KR20130130775A - 특정 에스터계 용매를 함유하는 배터리 전해질 용액, 및 상기 전해질 용액을 함유하는 배터리 - Google Patents
특정 에스터계 용매를 함유하는 배터리 전해질 용액, 및 상기 전해질 용액을 함유하는 배터리 Download PDFInfo
- Publication number
- KR20130130775A KR20130130775A KR1020137018140A KR20137018140A KR20130130775A KR 20130130775 A KR20130130775 A KR 20130130775A KR 1020137018140 A KR1020137018140 A KR 1020137018140A KR 20137018140 A KR20137018140 A KR 20137018140A KR 20130130775 A KR20130130775 A KR 20130130775A
- Authority
- KR
- South Korea
- Prior art keywords
- acetate
- battery
- electrolyte solution
- methylethyl
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000008151 electrolyte solution Substances 0.000 title claims abstract description 138
- 239000000243 solution Substances 0.000 title claims description 63
- 239000003759 ester based solvent Substances 0.000 title abstract description 7
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical class O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 claims abstract description 70
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims abstract description 50
- 239000002904 solvent Substances 0.000 claims abstract description 50
- 229910003002 lithium salt Inorganic materials 0.000 claims abstract description 32
- 159000000002 lithium salts Chemical class 0.000 claims abstract description 32
- BJWMSGRKJIOCNR-UHFFFAOYSA-N 4-ethenyl-1,3-dioxolan-2-one Chemical class C=CC1COC(=O)O1 BJWMSGRKJIOCNR-UHFFFAOYSA-N 0.000 claims abstract description 16
- -1 ether ester compound Chemical class 0.000 claims description 82
- 239000000203 mixture Substances 0.000 claims description 69
- 125000004432 carbon atom Chemical group C* 0.000 claims description 54
- 229910013870 LiPF 6 Inorganic materials 0.000 claims description 52
- XLLIQLLCWZCATF-UHFFFAOYSA-N 2-methoxyethyl acetate Chemical compound COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 claims description 36
- 229910052744 lithium Inorganic materials 0.000 claims description 33
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 30
- 125000000217 alkyl group Chemical group 0.000 claims description 24
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 18
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 239000000654 additive Substances 0.000 claims description 14
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 11
- 125000002947 alkylene group Chemical group 0.000 claims description 11
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 claims description 11
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical group [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 10
- 229910001416 lithium ion Inorganic materials 0.000 claims description 10
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 claims description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 9
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 9
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 8
- SHZIWNPUGXLXDT-UHFFFAOYSA-N ethyl hexanoate Chemical compound CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 claims description 8
- AOGQPLXWSUTHQB-UHFFFAOYSA-N hexyl acetate Chemical compound CCCCCCOC(C)=O AOGQPLXWSUTHQB-UHFFFAOYSA-N 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 239000003112 inhibitor Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 6
- PPXUHEORWJQRHJ-UHFFFAOYSA-N ethyl isovalerate Chemical compound CCOC(=O)CC(C)C PPXUHEORWJQRHJ-UHFFFAOYSA-N 0.000 claims description 6
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 claims description 6
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 6
- NUKZAGXMHTUAFE-UHFFFAOYSA-N methyl hexanoate Chemical compound CCCCCC(=O)OC NUKZAGXMHTUAFE-UHFFFAOYSA-N 0.000 claims description 6
