ethylene-propylene terpolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2009/00—Layered products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/755—Membranes, diaphragms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201461952180P | 2014-03-13 | 2014-03-13 | |
| US61/952,180 | 2014-03-13 | ||
| PCT/US2015/020173 WO2015138723A1 (en) | 2014-03-13 | 2015-03-12 | Asymmetric membranes and related methods |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20160132069A true KR20160132069A (ko) | 2016-11-16 |
Family
ID=54067919
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020167027936A Withdrawn KR20160132069A (ko) | 2014-03-13 | 2015-03-12 | 비대칭 막 및 관련 방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US10010835B2 (enExample) |
| EP (1) | EP3116633A4 (enExample) |
| JP (1) | JP2017516652A (enExample) |
| KR (1) | KR20160132069A (enExample) |
| CN (1) | CN106659983A (enExample) |
| BR (1) | BR112016021096A2 (enExample) |
| WO (1) | WO2015138723A1 (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105188893B (zh) * | 2013-04-26 | 2018-11-20 | 科廷科技大学 | 带通道的制品及其制造方法 |
| CN106659983A (zh) * | 2014-03-13 | 2017-05-10 | 3M创新有限公司 | 非对称膜和相关的方法 |
| JP2015186862A (ja) * | 2014-03-26 | 2015-10-29 | 三菱樹脂株式会社 | 気体透過性フィルム |
| WO2017104638A1 (ja) * | 2015-12-14 | 2017-06-22 | Dic株式会社 | 酒類の製造方法および酒類の脱気方法 |
| US20200139309A1 (en) | 2018-11-01 | 2020-05-07 | Entegris, Inc. | Porous polyethylene filter membrane with asymmetric pore structure, and related filters and methods |
| CN113226525A (zh) * | 2018-12-27 | 2021-08-06 | 3M创新有限公司 | 非对称中空纤维膜及其制备和使用方法 |
| EP3902623A4 (en) * | 2018-12-27 | 2022-09-21 | 3M Innovative Properties Company | HOLLOW FIBER MEMBRANE WITH NUCLATING AGENT AND METHOD OF MAKING AND USE THEREOF |
| CN113398779B (zh) * | 2021-06-17 | 2022-09-13 | 杭州格鸿新材料科技有限公司 | 一种不对称聚4-甲基-1-戊烯中空纤维的制备方法 |
| CN114634640B (zh) * | 2022-03-08 | 2023-11-03 | 宁夏科为企业管理合伙企业(有限合伙) | 一种聚4-甲基-1-戊烯多孔薄膜的制备方法 |
| TW202415444A (zh) * | 2022-08-26 | 2024-04-16 | 日商東麗股份有限公司 | 分離膜及其製造方法 |
| JPWO2024048359A1 (enExample) * | 2022-08-30 | 2024-03-07 | ||
| JP2025529351A (ja) | 2022-09-09 | 2025-09-04 | ソルベンタム インテレクチュアル プロパティズ カンパニー | 非対称中空繊維膜 |
| CN116731376A (zh) * | 2023-05-10 | 2023-09-12 | 暨南大学 | 一种非对称纳米孔道膜的制备及其在氧合方面的应用 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57209608A (en) * | 1981-06-22 | 1982-12-23 | Ube Ind Ltd | Preparation of composite polyimide separation film |
| US4415608A (en) * | 1982-01-15 | 1983-11-15 | Uop Inc. | Continuous production of polymethylpentene membranes |
| JPS59196706A (ja) * | 1983-04-22 | 1984-11-08 | Dainippon Ink & Chem Inc | 不均質膜およびその製造方法 |
| US4874399A (en) * | 1988-01-25 | 1989-10-17 | Minnesota Mining And Manufacturing Company | Electret filter made of fibers containing polypropylene and poly(4-methyl-1-pentene) |
| US4931181A (en) * | 1989-06-02 | 1990-06-05 | Membrane Technology & Research, Inc. | Composite membranes for fluid separations |
| JP2942867B2 (ja) * | 1990-04-16 | 1999-08-30 | 三菱レイヨン株式会社 | 多層複合膜 |
| JPH05137980A (ja) * | 1991-11-18 | 1993-06-01 | Nitto Denko Corp | 有機溶剤蒸気分離膜 |
| JPH07116483A (ja) * | 1993-10-26 | 1995-05-09 | Dainippon Ink & Chem Inc | 中空糸複合膜の製造方法 |
| JPH07155568A (ja) * | 1993-12-08 | 1995-06-20 | Kawamura Inst Of Chem Res | 内表面非多孔層型中空糸不均質膜の製造方法 |
| CA2289494C (en) * | 1997-04-30 | 2006-08-01 | Mitsubishi Rayon Co., Ltd. | Hollow fiber membrane for the degassing of inks, ink degassing method, ink degassing apparatus, method for the fabrication of an ink cartridge, and ink |
| JPH10298470A (ja) * | 1997-04-30 | 1998-11-10 | Mitsubishi Rayon Co Ltd | インクの脱気方法及びインク脱気装置 |
| JP4139456B2 (ja) * | 1997-10-02 | 2008-08-27 | 三菱レイヨン株式会社 | 脱気膜 |
| US7470488B2 (en) * | 2000-08-12 | 2008-12-30 | Lg Chemical Co., Ltd. | Multi-component composite film method for preparing the same |
| US7300571B2 (en) * | 2003-02-13 | 2007-11-27 | Zenon Technology Partnership | Supported biofilm apparatus |
| CN101223031B (zh) * | 2005-07-15 | 2014-01-08 | 东丽电池隔膜株式会社 | 聚烯烃多层微多孔膜及电池用隔离件 |
| EP2461974B1 (en) * | 2009-06-19 | 2017-01-11 | Toray Battery Separator Film Co., Ltd. | Multi-layer microporous film |
| EP2829643B1 (en) * | 2012-03-23 | 2019-07-24 | Toray Industries, Inc. | Polymethylpentene conjugate fiber and fiber structure comprising same |
| CN106659983A (zh) * | 2014-03-13 | 2017-05-10 | 3M创新有限公司 | 非对称膜和相关的方法 |
-
2015
- 2015-03-12 CN CN201580023477.4A patent/CN106659983A/zh active Pending
- 2015-03-12 US US14/645,972 patent/US10010835B2/en active Active
- 2015-03-12 JP JP2016575618A patent/JP2017516652A/ja active Pending
- 2015-03-12 KR KR1020167027936A patent/KR20160132069A/ko not_active Withdrawn
- 2015-03-12 BR BR112016021096A patent/BR112016021096A2/pt not_active Application Discontinuation
- 2015-03-12 EP EP15760640.1A patent/EP3116633A4/en not_active Withdrawn
- 2015-03-12 WO PCT/US2015/020173 patent/WO2015138723A1/en not_active Ceased
-
2018
- 2018-06-01 US US15/995,336 patent/US20180272290A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO2015138723A1 (en) | 2015-09-17 |
| CN106659983A (zh) | 2017-05-10 |
| BR112016021096A2 (pt) | 2017-08-15 |
| US10010835B2 (en) | 2018-07-03 |
| JP2017516652A (ja) | 2017-06-22 |
| US20180272290A1 (en) | 2018-09-27 |
| EP3116633A1 (en) | 2017-01-18 |
| EP3116633A4 (en) | 2017-11-22 |
| US20150258500A1 (en) | 2015-09-17 |
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