KR20150001727A - LixSy를 포함하는 전극을 갖는 에너지 저장 시스템 - Google Patents
LixSy를 포함하는 전극을 갖는 에너지 저장 시스템 Download PDFInfo
- Publication number
- KR20150001727A KR20150001727A KR1020147025039A KR20147025039A KR20150001727A KR 20150001727 A KR20150001727 A KR 20150001727A KR 1020147025039 A KR1020147025039 A KR 1020147025039A KR 20147025039 A KR20147025039 A KR 20147025039A KR 20150001727 A KR20150001727 A KR 20150001727A
- Authority
- KR
- South Korea
- Prior art keywords
- electrode
- current collector
- electrode current
- separator
- energy storage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004146 energy storage Methods 0.000 title claims abstract description 30
- 239000012530 fluid Substances 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims description 27
- 229910052744 lithium Inorganic materials 0.000 claims description 26
- 239000012071 phase Substances 0.000 claims description 26
- 229910052717 sulfur Inorganic materials 0.000 claims description 24
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 23
- 239000011593 sulfur Substances 0.000 claims description 23
- 239000007787 solid Substances 0.000 claims description 16
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 238000009830 intercalation Methods 0.000 claims description 7
- 230000002687 intercalation Effects 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- 239000011244 liquid electrolyte Substances 0.000 claims description 5
- 229910013716 LiNi Inorganic materials 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 229910013733 LiCo Inorganic materials 0.000 claims description 3
- 229910012851 LiCoO 2 Inorganic materials 0.000 claims description 3
- 229910010707 LiFePO 4 Inorganic materials 0.000 claims description 3
- 229910015118 LiMO Inorganic materials 0.000 claims description 3
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 claims description 3
- 229910021389 graphene Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229910021384 soft carbon Inorganic materials 0.000 claims description 3
- 239000007790 solid phase Substances 0.000 claims description 3
- 229910020599 Co 3 O 4 Inorganic materials 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002099 LiNi0.5Mn1.5O4 Inorganic materials 0.000 claims 2
- 239000013626 chemical specie Substances 0.000 claims 1
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 abstract description 3
- 229910018091 Li 2 S Inorganic materials 0.000 description 22
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 9
- 239000011149 active material Substances 0.000 description 8
- 150000008117 polysulfides Polymers 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000005077 polysulfide Substances 0.000 description 6
- 229920001021 polysulfide Polymers 0.000 description 6
- 230000001351 cycling effect Effects 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000006193 liquid solution Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 3
- 229910003003 Li-S Inorganic materials 0.000 description 3
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000002482 conductive additive Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910003473 lithium bis(trifluoromethanesulfonyl)imide Inorganic materials 0.000 description 2
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 229910007352 Li2Sy Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- QNIHZKIMYOTOTA-UHFFFAOYSA-N fluoroform;lithium Chemical compound [Li].FC(F)F.FC(F)F QNIHZKIMYOTOTA-UHFFFAOYSA-N 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- 239000003115 supporting electrolyte Substances 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/20—Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/581—Chalcogenides or intercalation compounds thereof
- H01M4/5815—Sulfides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/432,166 | 2012-03-28 | ||
| US13/432,166 US9406960B2 (en) | 2012-03-28 | 2012-03-28 | Energy storage systems having an electrode comprising LixSy |
| PCT/US2012/058402 WO2013147930A1 (en) | 2012-03-28 | 2012-10-02 | ENERGY STORAGE SYSTEMS HAVING AN ELECTRODE COMPRISING LixSy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20150001727A true KR20150001727A (ko) | 2015-01-06 |
Family
ID=49235446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020147025039A Withdrawn KR20150001727A (ko) | 2012-03-28 | 2012-10-02 | LixSy를 포함하는 전극을 갖는 에너지 저장 시스템 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9406960B2 (enExample) |