- LIPRQQHINVWJCH-UHFFFAOYSA-N 1-ethoxypropan-2-yl acetate Chemical compound CCOCC(C)OC(C)=O LIPRQQHINVWJCH-UHFFFAOYSA-N 0.000 claims description 4
- KBGLIBWPBYLNNK-UHFFFAOYSA-N 2-ethoxypropyl acetate Chemical compound CCOC(C)COC(C)=O KBGLIBWPBYLNNK-UHFFFAOYSA-N 0.000 claims description 4
- BTZVKSVLFLRBRE-UHFFFAOYSA-N 2-methoxypropyl acetate Chemical compound COC(C)COC(C)=O BTZVKSVLFLRBRE-UHFFFAOYSA-N 0.000 claims description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 4
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims description 4
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 claims description 3
- ICMAFTSLXCXHRK-UHFFFAOYSA-N Ethyl pentanoate Chemical compound CCCCC(=O)OCC ICMAFTSLXCXHRK-UHFFFAOYSA-N 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910013063 LiBF 4 Inorganic materials 0.000 claims description 3
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 claims description 3
- 125000003545 alkoxy group Chemical group 0.000 claims description 3
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 claims description 3
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 claims description 3
- 230000008021 deposition Effects 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 229940017219 methyl propionate Drugs 0.000 claims description 3
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- HUAZGNHGCJGYNP-UHFFFAOYSA-N propyl butyrate Chemical compound CCCOC(=O)CCC HUAZGNHGCJGYNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000007614 solvation Methods 0.000 claims description 3
- 239000003381 stabilizer Substances 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- ODDDCGGSPAPBOS-UHFFFAOYSA-N 1-ethoxypropan-2-yl propanoate Chemical compound CCOCC(C)OC(=O)CC ODDDCGGSPAPBOS-UHFFFAOYSA-N 0.000 claims description 2
- DOVZUKKPYKRVIK-UHFFFAOYSA-N 1-methoxypropan-2-yl propanoate Chemical compound CCC(=O)OC(C)COC DOVZUKKPYKRVIK-UHFFFAOYSA-N 0.000 claims description 2
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 claims description 2
- UHOPWFKONJYLCF-UHFFFAOYSA-N 2-(2-sulfanylethyl)isoindole-1,3-dione Chemical compound C1=CC=C2C(=O)N(CCS)C(=O)C2=C1 UHOPWFKONJYLCF-UHFFFAOYSA-N 0.000 claims description 2
- ZSDQQJHSRVEGTJ-UHFFFAOYSA-N 2-(6-amino-1h-indol-3-yl)acetonitrile Chemical compound NC1=CC=C2C(CC#N)=CNC2=C1 ZSDQQJHSRVEGTJ-UHFFFAOYSA-N 0.000 claims description 2
- BYVKCQBOHJQWIO-UHFFFAOYSA-N 2-ethoxyethyl propanoate Chemical compound CCOCCOC(=O)CC BYVKCQBOHJQWIO-UHFFFAOYSA-N 0.000 claims description 2
- LARBPNMSKNMEFW-UHFFFAOYSA-N 2-ethoxypropyl propanoate Chemical compound CCOC(C)COC(=O)CC LARBPNMSKNMEFW-UHFFFAOYSA-N 0.000 claims description 2
- VAHNPAMCADTGIO-UHFFFAOYSA-N 2-methoxyethyl propanoate Chemical compound CCC(=O)OCCOC VAHNPAMCADTGIO-UHFFFAOYSA-N 0.000 claims description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 claims description 2
- 229910015015 LiAsF 6 Inorganic materials 0.000 claims description 2
- JDZCKJOXGCMJGS-UHFFFAOYSA-N [Li].[S] Chemical compound [Li].[S] JDZCKJOXGCMJGS-UHFFFAOYSA-N 0.000 claims description 2
- 229940072049 amyl acetate Drugs 0.000 claims description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N anhydrous amyl acetate Natural products CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 claims description 2
- 229940093499 ethyl acetate Drugs 0.000 claims description 2
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 claims description 2
- MNWFXJYAOYHMED-UHFFFAOYSA-M heptanoate Chemical compound CCCCCCC([O-])=O MNWFXJYAOYHMED-UHFFFAOYSA-M 0.000 claims description 2
- HNBDRPTVWVGKBR-UHFFFAOYSA-N n-pentanoic acid methyl ester Natural products CCCCC(=O)OC HNBDRPTVWVGKBR-UHFFFAOYSA-N 0.000 claims description 2
