KR20150003389A - 폴리우레탄 (pu)-기재 시스템에서 가수분해 내성을 개선하는 방법 - Google Patents

폴리우레탄 (pu)-기재 시스템에서 가수분해 내성을 개선하는 방법 Download PDF

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Publication number
KR20150003389A
KR20150003389A KR20147033516A KR20147033516A KR20150003389A KR 20150003389 A KR20150003389 A KR 20150003389A KR 20147033516 A KR20147033516 A KR 20147033516A KR 20147033516 A KR20147033516 A KR 20147033516A KR 20150003389 A KR20150003389 A KR 20150003389A
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KR
South Korea
Prior art keywords
methyl
alkyl
independently
formula
carbodiimide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR20147033516A
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English (en)
Korean (ko)
Inventor
빌헬름 라우퍼
아르민 엑커르트
우베 하스
우베 뷔르츠
Original Assignee
라인 케미 라이나우 게엠베하
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 라인 케미 라이나우 게엠베하 filed Critical 라인 케미 라이나우 게엠베하
Publication of KR20150003389A publication Critical patent/KR20150003389A/ko
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/02—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only
    • C08G18/025—Polymeric products of isocyanates or isothiocyanates of isocyanates or isothiocyanates only the polymeric products containing carbodiimide groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/24—Catalysts containing metal compounds of tin
    • C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
    • C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/775—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/776—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
KR20147033516A 2012-05-03 2013-03-22 폴리우레탄 (pu)-기재 시스템에서 가수분해 내성을 개선하는 방법 Ceased KR20150003389A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20120166641 EP2660259A1 (de) 2012-05-03 2012-05-03 Neue Carbodiimid-haltige Zusammensetzungen, ein Verfahren zu deren Herstellung und deren Verwendung
EP12166641.6 2012-05-03
PCT/EP2013/056155 WO2013164135A1 (de) 2012-05-03 2013-03-22 Verfahren zur verbesserung der hydrolysestabilität in polyurethan(pu)-basierten systemen

Publications (1)

Publication Number Publication Date
KR20150003389A true KR20150003389A (ko) 2015-01-08

Family

ID=47915276

Family Applications (2)

Application Number Title Priority Date Filing Date
KR20147033516A Ceased KR20150003389A (ko) 2012-05-03 2013-03-22 폴리우레탄 (pu)-기재 시스템에서 가수분해 내성을 개선하는 방법
KR1020147033515A Expired - Fee Related KR101993498B1 (ko) 2012-05-03 2013-03-22 사슬-연장된 폴리우레탄 (pu)-기재 시스템에서 포트 수명을 제어 (연장)하는 방법

Family Applications After (1)

Application Number Title Priority Date Filing Date
KR1020147033515A Expired - Fee Related KR101993498B1 (ko) 2012-05-03 2013-03-22 사슬-연장된 폴리우레탄 (pu)-기재 시스템에서 포트 수명을 제어 (연장)하는 방법

Country Status (12)

Country Link
US (2) US20150133623A1 (https=)
EP (3) EP2660259A1 (https=)
JP (2) JP2015516491A (https=)
KR (2) KR20150003389A (https=)
CN (3) CN104364284B (https=)
BR (2) BR112014027440A2 (https=)
CA (2) CA2872090A1 (https=)
ES (1) ES2588830T3 (https=)
IN (1) IN2014DN09041A (https=)
MX (1) MX368470B (https=)
RU (2) RU2014148484A (https=)
WO (2) WO2013164135A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015027977A2 (pt) 2013-05-07 2017-07-25 Rhein Chemie Rheinau Gmbh método para a produção de formulações de óleo, formulações de óleo, e uso das formulações de óleo
CN109642009B (zh) * 2016-08-09 2021-12-10 科思创德国股份有限公司 硅烷官能的聚合聚氨酯
US12054576B2 (en) 2019-03-07 2024-08-06 Basf Se Adhesives based on carbodimide chemistry
WO2023104708A1 (en) * 2021-12-08 2023-06-15 Covestro Deutschland Ag Polyurethane elastomer with improved hydrolysis resistance