| EP (1) | EP2831938A4 (enExample) |
| KR (1) | KR20150001727A (enExample) |
| CN (1) | CN104170124A (enExample) |
| AU (1) | AU2012375202A1 (enExample) |
| BR (1) | BR112014020779A2 (enExample) |
| CA (1) | CA2863827A1 (enExample) |
| IN (1) | IN2014DN06606A (enExample) |
| WO (1) | WO2013147930A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109037643A (zh) * | 2018-08-07 | 2018-12-18 | 内蒙古三信实业有限公司 | 一种高容量高压实石墨复合材料及其制备方法 |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10230124B2 (en) * | 2013-12-03 | 2019-03-12 | Massachusetts Institute Of Technology | Gravity induced flow cell |
| US11050076B1 (en) | 2015-01-22 | 2021-06-29 | Battelle Memorial Institute | Flow cell systems, flow cell batteries, and hydrogen production processes |
| US11043686B2 (en) | 2015-01-22 | 2021-06-22 | Battelle Memorial Institute | Systems and methods of long-duration energy storage and regeneration of energy-bearing redox pairs |
| US11050078B2 (en) | 2015-01-22 | 2021-06-29 | Battelle Memorial Institute | Systems and methods of decoupled hydrogen generation using energy-bearing redox pairs |
| US11456454B2 (en) * | 2018-10-24 | 2022-09-27 | Samsung Electronics Co., Ltd. | Mixed conductor, electrochemical device including the same, and method of preparing the mixed conductor |
| KR102744305B1 (ko) * | 2018-12-18 | 2024-12-18 | 삼성전자주식회사 | 혼합전도체, 이를 포함하는 전기화학소자 및 그 제조방법 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4469761A (en) * | 1980-11-26 | 1984-09-04 | Diamond Shamrock Corporation | Rechargeable lithium/sulfur ammoniate battery |
| US6210832B1 (en) | 1998-09-01 | 2001-04-03 | Polyplus Battery Company, Inc. | Mixed ionic electronic conductor coatings for redox electrodes |
| KR100522694B1 (ko) | 2003-08-23 | 2005-10-19 | 삼성에스디아이 주식회사 | 리튬 설퍼전지 |
| US20060194115A1 (en) | 2005-02-14 | 2006-08-31 | Polyplus Battery Company | Intercalation anode protection for cells with dissolved lithium polysulfides |
| EP1867000B1 (en) | 2005-03-22 | 2011-10-05 | Oxis Energy Limited | Lithium sulphide battery and method of producing the same |
| KR100709218B1 (ko) | 2005-12-30 | 2007-04-18 | 삼성에스디아이 주식회사 | 리튬 이차 전지 |
| EP2684734B1 (en) | 2008-06-12 | 2017-04-12 | Massachusetts Institute Of Technology | High energy density redox flow device |
| US9786944B2 (en) * | 2008-06-12 | 2017-10-10 | Massachusetts Institute Of Technology | High energy density redox flow device |
| US8460814B2 (en) * | 2009-07-29 | 2013-06-11 | The Invention Science Fund I, Llc | Fluid-surfaced electrode |
| US8758914B2 (en) * | 2010-06-18 | 2014-06-24 | Polyplus Battery Company | Li-Ion/polysulfide flow battery |
| KR101826990B1 (ko) * | 2011-06-07 | 2018-02-07 | 현대자동차주식회사 | 폴리설파이드 구속층을 갖는 리튬황 전지 |
| CN102315473A (zh) | 2011-06-28 | 2012-01-11 | 北京好风光储能技术有限公司 | 一种锂离子液流电池 |
| CN102324550A (zh) * | 2011-08-19 | 2012-01-18 | 李桂云 | 半液流锂硫电池 |
-
2012
- 2012-03-28 US US13/432,166 patent/US9406960B2/en not_active Expired - Fee Related
- 2012-10-02 CN CN201280071088.5A patent/CN104170124A/zh active Pending
- 2012-10-02 WO PCT/US2012/058402 patent/WO2013147930A1/en not_active Ceased
- 2012-10-02 IN IN6606DEN2014 patent/IN2014DN06606A/en unknown
- 2012-10-02 KR KR1020147025039A patent/KR20150001727A/ko not_active Withdrawn
- 2012-10-02 BR BR112014020779A patent/BR112014020779A2/pt not_active IP Right Cessation
- 2012-10-02 EP EP12872738.5A patent/EP2831938A4/en not_active Withdrawn
- 2012-10-02 AU AU2012375202A patent/AU2012375202A1/en not_active Abandoned
- 2012-10-02 CA CA2863827A patent/CA2863827A1/en not_active Abandoned
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109037643A (zh) * | 2018-08-07 | 2018-12-18 | 内蒙古三信实业有限公司 | 一种高容量高压实石墨复合材料及其制备方法 |
| CN109037643B (zh) * | 2018-08-07 | 2020-10-20 | 内蒙古三信实业有限公司 | 一种高容量高压实石墨复合材料及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2012375202A1 (en) | 2014-08-28 |
| CA2863827A1 (en) | 2013-10-03 |
| US9406960B2 (en) | 2016-08-02 |
| EP2831938A1 (en) | 2015-02-04 |
| IN2014DN06606A (enExample) | 2015-05-22 |
| EP2831938A4 (en) | 2015-11-11 |
| US20130260204A1 (en) | 2013-10-03 |
| WO2013147930A1 (en) | 2013-10-03 |
| CN104170124A (zh) | 2014-11-26 |
| BR112014020779A2 (pt) | 2018-05-08 |
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