- TWSRVQVEYJNFKQ-UHFFFAOYSA-N pentyl propanoate Chemical compound CCCCCOC(=O)CC TWSRVQVEYJNFKQ-UHFFFAOYSA-N 0.000 claims description 2
- 229940090181 propyl acetate Drugs 0.000 claims description 2
- 230000001012 protector Effects 0.000 claims description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims description 2
- DOHSYWCDRJLXSV-UHFFFAOYSA-N 2-methoxypropyl propanoate Chemical compound CCC(=O)OCC(C)OC DOHSYWCDRJLXSV-UHFFFAOYSA-N 0.000 claims 1
- ZQCQTPBVJCWETB-UHFFFAOYSA-N 4-fluoro-1,3-dioxol-2-one Chemical compound FC1=COC(=O)O1 ZQCQTPBVJCWETB-UHFFFAOYSA-N 0.000 claims 1
- 229910013684 LiClO 4 Inorganic materials 0.000 claims 1
- 229940043232 butyl acetate Drugs 0.000 claims 1
- 239000003792 electrolyte Substances 0.000 abstract description 21
- SBLRHMKNNHXPHG-UHFFFAOYSA-N 4-fluoro-1,3-dioxolan-2-one Chemical class FC1COC(=O)O1 SBLRHMKNNHXPHG-UHFFFAOYSA-N 0.000 abstract description 9
- 230000000052 comparative effect Effects 0.000 description 127
- 229940021013 electrolyte solution Drugs 0.000 description 120
- 238000012360 testing method Methods 0.000 description 21
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 16
- SUXMMHQAHWCENP-UHFFFAOYSA-N 1-(ethylsulfonylmethoxy)ethane Chemical compound CCOCS(=O)(=O)CC SUXMMHQAHWCENP-UHFFFAOYSA-N 0.000 description 15
- 230000000737 periodic effect Effects 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 description 11
- 230000015572 biosynthetic process Effects 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 9
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
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- 229910052759 nickel Inorganic materials 0.000 description 7
- 239000002131 composite material Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 125000004122 cyclic group Chemical group 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- 229910052723 transition metal Inorganic materials 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 5
- 150000002431 hydrogen Chemical class 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- HNNFDXWDCFCVDM-UHFFFAOYSA-N methyl 4-methyl-3-oxopentanoate Chemical compound COC(=O)CC(=O)C(C)C HNNFDXWDCFCVDM-UHFFFAOYSA-N 0.000 description 5
- 239000010936 titanium Substances 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- 150000003624 transition metals Chemical class 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 229910019142 PO4 Inorganic materials 0.000 description 4
- 239000003660 carbonate based solvent Substances 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- WYACBZDAHNBPPB-UHFFFAOYSA-N diethyl oxalate Chemical compound CCOC(=O)C(=O)OCC WYACBZDAHNBPPB-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
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- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000011255 nonaqueous electrolyte Substances 0.000 description 4
- YLYBTZIQSIBWLI-UHFFFAOYSA-N octyl acetate Chemical compound CCCCCCCCOC(C)=O YLYBTZIQSIBWLI-UHFFFAOYSA-N 0.000 description 4
- 235000021317 phosphate Nutrition 0.000 description 4
- 125000004793 2,2,2-trifluoroethoxy group Chemical group FC(CO*)(F)F 0.000 description 3
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- 101150058243 Lipf gene Proteins 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 150000001242 acetic acid derivatives Chemical class 0.000 description 3
- 239000003570 air Substances 0.000 description 3
- 150000001721 carbon Chemical group 0.000 description 3
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- 229910052804 chromium Inorganic materials 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 230000001351 cycling effect Effects 0.000 description 3
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