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL273087A (https=) * 1960-12-31
US3522303A (en) 1964-08-12 1970-07-28 Upjohn Co Phosphorous compounds
US3406197A (en) * 1966-06-08 1968-10-15 Upjohn Co Transition metal carbonyl catalysts for converting organic isocyanates to carbodiimides
US3406198A (en) * 1966-08-05 1968-10-15 Upjohn Co Triarylarsines as catalysts for converting isocyanates to carbodiimides
DE2504400A1 (de) 1975-02-01 1976-08-05 Bayer Ag Lagerstabile, carbodiimidgruppen enthaltende polyisocyanate
DE2537685C2 (de) 1975-08-23 1989-04-06 Bayer Ag, 5090 Leverkusen Verfahren zur teilweisen Carbodiimidisierung der Isocyanatgruppen von organischen Polyisocyanaten
DE2941253A1 (de) 1979-10-11 1981-04-23 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von additionsverbindungen aus carbodiimiden und hydroxylgruppen aufweisenden verbindungen
US4306052A (en) * 1980-09-25 1981-12-15 The Upjohn Company Thermoplastic polyester polyurethanes
DE4318979A1 (de) * 1993-06-08 1994-12-15 Basf Ag Carbodiimide und/oder oligomere Polycarbodiimide auf Basis von 1,3-Bis-(1-methyl-1-isocyanato-ethyl)-benzol, ein Verfahren zu ihrer Herstellung und ihre Verwendung als Hydrolysestabilisator
US5574083A (en) * 1993-06-11 1996-11-12 Rohm And Haas Company Aromatic polycarbodiimide crosslinkers
JP3110633B2 (ja) 1994-02-02 2000-11-20 東レ株式会社 ポリエステル組成物、モノフィラメントおよび工業用織物
JP3733170B2 (ja) * 1996-04-02 2006-01-11 日清紡績株式会社 ポリウレタン樹脂
ATE293647T1 (de) * 1996-05-21 2005-05-15 Simula Inc Extrudierbares, thermoplastisches, elastomeres, harnstoff-kettenverlängertes polyurethan
US6258917B1 (en) * 1996-05-21 2001-07-10 Simula, Inc. Extrudable thermoplastic elastomeric urea-extended polyurethane
JP3422642B2 (ja) * 1996-12-24 2003-06-30 日清紡績株式会社 エステル基を有する樹脂の微生物による劣化に対する耐性を向上する薬剤及び同方法
JP3630527B2 (ja) 1997-05-16 2005-03-16 日清紡績株式会社 カルボジイミド系架橋剤及びその製造方法並びにコーティング材
DE19809634A1 (de) * 1998-03-06 1999-09-09 Basf Ag Carbodiimide und Verfahren zu deren Herstellung
DE19821666A1 (de) * 1998-05-14 1999-11-25 Basf Ag Carbodiimide auf der Basis von 1,3-Bis-(1-methyl-1-isocyanatoethyl)-benzol
JP2008004691A (ja) * 2006-06-21 2008-01-10 Toppan Printing Co Ltd 太陽電池裏面封止用シート
CN101679578B (zh) * 2007-04-11 2012-06-27 陶氏环球技术有限责任公司 具有增强的耐水解性的聚氨酯弹性体
CN101457018A (zh) * 2007-12-14 2009-06-17 烟台万华新材料科技有限公司 具有水解稳定性的热塑性聚氨酯弹性体及其制备方法

Also Published As

Publication number Publication date
JP2015516003A (ja) 2015-06-04
RU2014148485A (ru) 2016-06-27
BR112014027441A2 (pt) 2017-06-27
MX368470B (es) 2019-10-03
US9321879B2 (en) 2016-04-26
US20150126688A1 (en) 2015-05-07
CA2871712A1 (en) 2013-11-07
MX2014013359A (es) 2015-05-15
BR112014027440A2 (pt) 2017-06-27
ES2588830T3 (es) 2016-11-07
US20150133623A1 (en) 2015-05-14
KR101993498B1 (ko) 2019-06-26
CN104350077A (zh) 2015-02-11
IN2014DN09041A (https=) 2015-05-22
CA2872090A1 (en) 2013-11-07
JP2015516491A (ja) 2015-06-11
WO2013164134A1 (de) 2013-11-07
KR20150003388A (ko) 2015-01-08
EP2660259A1 (de) 2013-11-06
EP2844681A1 (de) 2015-03-11
RU2014148484A (ru) 2016-06-20
CN108299622A (zh) 2018-07-20
EP2844683A1 (de) 2015-03-11
CN104364284A (zh) 2015-02-18
WO2013164135A1 (de) 2013-11-07
CN104364284B (zh) 2016-06-08
EP2844681B1 (de) 2016-07-13

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