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- 125000001183 hydrocarbyl group Chemical group 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
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- 239000011701 zinc Substances 0.000 description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 2
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- FHNVMFCQKOUAON-UHFFFAOYSA-N 1-methoxypropan-2-yl 2-methoxyacetate Chemical compound COCC(C)OC(=O)COC FHNVMFCQKOUAON-UHFFFAOYSA-N 0.000 description 2
- ZOWSJJBOQDKOHI-UHFFFAOYSA-N 2,2,2-trifluoroethyl acetate Chemical compound CC(=O)OCC(F)(F)F ZOWSJJBOQDKOHI-UHFFFAOYSA-N 0.000 description 2
- TVZSWASQHNSLNX-UHFFFAOYSA-N 2,2,2-trifluoroethyl propaneperoxoate Chemical compound FC(COOC(CC)=O)(F)F TVZSWASQHNSLNX-UHFFFAOYSA-N 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
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- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 2
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- 125000003118 aryl group Chemical group 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
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- 239000003575 carbonaceous material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- WHRLOJCOIKOQGL-UHFFFAOYSA-N ethyl 2-methoxypropanoate Chemical compound CCOC(=O)C(C)OC WHRLOJCOIKOQGL-UHFFFAOYSA-N 0.000 description 2
- FMDMKDPUFQNVSH-UHFFFAOYSA-N ethyl 3,3,3-trifluoropropanoate Chemical compound CCOC(=O)CC(F)(F)F FMDMKDPUFQNVSH-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 150000002642 lithium compounds Chemical class 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
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- 230000008018 melting Effects 0.000 description 2
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
- H01M6/164—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solvent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0567—Liquid materials characterised by the additives
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US42314710P | 2010-12-15 | 2010-12-15 | |
| US61/423,147 | 2010-12-15 | ||
| PCT/US2011/064681 WO2012082760A1 (en) | 2010-12-15 | 2011-12-13 | Battery electrolyte solution containing certain ester-based solvents, and batteries containing such an electrolyte solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR20130130775A true KR20130130775A (ko) | 2013-12-02 |
Family
ID=45470700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020137018140A Withdrawn KR20130130775A (ko) | 2010-12-15 | 2011-12-13 | 특정 에스터계 용매를 함유하는 배터리 전해질 용액, 및 상기 전해질 용액을 함유하는 배터리 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9472813B2 (cg-RX-API-DMAC7.html) |
| EP (1) | EP2652832A1 (cg-RX-API-DMAC7.html) |
| JP (1) | JP5886870B2 (cg-RX-API-DMAC7.html) |
| KR (1) | KR20130130775A (cg-RX-API-DMAC7.html) |
| CN (1) | CN103262329B (cg-RX-API-DMAC7.html) |
| CA (1) | CA2821958A1 (cg-RX-API-DMAC7.html) |
| WO (1) | WO2012082760A1 (cg-RX-API-DMAC7.html) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017213441A1 (ko) * | 2016-06-09 | 2017-12-14 | 삼성에스디아이주식회사 | 리튬전지 |
| KR20220107202A (ko) * | 2019-11-05 | 2022-08-02 | 더 스쿨 코포레이션 칸사이 유니버시티 | 전해액, 리튬황 이차 전지 및 모듈 |
| WO2025048226A1 (ko) * | 2023-08-31 | 2025-03-06 | 주식회사 리베스트 | 비수계 전해질용 조성물 및 이를 포함하는 전기화학 셀 |
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| EP2720307B1 (en) * | 2011-06-08 | 2020-04-01 | LG Chem, Ltd. | Non-aqueous electrolyte and lithium secondary battery using the same |
| KR101387603B1 (ko) * | 2011-07-14 | 2014-04-21 | 주식회사 엘지화학 | 비수 전해액 및 이를 이용한 리튬 이차전지 |
| US20140227611A1 (en) * | 2011-09-20 | 2014-08-14 | Nec Corporation | Non-Aqueous Secondary Battery |
| JP2014078433A (ja) * | 2012-10-11 | 2014-05-01 | Fujifilm Corp | 非水二次電池用電解液および非水電解液二次電池 |
| JP5923747B2 (ja) | 2013-12-04 | 2016-05-25 | パナソニックIpマネジメント株式会社 | ナトリウム二次電池 |
| US10263283B2 (en) * | 2014-01-30 | 2019-04-16 | Wildcat Discovery Technologies, Inc | Electrolyte formulations |
| JP7272745B2 (ja) * | 2014-07-14 | 2023-05-12 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | リチウムイオン電池の燃焼を抑制するための組成物 |
| US9755235B2 (en) | 2014-07-17 | 2017-09-05 | Ada Technologies, Inc. | Extreme long life, high energy density batteries and method of making and using the same |
| KR102343690B1 (ko) | 2014-12-31 | 2021-12-29 | 삼성전자주식회사 | 리튬 이차전지용 전해액 및 이를 포함하는 리튬 이차전지 |
| EP3353844B1 (en) | 2015-03-27 | 2022-05-11 | Mason K. Harrup | All-inorganic solvents for electrolytes |
| WO2016209460A2 (en) * | 2015-05-21 | 2016-12-29 | Ada Technologies, Inc. | High energy density hybrid pseudocapacitors and method of making and using the same |
| CN106207262A (zh) * | 2015-05-25 | 2016-12-07 | 松下知识产权经营株式会社 | 电解液、及电池 |
| US9466857B1 (en) | 2015-06-22 | 2016-10-11 | Wildcat Discovery Technologies, Inc. | Electrolyte formulations for lithium ion batteries |
| US9887434B2 (en) | 2015-06-22 | 2018-02-06 | Wildcat Discovery Technologies, Inc | Electrolyte formulations for lithium ion batteries |
| US10547083B2 (en) | 2015-06-22 | 2020-01-28 | Wildcat Discovery Technologies, Inc. | Electrolyte formulations for lithium ion batteries |
| WO2017023797A1 (en) | 2015-07-31 | 2017-02-09 | Ada Technologies, Inc. | High energy and power electrochemical device and method of making and using same |
| CN105762410B (zh) * | 2016-04-01 | 2018-11-02 | 宁德新能源科技有限公司 | 一种非水电解液及使用该非水电解液的锂离子电池 |
| US10128537B2 (en) | 2016-08-30 | 2018-11-13 | Wildcat Discovery Technologies, Inc. | Electrolyte formulations for electrochemical cells containing a silicon electrode |
| US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
| US11024846B2 (en) | 2017-03-23 | 2021-06-01 | Ada Technologies, Inc. | High energy/power density, long cycle life, safe lithium-ion battery capable of long-term deep discharge/storage near zero volt and method of making and using the same |
| EP3706227A4 (en) * | 2017-10-31 | 2021-09-08 | Kanto Denka Kogyo Co., Ltd. | WATER-FREE ELECTROLYTE SOLUTION AND BATTERY WITH WATER-FREE ELECTROLYTE |
| US11945776B2 (en) * | 2018-01-30 | 2024-04-02 | Daikin Industries, Ltd. | Electrolyte, electrochemical device, lithium ion secondary battery, and module |
| CN110611084B (zh) * | 2018-06-15 | 2023-03-24 | 武汉大学 | 一种具有长循环寿命和100%库伦效率的锂硫二次电池 |
| US11522177B2 (en) | 2018-12-14 | 2022-12-06 | Cuberg, Inc. | System for an ionic liquid-based electrolyte for high energy battery |
| CN110534807A (zh) * | 2019-09-29 | 2019-12-03 | 河南省法恩莱特新能源科技有限公司 | 一种LiNi0.5Mn1.5O4正极锂离子电池电解液及制备方法 |
| GB201916354D0 (en) * | 2019-10-18 | 2019-12-25 | Mexichem Fluor Sa De Cv | Composition |
| US20210313583A1 (en) * | 2020-04-01 | 2021-10-07 | The Penn State Research Foundation | Stable metal anodes and batteries utilizing the same |
| JP2022172877A (ja) * | 2021-05-07 | 2022-11-17 | 株式会社Gsユアサ | 非水電解質蓄電素子 |
| US20230299362A1 (en) * | 2022-03-18 | 2023-09-21 | Sila Nanotechnologies, Inc. | Electrolyte compositions for lithium-ion battery cells with anodes comprising a blend of silicon-carbon composite particles and graphite particles |
| CN114725512A (zh) * | 2022-03-25 | 2022-07-08 | 深圳新宙邦科技股份有限公司 | 一种非水电解液及二次电池 |
| US12580195B2 (en) | 2022-04-06 | 2026-03-17 | Saft America | Lithium-ion secondary battery |
| WO2026002649A1 (en) * | 2024-06-24 | 2026-01-02 | Shell Internationale Research Maatschappij B.V. | Process for the production of alkylene carbonate |
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| JPH08250153A (ja) * | 1995-03-08 | 1996-09-27 | Yuasa Corp | 薄形電池 |
| JPH09147913A (ja) | 1995-11-22 | 1997-06-06 | Sanyo Electric Co Ltd | 非水電解質電池 |
| JP3809662B2 (ja) * | 1996-01-30 | 2006-08-16 | 宇部興産株式会社 | 非水二次電池 |
| US6492064B1 (en) | 1998-06-04 | 2002-12-10 | California Institute Of Technology | Organic solvents, electrolytes, and lithium ion cells with good low temperature performance |
| FR2787243B1 (fr) * | 1998-12-10 | 2003-10-03 | Cit Alcatel | Generateur electrochimique rechargeable au lithium utilisable a basse temperature |
| GB9929698D0 (en) * | 1999-12-15 | 2000-02-09 | Danionics As | Non-aqueous electrochemical cell |
| DE10111410C1 (de) * | 2001-03-08 | 2002-07-25 | Chemetall Gmbh | Elektrolyt, enthaltend Lithium-bis(oxalato)borat und dessen Verwendung |
| DE10209477A1 (de) * | 2002-03-05 | 2003-09-18 | Chemetall Gmbh | Elektrochemische Zelle für eine Lithiumionenbatterie mit verbesserter Hochtemperaturstabilität |
| US6787268B2 (en) | 2002-09-03 | 2004-09-07 | Quallion Llc | Electrolyte |
| EP1555711B1 (en) | 2002-10-22 | 2011-12-21 | Mitsubishi Chemical Corporation | Nonaqueous electrolytic solution and nonaqueous electrolyte secondary battery containing the same |
| JP4902163B2 (ja) * | 2005-09-26 | 2012-03-21 | 三洋電機株式会社 | 二次電池用非水電解液及び非水電解液二次電池 |
| US20070287071A1 (en) * | 2006-06-11 | 2007-12-13 | Sanyo Electric Co., Ltd. | Non-aqueous electrolyte solution for secondary battery and non-aqueous electrolyte secondary battery using the electrolyte solution |
| JP5235437B2 (ja) * | 2007-02-20 | 2013-07-10 | 三洋電機株式会社 | 二次電池用非水電解液及び非水電解液二次電池 |
| WO2008102493A1 (ja) * | 2007-02-20 | 2008-08-28 | Sanyo Electric Co., Ltd. | 二次電池用非水電解液及び非水電解液二次電池 |
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| WO2009127901A1 (en) | 2008-04-14 | 2009-10-22 | High Power Lithium S.A. | Lithium metal phosphate/carbon nanocomposites as cathode active materials for secondary lithium batteries |
| WO2010002089A1 (en) * | 2008-06-30 | 2010-01-07 | Lg Chem, Ltd. | Cylindrical lithium secondary battery |
| CN102089923B (zh) * | 2008-07-09 | 2014-08-13 | 大金工业株式会社 | 非水系电解液 |
| JP5461883B2 (ja) * | 2008-08-05 | 2014-04-02 | 三洋電機株式会社 | 二次電池用非水電解液及び非水電解液二次電池 |
| US8574773B2 (en) * | 2008-12-23 | 2013-11-05 | Dow Global Technologies Llc | Battery electrolyte solutions containing aromatic phosphorus compounds |
-
2011
- 2011-12-13 JP JP2013544702A patent/JP5886870B2/ja not_active Expired - Fee Related
- 2011-12-13 CA CA2821958A patent/CA2821958A1/en not_active Abandoned
- 2011-12-13 US US13/990,387 patent/US9472813B2/en not_active Expired - Fee Related
- 2011-12-13 EP EP11807808.8A patent/EP2652832A1/en not_active Withdrawn
- 2011-12-13 CN CN201180060551.1A patent/CN103262329B/zh not_active Expired - Fee Related
- 2011-12-13 KR KR1020137018140A patent/KR20130130775A/ko not_active Withdrawn
- 2011-12-13 WO PCT/US2011/064681 patent/WO2012082760A1/en not_active Ceased
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017213441A1 (ko) * | 2016-06-09 | 2017-12-14 | 삼성에스디아이주식회사 | 리튬전지 |
| US10873108B2 (en) | 2016-06-09 | 2020-12-22 | Samsung Sdi Co., Ltd. | Lithium battery |
| KR20220107202A (ko) * | 2019-11-05 | 2022-08-02 | 더 스쿨 코포레이션 칸사이 유니버시티 | 전해액, 리튬황 이차 전지 및 모듈 |
| WO2025048226A1 (ko) * | 2023-08-31 | 2025-03-06 | 주식회사 리베스트 | 비수계 전해질용 조성물 및 이를 포함하는 전기화학 셀 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012082760A1 (en) | 2012-06-21 |
| CA2821958A1 (en) | 2012-06-21 |
| CN103262329B (zh) | 2016-02-10 |
| JP2014503964A (ja) | 2014-02-13 |
| CN103262329A (zh) | 2013-08-21 |
| US9472813B2 (en) | 2016-10-18 |
| JP5886870B2 (ja) | 2016-03-16 |
| US20130260229A1 (en) | 2013-10-03 |
| EP2652832A1 (en) | 2013-10-23 |
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